Statistical tests of chondrule sorting     

Seth A. TEITLER  Julie M. PAQUE  Jeffrey N. CUZZI  Robert C. HOGAN 《Meteoritics & planetary science》2010,45(7):1124-1135

Abstract– The variation in sizes of chondrules from one chondrite to the next is thought to be due to some sorting process in the early solar nebula. Hypotheses for the sorting process include chondrule sorting by mass and sorting by some aerodynamic mechanism; one such aerodynamic mechanism is the process of turbulent concentration (TC). We present the results of a series of statistical tests of chondrule data from several different chondrites. The data do not clearly distinguish between various options for the sorting parameter, but we find that the data are inconsistent with being drawn from lognormal or (three‐parameter) Weibull distributions in chondrule radius. We also find that all but one of the chondrule data sets tested are consistent with being drawn from the TC distribution.  相似文献   

EC 11481–2303—a peculiar subdwarf OB star revisited     

Thomas Rauch  Klaus Werner  Jeffrey W. Kruk 《Astrophysics and Space Science》2010,329(1-2):133-139

EC?11481–2303 is a peculiar, hot, high-gravity pre-white dwarf. Previous optical spectroscopy revealed that it is a sdOB star with T _eff=41?790 K, log?g=5.84, and He/H = 0.014 by number. We present an on-going spectral analysis by means of non-LTE model-atmosphere techniques based on high-resolution, high-S/N optical (VLT-UVES) and ultraviolet (FUSE, IUE) observations.We are able to reproduce the optical and UV observations simultaneously with a chemically homogeneous NLTE model atmosphere with a significantly higher effective temperature and lower He abundance (T _eff=55?000 K, log?g=5.8, and He/H=0.0025 by number). While C, N, and O appear less than 0.15 times solar, the iron-group abundance is strongly enhanced by at least a factor of ten.  相似文献   

Mercury surface composition: Integrating petrologic modeling and remote sensing data to place constraints on FeO abundance     

Miriam A. Riner  Francis M. McCubbin  G. Jeffrey Talyor 《Icarus》2010,209(2):301-313

A significant opaque component in Mercury’s crust is inferred based on albedo and spectral observations. Previous workers have favored iron-titanium bearing oxide minerals as the spectrally neutral opaque. A consequence of this hypothesis is that Mercury’s surface would have a high FeO content. An array of remote sensing techniques have not provided definitive constraints on the FeO content of Mercury’s surface. However, spectral observations have not detected a diagnostic 1 μm absorption band and have thus limited the FeO in coexisting silicates to <2 wt.% FeO. In this paper, we assess equilibrium among oxide and silicate minerals to constrain the distribution of iron between opaque oxides and silicates under a variety of environmental conditions. Equilibrium modeling is favored here because the geologic process that produced Mercury’s low-albedo intermediate terrain must have occurred globally, which favors a common widespread igneous process. Based on our modeling, we find that iron-rich ilmenite cannot occur with silicates that do not display a 1 μm absorption feature unless plagioclase abundances are high. However, such high plagioclase abundances are precluded by Mercury’s low albedo. Incorporating equilibrium crystallization modeling with spectral and albedo constraints we find the iron abundance of Mercury’s intermediate terrain is ?10 wt.% FeO. This intermediate iron composition matches constraints provided by visible albedo and total neutron absorption observed by MESSENGER. In fact, the total neutron absorption of mixtures of oxide, plagioclase, olivine and pyroxene for the oxide abundances estimated for Mercury, favor Mg-rich members of the ilmenite-geikielite solid-solution series. This work offers compositional constraints for Fe, Ti, and Mg that will be testable by various MESSENGER instrument data sets after it begins its orbital mission.  相似文献   

Migrating magmatism in the northern US Cordillera: in situ U–Pb geochronology of the Idaho batholith     

Richard M. Gaschnig  Jeffrey D. Vervoort  Reed S. Lewis  William C. McClelland 《Contributions to Mineralogy and Petrology》2010,159(6):863-883

New in situ laser ablation-inductively coupled plasma-mass spectrometry and sensitive high-resolution ion microprobe U–Pb geochronology of zircons from the Idaho batholith and spatially overlapping Challis intrusions reveals a series of discrete magmatic belts of different ages and compositions. Following the accretion of the Blue Mountains province to North America along the Salmon River suture zone, two compositionally diverse belts of metaluminous plutons formed both adjacent to the suture and well inboard of it. These were constructed from ~100 to 85 Ma and were followed by a voluminous pulse of peraluminous magmatism, forming the bulk of the Atlanta lobe and largest fraction of the batholith between ~80 and 67 Ma. Around 70 Ma, a later and more spatially restricted suite of metaluminous plutons formed around the Bitterroot lobe of the batholith. This was followed by another pulse of voluminous peraluminous magmatism in the Bitterroot lobe, lasting from ~66 to 54 Ma. The changes from low volume metaluminous to high volume peraluminous magmatism may reflect a combination of changes in the angle and segmentation of the subducting Farallon plate and over thickening of the continental lithosphere. All of these features were then cut by plutons and dikes associated with the Challis volcanic field, lasting from ~51 to 43 Ma. Inherited components are pervasive in zircons from most phases of the batholith. While Precambrian components are very common, zircons also often contain cores or mantles that are 5–20 million years older than their rims. This suggests that the early phases of the batholith were repeatedly cannibalized by subsequent magmas. This also implies that the older suites may have been originally more aerially extensive than their currently exposed forms.  相似文献   

Structure and oxidation state of hematite surfaces reacted with aqueous Fe(II) at acidic and neutral pH     

Jeffrey G. Catalano  Paul Fenter  Zhan Zhang 《Geochimica et cosmochimica acta》2010,74(5):1498-182

Structural changes and surface oxidation state were examined following the reaction of hematite (0 0 1), (0 1 2), and (1 1 0) with aqueous Fe(II). X-ray reflectivity measurements indicated that Fe(II) induces changes in the structure of all three surfaces under both acidic (pH 3) and neutral (pH 7) conditions. The structural changes were generally independent of pH although the extent of surface transformation varied slightly between acidic and neutral conditions; no systematic trends with pH were observed. Induced changes on the (1 1 0) and (0 1 2) surfaces include the addition or removal of partial surface layers consistent with either growth or dissolution. In contrast, a <1 nm thick, discontinuous film formed on the (0 0 1) surface that appears to be epitaxial yet is not a perfect extension of the underlying hematite lattice, being either structurally defective, compositionally distinct, or nanoscale in size and highly relaxed. Resonant anomalous X-ray reflectivity measurements determined that the surface concentration of Fe(II) present after reaction at pH 7 was below the detection limit of approximately 0.5-1 μmol/m² on all surfaces. These observations are consistent with Fe(II) oxidative adsorption, whereby adsorbed Fe(II) is oxidized by structural Fe(III) in the hematite lattice, with the extent of this reaction controlled by surface structure at the atomic scale. The observed surface transformations at pH 3 show that Fe(II) oxidatively adsorbs on hematite surfaces at pH values where little net adsorption occurs, based on historical macroscopic Fe(II) adsorption behavior on fine-grained hematite powders. This suggests that Fe(II) plays a catalytic role, in which an electron from an adsorbed Fe(II) migrates to and reduces a lattice Fe(III) cation elsewhere, which subsequently desorbs in a scenario with zero net reduction and zero net adsorption. Given the general pH-independence and substantial mass transfer involved, this electron and atom exchange process appears to be a significant subsystem within macroscopic pH-dependent Fe(II) adsorption.  相似文献   

Low-molecular weight hydrocarbons in vent fluids from the Main Endeavour Field, northern Juan de Fuca Ridge     

Anna M. Cruse  Jeffrey S. Seewald 《Geochimica et cosmochimica acta》2010,74(21):6126-6140

Despite its location on sediment-free basalt, vent fluids from the Main Endeavour Field (MEF) contain chemical species that indicate fluids have interacted with sediments during circulation. We report on the distribution and isotopic abundances of organic compounds (C₁-C₃ alkanes and alkenes, benzene and toluene) in fluids collected from the Main Endeavour Field (MEF) in July, 2000, to understand the processes that regulate their abundances and characterize fluid sources. Aqueous organic compounds are derived from the thermal alteration of sedimentary organic matter and subsequently undergo further oxidation reactions during fluid flow. Fluid:sediment mass ratios calculated using ΣNH₄ concentrations indicate that the sediments are distal to the MEF, resulting in a common reservoir of fluids for all of the vents. Following the generation from sediment alteration, aqueous organic compounds undergo secondary alteration reactions via a stepwise oxidation reaction mechanism. Alkane distributions and isotopic compositions indicate that organic compounds in MEF fluids have undergone a greater extent of alteration as compared to Middle Valley fluids, either due to differences in subsurface redox conditions or the residence time of fluids at subsurface conditions. The distributions of the aromatic compounds benzene and toluene are qualitatively consistent with the subsurface conditions indicated by equilibration of aqueous alkanes and alkanes. However, benzene and toluene do not achieve chemical equilibrium in the subsurface. Methane and CO₂ also do not equilibrate chemically or isotopically at reaction zone temperatures, a likely result of an insufficient reaction time after addition of CO₂ from magmatic sources during upflow. The organic geochemistry supports the assumption that the sediments with which MEF fluids interact has the same composition as sediments present in Middle Valley itself, and highlight differences in subsurface reaction zone conditions and fluid flow pathways at these two sites.  相似文献   

The Triassic age for oceanic eclogites in the Dabie orogen: Entrainment of oceanic fragments in the continental subduction     

Hao Cheng  S. Andrew DuFrane  Jeffrey D. Vervoort  Eizo Nakamura  Qiuli Li  Zuyi Zhou 《Lithos》2010,117(1-4):82-98

Low-temperature and high-pressure eclogites with an oceanic affinity in the western part of the Dabie orogen have been investigated with combined Lu–Hf and U–Pb geochronology. These eclogites formed over a range of temperatures (482–565 °C and 1.9–2.2 GPa). Three eclogites, which were sampled from the Gaoqiao country, yielded Lu–Hf ages of 240.7 ± 1.2 Ma, 243.3 ± 4.1 Ma and 238.3 ± 1.2 Ma, with a corresponding lower-intercept U–Pb zircon age of 232 ± 26 Ma. Despite the well-preserved prograde major- and trace-element zoning in garnets, these Lu–Hf ages mostly reflect the high-pressure eclogite-facies metamorphism instead of representing the early phase of garnet growth due to the occurrence of omphacite inclusions from core to rim and the shell effect. An upper-intercept zircon U–Pb age of 765 ± 24 Ma is defined for the Gaoqiao eclogite, which is consistent with the weighted-mean age of 768 ± 21 Ma for the country gneiss. However, the gneiss has not been subjected to successive high-pressure metamorphism. The new Triassic ages are likely an estimate of the involvement of oceanic fragments in the continental subduction.  相似文献   

Submarine channel levee shape and sediment waves from physical experiments     

Ian A. Kane  William D. McCaffrey  Jeffrey Peakall  Benjamin C. Kneller 《Sedimentary Geology》2010,223(1-2):75-85

Submarine channel levees aggrade through repeated overspill events from the channel axis. The shape of the levees may therefore reflect some characteristic(s) of the overspilling flow. It has been noted that basin floor levees typically have a relatively low-relief and taper exponentially to their termination; in contrast slope channel levees may be much steeper close to the channel. A simple physical experiment was performed where a surge-like sediment-laden current flowed through a curved channel. Significant overspill occurred and generated a deposit flanking the channel on either side. The experiment was repeated 25 times to build up low-relief channel-levees. It was found that in proximal areas, levees were steep and characterised by power-law decays, a transitional zone of logarithmically thinning levee was found a little further down-channel, followed by exponential decays in medial to distal areas. The style of levee decay is a function of spatial variation in overbank sedimentation rates. Where flows rapidly lose momentum and deposit across the grain-size spectrum, i.e., in proximal areas, levees tend to be steep; farther down the channel, the steep levee slope gives way to a more gradually tapering deposit. In more distal parts of the channel, deposition is directly related to sediment settling velocity (rather than the suspended load exceeding flow transport capacity as is the case in proximal areas), the deposit reflects this with relatively simple exponential thickness decays. Additionally, small-scale sediment waves developed under lee wave conditions on the inner-bend overbank. The waves initially migrated slightly towards the channel, but as the style of overspill evolved due to intra-channel deposition, flows moved out of the lee wave window and sedimentation became out of phase with the wavelength of the features and the topography was healed.  相似文献   

Mineralization of contaminant uranium and leach rates in sediments from Hanford,Washington     

Christopher F. Brown  R. Jeffrey Serne  Jeffrey G. Catalano  Kenneth M. Krupka  Jonathan P. Icenhower 《Applied Geochemistry》2010

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Phosphorus Burial in Sediments Along the Salinity Gradient of the Patuxent River,a Subestuary of the Chesapeake Bay (USA)   总被引：2，自引：0，他引：2  

Jeanne L. Hartzell  Thomas E. Jordan  Jeffrey C. Cornwell 《Estuaries and Coasts》2010,33(1):92-106

We used a sequential extraction technique and ²¹⁰Pb dating to determine the chemical form and amount of particulate phosphorus (PP) that is retained during burial in 1-m-long sediment cores collected along a salinity gradient from tidal freshwater to the mesohaline waters of the Patuxent River, a subestuary of the Chesapeake Bay. PP buried in the study sites with salinity values ≤3 was similar in concentration and form to PP entering the Patuxent from the watershed, suggesting efficient sequestration by the sediments at these low-salinity sites. PP extracted with citrate–dithionite–bicarbonate was the dominant form of PP at all salinities and all depths, and organic-P was the second most abundant fraction. We estimated that 81% of PP entering from the watershed is trapped in the sediments of the upper Patuxent subestuary and that the subtidal sediments retain three times as much PP as the marshes adjacent to the study sites.  相似文献