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81.
Epithermal precious- and base-metal deposits are diverse, reflecting the different tectonic, igneous and structural settings in which they occur, the complexities of their local setting, and the many processes involved in their formation. Most epithermal deposits form at shallow crustal levels where abrupt changes in physical and chemical conditions result in metal deposition and attendant hydrothermal alteration. The principal factors that influence the conditions prevailing in the epithermal environment, and which ultimately determine the sites and character of mineralization, include: geology (structure, stratigraphy, intrusions and rock type, which affect the style and degree of permeability and the reactivity of the host); pressure and temperature (which in the epithermal environment are related on the boiling point with depth curve); hydrology (the relationship between permeability and topography which governs fluid flow, and discharge/recharge characteristics, as well as access of steam-heated waters); chemistry of the mineralizing fluid (which determines the metal-carrying capacity, as well as the associated vein and alteration assemblage); and syn-hydrothermal development of permeability and/or changes in hydraulic gradients.Many attempts have been made to classify epithermal deposits based on mineralogy and alteration, the host rocks, deposit form, genetic models, and standard deposits. All have their strengths and weaknesses. We prefer a simple approach using the fundamental fluid chemistry (high or low sulfidation, reflecting relatively oxidized or reduced conditions, respectively) as readily inferred from vein and alteration mineralogy and zoning, together with the form of the deposit, and using comparative examples to clarify the character of the deposit.Guidelines for exploration vary according to the scale at which work is conducted, and are commonly constrained by a variety of local conditions. On a regional scale the tectonic, igneous and structural settings can be used, together with assessment of the depth of erosion, to select areas for project area scale exploration. At project area scale, direct (i.e. geochemical) or indirect guidelines may be used. Indirect methods involve locating and interpreting hydrothermal alteration as a guide to ore, with the topographic and hydrologic reconstruction of the system being of high priority. These pursuits may involve mineralogic, structural, geophysical or remote sensing methods. On a prospect scale, both direct and indirect methods may be used; however, they can only be effective in the framework of a sound conceptual understanding of the processes that occur in the epithermal environment, and the signatures they leave.  相似文献   
82.
Many inclusions in Allende, particularly those with irregular shapes, are surrounded by a sequence of thin layers which differ from one another in texture, mineralogy and mineral-chemistry. The layer underlying all others contains either: IA, pyroxene needles + olivine + clumps of hedenbergite and andradite; IB, olivine doughnuts; or IC, rectangular olivine crystals. The next layer outward, II, contains tiny (<5 μm) olivine plates and Layer III large (5–10 μm) olivine laths. The final layer, IV, occurs as clumps of andradite + hedenbergite surrounded by magnesium-rich pyroxene needles. It separates Layer III from the Allende matrix which is more poorly sorted and more sulfide-rich than Layer III. Nepheline and iron sulfide are common constituents of most layers, the latter being particularly fine-grained and abundant in Layer II. Although not every layer is present on every inclusion, the sequence of layers is constant. Evidence that the rims are accretionary aggregates includes the presence of highly disequilibrium mineral assemblages and the fact that they are highly porous masses consisting of many euhedral crystals with few intergrowths. In addition, the layers are thickest in topographic hollows on the surfaces of inclusions and the inner layers are absent or discontinuous beyond such irregularities, suggesting that the probability of accretion of crystals was low initially, except in pockets, and became greater later, after a soft cushion of accreted condensate crystals had already formed. Separation of assemblages of different mineralogy, mineral-chemistry and texture into different rim layers seems best explained by nebular models in which long, slow cooling histories allow differentiation during condensation by grain/gas separation processes.  相似文献   
83.
Field observations of shoreline conditions at Hyrum Reservoir, Utah, were conducted during the summers of 1991 to 1993. A process of bluff retreat is described for a multiple-layered bluff environment of sand and clay layers. Failure is initiated by wetting and drying of clay sediments, which produces horizontal cracks within bluff material. These cracks appear to penetrate to a depth of approximately 100-150 mm before initiating vertical cracking in the sediments. The vertical cracks are propagated by continued drying of the surface sediment, ultimately leading to failure of the bluff material. The physical dimensions of sediment blocks succumbing to this mechanism range from a few hundred millimetres up to 3 m on a side, with a depth of approximately 100-150 mm. The mechanism described here appears to operate optimally when the supply of subsurface moisture is abundant and nearly continuous throughout the spring and early summer. Reservoir draw-down, large capillary fringe effects in the bluff and periodic wetting from upslope undrained hollows are the dominant moisture controls at this site. Moisture delivery to the face is strongly influenced by anisotropy of saturated hydraulic conductivity in the alternating clay and sand layers and related differences in sediment texture.  相似文献   
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86.
Interest in artificially recharging selected shallow sands in South Louisiana with fresh water has been stimulated by the desire to retard contamination of municipal groundwater supplies by brackish water, to retard ground subsidence and decrease pumping lifts, and to develop emergency subsurface supplies of potable water for communities dependent on surface waters susceptible to contamination. Results of field experiments, laboratory work, and model calculations demonstrate that ion exchange reactions involving clays dispersed in aquifer sands can be expected to modify significantly the composition of waters injected into Gulf Coast sediments. As little as 0.1 weight percent smectite (montmorillonite) can remove, by exchange with absorbed Na, a significant fraction of the dissolved Ca and Mg present in the injected water. The hardness of the water is thus reduced, which may be a desirable modification in water quality. Exchange occurs as fast as the fluids can be pumped into or out of the aquifer, and the water-softening capacity of the aquifer can be restored by allowing sodium-rich native pore waters to sweep back over the dispersed clays. Each acre of an aquifer 50 feet thick and containing 0.1 wt % smectite could soften half a million gallons of injected Mississippi River water. Many individual Gulf Coast aquifers underlie tens of thousands of acres, and their potential softening capacity is thus enormous. Additional exchange processes involving adjacent aquitard shales presumably will operate over long-term periods. It is possible that Gulf Coast aquifers will be used at some point in the future as processing plants to treat injected water to improve its quality for a variety of municipal and industrial purposes.  相似文献   
87.
Thermoluminescence sensitivity measurements have been made on 18 unequilibrated ordinary chondrites; 12 finds from Antarctica, 5 non-Antarctic finds and 1 fall. The TL sensitivities of these meteorites, normalized to Dhajala, range from 0.034 (St. Mary's County) to 2.3 (Allan Hills A78084), and, based primarily on these data, petrologic type assignments range from 3.3 (St. Mary's County) to 3.9 (Allan Hills A78084). Although the very low levels of metamorphism experienced by types 3.0 to ~3.4 evidently cause large changes in TL sensitivity, the new data demonstrate that they are unable to cause any appreciable homogenization of silicate compositions. We have therefore slightly revised the silicate heterogeneity ranges corresponding to the lower petrologic types.We have discovered that the temperature of maximum TL emission and the broadness of the major TL peak, vary systematically with TL sensitivity; as TL increases these parameters first decrease and then increase. Several mechanisms which could account, partially or completely, for the relationship between TL sensitivity and metamorphism are discussed. Those which involve the formation of feldspar—the TL phosphor in equilibrated meteorites—seem to be consistent with the trends in peak temperature and peak width since experiments on terrestrial albite show that the TL peak broadens and moves to higher temperatures as the stable form changes from the low (ordered) state to the high (disordered) state. (The post-metamorphism equilibration temperature of type ~3.5 meteorites would then correspond to the transformation temperature for the high to low form of meteorite feldspar.) Other factors which may be involved are obscuration of the TL by carbonaceous material, changes in the composition of the phosphor and changes in the identity of the phosphor.  相似文献   
88.
This study considered the rate at which striped bass larvae disintegrate following death as well as the ability of experienced taxonomists to distinguish larvae which were liver or dead on collection from preserved samples. The rate of disintegration was dependent on age (size) of the larvae with pro-larvae being unrecognizable in 8 to 16 h following death (17 to 19°C). Post-larvae decomposed somewhat more slowly, but were unrecognizable as to species after 16 h. Experienced taxonomists were unable to distinguish pro- and post-larvae which had been live or dead prior to preservation. However, the viability of metamorphosed larvae could readily be distinguished.  相似文献   
89.
Sediment accumulation rate studies utilizing excess 210Pb and 137Cs were conducted as part of recent investigations of biogeochemical cycling at a single site in Cape Lookout Bight, a rapidly changing coastal basin on the Outer Banks of North Carolina (U.S.A.). Cores three meters in length reveal a depositional history for the bight interior characterized by a gradual transition in texture from coarse-grained to fine-grained material over the period 1946–1979. This transition is controlled by progressive enclosure of the bight by an active northerly migrating recurved spit. The textural gradation is periodically interrupted by layers of well-sorted sand associated with major storm events. Lead-210 data indicate that the upper meter of the sediment has accumulated at a rate of 3.35 to 4.71 g · cm?2 · yr?1 or approximately 8.4 to 11.8 cm · yr?1 (at ø = 0.84). Below 120 cm depth, dilution of clay and silt by low activity sand necessitates correction of the 210Pb profile in order to establish a geochronology. Grain size 210Pb distribution measurements at three depths reveal that the specific activity (dpm · g?1) of clay is 3.2 times that of silt and 24.7 times that of sand. Corrections of bulk sediment excess 210Pb activities based on these measurements lead to dates for textural changes which are consistent with charted changes in basin morphology and major storm events.Sixteen 137Cs measurements between 33–241 cm depth reveal a peak activity at 105–115 cm and indicate a minimum sedimentation rate of approximately 2.7 g · cm?2 · yr?1.  相似文献   
90.
Both pyruvic and α-ketobutyric acids are formed during heating experiments with modern Chione shells. These α-keto acids are also present in fossil specimens. These findings provide additional evidence that the dehydration reaction of free serine and threonine or the β-elimination reaction of peptide bound serine and threonine occurred in fossil materials. These experiments suggest that the formation of α-keto acids occurs early in protein diagenesis. A large fraction of the α-keto acids which were formed have been lost either by subsequent reactions or by diffusion out of the shell matrix.  相似文献   
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