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Changling He Jesper Bartholdy Christian Christiansen 《Environmental Earth Sciences》2012,67(3):759-769
To understand the behavior of trace metals in the salt marsh at Skallingen, Danish Wadden Sea, we investigated a profile from surface to 25?cm depth of the salt marsh sediment, focusing primarily on clay mineralogy and grain size distribution of the sediments and their relationship with trace metals. The clay assembly of the sediment consists of illite, kaolinite and much less chlorite and smectite. The major clay minerals of illite, kaolinite as well as chlorite correlate very poorly with all the trace metals investigated, due probably to the weak competing strength of these clays compared with the other adsorbents and to low availability of the mobile trace metals in the system. Correlation between trace metals and clay minerals may therefore be used as an indicator in environmental assessment. Fine grain fractions of the sediment increased markedly after salt marsh invasion in about 1931 but decreased after 1964. This increase was contributed mainly by the grains finer than 20???m while the fraction of 40?C63???m actually decreased soon after the invasion. The relation between most of the trace metals and grain size distributions is close in general but far from linear. The drastic turning point is observed at about 30???m, around where the correlation coefficient r drops from 0.8 to 0.1. Adsorption is the controlling mechanism for the behavior of trace metals in the salt marsh. Fe/Mn (hydr)oxides and organic matter play the key role. 相似文献
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Novaya Zemlya was covered by the eastern part of the Barents–Kara ice sheet during the glacial maximum of marine isotope stage 2 (MIS 2). We obtained 14 C ages on 37 samples of mollusc shells from various sites on the islands. Most samples yielded ages in the range of 48–26 14 C Ky. Such old samples are sensitive to contamination by young 14 C, and therefore their reliability was assessed using replicate analyses and amino acid geochronology. The extent of aspartic acid racemization (Asp D/L) indicates that many of the 14 C ages are correct, whereas some are minimum ages only. The results indicate that a substantial part of Novaya Zemlya was ice-free about 35–27 14 C Kya, and probably even earlier. Corresponding shorelines up to >140 m a.s.l. indicate a large Barents–Kara ice sheet during early MIS 3. These results are consistent with findings from Svalbard and northern Russia: in both places a large MIS 4/3 Barents–Kara ice sheet is postulated to have retreated about 50 Kya, followed by an ice-free interstadial that lasted until up to ca. 25 Kya. The duration of the MIS 2 glaciation in Novaya Zemlya was calculated by applying the D/L values to a kinetic equation for Asp racemization. This indicates that the islands were ice covered for less than 3000 years if the basal temperature was 0o C, and for less than 10 000 years if it was −5o C. 相似文献
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Jesper Rasmussen † Trevor J. Ponman Lourdes Verdes-Montenegro Min S. Yun Sanchayeeta Borthakur 《Monthly notices of the Royal Astronomical Society》2008,388(3):1245-1264
Galaxies in compact groups tend to be deficient in neutral hydrogen compared to isolated galaxies of similar optical properties. In order to investigate the role played by a hot intragroup medium (IGM) for the removal and destruction of H i in these systems, we have performed a Chandra and XMM–Newton study of eight of the most H i deficient Hickson compact groups. Diffuse X-ray emission associated with an IGM is detected in four of the groups, suggesting that galaxy–IGM interactions are not the dominant mechanism driving cold gas out of the group members. No clear evidence is seen for any of the members being currently stripped of any hot gas, nor for galaxies to show enhanced nuclear X-ray activity in the X-ray bright or most H i deficient groups. Combining the inferred IGM distributions with analytical models of representative disc galaxies orbiting within each group, we estimate the H i mass-loss due to ram-pressure and viscous stripping. While these processes are generally insufficient to explain observed H i deficiencies, they could still be important for H i removal in the X-ray bright groups, potentially removing more than half of the interstellar medium in the X-ray bright HCG 97. Ram pressure may also have facilitated strangulation through the removal of galactic coronal gas. In X-ray undetected groups, tidal interactions could be playing a prominent role, but it remains an open question whether they can fully account for the observed H i deficiencies. 相似文献
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Abyssal recipes II: energetics of tidal and wind mixing 总被引:11,自引:0,他引:11
Walter Munk Carl Wunsch 《Deep Sea Research Part I: Oceanographic Research Papers》1998,45(12):1977-2010
Without deep mixing, the ocean would turn, within a few thousand years, into a stagnant pool of cold salty water with equilibrium maintained locally by near-surface mixing and with very weak convectively driven surface-intensified circulation. (This result follows from Sandström’s theorem for a fluid heated and cooled at the surface.) In this context we revisit the 1966 “Abyssal Recipes”, which called for a diapycnal diffusivity of 10-4m2/s (1 cgs) to maintain the abyssal stratification against global upwelling associated with 25 Sverdrups of deep water formation. Subsequent microstructure measurements gave a pelagic diffusivity (away from topography) of 10-5 m2/s — a low value confirmed by dye release experiments.A new solution (without restriction to constant coefficients) leads to approximately the same values of global upwelling and diffusivity, but we reinterpret the computed diffusivity as a surrogate for a small number of concentrated sources of buoyancy flux (regions of intense mixing) from which the water masses (but not the turbulence) are exported into the ocean interior. Using the Levitus climatology we find that 2.1 TW (terawatts) are required to maintain the global abyssal density distribution against 30 Sverdrups of deep water formation.The winds and tides are the only possible source of mechanical energy to drive the interior mixing. Tidal dissipation is known from astronomy to equal 3.7 TW (2.50±0.05 TW from M2 alone), but nearly all of this has traditionally been allocated to dissipation in the turbulent bottom boundary layers of marginal seas. However, two recent TOPEX/POSEIDON altimetric estimates combined with dynamical models suggest that 0.6–0.9 TW may be available for abyssal mixing. A recent estimate of wind-driving suggests 1 TW of additional mixing power. All values are very uncertain.A surprising conclusion is that the equator-to-pole heat flux of 2000 TW associated with the meridional overturning circulation would not exist without the comparatively minute mechanical mixing sources. Coupled with the findings that mixing occurs at a few dominant sites, there is a host of questions concerning the maintenance of the present climate state, but also that of paleoclimates and their relation to detailed continental configurations, the history of the Earth–Moon system, and a possible great sensitivity to details of the wind system. 相似文献
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Rapid recharge of fresh water to the halite‐hosted brine aquifer of Salar de Atacama,Chile
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We document, analyse, and interpret direct and rapid infiltration of precipitation to the southern margin of the Salar de Atacama halite‐hosted brine aquifer during two intense precipitation events in 2012–2013. We present physical, geochemical, and stable and radioactive isotope data to detail this influx of water. The two events differ distinctly in the mechanisms of recharge. The 2012 event did not produce direct precipitation onto the salar surface, while the 2013 event did. Both events are recorded by abrupt changes in head in observation wells along the halite aquifer margin. Spatially distributed water levels rose by over 30 cm during the larger 2013 event consistent with remotely sensed observations of surface water extent. The lithium concentration and stable isotopic composition of water indicate dilution of brine and dissolution of salt with fresh water. Tritium measurements of precipitation, surface water, and groundwater all indicate modern influx of water to the halite aquifer along the southern margin. We extend these observations by examining the response of the halite aquifer as a whole to precipitation events during the period of 2000–2010. This study suggests that local recharge to the aquifer during sporadic precipitation onto the halite nucleus is an important component of the modern water budget in this hyper‐arid environment. The rapid dissolution and salinization along the southern margin of the salar halite nucleus are aided by such precipitation events contributing a modern fresh water component to the water budget of the economically valuable lithium‐rich brine. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献