Crystal chemistry, thermal expansion, and Raman spectra of hydroxyl-clinohumite: implications for water in Earth’s interior     

Yu Ye  Joseph R. Smyth  Steven D. Jacobsen  Céline Goujon 《Contributions to Mineralogy and Petrology》2013,165(3):563-574

Two samples of hydroxyl-clinohumite, sample SZ0407B with approximate composition Mg_8.674(14)Fe_0.374(4)(Si_0.99(1)O₄)₄(OH)₂ and sample SZ0411B with composition Mg₉(SiO₄)₄(OH)₂, were synthesized at 12 GPa and 1,250 °C coexisting with olivine. Unit-cell parameters determined by single-crystal X-ray diffraction are given as follows: a = 4.7525(4) Å, b = 10.2935(12) Å, c = 13.7077(10) Å, α = 100.645(9)°, V = 659.04(9) Å³ for SZ0407B, and a = 4.7518(6) Å, b = 10.2861(12) Å, c = 13.7008(9) Å, α = 100.638(9)°, V = 658.15(9) Å³ for SZ0411B. Single-crystal X-ray intensity data were collected for crystal structure refinements of both samples. Relative to the pure-Mg sample, Fe decreases M3–OH bond lengths by ~0.010(3) Å, consistent with some ferric iron ordering into M3. Raman spectroscopy shows two strong bands in the lattice-mode region at 650 and 690 cm^?1 in the Fe-bearing sample, which are not observed in the pure-Mg sample. Spectra in the H₂O region show at least five bands, which are deconvolved into seven distinct O–H-stretching modes. Thermal expansion measurements were carried out for both samples from 153 to 787 K by single-crystal X-ray diffraction. The average a-, b-, c-axial and volumetric thermal expansion coefficients (10^?6 K^?1) are 10.5(1), 12.3(2), 12.5(2) and 34.9(5) for SZ0407B, respectively, and 11.1(1), 12.6(3), 13.7(3), 36.8(6) for SZ0411B, respectively. After heating, the unit-cell parameters were refined again for each sample at ambient condition, and no significant changes were observed, indicating no significant oxidation or dehydration during the experiment. For the DHMS phases along the brucite–forsterite join, linear regression gives a systematic linear decrease in expansivity with increasing density. Further, substitution of ferrous iron into these structures decreases thermal expansivity, making the Fe-bearing varieties slightly stiffer.  相似文献   

Monitoring Spatial and Temporal Land Use/Cover Changes; a Case Study in Western Black Sea Region of Turkey     

M. Alkan  M. Oruc  Y. Yildirim  D. Z. Seker  K. Jacobsen 《Journal of the Indian Society of Remote Sensing》2013,41(3):587-596

Rapid land use/land cover changes have taken place in many cities of Turkey. Land use and land cover changes are essential for wide range of applications. In this study, Landsat TM satellite imageries date from 1987, 1993, 2000 and 2010 were used to analyse temporal and spatial changes in the Western Black Sea Region of Turkey. Zonguldak and Eregli two largest and economic important cities which have been active coal mining and iron fabric areas. Maximum Likelihood Classification technique was implemented and the results were represented in classes of open area, forest, agricultural, water, mining, urban and pollution in the sea. Urban areas on both cities increased from 1987 to 2010. The agricultural and open areas from 1987 to 2010 decreased in parallel to land use and land cover change in both cities. Meanwhile, forest areas increased continuously with about 20 % from 1987 to 2010 in both cities. As industrial activity, the coal fields doubled from 1987 to 2010.  相似文献   

An integrated laser anemometer and dust accumulator for studying wind-induced dust transport on Mars     

J.P. Merrison  H.P. Gunnlaugsson  K. Kinch  T.L. Jacobsen  A.E. Jensen  P. Nørnberg  H. Wahlgreen 《Planetary and Space Science》2006,54(11):1065-1072

Windborne dust is one of the most important and dynamic factors affecting the Martian surface and its atmosphere, yet there lacks a detailed physical understanding how it is transported. We present a miniature laser-based optoelectronic instrument for use on a Mars lander. It integrates sensors capable of quantifying important parameters needed for the understanding and modeling of dust transport on Mars, these include wind speed, wind direction, suspended dust concentration, dust deposition and removal rates as well as the electrification of the Martian dust. Dust electrification has been seen from experimental simulations to be of considerable importance to the processes of adhesion and cohesion, specifically prompting the formation of low mass density dust aggregates. Testing of this prototype instrument has been performed under simulated Martian conditions in a wind tunnel facility. The results and analysis of its functionality will be presented.  相似文献   

High-pressure behavior of natural single-crystal epidote and clinozoisite up to 40 GPa   总被引：2，自引：0，他引：2  

Fei Qin  Xiang Wu  Ying Wang  Dawei Fan  Shan Qin  Ke Yang  Joshua P. Townsend  Steven D. Jacobsen 《Physics and Chemistry of Minerals》2016,43(9):649-659

The comparative compressibility and high-pressure stability of a natural epidote (0.79 Fe-total per formula unit, Fe_tot pfu) and clinozoisite (0.40 Fe_tot pfu) were investigated by single-crystal X-ray diffraction and Raman spectroscopy. The lattice parameters of both phases exhibit continuous compression behavior up to 30 GPa without evidence of phase transformation. Pressure–volume data for both phases were fitted to a third-order Birch–Murnaghan equation of state with V ₀ = 461.1(1) ų, K ₀ = 115(2) GPa, and \(K_{0}^{'}\) = 3.7(2) for epidote and V ₀ = 457.8(1) ų, K ₀ = 142(3) GPa, and \(K_{0}^{'}\) = 5.2(4) for clinozoisite. In both epidote and clinozoisite, the b-axis is the stiffest direction, and the ratios of axial compressibility are 1.19:1.00:1.15 for epidote and 1.82:1.00:1.19 for clinozoisite. Whereas the compressibility of the a-axis is nearly the same for both phases, the b- and c-axes of the epidote are about 1.5 times more compressible than in clinozoisite, consistent with epidote having a lower bulk modulus. Raman spectra collected up to 40.4 GPa also show no indication of phase transformation and were used to obtain mode Grüneisen parameters (γ _i) for Si–O vibrations, which were found to be 0.5–0.8, typical for hydrous silicate minerals. The average pressure coefficient of Raman frequency shifts for M–O modes in epidote, 2.61(6) cm^?1/GPa, is larger than found for clinozoisite, 2.40(6) cm^?1/GPa, mainly due to the different compressibility of FeO₆ and AlO₆ octahedra in M3 sites. Epidote and clinozoisite contain about 2 wt% H₂O are thus potentially important carriers of water in subducted slabs.  相似文献   

Dating recent floodplain sediments in the Hawkesbury‐Nepean River system,eastern Australia using single‐grain quartz OSL     

Anna K. Sim  Kristina J. Thomsen  Andrew S. Murray  Geraldine Jacobsen  Russell Drysdale  Wayne Erskine 《Boreas: An International Journal of Quaternary Research》2014,43(1):1-21

Two fluvial sediment cores taken from a floodplain of the Hawkesbury‐Nepean River system in the Sydney region, eastern Australia are dated using Optically Stimulated Luminescence (OSL) to provide a reliable chronology essential for the management and planning of water resources. Nine charcoal ¹⁴C (AMS) dates constrain these OSL ages. Quartz extracted from seven OSL samples from each of the cores was measured using both single‐grain and multi‐grain OSL techniques. Three of the single‐grain natural dose distributions appear to be well bleached, but the others appear to be incompletely bleached to various degrees. Three minimum‐age models (MAM, MAM_UL and IEU) are applied to the single‐grain dose distributions. We conclude that these models give consistent age estimates. For one of the cores it appears to be necessary to use a minimum‐age model to obtain accurate ages, but in the other core incomplete bleaching is probably less important than postdepositional mixing and mixing during sampling. As a result, the burial age is probably best estimated using the weighted average of the individual single‐grain dose estimates. The application of multi‐grain OSL techniques to these samples results in an average apparent age overestimation of ～200 years, which is significant for these samples, but negligible for sediments older than a few thousand years. The intention is that the chronology obtained in this study will be used in conjunction with a proxy flood record, derived from floodplain sediments, to gain an understanding of the long‐term variability in periods of high and low rainfall in eastern Australia.  相似文献   

The use of soft X-ray spectromicroscopy to investigate the distribution and composition of organic matter in a diatom frustule and a biomimetic analog     

Lynn Abramson  Sue Wirick  Cindy Lee  Chris Jacobsen  Jay A. Brandes 《Deep Sea Research Part II: Topical Studies in Oceanography》2009,56(18):1369-1380

Diatoms play a significant role in the global carbon cycle through their role in biogenic silica production and the transport of organic matter to the seafloor. Recent work has shown that silicified diatom frustules contain a significant amount of organic matter, and that the proportion of diatom-bound organic matter increases with depth in the water column and sediments. Here, we investigate the association between organic matter and the mineral phase. We used a combination of scanning transmission X-ray microscopy (STXM) and carbon X-ray absorption near-edge structure (XANES) spectroscopy to characterize the distribution and composition of organic matter in frustules of the diatom Cylindrotheca closterium and a biomimetic silica gel. To our knowledge, this study represents the first successful attempt to simultaneously image and obtain chemical information about the organic matter within a diatom frustule using X-ray spectromicroscopy near the carbon edge. Organic carbon, most likely protein, was distributed throughout the frustules and was not removed by harsh chemical treatment. The physical structure of the frustules appeared to be related to the chemical composition of this organic matter, with aromatic or unsaturated carbon being concentrated in the most intricately patterned regions of the frustule. A similar physical and chemical structure was observed in a biomimetic silica gel precipitated spontaneously with polylysine. These results are consistent with the theory that organic constituents of diatom frustules direct silica precipitation and become incorporated within the silica matrix as it forms. The relationship between organic matter composition and silica morphology, the failure of harsh chemical treatments to remove this organic matter, and the spontaneous nature of the co-precipitation of silica and organic matter indicate some chemical interaction between the siliceous and organic components of diatom frustules. Frustule-bound organic matter should therefore be protected from decomposition in the water column or diagenetic alteration in sediments unless the frustule dissolves.  相似文献   

Optimal selection of temperature areas by juvenile cod (Gadus morhua L.) in the Barents Sea modelled by dynamic optimisation     

Kristiansen  Tore S.; Michalsen  Kathrine; Jacobsen  Jan Arge; Huse  Irene 《ICES Journal of Marine Science》2001,58(1):172-182

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Comparison of Five Eulerian Air Pollution Forecasting Systems for the Summer of 1999 Using the German Ozone Monitoring Data     

Stefan Tilmes  JØrgen Brandt  Frode FlatØy  Robert Bergström  Johannes Flemming  Joakim Langner  Jesper H. Christensen  Lise M. Frohn  Øystein Hov  Ingo Jacobsen  Eberthard Reimer  Rainer Stern  Jörg Zimmermann 《Journal of Atmospheric Chemistry》2002,42(1):91-121

Eulerian state-of-the-art air pollution forecasting systems on the European scale are operated routinely by several countries in Europe. DWD and FUB, both Germany, NERI, Denmark, NILU, Norway, and SMHI, Sweden, operate some of these systems. To apply such modeling systems, e.g. for regulatory purposes according to new EU directives, an evaluation and comparison of the model systems is fundamental in order to assess their reliability. One step in this direction is presented in this study: The model forecasts from all five systems have been compared to measurements of ground level ozone in Germany. The outstanding point in this investigation is the availability of a huge amount of data – from forecasts by the different model systems and from observations. This allows for a thorough interpretation of the findings and assures the significance of the observed features. Data from more than 300 measurement stations for a 5-month period (May–September 1999) of the German monitoring networks have been used in this comparison. Different spatial and temporal statistical parameters were applied in the evaluation. Generally, it was found that the most comprehensive models gave the best results. However, the less comprehensive and computational cheaper models also produced good results. The extensive comparison made it possible to point out weak points in the different models and to describe the individual model behavior for a full summer period in a climatological sense. The comparison also gave valuable information for an assessment of individual measurement stations and complete monitoring networks in terms of the representativeness of the observation data.  相似文献   

Rb-Sr isotope systematics in metamorphic rocks,Kongsberg sector,south Norway     

Stein B. Jacobsen  Knut S. Heier 《Lithos》1978,11(4):257-276

Rb-Sr isotope data are presented for gneisses, migmatite neosome material and granitic and gabbroic intrusive rocks from the southern part of the Kongsberg sector, south Norway. The maximum age of the crust in this area appears to be ～1.6 AE. Two metamorphic episodes at ～1.5–1.6 AE and at ～1.1–1.2 AE are recognized. Initial ⁸⁷Sr/⁸⁶Sr ratios for the granitic rocks give evidence for reworking of sialic crust and indicate that approximately 1.6 AE old crust repeatedly acted as a source for granitic magmas for a timespan of ～0.5 AE.  相似文献   

The copper-bearing breccia pipes of the Messina district South Africa     

J. B. E. Jacobsen  T. S. McCarthy  G. J. Laing 《Mineralium Deposita》1976,11(1):33-45

The Messina Copper Mines comprise a group of breccia pipes, disseminated replacement and fissure deposits within an area 20 km long by 1 km wide, emplaced within high-grade metamorphic rocks of the Limpopo mobile belt. Breccia pipes as well as associated hydrothermal copper deposits are aligned along a northeast trend which forms a southwestern projection of the Nuanetsi Igneous Province. The "L" and West lode breccia columns are known over a vertical extent of 1 250 metres, and are not exposed on surface; they are circular to polygonal in plan outline, as a result of joint controls. Peripheral microbreccia grades downwards and inwards to macrobreccia. Downward displacement of country rock marker zones indicate a maximum 1 – 3 per cent volume increase, while observed interfragmental fill constitutes 15 – 25 per cent. Hydrothermal alteration of wallrock gneiss mantles the breccia columns and does not extend to surface; it is comprised of distinct zones, the outermost characterized by sericitized gneiss, grading to an albitite, and finally to zoisite-quartz rock around the immediate brecciated contacts, and within the pipes. The interfragmental fill consists largely of quartz and sulphides, and grades downwards to albite + sulphides in the West Lode pipe. Sulphide mineral distribution is zoned, pyrite dominating in the apex of the pipes, grading downwards to chalcopyrite-bornite and then bornite-chalcocite at deeper levels. The nature of the fragmentation precludes normal stoping collapse mechanisms for brecciation and suggests a single implosive event. Chemical reaction induced shrinkage of fragments probably created the bulk of the interfragmental volume.  相似文献