Modelling biofilm growth in the presence of carbon dioxide and water flow in the subsurface     

Anozie Ebigbo  Rainer Helmig  Alfred B. Cunningham  Holger Class  Robin Gerlach 《Advances in water resources》2010

The concentration of greenhouse gases – particularly carbon dioxide (CO₂) – in the atmosphere has been on the rise in the past decades. One of the methods which have been proposed to help reduce anthropogenic CO₂ emissions is the capture of CO₂from large, stationary point sources and storage in deep geological formations. The caprock is an impermeable geological layer which prevents the leakage of stored CO₂, and its integrity is of utmost importance for storage security. Due to the high pressure build-up during injection, the caprock in the vicinity of the well is particularly at risk of fracturing. Biofilms could be used as biobarriers which help prevent the leakage of CO₂ through the caprock in injection well vicinity by blocking leakage pathways. The biofilm could also protect well cement from corrosion by CO₂-rich brine.  相似文献   

Significance of boulder shape,shoreline configuration and pre-transport setting for the transport of boulders by tsunamis     

Jan Oetjen  Max Engel  Shiva P. Pudasaini  Holger Schuettrumpf 《地球表面变化过程与地形》2020,45(9):2118-2133

Research on tsunami-induced coarse-clast transport is a field of rising interest since such deposits have been identified as useful proxies for extreme-wave events (tsunamis, storm waves) that provide crucial information for coastal hazard assessment. Physical experiments are, beside in-situ observations, the foundation of our understanding of how boulders are transported by tsunamis and provide clues to the development of empirical equations and numerical models describing the processes and fundamental mechanics. Nevertheless, investigating tsunami-induced boulder transport is a comparatively young discipline and only a few experimental studies focusing on this topic have been published so far. To improve the knowledge on nearshore tsunami hydrodynamics, physical experiments utilizing real-world boulder shapes have been carried out simulating three different shore types in a wave flume. Crucial insights were gained into boulder transport hydrodynamics and data resulting from the experiments were analysed in an empirical, statistical, quantitative and qualitative manner. The regular cuboid boulder – one of the specific shapes used in the experiments – showed the longest transport distances compared to a complex, natural boulder and a flat cuboid boulder, but also significant fluctuations regarding the total transport distance. The experiments indicate a strong influence of the shore shape on boulder transport behaviour. Experimental setups of increased mean transport distances also led to a higher spreading of results. This spreading was further amplified between the idealized-shaped cuboid and the complex-shaped boulder, which is associated with a lower drag coefficient. Due to the highly sensitive boulder reaction to divergent experimental setups, the need to recognize boundary conditions overcoming commonly considered parameters (e.g. roughness or Flatness Index) in field studies and numerical models is underlined. Beside the strong influence of initial boulder submergence and alignment, both the boulder shape and shore type influence the boulder transport pattern, increasing the total transport distance by more than 350% in some cases. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   

The crustal structure of Central East Greenland:results from combined land–sea seismic refraction experiments     

Holger A.F. Mandler  & Wilfried Jokat 《Geophysical Journal International》1998,135(1):63-76

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Late Quaternary vegetation,climate and fire dynamics inferred from the El Tiro record in the southeastern Ecuadorian Andes     

Holger Niemann  Hermann Behling 《第四纪科学杂志》2008,23(3):203-212

In order to study the stability and dynamics of mountain rainforest and paramo ecosystems, including the biodiversity of these ecosystems, the Holocene and late Pleistocene climate and fire variability, and human impact in the southeastern Ecuadorian Andes, we present a high‐resolution pollen record from El Tiro Pass (2810 m elevation), Podocarpus National Park. Palaeoenvironmental changes, investigated by pollen, spores and charcoal analysis, inferred from a 127 cm long core spanning the last ca. 21 000 cal. yr BP, indicate that grass‐paramo was the main vegetation type at the El Tiro Pass during the late Pleistocene period. The grass‐paramo was rich in Poaceae, Plantago rigida and Plantago australis, reflecting cold and moist climatic conditions. During the early Holocene, from 11 200 to 8900 cal. yr BP, subparamo and upper mountain rainforest vegetation expanded slightly, indicating a slow warming of climatic conditions during this period. From 8900 to 3300 cal. yr BP an upper mountain rainforest developed at the study site, indicated by an increase in Hedyosmun, Podocarpaceae, Myrsine and Ilex. This suggests a warmer climate than the present day at this elevation. The modern subparamo vegetation became established since 3300 cal. yr BP at El Tiro Pass. Fires, probably anthropogenic origin, were very rare during the late Pleistocene but became frequent after 8000 cal. yr BP. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Diffusion,degradation or on-site stabilisation – Identifying causes of kinetic processes involved in metal–humate complexation     

Holger Lippold  Sascha Eidner  Michael U. Kumke  Johanna Lippmann-Pipke 《Applied Geochemistry》2012

The applicability of equilibrium models for humic-bound transport of toxic or radioactive metals is affected by kinetic processes leading to an increasing inertness of metal–humic complexes. The chemical background is not yet understood. It is widely believed that bound metals undergo an in-diffusion process within the humic colloids, changing from weaker to stronger binding sites. This work is focussed on the competition effect of Al(III) on complexation of Tb(III) or Eu(III) as analogues of trivalent actinides. By using ion exchange and spectroscopic methods, their bound fractions were determined for solutions of Al and humic acid that had been pre-equilibrated for different periods of time. Whilst the amount of bound Al remained unchanged, its blocking effect was found to increase over a time frame of 2 days, which corresponds to the kinetics of the increase in complex inertness reported in most pertinent studies. Thus, the derived “diffusion theory” turned out to be inapplicable, since it cannot explain an increase in competition for the “initial” sites. A delayed degradation of polynuclear species (as found for Fe) does not occur. Consequently, the temporal changes must be based on structural rearrangements in the vicinity of bound Al, complicating the exchange or access. Time-dependent studies by laser fluorescence spectroscopy (steady-state and time-resolved) yielded evidence of substantial alterations, which were, however, immediately induced and did not show any significant trend on the time scale of interest, suggesting that the stabilisation process is based on comparatively moderate changes.  相似文献   

Nanoparticles and their influence on radionuclide mobility in deep geological formations     

Thorsten Schäfer  Florian Huber  Holger Seher  Tiziana Missana  Ursula Alonso  Michael Kumke  Sascha Eidner  Francis Claret  Frieder Enzmann 《Applied Geochemistry》2012

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Modification of fluid inclusions in quartz by deviatoric stress. II: experimentally induced changes in inclusion volume and composition     

Larryn W. Diamond  Alexandre Tarantola  Holger Stünitz 《Contributions to Mineralogy and Petrology》2010,160(6):845-864

Fluid inclusions in quartz are known to modify their densities during shear deformation. Modifications of chemical composition are also suspected. However, such changes have not been experimentally demonstrated, their mechanisms remain unexplained, and no criteria are available to assess whether deformed inclusions preserve information on paleofluid properties. To address these issues, quartz crystals containing natural CO₂–H₂O–NaCl fluid inclusions have been experimentally subjected to compressive deviatoric stresses of 90–250 MPa at 700°C and ~600 MPa confining pressure. The resulting microcracking of the inclusions leads to expansion by up to 20%, producing low fluid densities that bear no relation to physical conditions outside the sample. Nevertheless, the chemical composition of the precursor inclusions is preserved. With time the microcracks heal and form swarms of tiny satellite inclusions with a wide range of densities, the highest reflecting the value of the maximum principle stress, σ ₁. These new inclusions lose H₂O via diffusion, thereby passively increasing their salt and gas contents, and triggering plastic deformation of the surrounding quartz via H₂O-weakening. Using microstructural criteria to identify the characteristic types of modified inclusions, both the pre-deformation fluid composition and syn-deformation maximum stress on the host mineral can be derived from microthermometric analysis and thermodynamic modelling.  相似文献   

A new method to create initially mass segregated star clusters in virial equilibrium     

L. &#;ubr  P. Kroupa  H. Baumgardt 《Monthly notices of the Royal Astronomical Society》2008,385(3):1673-1680

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Ejection of hypervelocity stars from the Galactic Centre by intermediate-mass black holes     

H. Baumgardt  A. Gualandris  S. Portegies Zwart 《Monthly notices of the Royal Astronomical Society》2006,372(1):174-182

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Bayesian updating via bootstrap filtering combined with data-driven polynomial chaos expansions: methodology and application to history matching for carbon dioxide storage in geological formations     

Sergey Oladyshkin  Holger Class  Wolfgang Nowak 《Computational Geosciences》2013,17(4):671-687

Model calibration and history matching are important techniques to adapt simulation tools to real-world systems. When prediction uncertainty needs to be quantified, one has to use the respective statistical counterparts, e.g., Bayesian updating of model parameters and data assimilation. For complex and large-scale systems, however, even single forward deterministic simulations may require parallel high-performance computing. This often makes accurate brute-force and nonlinear statistical approaches infeasible. We propose an advanced framework for parameter inference or history matching based on the arbitrary polynomial chaos expansion (aPC) and strict Bayesian principles. Our framework consists of two main steps. In step 1, the original model is projected onto a mathematically optimal response surface via the aPC technique. The resulting response surface can be viewed as a reduced (surrogate) model. It captures the model’s dependence on all parameters relevant for history matching at high-order accuracy. Step 2 consists of matching the reduced model from step 1 to observation data via bootstrap filtering. Bootstrap filtering is a fully nonlinear and Bayesian statistical approach to the inverse problem in history matching. It allows to quantify post-calibration parameter and prediction uncertainty and is more accurate than ensemble Kalman filtering or linearized methods. Through this combination, we obtain a statistical method for history matching that is accurate, yet has a computational speed that is more than sufficient to be developed towards real-time application. We motivate and demonstrate our method on the problem of CO₂ storage in geological formations, using a low-parametric homogeneous 3D benchmark problem. In a synthetic case study, we update the parameters of a CO₂/brine multiphase model on monitored pressure data during CO₂ injection.  相似文献