Geostatistical Interplay Between Geophysical and Geochemical Data: Mapping Litho-Structural Assemblages of Mesozoic Igneous Activities in the Parnaíba Basin (NE Brazil)     

David L. de Castro  Diógenes C. Oliveira  Maria Helena B. M. Hollanda 《Surveys in Geophysics》2018,39(4):683-713

Two widespread magmatic events are recorded in the Parnaíba basin (NE Brazil) during the Jurassic/Cretaceous opening of the Central and South Atlantic Oceans. The Early Jurassic (~ 200 Ma) lava flows of the Mosquito Formation occur essentially in the western and southern basin segments, representing one of the largest expressions of the Central Atlantic Magmatic Province in the South American Plate. In contrast, sill complexes and dike swarms of the Early Cretaceous (129–124 Ma) Sardinha Formation occur in the eastern part of the basin and are chrono-correlated to the large Paraná–Etendeka igneous province and to the Rio Ceará–Mirim Dike Swarm. We gathered geophysical, well logging, outcrop analogs and geochemical data to recognize geometrical shapes and areal distribution patterns of igneous-related constructions. Seismic and well data reveal hundreds of km wide multilayered sill complexes and dikes, which are widespread across vast regions of the basin without evident structural control from either the Precambrian basement grain or the basin internal architecture. Anomaly enhancement techniques and self-organizing maps (SOM) procedure were applied on airborne magnetic data, unraveling near-surface magmatic features in four distinct magnetic domains. Using SOM analysis, the basaltic rocks were divided into six groups based on magnetic susceptibility and major elements composition. These results suggest common origin for both magmatic episodes, probably a combination of effects of edge-driven convection and large-scale mantle warming under the westward moving West Gondwana during the Central and South Atlantic opening, which caused a shifted emplacement to the east of the igneous rocks in the Parnaíba basin.  相似文献   

Fluorescence as a Tool for Tracing the Organic Contamination from Pulp Mill Effluents in Surface Waters     

Eduarda B. H. Santos  Olga M. S. Filipe  Regina M. B. O. Duarte  Helena Pinto  Armando C. Duarte 《洁净——土壤、空气、水》2001,28(7):364-371

Three‐dimensional fluorescence spectra of water samples from an eucalyptus bleached kraft pulp mill and from a river, upstream and downstream of the discharge of the effluent, revealed the existence of a peak at δ_exc = 280 nm and δ_em = 340 nm Δδ = 60 nm), characteristic of effluentπs organic matter. Humic substances were isolated from the effluent by sequential adsorption onto resins XAD‐8 and XAD‐4 in series. Their synchronous fluorescence spectra with Δδ = 60 nm do also exhibit an intense signal at δ_exc = 280 nm (≈ 300 nm in the humic acid fraction). The peak is absent in the spectra of humic substances isolated from a non‐polluted site of the river, but it is clearly seen in the spectra of the humic substances from a site downstream of the discharge of the effluent. Synchronous fluorescence spectra (Δδ = 60 nm) of water samples from the river and its lagoon were recorded and revealed to be an easy and fast way of tracing the organic contamination from the effluent.  相似文献