Can stable isotopes be used to monitor landfill leachate impact on surface waters?     

Jessica C. North  Russell D. Frew  Robert Van Hale 《Journal of Geochemical Exploration》2006,88(1-3):49

Bacterially mediated methanogenesis in municipal solid waste landfills has been shown to cause an enrichment of carbon stable isotope ratios of dissolved inorganic carbon and hydrogen stable isotope ratios of water in landfill leachate. In the present study, we investigate the universality of this enrichment in leachate obtained from four diverse landfill sites in New Zealand. At each site, surface water samples upstream and downstream of landfills were analysed to examine the applicability of stable isotope ratios as a tool for monitoring leachate contamination in landfill-associated streams. The design of leachate collection systems, operational history, and landfill location appeared to strongly influence leachate isotopic values and the effectiveness of isotope ratios as an environmental monitoring tool for surface water.  相似文献   

Geochemical evolution of the Capim River kaolin, Northern Brazil     

D.J.L. Sousa  A.F.D.C. Varajo  J. Yvon 《Journal of Geochemical Exploration》2006,88(1-3):329

The Capim River kaolin, located in the eastern Brazilian Amazon, constitutes one of the most important kaolin deposits in the world. Known for its high whiteness, its noble application is in the paper industry. Studies were carried out on samples from the six facies of the deposit (sand kaolin, soft kaolin, lower transition facies, ferruginous crust, upper transition facies and flint kaolin) in order to trace its geochemical evolution. The kaolin developed at the expense of Cretaceous sandy–clayey sediments of the Ipixuna Formation. Intense lateritic processes characterized by ferruginization and deferruginization mechanisms led to the distinction of the different facies.  相似文献   

Holocene record of productivity in the NW Iberian continental shelf     

V. Alves Martins  C. Patinha  E. Ferreira da Silva  J.-M. Jouanneau  O. Weber  F. Rocha   《Journal of Geochemical Exploration》2006,88(1-3):408

A multiproxy approach (textural characteristics, heavy metal concentrations and benthic foraminifera data) was adopted to study the OMEX core KSGX 40, collected at the Galicia Mud Deposit (NW Iberian outer continental shelf) and recording the last ca. 4.8 ka cal BP. Geochemical profiles of Fe, Mn, Zn, Co, Cr, Cu, Ni, Pb, Al and Ca show significant temporal variations. Benthic foraminifera productivity proxy suggests that the recorded muddy events were contemporaneous of a higher C_org flux to the marine benthic environment. The higher flux of organic matter, following a long-term intensification of the upwelling and coinciding with a finer sedimentation, led to depressed levels of oxygen beneath the water-sediments interface and to early diagenetic processes of several redox-sensitive elements.  相似文献   

Platinum and palladium mobility in supergene environment: The residual origin of the Pirogues River mineralization, New Caledonia     

D. Traor  A. Beauvais  T. Aug  F. Chabaux  J.-C. Parisot  M. Cathelineau  C. Peiffert  F. Colin 《Journal of Geochemical Exploration》2006,88(1-3):350

Eluvial concentration of platinum-group minerals (PGM) has developed in the south of New Caledonia, from the weathering of a mafic and ultramafic cumulate. The platinum/palladium (Pt/Pd) ratio evolution from the bottom to the top of the weathering profile indicates a chemical mobilization of Pd in supergene environment. The examination by scanning electron microscopy of the residual PGM collected in the weathering profile and their chemical characterization by electronic microprobe show a preservation of the structure and chemical signature (in the core of the grains) of the fresh PGM. This clearly demonstrates that the PGM studied here are residual and are affected by dissolution process.  相似文献   

Developments in the characterisation of waste materials for environmental impact assessment purposes     

H.A. van der Sloot  J.C.L. Meeussen  A. van Zomeren  D.S. Kosson 《Journal of Geochemical Exploration》2006,88(1-3):72

The characterisation of waste is entering a new phase with the latest developments of characterisation leaching tests and associated modelling capabilities. The currently applied too simple testing approaches lead to poor choices in waste management. With the increased insight in release controlling processes chemical speciation aspects can be addressed even in the most complex and heterogeneous waste materials. From a composition perspective materials may be highly variable, but often materials are far more consistent in their leaching behaviour. This aspect should be exploited more extensively as it holds the key to treat waste materials in such a way that long term solutions are achieved rather than reaching temporary gains.  相似文献   

Cosmogenic nuclide methods for measuring long-term rates of physical erosion and chemical weathering     

James W. Kirchner  Clifford S. Riebe  Kenneth L. Ferrier  Robert C. Finkel 《Journal of Geochemical Exploration》2006,88(1-3):296

Understanding the evolution of geochemical and geomorphic systems requires measurements of long-term rates of physical erosion and chemical weathering. Erosion and weathering rates have traditionally been estimated from measurements of sediment and solute fluxes in streams. However, modern sediment and solute fluxes are often decoupled from long-term rates of erosion and weathering, due to storage or re-mobilization of sediment and solutes upstream from the sampling point. Recently, cosmogenic nuclides such as ¹⁰Be and ²⁶Al have become important new tools for measuring long-term rates of physical erosion and chemical weathering. Cosmogenic nuclides can be used to infer the total denudation flux (the sum of the rates of physical erosion and chemical weathering) in actively eroding terrain. Here we review recent work showing how this total denudation flux can be partitioned into its physical and chemical components, using the enrichment of insoluble tracers (such as Zr) in regolith relative to parent rock. By combining cosmogenic nuclide measurements with the bulk elemental composition of rock and soil, geochemists can measure rates of physical erosion and chemical weathering over 1000- to 10,000-year time scales.  相似文献   

Airborne gamma-ray spectrometry to quantify chemical erosion processes     

F. Carrier  B. Bourdon  . Pili  C. Truffert  R. Wyns 《Journal of Geochemical Exploration》2006,88(1-3):266

Airborne gamma-ray spectrometry data (uranium, potassium and thorium contents) reveal geochemical heterogeneities within the monolithological Hyrôme watershed (ca. 150 km²) in the Armorican massif (western France). Our observations and computations provide important constraints on the spatial distribution and the associated magnitudes of chemical erosion processes at the scale of a small watershed. Two distinct, partially preserved, weathering profiles exhibit a strong correlation between regolith evolution and airborne-derived K/Th ratios, suggesting that the variability is linked to supergene processes. Using both airborne data and laboratory measurements on rock samples, the total net export of potassium has been estimated at 422 ± 50 kg/m² and the chemical weathering rate of potassium at 17 ± 2 kg/km²/a.  相似文献   

Micro-spectroscopic investigations of highly heterogeneous waste repository materials   总被引：1，自引：0，他引：1  

A.M. Scheidegger  D. Grolimund  C.R. Cheeseman  R.D. Rogers 《Journal of Geochemical Exploration》2006,88(1-3):59

Assuring safe disposal and long-term storage of radioactive and toxic wastes corresponds to a primary environmental task of present societies. To improve any technical limitation, a mechanistic understanding of the processes governing the binding of heavy metals and radionuclides is required. In this study, the significance of synchrotron-based X-ray microprobes for elucidating the spatial distribution and the speciation of radionuclides in highly heterogeneous waste repository materials will be outlined. A case study on the uptake process of Co in cementitious engineered barrier materials exposed to microbial degradation will be presented.  相似文献   

Constraints of stable isotopes on the origin of alunite from advanced argillic alteration systems in Bulgaria     

C. Lerouge  A. Kunov  C. Flhoc  S. Georgieva  A. Hikov  J.L. Lescuyer  R. Petrunov  N. Velinova 《Journal of Geochemical Exploration》2006,90(3):166-182

Voluminous areas of advanced argillic alteration (AAA) constitute major exploration targets for surficial Cu–Au epithermal and potentially underlying porphyry-type deposits. In Bulgaria, more than 30 alunite occurrences are recognised, few of them being associated with a mineralised system. A mineralogical study combined with a stable isotopic (O, H, S) study has been carried out on nine alunite occurrences of advanced argillic zones hosted by volcanic rocks of Late Cretaceous age in the Srednogorie belt and of Oligocene age in the Rhodopes belt. This work was realised in order to constrain the origin of alunite and to define criteria to discriminate alunite from ore deposits and alunite from large barren alteration systems.Mineralogy of the nine occurrences consists of alunite + quartz + minor alumino-phospho-sulphates, associated with more or less kaolinite, dickite, pyrophyllite, diaspore and zunyite, depending on formation temperature. Alunite generally occurs as tabular crystals but is also present as fine-crystalline pseudocubic phases at Boukovo and Sarnitsa, in Eastern Rhodopes. In the advanced argillic alterations associated with economic ore, the presence of zunyite in the deeper parts indicates acid–fluorine–sulphate hydrothermal systems, whereas it is absent in uneconomic and barren advanced argillic alteration. All occurrences are formed at temperatures between 200 and 300 °C.(H, O, S) isotopic signatures of alunite combined with mineralogical features from all the studied occurrences, whatever their type, show characteristics of magmatic-hydrothermal systems. Sulphur data indicate essentially a magmatic origin for sulphur. Oxygen and hydrogen data suggest that hydrothermal fluids result from a mixing between magmatic fluids and an external component, which is identified as seawater-derived fluids or meteoric water in the vicinity of a sea. In most of the alunite occurrences, magmatic fluids are dominant and H₂S/SO₄ ratios are estimated to be higher than 2. Two exceptions exist in the Rhodopes. At Boukovo and Sarnitsa, where the estimated formation temperatures of alunite are the lowest, the external fluids are dominant and H₂S/SO₄ratios are estimated to be lower than or close to 1.At this stage of the work, the mineralogical and isotopic criteria do not enable a clear distinction between economic and uneconomic systems. However, some features are common in the economic ore deposits: the presence of zunyite in the deeper part of the system, the relatively high temperatures suggested by the zunyite + pyrophyllite + alunite + diaspore assemblages, the (O, H, S) signature of alunite, which is characteristic of dominant magmatic–hydrothermal acid–sulphate–fluorine systems.  相似文献   

Neoproterozoic alkaline magmatism at Sivamalai, southern India     

D. Upadhyay  S. Jahn-Awe  C. Pin  J.L. Paquette  I. Braun 《Gondwana Research》2006,10(1-2):156

The Sivamalai alkaline complex lies at the southern margin of the Cauvery Shear System that separates the Archaean and Proterozoic domains of the Southern Granulite Terrain in India. U–Pb TIMS dating of zircon from a pegmatitic syenite sample in the complex yields a concordant age of 590.2 ± 1.3 (2σ) Ma which is interpreted to date the intrusion of the alkaline rocks. A lower concordia intercept at 168 ± 210 Ma defined by two grains with high common lead may indicate post-magmatic disturbances due to recrystallisation which is also evident in the CL images of the zircons. EPMA dating of monazite from a post-kinematic pegmatite which intrudes the crystalline basement hosting the alkaline rocks yields an age of 478 ± 29 (2σ) Ma and provides a lower bracket for the main phase of tectonism in this part of the Southern Granulite Terrain. The Pan-African high-grade metamorphism and ductile deformation has thus most likely affected the alkaline rocks. This is supported by the presence of a metamorphic foliation and extensive recrystallisation textures seen in the rocks. The major and trace element concentrations measured on selected samples reveals the presence of both enriched and depleted rock types. The enriched group includes ferrosyenite and nepheline syenite while the depleted group has only nepheline syenites. The trace element depletion of some nepheline syenites is interpreted to be a result of fractional crystallization involving the removal of accessory phases like zircon, titanite, apatite and allanite.  相似文献