Palaeohydrogeology: A methodology based on fracture mineral studies     

Eva-Lena Tullborg  Henrik Drake  Björn Sandström 《Applied Geochemistry》2008

Two sites on the east coast of Sweden (Forsmark and Laxemar/Simpevarp) are currently being investigated as potential geologic hosts for a deep repository isolating high-level nuclear waste. In this paper, a methodology for fracture mineral studies is suggested with focus on the variation in depth of the fresh/saline water interface and location of the redox front in the bedrock. The most commonly precipitated fracture minerals in crystalline rocks are chlorite, calcite, quartz, K-feldspar, Ca–Al-silicates like epidote, prehnite and laumontite, sulphides and Fe-oxides. Of these, calcite is the mineral best suited for palaeohydrological studies since it precipitates during a wide range of conditions including low-temperature conditions during the Pleistocene and Holocene epochs. Sulphides and Fe-oxides/hydroxides provide information on the position of the redox front. In order to carry out palaeohydrological studies, a number of prerequisites are required such as; high quality drill core material, geological knowledge of the sequence of fracture mineralizations; the post-glacial (Holocene) evolution in the area; high quality groundwater chemistry, including stable isotopes; and a conceptual model of the hydrogeochemistry that is to be tested. The choice of methods used here is based on the fact that both the Forsmark and Laxemar/Simpevarp sites are situated in Palaeoproterozoic crystalline rocks with reactivation of fractures over at least 1.5 Ga, and they have been exposed to glaciations/deglaciations and transgressions/regressions of the Baltic Sea during the Quaternary. This has resulted in a palaeohydrology with a range of groundwaters of quite different chemistry and stable isotopic composition. The suggested scheme for solving the variation in depth of the fresh/saline water interface focuses on fracture calcite. It includes a step-by-step procedure with;

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Initial δ¹⁸O and δ¹³C, analyses and complementary petrographic studies of thin sections and crystal morphology followed by  相似文献   

Provenance of the Lower Triassic Bunter Sandstone Formation: implications for distribution and architecture of aeolian vs. fluvial reservoirs in the North German Basin          下载免费PDF全文

Mette Olivarius  Rikke Weibel  Henrik Friis  Lars O. Boldreel  Nynke Keulen  Tonny B. Thomsen 《Basin Research》2017,29(Z1):113-130

Zircon U–Pb geochronometry, heavy mineral analyses and conventional seismic reflection data were used to interpret the provenance of the Lower Triassic Bunter Sandstone Formation. The succession was sampled in five Danish wells in the northern part of the North German Basin. The results show that sediment supply was mainly derived from the Ringkøbing‐Fyn High situated north of the basin and from the Variscan belt located south of the basin. Seismic reflection data document that the Ringkøbing‐Fyn High was a local barrier for sediment transport during the Early Triassic. Hence, the Fennoscandian Shield did not supply much sediment to the basin as opposed to what was previously believed. Sediment from the Variscan belt was transported by wind activity across the North German Basin when it was dried out during deposition of the aeolian part of the Volpriehausen Member (lower Bunter Sandstone). Fluvial sand was supplied from the Ringkøbing‐Fyn High to the basin during precipitation events which occurred most frequently when the Solling Member was deposited (upper Bunter Sandstone). Late Neoproterozoic to Carboniferous zircon ages predominate in the Volpriehausen Member where the dominant age population with a peak age of 337 Ma corresponds to the culmination of Variscan high‐grade metamorphism, whereas a secondary age population with a peak at 300 Ma matches the timing of volcanism and magmatism at the Carboniferous/Permian boundary in the northern Variscan belt. Parts of the basement in the Ringkøbing‐Fyn High were outcropping during the Early Triassic and zircon ages similar to this Mesoproterozoic basement are present in the Bunter Sandstone. The heavy mineral assemblage of the Solling Member is uniform and has a high garnet content compared to the contemporaneous sediments in the Norwegian‐Danish Basin and in the southern part of the North German Basin. This finding confirms that a local source in the Ringkøbing‐Fyn High supplied most of the fluvial sediment in the northern part of the North German Basin. The northernmost part of the Bunter Sandstone is situated on a platform area that is separated from the basin area by a broad WNW–ESE‐oriented fault zone. The most promising reservoir in the basin area is the aeolian Volpriehausen Member since the sandstone has a wide lateral distribution and a constant thickness. The alluvial to ephemeral fluvial Solling Member may be a good reservoir in the platform area and marginal basin area, but the complex sand‐body architecture makes it difficult to predict the reservoir quality.  相似文献   

Thermal stability of extended clusters in dravite: a combined EMP,SREF and FTIR study     

Ferdinando Bosi  Henrik Skogby  Tonči Balić-Žunić 《Physics and Chemistry of Minerals》2016,43(6):395-407

A dravite from Yemen of near end-member composition was treated in air and hydrogen atmospheres at 600–900 °C to reveal changes in Mg and Al order over the octahedrally coordinated Y and Z sites, and to explore related changes in the characteristic vibrational bands in the principal (OH)-stretching frequency. Relevant information was obtained using electron microprobe analysis (EMPA), structural refinement (SREF) and polarized infrared (IR) single-crystal spectroscopy. Overall, the EMPA, SREF and IR data show that only minor changes occur during thermal treatment up to at least 800 °C, including variations in structural parameters, Mg–Al order–disorder and (OH)-stretching bands, indicating limited hydrogen loss. Untreated and treated dravite samples have very similar long-range and short-range atomic structures, which may be related to the occurrence of stable Al–Mg extended clusters around the O1 (=W) and O3 (=V) sites: ^W(F)–^Y(MgMgMg)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]; ^W(OH)–^Y(MgMgAl)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]; ^W(O^2–)–^Y(AlAlAl)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]. These extended clusters remain stable to temperatures close to the observed start of decomposition (~900 °C).  相似文献   

Recovery of Danish Coastal Ecosystems After Reductions in Nutrient Loading: A Holistic Ecosystem Approach     

Bo Riemann  Jacob Carstensen  Karsten Dahl  Henrik Fossing  Jens W. Hansen  Hans H. Jakobsen  Alf B. Josefson  Dorte Krause-Jensen  Stiig Markager  Peter A. Stæhr  Karen Timmermann  Jørgen Windolf  Jesper H. Andersen 《Estuaries and Coasts》2016,39(1):82-97

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Changes in monsoon-driven upwelling in the South China Sea over glacial Terminations I and II: a multi-proxy record     

Henrik Sadatzki  Michael Sarnthein  Nils Andersen 《International Journal of Earth Sciences》2016,105(4):1273-1285

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Silver eel migration behaviour in the Baltic     

Westerberg  Hakan; Lagenfelt  Ingvar; Svedang  Henrik 《ICES Journal of Marine Science》2007,64(7):1457-1462

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Using AMOEBAs to display multispecies, multifleet fisheries advice     

Collie  Jeremy S.; Gislason  Henrik; Vinther  Morten 《ICES Journal of Marine Science》2003,60(4):709-720

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An estimate of the total biomass of fish in the North Sea   总被引：2，自引：4，他引：2  

Sparholt  Henrik 《ICES Journal of Marine Science》1990,46(2):200-210

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Verification of multispecies interactions in the North Sea by trawl survey data on Norway pout (Trisopterus esmarkii)     

Sparholt  Henrik; Larsen  Lena I.; Nielsen  J.Rasmus 《ICES Journal of Marine Science》2002,59(6):1270-1275

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Nitrogen cycling in deep-sea sediments of the Porcupine Abyssal Plain, NE Atlantic   总被引：2，自引：0，他引：2  

Jenny Brunnegrd  Sibylle Grandel  Henrik Sthl  Anders Tengberg  Per O.J. Hall 《Progress in Oceanography》2004,63(4):159-181

Rates of transformation, recycling and burial of nitrogen and their temporal and spatial variability were investigated in deep-sea sediments of the Porcupine Abyssal Plain (PAP), NE Atlantic during eight cruises from 1996 to 2000. Benthic fluxes of ammonium (NH₄) and nitrate (NO₃) were measured in situ using a benthic lander. Fluxes of dissolved organic nitrogen (DON) and denitrification rates were calculated from pore water profiles of DON and NO₃, respectively. Burial of nitrogen was calculated from down core profiles of nitrogen in the solid phase together with ¹⁴C-based sediment accumulation rates and dry bulk density. Average NH₄ and NO₃-effluxes were 7.4 ± 19 μmol m⁻² d⁻¹ (n = 7) and 52 ± 30 μmol m⁻² d⁻¹ (n = 14), respectively, during the period 1996–2000. During the same period, the DON-flux was 11 ± 5.6 μmol m⁻² d⁻¹ (n = 5) and the denitrification rate was 5.1 ± 3.0 μmol m⁻² d⁻¹ (n = 22). Temporal and spatial variations were only found in the benthic NO₃ fluxes. The average burial rate was 4.6 ± 0.9 μmol m⁻² d⁻¹. On average over the sampling period, the recycling efficiency of the PON input to the sediment was 94% and the burial efficiency hence 6%. The DON flux constituted 14% of the nitrogen recycled, and it was of similar magnitude as the sum of burial and denitrification. By assuming the PAP is representative of all deep-sea areas, rates of denitrification, burial and DON efflux were extrapolated to the total area of the deep-sea floor (>2000 m) and integrated values of denitrification and burial of 8 ± 5 and 7 ± 1 Tg N year⁻¹, respectively, were obtained. This value of total deep-sea sediment denitrification corresponds to 3–12% of the global ocean benthic denitrification. Burial in deep-sea sediments makes up at least 25% of the global ocean nitrogen burial. The integrated DON flux from the deep-sea floor is comparable in magnitude to a reported global riverine input of DON suggesting that deep-sea sediments constitute an important source of DON to the world ocean.  相似文献