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101.
102.
The Agenian is the earliest Neogene European Land Mammal Age. It encompasses the mammalian zones MN1 (23.03–22.7 Ma) and MN2 (22.7–20.0 Ma) and roughly coincides with the Aquitanian standard age. Agenian mammalian assemblages from Western Europe encompass a mixture of rhinocerotid taxa of Oligocene affinities and of Miocene newcomers, mostly recorded in France, Germany, Switzerland, and to a lesser extent, Spain. Rhinocerotidae are documented by seven species referred to five genera (Pleuroceros pleuroceros, Protaceratherium minutum, Plesiaceratherium aquitanicum, Mesaceratherium paulhiacense, Diaceratherium lemanense, D. asphaltense, and D. aginense), further attesting to a low suprageneric diversity. Their systematics, morphology, ecology, stratigraphical and geographical ranges are detailed in the present article. Occurrences and geographical ranges of all seven rhinocerotid species are illustrated on palaeogeographical maps of the circum-Mediterranean region at 23 Ma (MN1) and 21 Ma (MN2). The richest Agenian localities (Paulhiac, MN1; Laugnac, MN2) record a specific diversity similar to that of Orleanian rhinocerotid assemblages, with up to five/six associated species. All Agenian rhinocerotid species from Western Europe are endemic to the concerned region, which is consistent with the complete geographic isolation of Western Europe by earliest Miocene times. However, all five genera are documented by twin species in coeval localities of South and Central Asia, which implies (1) vicariant speciation events by latest Oligocene times and (2) the existence of intermittent pathways for terrestrial megamammals such as rhinocerotids during the concerned interval. 相似文献
103.
104.
The Lippmann diagram for the system(Ba, Sr)SO4-H2O was computed at 25 °Cby determining the solid-phase activity coefficientsfrom first principles calculations. Directcalculations of the mixing properties of thebarite-celestite series indicate this solid solutionbehaves as non-ideal and non-regular. At 25 °C,the enthalpy of mixing shows a minimum around 50 mole% SrSO4 due to an ordering tendency. Thefree energy of mixing shows two minima that delimit awide and symmetric miscibility gap (from 2.1 to 97.9 mole% SrSO4) at this temperature. The excessfree energy of mixing requires a Guggenheim expansionseries of 5 terms to be described, where the termswith odd exponents are null as a consequence of thesymmetric distribution of the mixing properties withcomposition. The Lippmann diagram shows a peritecticpoint that corresponds to the composition of an aqueoussolution which is simultaneously at equilibrium withthe two extremes of the miscibility gap. The largedifference between the solubility products of theendmembers involves a strong preferential partitioningof the less soluble endmember towards the solid phase,which explains the extremely Ba-poor composition ofthe aqueous solution (aqueous activity fraction forBa2+ = 0.000446 ) at the peritectic point. 相似文献
105.
Juan Pedro Montávez Juan Ignacio Jiménez Antonio Sarsa 《Boundary-Layer Meteorology》2000,96(3):433-452
A model for the urban canyon is formulated for meteorologicalconditions of weak winds at night time. Thermal radiation, conductivity and convection are simulated by means of the Monte Carlo method. These are the main physical processesof energy transfer that give rise to the characteristic temperaturedistribution in these systems. The model has been satisfactory tested under ideal conditions for which analytical solutions exist.The predictions of the model under morerealistic conditions accurately reproduce the observationalresults. A strong temperature gradient across streets, with the canyon corners up to 4 °C warmer than the canyon centre, is found for the deepest canyons. This theoretical predictionhas been successfully verified with measurementstaken in a number of streets of the city of Granada in Spain. 相似文献
106.
The Ardara pluton as part of the Donegal batholith was intruded into Neoproterozoic metasediments and metadolerites at mid-crustal
levels. The emplacement mechanism of the Ardara granite is very controversial, and mechanisms ranging from diapirism, ballooning
and stoping followed by nested diapirism have been proposed. Magnetic fabrics, rock fabrics and K/Ar dating of micas are used
here to constrain the emplacement history. The compositional zoning of the Ardara pluton is clearly reflected in the different
bulk magnetic susceptibilities between the outer quartz monzodiorite and the central granodiorite, whereas the intervening
tonalite is of intermediate nature. The magnetic carriers are characterized by the anisotropy of the magnetic susceptibility
(AMS), thermomagnetic measurements and through high field analyses (HFA). The separation of the ferrimagnetic and paramagnetic
contributions revealed that biotite and magnetite control the AMS in the quartz monzodiorite. Both minerals are oriented in
such a way that their summed contribution is constructive and originates from the shape fabric of magnetite and the texture
of biotite. Biotite is responsible mainly for the AMS in the tonalite and granodiorite. The magnetic foliation can be directly
related to the macroscopic foliation and also to the D4 structures in the country rocks. The foliation is consistent with
the geometry of the roughly circular shape and has a mostly steep to vertical dip. Towards the central granodiorite the magnetic
foliation dies out, although plagioclase texture measurements indicate a weak magmatic shape fabric. With the exception of
the tail, the Kmax axes (magnetic lineation) vary from steeply to gently plunging. The so-called lineation factor is approximately 1.01 and
therefore points to a less significant axial symmetry. These observations coincide with strain estimates on mafic enclaves
that show a very consistent pattern of K ∼0 flattening strain. Texture analyses of biotite and quartz additionally support
the observations made by the strain analyses and the magnetic fabric data. Microstructural investigations give evidence that
the fabrics are associated with the emplacement over a range of temperatures from truly magmatic to high-temperature solid-state
conditions. The age of the intrusion is still under discussion, but a new cooling age was determined by K/Ar dating of biotite
at 403.7±8 Ma corresponding to a temperature range between 450 and 300°C. For a mylonite along the southern contact between
the Ardara pluton and the country rock a K/Ar muscovite age of 378.8±7 Ma indicates a minimum age for the shear zone when
the Ardara pluton must have already been cooled down below 350±50°C.
Received: 28 January 1999 / Accepted: 28 December 1999 相似文献
107.
This paper describes a particular formulation of the extended finite element method (XFEM) specifically conceived for application to existing discontinuities of fixed location, for instance, in geological media. The formulation is based on two nonstandard assumptions: (1) the use of sub-interpolation functions for each subdomain and (2) the use of fictitious displacement variables on the nodes across the discontinuity (instead of the more traditional jump variables). Thanks to the first of those assumptions, the proposed XFEM formulation may be shown to be equivalent to the standard finite element method with zero-thickness interface elements for the discontinuities (FEM+z). The said equivalence is theoretically proven for the case of quadrangular elements cut in two quadrangles by the discontinuity, and only approximate for other types of intersections of quadrangular or triangular elements, in which the XFEM formulation corresponds to a kinematically restricted version of the corresponding interface plus continuum scheme. The proposed XFEM formulation with sub-interpolation, also helps improving spurious oscillations of the results obtained with natural interpolation functions when the discontinuity runs skew to the mesh. A possible explanation for these oscillations is provided, which also explains the improvement observed with sub-interpolation. The paper also discusses the oscillations observed in the numerical results when some nodes are too close to the discontinuity and proposes the remedy of moving those nodes onto the discontinuity itself. All the aspects discussed are illustrated with some examples of application, the results of which are compared with closed-form analytical solutions or to existing XFEM results from the literature. 相似文献
108.
109.
M. Merck A. Karle S. Martinez F. Arqueros K. H. Becker M. Bott-Bodenhausen R. Eckmann E. Faleiro J. Fernandez P. Fernandez V. Fonseca V. Haustein G. Heinzelmann I. Holl F. Just F. Krennrich M. Kühn E. Lorenz H. Meyer N. Müller R. Plaga J. Prahl M. Probst M. Rozanska M. Samorski H. Sander K. Sauerland C. Sesea W. Stamm 《Astroparticle Physics》1996,5(3-4):379-392
A precise knowledge of the angular resolution of scintillator arrays used to observe extended air showers (EAS) is of key importance in the search for VHE/UHE γ point sources. Four independent methods have been used to determine the mean resolution for which a value of ΔΘ63 of 0.8°(1.0°) at a proton threshold of 50 (40) TeV has been found for the HEGRA EAS-array. 相似文献
110.
A proposed new type of arsenian pyrite: Composition, nanostructure and geological significance 总被引:8,自引:0,他引:8
Artur P. Deditius Udo Becker Stephen E. Kesler 《Geochimica et cosmochimica acta》2008,72(12):2919-2933
This report describes a new form of arsenian pyrite, called As3+-pyrite, in which As substitutes for Fe [(Fe,As)S2], in contrast to the more common form of arsenian pyrite, As1−-pyrite, in which As1− substitutes for S [Fe(As,S)2]. As3+-pyrite has been observed as colloformic overgrowths on As-free pyrite in a hydrothermal gold deposit at Yanacocha, Peru. XPS analyses of the As3+-pyrite confirm that As is present largely as As3+. EMPA analyses show that As3+-pyrite incorporates up to 3.05 at % of As and 0.53 at. %, 0.1 at. %, 0.27 at. %, 0.22 at. %, 0.08 at. % and 0.04 at. % of Pb, Au, Cu, Zn, Ni, and Co, respectively. Incorporation of As3+ in the pyrite could be written like: As3++yAu++1-y(□)⇔2Fe2+; where Au+ and vacancy (□) help to maintain the excess charge. HRTEM observations reveal a sharp boundary between As-free pyrite and the first overgrowth of As3+-pyrite (20-40 nm thick) and co-linear lattice fringes indicating epitaxial growth of As3+-pyrite on As-free pyrite. Overgrowths of As3+-pyrite onto As-free pyrite can be divided into three groups on the basis of crystal size, 8-20 nm, 100-300 nm and 400-900 nm, and the smaller the crystal size the higher the concentration of toxic arsenic and trace metals. The Yanacocha deposit, in which As3+-pyrite was found, formed under relatively oxidizing conditions in which the dominant form of dissolved As in the stability field of pyrite is As3+; in contrast, reducing conditions are typical of most environments that host As1−-pyrite. As3+-pyrite will likely be found in other oxidizing hydrothermal and diagenetic environments, including high-sulfidation epithermal deposits and shallow groundwater systems, where probably kinetically controlled formation of nanoscale crystals such as observed here would be a major control on incorporation and release of As3+ and toxic heavy metals in oxidizing natural systems. 相似文献