Quaternary minettes and associated volcanic rocks of Mascota,western Mexico: a consequence of plate extension above a subduction modified mantle wedge   总被引：12，自引：0，他引：12  

I. S. E. Carmichael  R. A. Lange  James F. Luhr 《Contributions to Mineralogy and Petrology》1996,124(3-4):302-333

 Pleistocene-Holocene volcanism in the Jalisco block of western Mexico is confined to two conspicuous grabens, where potassic eruptives range from absarokites (48–52% SiO₂) and minettes (49–54% SiO₂) through basaltic andesites (53–57% SiO₂), the most voluminous type, to andesites and their lamprophyric equivalent spessartite (58–62% SiO₂); there are no contemporary rhyolitic rocks. This suite has high concentrations of Mg, Cr (<550 ppm) and Ni (<450 ppm) accompanied by large concentrations of K, P, Ba (<4000 ppm) and Sr (<5000 ppm) and elements such as LREE and Zr (<600 ppm). No combination of crystal fractionation and/or crustal contamination can reproduce the compositional range of these magmas, which nevertheless are believed to be genetically related because of their proximity in time and space. Hydrous minerals in the lamprophyres and the typical absence of plagioclase phenocrysts in both basaltic andesites and andesites reflect the relatively high concentrations of water in the magmas, which suppressed the crystallisation of feldspar. Experimental verification of the minimal amounts of water required to reproduce the phenocryst assemblages in selected rocks range from 3.5 to 6%. During ascent in a volcanic conduit, andesitic magma may lose water and consequently precipitate plagioclase, or it may ascend more rapidly, retaining more of its initial water, which stabilises phenocrysts of hornblende at the expense of plagioclase. Our estimates of water concentrations, which are consistent with the various low pressure phenocryst assemblages, will be minimal for the magmas in their source regions, and the process of magmatic dewatering on ascent may be typical in well established volcanic conduits. In accord with the compositions of phenocrystic olivine in the basaltic andesites and the minettes, the values of FeO and Fe₂O₃ of the bulk lavas and scoriae are demonstrably pristine. As a consequence, there are two characteristic features of the Mascota suite: the high range of relative oxygen fugacities (ΔNNO=1–5) and the high Mg# (MgO/MgO+FeO) that ranges from 0.70 to 0.91 (with only one andesite as low as 0.66). From the evidence of phlogopite phenocrysts, a partial melt involving phlogopite would have a higher Mg# than one from olivine (Fo₉₀) and pyroxene alone. As the Mascota series shows a correlation between K₂O and Mg#, we conclude that it was generated by partial fusion of the mantle wedge, with a variable contribution of phlogopite and apatite from veins throughout the lherzolitic assemblage. In conformity with an origin by varying increments of partial fusion of a phlogopite-bearing mantle, all incompatible elements vary linearly with Ti (or K) as if phlogopite (+apatite) in the source dominated their contribution to the partial melts. Fluids from dehydration of the subducting slab presumably deposit hydrous and other minerals in veins in the mantle wedge and also increase its redox state. As the Mascota volcanism occurs in grabens closer to the trench than the main andesite arc, it is concluded that the eruption of these small volumes of hydrous magmas require the tectonically favored ascent paths offered by the extensional grabens to reach the surface from their mantle sources. Received: 24 January 1995 / Accepted: 21 February 1996  相似文献   

Contrasting stable isotope behavior between calcite and dolomite marbles,Lone Mountain,Nevada     

I. J. Richards  Theodore C. Labotka  Robert T. Gregory 《Contributions to Mineralogy and Petrology》1996,123(2):202-221

 Late Proterozoic to Cambrian carbonate rocks from Lone Mountain, west central Nevada, record multiple post-depositional events including: (1) diagenesis, (2) Mesozoic regional metamorphism, (3) Late Cretaceous contact metamorphism, related to the emplacement of the Lone Mountain granitic pluton and (4) Tertiary hydrothermal alteration associated with extension, uplift and intrusion of silicic porphyry and lamprophyre dikes. Essentially pure calcite and dolomite marbles have stable isotopic compositions that can be divided into two groups, one with positive δ¹³C values from+3.1 to +1.4 ‰ (PDB) and high δ¹⁸O values from +21.5 to +15.8 ‰ (SMOW), and the other with negative δ¹³C values from –3.3 to –3.6‰ and low δ¹⁸O values from +16.9 to +11.1‰. Marbles also contain minor amounts of quartz, muscovite and phlogopite. Brown and blue luminescent, clear, smooth textured quartz grains from orange luminescent calcite marbles have high δ¹⁸O values from +23.9 to +18.1‰, while brown luminescent, opaque, rough textured quartz grains from red luminescent dolomite marbles typically have low δ¹⁸O values from +2.0 to +9.3‰. The δ¹⁸O values of muscovite and phlogopite from marbles are typical of micas in metamorphic rocks, with values between +10.4 and +14.4‰, whereas mica δD values are very depleted, varying from −102 to −156‰. No significant lowering of the δ¹⁸O values of Lone Mountain carbonates is inferred to have occurred during metamorphism as a result of devolatilization reactions because of the essentially pure nature of the marbles. Bright luminescence along the edges of fractures, quartz cements and quartz overgrowths in dolomite marbles, low δD values of micas, negative δ¹³C values and low δ¹⁸O values of calcite and dolomite, and depleted δ¹⁸O values of quartz from dolomite marbles all indicate that meteoric fluids interacted with Lone Mountain marbles during the Tertiary. Partial oxygen isotopic exchange between calcite and low ¹⁸O meteoric fluids lowered the δ¹⁸O values of calcite, resulting in uniform quartz-calcite fractionations that define an apparent pseudoisotherm. These quartz-calcite fractionations significantly underestimate both the temperature of metamorphism and the temperature of post-metamorphic alteration. Partial oxygen isotopic exchange between quartz and meteoric fluids also resulted in ¹⁸O depletion of quartz from dolomite marbles. This partial exchange was facilitated by an increase in the surface area of the quartz as a result of its dissolution by meteoric fluids. The negative δ¹³C values in carbonates result from the oxidation of organic material by meteoric fluids following metamorphism. Stable isotopic data from Lone Mountain marbles are consistent with the extensive circulation of meteoric hydrothermal fluids throughout western Nevada in Tertiary time. Received: 1 February 1994/Accepted: 12 September 1995  相似文献   

Current controlled sediment deposition from the shelf to the deep ocean: the cenozoic evolution of circulation through the SW pacific gateway     

R. M. Carter  L. Carter  I. N. McCave 《International Journal of Earth Sciences》1996,85(3):438-451

 The circulation of cold, deep water is one of the controlling factors of the Earth's climate. Forty percent of this water enters the world ocean through the Southwest Pacific as a deep western boundary current (DWBC) flowing northwards at bathyal to abyssal depths, east of the New Zealand microcontinent. South of latitude 50°S, the DWBC is intimately linked with the Antarctic circumpolar current (ACC), which is the prominent force for the shallow-water circulation. The Pacific DWBC is presently the largest single contributor of deep ocean water, and deciphering its evolution is of fundamental importance to understanding ocean and climate history, and global ocean hydrography. The evolution of the DWBC system, and of related circum-Antarctic currents, has taken place since 30–25 Ma when plate movements created the first oceanic gaps south of Australia and South America. The stratigraphic record preserved in sediment drifts of the Southwest Pacific, in eastern New Zealand, is the best available for deciphering the Neogene history of Southern Ocean water masses, and of the circulation of the ACC, DWBC and their precursor systems. Major current activity commenced on the New Zealand margin in the late Eocene or early Oligocene (Hoiho Drift; early ACC) and was widespread by the mid-late Oligocene (Marshall Paraconformity and Weka Pass Limestone drift; ACC). During the Neogene the eastern South Island continental shelf built seawards by accretion at its outer edge of large Miocene current drifts up to tens of kilometres long and hundreds of metres thick (Canterbury drifts). Also commencing in the mid-Cenozoic, but in depths >2000 m, the DWBC emplaced large deep-water sediment drifts. Rates of drift deposition accelerated considerably in the late Neogene, when climatic change (and particularly glacial sea-level falls) caused the delivery of large volumes of turbiditic sediment into the path of the DWBC via the Bounty and Hikurangi channels. Received: 9 August 1995 / Accepted: 15 January 1996  相似文献   

Croatia — a coastal and maritime country     

Nikola Stražičić 《GeoJournal》1996,38(4):445-453

Croatia, through its geographic position, is a Mediterranean/Adriatic and Central European/Danube state. As an Adriatic coastal state, it has a long maritime tradition, which is apparent in its well-developed shipping (2.4 million GT), the high-quality ship-building industry (among the top six in the world) and through its numerous sea ports, of which many were established in ancient times. The leading national port is Rijeka, which is at the same time an important transit port for Austria, Hungary, Slovakia and the Czech Republic.The exceptionally indented Croatian Adriatic coast with its attractive archipelagos and favorable climatic and oceanographic conditions in the coastal sea offers very advantageous conditions for comprehensive tourist utilization. This is particularly true of nautical tourism, which is complimented by a larger number of constructed and well-equipped yachting ports/marinas on the coast and islands.  相似文献   

Geotechnical study of landslides resulting from a highway construction in Jordan   总被引：1，自引：0，他引：1  

Abdallah I. Husein Malkawi  Salah A. Taqieddin 《Natural Hazards》1996,13(1):1-15

Landslides in Jordan have caused numerous problems during the past 40 years. The most critical slides occurred during the period of 1991/1992 after exceptional heavy rain and snowfall. Many disastrous landslides occurred along the newly reconstructed international highway that links Amman, Jerash and Irbid. Causes for these slides are attributed mainly to the lack of a comprehensive overview and geotechnical understanding of the problem.Many investigators have been interested in this problem of finding an adequate solution to such landslides in Jordan either by using theoretical analysis or by using computer software to solve the slope instability problems. A detailed study was conducted at the Jordan University of Science and Technology to investigate the potential causes and measures for this problem. Seven landslides along the mountainous section of this international highway were reviewed. One of these landslides was thoroughly investigated using a three-dimensional computer program called JUST-SLOPE introduced at the Jordan University of Science and Technology campus. Results of this study indicate that landslides at this site could have been predicted had this technique been applied prior to the occurrence of this slide.  相似文献   

Mineral inclusions in diamonds from the Sputnik kimberlite pipe, Yakutia   总被引：9，自引：0，他引：9  

N. V. Sobolev  F. V. Kaminsky  W. L. Griffin  E. S. Yefimova  T. T. Win  C. G. Ryan  A. I. Botkunov 《Lithos》1997,39(3-4):135-157

The Sputnik kimberlite pipe is a small “satellite” of the larger Mir pipe in central Yakutia (Sakha), Russia. Study of 38 large diamonds (0.7-4.9 carats) showed that nine contain inclusions of the eclogitic paragenesis, while the remainder contain inclusions of the peridotitic paragenesis, or of uncertain paragenesis. The peridotitic inclusion suite comprises olivine, enstatite, Cr-diopside, chromite, Cr-pyrope garnet (both lherzolitic and harzburgitic), ilmenite, Ni-rich sulfide and a Ti-Cr-Fe-Mg-Sr-K phase of the lindsleyite-mathiasite (LIMA) series. The eclogitic inclusion suite comprises omphacite, garnet, Ni-poor sulfide, phlogopite and rutile. Peridotitic ilmenite inclusions have high Mg, Cr and Ni contents and high Nb/Zr ratios; they may be related to metasomatic ilmenites known from peridotite xenoliths in kimberlite. Eclogitic phlogopite is intergrown with omphacite, coexists with garnet, and has an unusually high TiO₂ content. Comparison with inclusions in diamonds from Mir shows general similarities, but differences in details of trace-element patterns. Large compositional variations among inclusions of one phase (olivine, garnet, chromite) within single diamonds indicate that the chemical environment of diamond crystallisation changed rapidly relative to diamond growth rates in many cases. P-T conditions of formation were calculated from multiphase inclusions and from trace element geothermobarometry of single inclusions. The geotherm at the time of diamond formation was near a 35 mW/m² conductive model; that is indistinguishable from the Paleozoic geotherm derived by studies of xenoliths and concentrate minerals from Mir. A range of Ni temperatures between garnet inclusions in single diamonds from both Mir and Sputnik suggests that many of the diamonds grew during thermal events affecting a relatively narrow depth range of the lithosphere, within the diamond stability field. The minor differences between inclusions in Mir and Sputnik may reflect lateral heterogeneity in the upper mantle.  相似文献   

Parental melts of melilitolite and origin of alkaline carbonatite: evidence from crystallised melt inclusions, Gardiner complex     

T. F. D. Nielsen  I. P. Solovova  I. V. Veksler 《Contributions to Mineralogy and Petrology》1997,126(4):331-344

Perovskite and melilite crystals from melilitolites of the ultramafic alkaline Gardiner complex (East Greenland) contain crystallised melt inclusions derived from: (1) melilitite; (2) low-alkali carbonatite; (3) natrocarbonatite. The melilitite inclusion (1) homogenisation temperature of 1060 °C is similar to liquidus temperatures of experimentally investigated natural melilitites. The compositions are peralkaline, low in MgO (ca.␣5 wt%), Ni and Cr, and they are low-pressure fractionates of more magnesian larnite-normative ultramafic lamprophyre-type melts of primary mantle origin. Low-alkali carbonatite compositions (2) homogenise at 1060–1030 °C and are compositionally similar to immiscible calcite carbonatite dykes derived from the melilitolite magma. Natrocarbonatite inclusions (3) homogenise between 1030 and 900 °C and are compositionally similar to natrocarbonatite lava from Oldoinyo Lengai. Nephelinitic to phonolitic dykes which are related to the calcite carbonatite dykes, are very Zr-rich and agpaitic (molecular Na₂O + K₂O/Al₂O₃ > 1.2) and resemble nephelinites of Oldoinyo Lengai. The petrographic, geochemical and temporal relationships indicate unmixing of carbonatite compositions (ca. 10% alkalies) from evolving melilitite melt and continued fractionation of melilitite to nephelinite. It is suggested that the natrocarbonatite compositions represent degassed supercritical high temperature fluid formed in a cooling body of strongly larnite-normative nephelinite or evolved melilitite. The Gardiner complex and similar melilitolite and carbonatite-bearing ultramafic alkaline complexes are believed to represent subvolcanic complexes formed beneath volcanoes comparable to Oldoinyo Lengai and that the suggested origin of natrocarbonatite may be applied to natrocarbonatites of Oldoinyo Lengai. Received: 18 January 1996 / Accepted: 2 September 1996  相似文献   

A mean behavior model of aerobic biodegradation in heterogeneous formation     

M. W. Kemblowski  C-M. Chang  I. Kamil 《Stochastic Environmental Research and Risk Assessment (SERRA)》1997,11(3):255-266

It has been observed that the field biodegradation rates for soluble hydrocarbon plumes are significantly smaller than the aerobic rates observed in the laboratory. It is believed that this difference is related to the fact that in the field oxygen and hydrocarbon must be mixed before the biodegradation reaction can occur, and that the effective degradation rate is controlled by the actual, not mean, concentrations of oxygen and hydrocarbon. In this work, we present a conceptual model of oxygen-mixing limited biodegradation, which indicates that the effective degradation rate should depend on the cross correlation between the oxygen and hydrocarbon concentration fluctuations. This is followed by a development of a rigorous, field-scale model.  相似文献   

Repeated Geodetic Measurements in the West Bohemia Seismoactive Region: Period 1993 - 1996     

Špičák  A.  Mrlina  J.  Jindra  D.  Mervart  L. 《Studia Geophysica et Geodaetica》1997,41(4):319-328

The western part of the Bohemian Massif is characterized by repeated occurrences of intraplate earthquake swarms. To study surface deformations of this anomalous region, a network covering about 2000 square kilometres for repeated geodetic measurements was established in 1993 - 1994. The positions of the individual points of the network were carefully picked with respect to local tectonic structure and earthquake foci distribution. GPS and precise levelling measurements were performed 1-2 times a year. The GPS data were processed by Bernese GPS software. No tendency to any displacement - either horizontal or vertical - of geological blocks was derived from the geodetic data for the period 1993 - 96. Only displacements of less than 5 mm/year in average could occur in the whole region in that period; larger displacements would have been revealed by our measurements.  相似文献   

A statistical study of underestimates of wind speeds by VHF radar   总被引：1，自引：0，他引：1  

L. Thomas  I. Astin  R. M. Worthington 《Annales Geophysicae》1997,15(6):805-812

Comparisons are made between horizontal wind measurements carried out using a VHF-radar system at Aberystwyth (52.4°N, 4.1°W) and radiosondes launched from Aberporth, some 50 km to the southwest. The radar wind results are derived from Doppler wind measurements at zenith angles of 6° in two orthogonal planes and in the vertical direction. Measurements on a total of 398 days over a 2-year period are considered, but the major part of the study involves a statistical analysis of data collected during 75 radiosonde flights selected to minimise the spatial separation of the two sets of measurements. Whereas good agreement is found between the two sets of wind direction, radar-derived wind speeds show underestimates of 4–6% compared with radiosonde values over the height range 4–14 km. Studies of the characteristics of this discrepancy in wind speeds have concentrated on its directional dependence, the effects of the spatial separation of the two sets of measurements, and the influence of any uncertainty in the radar measurements of vertical velocities. The aspect sensitivity of radar echoes has previously been suggested as a cause of underestimates of wind speeds by VHF radar. The present statistical treatment and case-studies show that an appropriate correction can be applied using estimates of the effective radar beam angle derived from a comparison of echo powers at zenith angles of 4.2° and 8.5°.  相似文献