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In 1983, Lay and Helmberger [Geophys. J. R. Astron. Soc. 75 (1983) 799–837] reported the detection of a precursor to the seismic phase ScS. They attributed this precursor to a sharp seismic discontinuity located several hundred kilometers above the core–mantle boundary. Such a lowermost mantle discontinuity implies the existence of a sharp phase change or a chemical boundary. Precursors to ScS and, less frequently, PcP have since been observed in numerous locations, but are not a global phenomenon. Frequently, PcP precursors are weak or absent when ScS precursors are observed in the same location, and vice versa. There can be significant variations in the amplitude and arrival time of the precursor relative to the main phase. The presence or absence of these precursors has led to speculations about the nature of the lowermost mantle. Here we demonstrate that ScS or PcP precursors may be produced by gradients in seismic wave speed associated with large-scale lowermost mantle heterogeneity. Rather than a phase or chemical boundary with substantial topography, such gradients require lateral variations in temperature and, close to the core–mantle boundary, composition.  相似文献   
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We present a complete ray theory for the calculation of surface-wave observables from anisotropic phase-velocity maps. Starting with the surface-wave dispersion relation in an anisotropic earth model, we derive practical dynamical ray-tracing equations. These equations allow calculation of the observables phase, arrival-angle and amplitude in a ray theoretical framework. Using perturbation theory, we also obtain approximate expressions for these observables. We assess the accuracy of the first-order approximations by using both theories to make predictions on a sample anisotropic phase-velocity map. A comparison of the two methods illustrates the size and type of errors which are introduced by perturbation theory. Perturbation theory phase and arrival-angle predictions agree well with the exact calculation, but amplitude predictions are poor. Many previous studies have modelled surface-wave propagation using only isotropic structure, not allowing for anisotropy. We present hypothetical examples to simulate isotropic modelling of surface waves which pass through anisotropic material. Synthetic data sets of phase and arrival angle are produced by ray tracing with exact ray theory on anisotropic phase-velocity maps. The isotropic models obtained by inverting synthetic anisotropic phase data sets produce deceptively high variance reductions because the effects of anisotropy are mapped into short-wavelength isotropic structure. Inversion of synthetic arrival-angle data sets for isotropic models results in poor variance reductions and poor recovery of the isotropic part of the anisotropic input map. Therefore, successful anisotropic phase-velocity inversions of real data require the inclusion of both phase and arrival-angle measurements.  相似文献   
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Spatial decision support systems (SDSS) are designed to make complex resource allocation problems more transparent and to support the design and evaluation of allocation plans. Recent developments in this field focus on the design of allocation plans using optimization techniques. In this paper we analyze how uncertainty in spatial (input) data propagates through, and affects the results of, an optimization model. The optimization model calculates the optimal location for a ski run based on a slope map, which is derived from a digital elevation model (DEM). The uncertainty propagation is a generic method following a Monte Carlo approach, whereby realizations of the spatially correlated DEM error are generated using 'sequential Gaussian simulation'. We successfully applied the methodology to a case study in the Austrian Alps, showing the influence of spatial uncertainty on the optimal location of a ski run and the associated development costs. We also discuss the feasibility of routine incorporation of uncertainty propagation methodologies in an SDSS.  相似文献   
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Abstract Positive shifts in global seawater δ13CDIC are related to changes in the ratio of organic relative to inorganic carbon burial in oceanic basins, whereas factors such as climatic cooling and the accumulation of polar ice are known to cause positive shifts in δ18O. Here, an alternative model is proposed for the formation of local positive isotope shifts in shallow-marine settings. The model involves geochemically altered platform-top water masses and the effects of early meteoric diagenesis on carbonate isotopic composition. Both mechanisms are active on modern (sub)tropical carbonate platforms and result in low carbonate δ13C and δ18O relative to typical oceanic values. During high-amplitude transgressive events, the impact of isotopically light meteoric fluids on the carbonate geochemistry is much reduced, and 13C-depleted platform-top water mixes with open oceanic water masses having higher isotope values. Both factors are recorded as a transient increase in carbonate 13C and 18O relative to low background values. These processes must be taken into consideration when interpreting the geochemical record of ancient epeiric seas.  相似文献   
46.
Under natural conditions, the adsorption of ions at the solid-water interface may be strongly influenced by the adsorption of organic matter. In this paper, we describe the adsorption of fulvic acid (FA) by metal(hydr)oxide surfaces with a heterogeneous surface complexation model, the ligand and charge distribution (LCD) model. The model is a self-consistent combination of the nonideal competitive adsorption (NICA) equation and the CD-MUSIC model. The LCD model can describe simultaneously the concentration, pH, and salt dependency of the adsorption with a minimum of only three adjustable parameters. Furthermore, the model predicts the coadsorption of protons accurately for an extended range of conditions. Surface speciation calculations show that almost all hydroxyl groups of the adsorbed FA molecules are involved in outer sphere complexation reactions. The carboxylic groups of the adsorbed FA molecule form inner and outer sphere complexes. Furthermore, part of the carboxylate groups remain noncoordinated and deprotonated.  相似文献   
47.
Oceanic plateaus, aseismic ridges or seamount chains all have a thickened crust and their subduction has been proposed as a possible mechanism to explain the occurrence of flat subduction and related absence of arc magmatism below Peru, Central Chile and at the Nankai Trough (Japan). Their extra compositional buoyancy could prohibit the slab from sinking into the mantle. With a numerical thermochemical convection model, we simulated the subduction of an oceanic lithosphere that contains an oceanic crustal plateau of 18-km thickness. With a systematic variation, we examined the required physical parameters to obtain shallow flat subduction. Metastability of the basaltic crust in the eclogite stability field is of crucial importance for the slab to remain buoyant throughout the subduction process. In a 44-Ma-old subducting plate, basalt must be able to survive a temperature of 600–700 °C to keep the plate buoyant sufficiently long to cause a flat-slab segment. We found that the maximum yield stress in the slab must be limited to about 600 MPa to allow for the necessary bending to the horizontal. Young slabs show flat subduction for larger parameter ranges than old slabs, since they are less gravitationally unstable and show less resistance against bending. Hydrous weakening of the mantle wedge area and lowermost continent are required to allow for the necessary deformation of a change in subduction style from steep to flat. The maximum flat slab extent is about 300 km, which is sufficient to explain the observed shallow flat subduction near the Nankai Trough (Japan). However, additional mechanisms, such as active overthrusting by an overriding continental plate, need to be invoked to explain the flat-slab segments up to 500 km long below Peru and Central Chile.  相似文献   
48.
We study the mechanical deformation of fractures under normal stress, via tangent and specific fracture stiffnesses, for different length scales using numerical simulations and analytical insights. First, we revisit an equivalent elastic layer model that leads to two expressions: the tangent stiffness is the sum of an “intrinsic” stiffness and the normal stress, and the specific stiffness is the tangent stiffness divided by the fracture aperture at current stress. Second, we simulate the deformation of rough fractures using a boundary element method where fracture surfaces represented by elastic asperities on an elastic half‐space follow a self‐affine distribution. A large number of statistically identical “parent” fractures are generated, from which sub‐fractures of smaller dimensions are extracted. The self‐affine distribution implies that the stress‐free fracture aperture increases with fracture length with a power law in agreement with the chosen Hurst exponent. All simulated fractures exhibit an increase in the specific stiffness with stress and an average decrease with increase in length consistent with field observations. The simulated specific and tangent stiffnesses are well described by the equivalent layer model provided the “intrinsic” stiffness slightly decreases with fracture length following a power law. By combining numerical simulations and the analytical model, the effect of scale and stress on fracture stiffness measures can be easily separated using the concept of “intrinsic” stiffness. We learn that the primary reason for the variability in specific stiffness with length comes from the fact that the typical aperture of the self‐affine fractures itself scales with the length of the fractures.  相似文献   
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