Evidence for fullerenes in solid bitumen from pillow lavas of Proterozoic age from Mítov (Bohemian Massif, Czech Republic)     

Jan Jehli?ka  Aleš Svatoš  Filip Uhlík 《Geochimica et cosmochimica acta》2003,67(8):1495-1506

Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C₆₀, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C₇₀ was detected, nor was C₆₀ found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C₆₀ in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation.  相似文献   

Aquatic chemistry: 3rd ed. by W. Stumm and J. J. Morgan. A Wiley-Interscience Publication, John Wiley & Sons, Inc., 1996, xvi + 1022p., US $29.95 (ISBN 0-471-51184-6)     

Tomas Pa?es 《Geochimica et cosmochimica acta》1996,60(24):5158-5159

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Quantitative methods in the earth sciences     

A. F?rster  D. F. Merriam 《Mathematical Geology》1997,29(2):315

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Simulation of normal distributed smooth fields by Karhunen-Loéve expansion in combination with kriging     

Nils-Otto Kitterr?d  Lars Gottschalk 《Stochastic Hydrology and Hydraulics》1997,11(6):459-482

Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function. This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the 2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the predefined covariance functions are evaluated.  相似文献   

Bathymetric and geochemical investigation of Kawah Ijen Crater Lake, East Java, Indonesia     

B. Takano  K. Suzuki  K. Sugimori  T. Ohba  S. M. Fazlullin  A. Bernard  S. Sumarti  R. Sukhyar  M. Hirabayashi 《Journal of Volcanology and Geothermal Research》2004,135(4):299-329

A bathymetric survey of Kawah Ijen crater lake was conducted by acoustic sounding in 1996 to compare the lake morphology with those measured in 1922, 1925 and 1938, and to calculate the present lake volume. Even though the lake experienced several hydrothermal eruptions, the maximum depth became shallower (182 m) than before (200 m), resulting in a reduced lake volume (3.0×10⁷ m³).Fifty-two major and minor constituents including rare earth elements and polythionates (PT) of the lake waters at various depths were determined by ICP-AES, ICP-MS and HPLC, respectively. These ions except for several volatile elements are taken up by lake fringe through congruent dissolution of pyroclastics of Kawah Ijen volcano. Most ions are homogeneously distributed throughout the lake, although PT showed a considerable vertical variation. Rare earth elements (REE) in the Kawah Ijen water as well as those from other hyper-acidic crater lakes show distribution patterns likely due to the three rock dissolution (preferential, congruent and residual) types, and their logarithmic concentrations linearly depend upon the pH values of the lake waters.Using the PT degradation kinetics data, production rates of PT, injection rates of SO₂ and H₂S into the lake were estimated to be 114, 86 and 30 tons/day, respectively. Also travel time of the spring water at the Banyupahit Riverhead from Kawah Ijen was estimated to be 600–1000 days through the consideration of decreasing rates of PT. Molten sulfur stocks containing Sn, Cu, Bi sulfides and Pb-barite exposed on the inner crater slope were presumed to be extinct molten sulfur pools at the former lake bottom. This was strongly supported by the barite precipitation temperature estimated through the consideration of the temperature dependence of Pb-chlorocomplex formation.  相似文献   

Structure and tectonics of convergent plate margins     

Aleš Špi?ák  Ond?ej ?adek  E.Robert Engdahl 《Physics of the Earth and Planetary Interiors》2004,141(4):241

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Influence of the zone of weakness on dip angle and shear heating of subducted slabs     

Martin Kuka?ka  Ctirad Matyska 《Physics of the Earth and Planetary Interiors》2004,141(4):243-252

We study the importance of the zones of weakness and the pattern of downgoing flow in steady-state models of subducting lithosphere, which interacts mechanically and thermally with the ambient mantle. The non-linear system of governing equations consists of (i) the momentum equation in stream function formulation and (ii) the steady-state heat transfer equation including conduction and advection of heat and dissipation. A finite element method has been applied to this system. We consider the viscosity to be a non-linear function of both the temperature and the stream function. In steady-state two-dimensional (2D) flow, the stream function isolines follow material trajectories. They are used to follow the top of the subducting slab, which because of its possible increase in water content, is assumed to have a lower viscosity. The zone of weakness has been thus obtained in the self-consistent fashion since the stream function as well as the temperature are the output from our modeling and no a priori assumptions about the shape of the bending lithosphere are taken into account. It was shown that several orders decrease of viscosity in the zone of weakness is required to obtain the dip angle of about 45°. If the decrease of viscosity is not sufficient enough, the subducted slab either sinks almost vertically or does not exhibit a plate-like behavior. We have also demonstrated that shear heating can unrealistically increase at the zone of weakness for fast subductions if decrease of viscosity is underestimated.  相似文献   

A Modeling Study of the Effects of Anomalous Snow Cover over the Tibetan Plateau upon the South Asian Summer Monsoon   总被引：1，自引：0，他引：1  

刘华强  孙照渤王举 闵锦忠 《大气科学进展》2004,21(6):964-975

The effect of anomalous snow cover over the Tibetan Plateau upon the South Asian summer monsoon is investigated by numerical simulations using the NCAR regional climate model (RegCM2) into which gravity wave drag has been introduced. The simulations adopt relatively realistic snow mass forcings based on Scanning Multi-channel Microwave Radiometer (SNINIR) pentad snow depth data. The physical mechanism and spatial structure of the sensitivity of the South Asian early summer monsoon to snow cover anomaly over the Tibetan Plateau are revealed. The main results are summarized as follows. The heavier than normal snow cover over the Plateau can obviously reduce the shortwave radiation absorbed by surface through the albedo effect, which is compensated by weaker upward sensible heat flux associated with colder surface temperature, whereas the effects of snow melting and evaporation are relatively smaller.The anomalies of surface heat fluxes can last until June and become unobvious in July. The decrease of the Plateau surface temperature caused by heavier snow cover reaches its maximum value from late April to early May. The atmospheric cooling in the mid-upper troposphere over the Plateau and its surrounding areas is most obvious in May and can keep a fairly strong intensity in June. In contrast, there is warming to the south of the Plateau in the mid-lower troposphere from April to June with a maximum value in May.The heavier snow cover over the Plateau can reduce the intensity of the South Asian summer monsoon and rainfall to some extent, but this influence is only obvious in early summer and almost disappears in later stages.  相似文献   

Effects of inertial and kinematic interaction on seismic behavior of pile with embedded foundation   总被引：4，自引：0，他引：4  

Kohji Tokimatsu  Hiroko Suzuki  Masayoshi Sato 《Soil Dynamics and Earthquake Engineering》2005,25(7-10):753-762

Effects of inertial and kinematic forces on pile stresses are studied based on large shaking table tests on pile-structure models with a foundation embedded in dry and liquefiable sand deposits. The test results show that, if the natural period of the superstructure, T_b, is less than that of the ground, T_g, the ground displacement tends to be in phase with the inertial force from the superstructure, increasing the shear force transmitted to the pile. In contrast, if T_b is greater than T_g, the ground displacement tends to be out of phase with the inertial force, restraining the pile stress from increasing. With the effects of earth pressures on the embedded foundation and pile incorporated in, pseudo-static analysis is conducted to estimate maximum moment distribution in pile. It is assumed that the maximum moment is equal to the sum of the two stresses caused by the inertial and kinematic effects if T_b<T_g or the square root of the sum of the squares of the two if T_b>T_g. The estimated pile stresses are in good agreement with the observed ones regardless of the occurrence of soil liquefaction.  相似文献   

Viscosity of peridotite liquid up to 13 GPa: Implications for magma ocean viscosities     

Christian Liebske  Bettina Schmickler  Hidenori Terasaki  Brent T. Poe  Akio Suzuki  Ken-ichi Funakoshi  Ryota Ando  David C. Rubie 《Earth and Planetary Science Letters》2005,240(3-4):589-604

The viscosity of synthetic peridotite liquid has been investigated at high pressures using in-situ falling sphere viscometry by combining a multi-anvil technique with synchrotron radiation. We used a newly designed capsule containing a small recessed reservoir outside of the hot spot of the heater, in which a viscosity marker sphere is embedded in a forsterite + enstatite mixture having a higher solidus temperature than the peridotite. This experimental setup prevents spheres from falling before a stable temperature above the liquidus is established and thus avoids difficulties in evaluating viscosities from velocities of spheres falling through a partially molten sample.

Experiments have been performed between 2.8 and 13 GPa at temperatures ranging from 2043 to 2523 K. Measured viscosities range from 0.019 (± 0.004) to 0.13 (± 0.02) Pa s. At constant temperature, viscosity increases with increasing pressure up to  8.5 GPa but then decreases between  8.5 and 13 GPa. The change in the pressure dependence of viscosity is likely associated with structural changes of the liquid that occur upon compression. By combining our results with recently published 0.1 MPa peridotite liquid viscosities [D.B. Dingwell, C. Courtial, D. Giordano, A. Nichols, Viscosity of peridotite liquid, Earth Planet. Sci. Lett. 226 (2004) 127–138.], the experimental data can be described by a non-Arrhenian, empirical Vogel-Fulcher-Tamman equation, which has been modified by adding a term to account for the observed pressure dependence of viscosity. This equation reproduces measured viscosities to within 0.08 log₁₀-units on average. We use this model to calculate viscosities of a peridotitic magma ocean along a liquid adiabat to a depth of  400 km and discuss possible effects on viscosity at greater pressures and temperatures than experimentally investigated.  相似文献