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In recent years, high‐molecular‐weight anionic polyacrylamides (PAMs) have been tested on a variety of soils, primarily in temperate climates. However, little information is available regarding the effectiveness of PAM for preventing soil loss through runoff in tropical settings. Screening tests were performed using three negatively charged PAMs and one positively charged PAM on five Hawaii soils (two Oxisols, one Vertisol, and two Aridisols) to determine erosion loss, sediment settling, and aggregate stability. A laboratory‐scale rainfall simulator was used to apply erosive rainfall at intensities from 5 to 8·5 cm h?1 at various PAM doses applied in both dry and solution forms. Soil detachment due to splash and runoff, as well as the runoff and percolate water volumes, were measured for initial and successive storms. The impact of PAM on particle settling and aggregate stability was also evaluated for selected soil‐treatment combinations. Among the PAMs, Superfloc A‐836 was most effective, and significantly reduced runoff and splash sediment loss for the Wahiawa Oxisol and Pakini Andisol at rates varying between 10 and 50 kg ha?1. Reduced runoff and splash sediment loss were also noted for PAM Aerotil‐D when applied in solution form to the Wahiawa Oxisol. Significant reductions in soil loss were not noted for either the Lualualei Vertisol or the Holomua Oxisol. It is believed that the high montmorillonite content of the Lualualei Vertisol and the low cation‐exchange capacity of the Holomua Oxisol diminished the effectiveness of the various PAMs tested. The polymers were also found to enhance sediment settling of all soils and helped improve their aggregate stability. This screening study shows the potential use of PAM for tropical soils for applications such as infiltration enhancement, runoff reduction, and enhanced sedimentation of detention ponds. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
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The Mangala Valles system is an ∼ ∼900 km fluvially carved channel system located southwest of the Tharsis rise and is unique among the martian outflow channels in that it heads at a linear fracture within the crust as opposed to a collapsed region of chaos as is the case with the circum-Chryse channels. Mangala Valles is confined within a broad, north–south trending depression, and begins as a single valley measuring up to 350 km wide that extends northward from a Memnonia Fossae graben, across the southern highlands toward the northern lowlands. Approximately 600 km downstream, this single valley branches into multiple channels, which ultimately lose their expression at the dichotomy boundary. Previous investigations of Mangala Vallis suggested that many of the units mapped interior to the valley were depositional, related to flooding, and that a minimum of two distinct periods of flooding separated by tens to hundreds of millions of years were required to explain the observed geology. We use infrared and visible images from the THermal EMission Imaging System (THEMIS), and topographic data from the Mars Orbiting Laser Altimeter (MOLA), to investigate the nature of the units mapped within Mangala Vallis. We find that the geomorphology of the units, as well as their topographic and geographic distribution, are consistent with most of them originating from a single assemblage of volcanic flow deposits, once continuous with volcanic flows to the south of the Memnonia Fossae source graben. These flows resurfaced the broad, north–south trending depression into which Mangala Vallis formed prior to any fluvial activity. Later flooding scoured and eroded this volcanic assemblage north of the Mangala source graben, resulting in the present distribution of the units within Mangala Vallis. Additionally, our observations suggest that a single period of catastrophic flooding, rather than multiple periods separated by tens to hundreds of millions of years, is consistent with and can plausibly explain the interior geology of Mangala Vallis. Further, we present a new scenario for the source and delivery of water to the Mangala source graben that models flow of groundwater through a sub-cryosphere aquifer and up a fracture that cracks the cryosphere and taps this aquifer. The results of our model indicate that the source graben, locally enlarged to a trough near the head region of Mangala, would have required less than several days to fill up prior to any spill-over of water to the north. Through estimates of the volume of material missing from Mangala (13,000–20,000 km3), and calculation of mean discharge rates through the channel system (∼ ∼5 × 106 m3 s−1), we estimate that the total duration of fluvial activity through the Mangala Valles was 1–3 months.  相似文献   
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On the practice of estimating fractal dimension   总被引:11,自引:0,他引:11  
Coastlines epitomize deterministic fractals and fractal (Hausdorff-Besicovitch) dimensions; a divider [compass] method can be used to calculate fractal dimensions for these features. Noise models are used to develop another notion of fractals, a stochastic one. Spectral and variogram methods are used to estimate fractal dimensions for stochastic fractals. When estimating fractal dimension, the objective of the analysis must be consistent with the method chosen for fractal dimension calculation. Spectal and variogram methods yield fractal dimensions which indicate the similarity of the feature under study to noise (e.g., Brownian noise). A divider measurement method yields a fractal dimension which is a measure of complexity of shape.  相似文献   
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Skeletal cadmium-to-calcium (Cd/Ca) ratios in hermatypic stony corals have been used to reconstruct changes in upwelling over time, yet there has not been a systematic evaluation of this tracer’s natural variability within and among coral species, between depths and across environmental conditions. Here, coral skeletal Cd/Ca ratios were measured in multiple colonies of Pavona clavus, Pavona gigantea and Porites lobata reared at two depths (1 and 7 m) during both upwelling and nonupwelling intervals in the Gulf of Panama (Pacific). Overall, skeletal Cd/Ca ratios were significantly higher during upwelling than during nonupwelling, in shallow than in deep corals, and in both species of Pavona than in P. lobata. P. lobata skeletal Cd/Ca ratios were uniformly low compared to those in the other species, with no significant differences between upwelling and nonupwelling values. Among colonies of the same species, skeletal Cd/Ca ratios were always higher in all shallow P. gigantea colonies during upwelling compared to nonupwelling, though the magnitude of the increase varied among colonies. For P. lobata, P. clavus and deep P. gigantea, changes in skeletal Cd/Ca ratios were not consistent among all colonies, with some colonies having lower ratios during upwelling than during nonupwelling. No statistically significant relationships were found between skeletal Cd/Ca ratios and maximum linear skeletal extension, δ13C or δ18O, suggesting that at seasonal resolution the Cd/Ca signal was decoupled from growth rate, coral metabolism, and ocean temperature and salinity, respectively. These results led to the following conclusions, (1) coral skeletal Cd/Ca ratios are independent of skeletal extension, coral metabolism and ambient temperature/salinity, (2) shallow P. gigantea is the most reliable species for paleoupwelling reconstruction and (3) the average Cd/Ca record of several colonies, rather than of a single coral, is needed to reliably reconstruct paleoupwelling events.  相似文献   
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We present molecular orbital/density functional theory (MO/DFT) calculations that predict a greater isotopic fractionation in redox reactions than in reactions involving ligand exchange. The predicted fractionation factors, reported as 1000·ln(56-54α), associated with equilibrium between Fe-organic and Fe-H2O species were <1.6‰ in vacuo and <1.2‰ in solution when the oxidation state of the system was held constant. These fractionation factors were significantly smaller than those predicted for equilibrium between different oxidation states of Fe, for which 1000·ln(56-54α) was >2.7‰ in vacuo and >2.2‰ in solution when the bound ligands were unchanged. The predicted 56Fe/54Fe ratio was greater in complexes containing Fe3+ and in complexes with shorter Fe-O bond lengths; both of these trends follow previous theoretical results. Our predictions also agree with previous experimental measurements that suggest that the largest biological fractionations will be associated with processes that change the oxidation state of Fe, and that identification of biologically controlled Fe isotope fractionation may be difficult when abiotic redox fractionations are present in the system. The models studied here also have important implications for future theoretical isotope calculations, because we have discovered the necessity of using vibrational frequencies instead of reduced masses when predicting reduced partition functions in aqueous-phase species.  相似文献   
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The dissolution and growth of uranophane [Ca(UO2)2(SiO3OH)2·5H2O] have been examined in Ca- and Si-rich test solutions at low temperatures (20.5 ± 2.0 °C) and near-neutral pH (∼6.0). Uranium-bearing experimental solutions undersaturated and supersaturated with uranophane were prepared in matrices of ∼10−2 M CaCl2 and ∼10−3 M SiO2(aq). The experimental solutions were reacted with synthetic uranophane and analyzed periodically over 10 weeks. Interpretation of the aqueous solution data permitted extraction of a solubility constant for the uranophane dissolution reaction and standard state Gibbs free energy of formation for uranophane ( kJ mol−1).  相似文献   
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