Isothermal decompression history in the “Western Granulite” terrain, central Tanzania: Evidence from reaction textures and trapped fluids in metapelites     

Holger Sommer  Christoph Hauzenberger  Alfred Krner  Sospeter Muhongo 《Journal of African Earth Sciences》2008,51(3):123-144

The Mozambique Belt (MB) of the East Africa Orogen contains large areas of granulite-facies migmatitic gneisses with Archaean and Palaeoproterozoic protolith ages and that were recycled during the Neoproterozoic Pan-African orogeny. The study area is situated along the Great Ruaha River and within the Mikumi National Park in central Tanzania where migmatitic gneisses and mafic to intermediate granulites are interlayered with Neoproterozoic granulite-facies migmatitic metapelites. Mineral textures suggest isothermal decompression, with the peak mineral assemblage comprising Grt–Bt–Ky–Kfs–Pl–Qtz ± Phn ± Ti-Oxide ± melt and amphibolite-facies retrograde assemblage Grt–Bt–Sil–Ms–Kfs–Pl–Qtz ± Fe–Ti-Oxide. The near isothermal retrograde overprint is seen in well-developed formation of pseudomorphs after garnet. The HP granulite-facies assemblages record P–T conditions of 13–14 kbar at 760–800 °C. Retrogression and the release of fluids from crystallizing melts occurred at 7 kbar and 650–700 °C. A fluid inclusion study shows three types of fluid inclusion consisting of nearly pure CO₂, as well as H₂O–NaCl and H₂O–CO₂ mixtures. We suggest that a immiscible CO₂-bearing brine represents the fluid composition during high-grade peak metamorphism, and that the fluid inclusions containing H₂O–NaCl or nearly pure CO₂ represent trapped fluids from in situ crystallised melt. The results suggest strong isothermal decompression, which is probably related to a fast exhumation after crustal thickening in the central part of the Mozambique Belt in Tanzania.  相似文献   

Comparison of spatial interpolation methods for the estimation of precipitation distribution in Distrito Federal,Brazil     

Pablo de Amorim Borges  Johannes Franke  Yumiko Marina Tanaka da Anunciação  Holger Weiss  Christian Bernhofer 《Theoretical and Applied Climatology》2016,123(1-2):335-348

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Late Quaternary vegetation,climate and fire dynamics inferred from the El Tiro record in the southeastern Ecuadorian Andes     

Holger Niemann  Hermann Behling 《第四纪科学杂志》2008,23(3):203-212

In order to study the stability and dynamics of mountain rainforest and paramo ecosystems, including the biodiversity of these ecosystems, the Holocene and late Pleistocene climate and fire variability, and human impact in the southeastern Ecuadorian Andes, we present a high‐resolution pollen record from El Tiro Pass (2810 m elevation), Podocarpus National Park. Palaeoenvironmental changes, investigated by pollen, spores and charcoal analysis, inferred from a 127 cm long core spanning the last ca. 21 000 cal. yr BP, indicate that grass‐paramo was the main vegetation type at the El Tiro Pass during the late Pleistocene period. The grass‐paramo was rich in Poaceae, Plantago rigida and Plantago australis, reflecting cold and moist climatic conditions. During the early Holocene, from 11 200 to 8900 cal. yr BP, subparamo and upper mountain rainforest vegetation expanded slightly, indicating a slow warming of climatic conditions during this period. From 8900 to 3300 cal. yr BP an upper mountain rainforest developed at the study site, indicated by an increase in Hedyosmun, Podocarpaceae, Myrsine and Ilex. This suggests a warmer climate than the present day at this elevation. The modern subparamo vegetation became established since 3300 cal. yr BP at El Tiro Pass. Fires, probably anthropogenic origin, were very rare during the late Pleistocene but became frequent after 8000 cal. yr BP. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Diffusion,degradation or on-site stabilisation – Identifying causes of kinetic processes involved in metal–humate complexation     

Holger Lippold  Sascha Eidner  Michael U. Kumke  Johanna Lippmann-Pipke 《Applied Geochemistry》2012

The applicability of equilibrium models for humic-bound transport of toxic or radioactive metals is affected by kinetic processes leading to an increasing inertness of metal–humic complexes. The chemical background is not yet understood. It is widely believed that bound metals undergo an in-diffusion process within the humic colloids, changing from weaker to stronger binding sites. This work is focussed on the competition effect of Al(III) on complexation of Tb(III) or Eu(III) as analogues of trivalent actinides. By using ion exchange and spectroscopic methods, their bound fractions were determined for solutions of Al and humic acid that had been pre-equilibrated for different periods of time. Whilst the amount of bound Al remained unchanged, its blocking effect was found to increase over a time frame of 2 days, which corresponds to the kinetics of the increase in complex inertness reported in most pertinent studies. Thus, the derived “diffusion theory” turned out to be inapplicable, since it cannot explain an increase in competition for the “initial” sites. A delayed degradation of polynuclear species (as found for Fe) does not occur. Consequently, the temporal changes must be based on structural rearrangements in the vicinity of bound Al, complicating the exchange or access. Time-dependent studies by laser fluorescence spectroscopy (steady-state and time-resolved) yielded evidence of substantial alterations, which were, however, immediately induced and did not show any significant trend on the time scale of interest, suggesting that the stabilisation process is based on comparatively moderate changes.  相似文献   

Nanoparticles and their influence on radionuclide mobility in deep geological formations     

Thorsten Schäfer  Florian Huber  Holger Seher  Tiziana Missana  Ursula Alonso  Michael Kumke  Sascha Eidner  Francis Claret  Frieder Enzmann 《Applied Geochemistry》2012

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Modification of fluid inclusions in quartz by deviatoric stress. II: experimentally induced changes in inclusion volume and composition     

Larryn W. Diamond  Alexandre Tarantola  Holger Stünitz 《Contributions to Mineralogy and Petrology》2010,160(6):845-864

Fluid inclusions in quartz are known to modify their densities during shear deformation. Modifications of chemical composition are also suspected. However, such changes have not been experimentally demonstrated, their mechanisms remain unexplained, and no criteria are available to assess whether deformed inclusions preserve information on paleofluid properties. To address these issues, quartz crystals containing natural CO₂–H₂O–NaCl fluid inclusions have been experimentally subjected to compressive deviatoric stresses of 90–250 MPa at 700°C and ~600 MPa confining pressure. The resulting microcracking of the inclusions leads to expansion by up to 20%, producing low fluid densities that bear no relation to physical conditions outside the sample. Nevertheless, the chemical composition of the precursor inclusions is preserved. With time the microcracks heal and form swarms of tiny satellite inclusions with a wide range of densities, the highest reflecting the value of the maximum principle stress, σ ₁. These new inclusions lose H₂O via diffusion, thereby passively increasing their salt and gas contents, and triggering plastic deformation of the surrounding quartz via H₂O-weakening. Using microstructural criteria to identify the characteristic types of modified inclusions, both the pre-deformation fluid composition and syn-deformation maximum stress on the host mineral can be derived from microthermometric analysis and thermodynamic modelling.  相似文献   

Mid-Wisconsinan environments on the eastern Great Plains     

R.G. Baker  E.A. Bettis  R.D. Mandel  J.A. Dorale  G.G. Fredlund 《Quaternary Science Reviews》2009,28(9-10):873-889

Few sites on the eastern Great Plains contain paleobotanical records for the mid-Wisconsin. We report on four sites, two stream cutbanks and two quarry exposures, ranging in age from >50 to ～23.4 ka. The oldest site at >50 ka contains a suite of macrofossils from prairie and disturbed ground habitats, with no representation of trees, indicating an open prairie. By ～38 ka the assemblages include aquatic, wetland, mudflat, and prairie elements with rare specimens of Populus, Betula cf. papyrifera, Salix and at the most northerly site, Picea. This assemblage suggests a prairie/parkland with interspersed marshes, cooler temperatures and increased moisture. Populus and Salix continued to be represented from ～36 to ～29 ka, but the only other taxon was Carex. A hiatus may be present at some time during this interval. After ～29 ka, Picea became dominant on the uplands and it was joined by sedges in local wetlands. At sites near riverine loess sources, loess accumulation began to fill in the wetlands and organic deposition ceased some time after 29 ka.  相似文献   

The Solar Irradiance Spectrum at Solar Activity Minimum Between Solar Cycles 23 and 24     

G. Thuillier  D. Bolsée  G. Schmidtke  T. Foujols  B. Nikutowski  A. I. Shapiro  R. Brunner  M. Weber  C. Erhardt  M. Hersé  D. Gillotay  W. Peetermans  W. Decuyper  N. Pereira  M. Haberreiter  H. Mandel  W. Schmutz 《Solar physics》2014,289(6):1931-1958

On 7 February 2008, the SOLAR payload was placed onboard the International Space Station. It is composed of three instruments, two spectrometers and a radiometer. The two spectrometers allow us to cover the 16?–?2900 nm spectral range. In this article, we first briefly present the instrumentation, its calibration and its performance in orbit. Second, the solar spectrum measured during the transition between Solar Cycles 23 to 24 at the time of the minimum is shown and compared with other data sets. Its accuracy is estimated as a function of wavelength and the solar atmosphere brightness-temperature is calculated and compared with those derived from two theoretical models.  相似文献   

The Solar Spectral Irradiance from 200 to 2400 nm as Measured by the SOLSPEC Spectrometer from the Atlas and Eureca Missions     

Thuillier  G.  Hersé  M.  Labs  D.  Foujols  T.  Peetermans  W.  Gillotay  D.  Simon  P.C.  Mandel  H. 《Solar physics》2003,214(1):1-22

The SOLar SPECtrum (SOLSPEC) and the SOlar SPectrum (SOSP) spectrometers are two twin instruments built to carry out solar spectral irradiance measurements. They are made of three spectrometers dedicated to observations in the ultraviolet, visible and infrared domains. SOLSPEC flew with the ATmospheric Laboratory for Applications and Science (ATLAS) while SOSP flew on the EUropean Retrieval CArrier (EURECA) missions. ATLAS 1 and 2 data being already published, this paper is mostly dedicated to the ATLAS 3 and EURECA data in the IR domain. Comparisons between the ATLAS data sets and the Upper Atmosphere Research Satellite (UARS) results are made. EURECA IR data are shown and compared with previous results. Our best UV, visible and IR spectra are finally merged into a single absolute solar irradiance spectrum covering the 200 to 2400 nm domain.  相似文献   

Bayesian updating via bootstrap filtering combined with data-driven polynomial chaos expansions: methodology and application to history matching for carbon dioxide storage in geological formations     

Sergey Oladyshkin  Holger Class  Wolfgang Nowak 《Computational Geosciences》2013,17(4):671-687

Model calibration and history matching are important techniques to adapt simulation tools to real-world systems. When prediction uncertainty needs to be quantified, one has to use the respective statistical counterparts, e.g., Bayesian updating of model parameters and data assimilation. For complex and large-scale systems, however, even single forward deterministic simulations may require parallel high-performance computing. This often makes accurate brute-force and nonlinear statistical approaches infeasible. We propose an advanced framework for parameter inference or history matching based on the arbitrary polynomial chaos expansion (aPC) and strict Bayesian principles. Our framework consists of two main steps. In step 1, the original model is projected onto a mathematically optimal response surface via the aPC technique. The resulting response surface can be viewed as a reduced (surrogate) model. It captures the model’s dependence on all parameters relevant for history matching at high-order accuracy. Step 2 consists of matching the reduced model from step 1 to observation data via bootstrap filtering. Bootstrap filtering is a fully nonlinear and Bayesian statistical approach to the inverse problem in history matching. It allows to quantify post-calibration parameter and prediction uncertainty and is more accurate than ensemble Kalman filtering or linearized methods. Through this combination, we obtain a statistical method for history matching that is accurate, yet has a computational speed that is more than sufficient to be developed towards real-time application. We motivate and demonstrate our method on the problem of CO₂ storage in geological formations, using a low-parametric homogeneous 3D benchmark problem. In a synthetic case study, we update the parameters of a CO₂/brine multiphase model on monitored pressure data during CO₂ injection.  相似文献