Ab initio calculated electron densities for tetrahedral sheet [H2Si2O5]∞ in phyllosilicates     

Ľ. Benco  Ľ. Smrčok 《Physics and Chemistry of Minerals》1994,21(6):401-406

Periodic ab initio Hartree-Fock LCAO calculations have been carried out on the two dimensional sheet of SiO₄ tetrahedra, representing one of the basic constituting units of layer silicates, using Huzinaga's DZP basis sets. The influence of the basis set on the chemical bonding picture is characterized by Mulliken atomic charges and by electron density maps. Silicon atomic charges +1.6 ¦e¦ are more realistic than those +2.4 ¦e¦ reported for smaller basis sets. The silicon d orbital population is found to be 0.6 in close agreement with molecular data. Electron density maps indicate the absence of charge density in the center of the ditrigonal cavity. The charge buildup of nonbonding basal oxygen orbitals is directed mainly downwards perpendicular to the sheet plane.  相似文献   

Geomagnetic activity as a possible cause of changes in the middle atmosphere and troposphere; observations made in Prague in the years 1932–1987     

Josef Bochníček  Josef Pýcha 《Studia Geophysica et Geodaetica》1994,38(1):103-107

Summary A possible relation between the 10-day, 1-month, and 2-month geomagnetic as well as solar activity, characterized by Kp and Wolf's number R, and temperatures measured at the Prague-Klementinum meteorological station in January–February of the years 1932–1987 was sought. It was found that:1) Kp correlates with the temperature in Prague better than Wolf's number R.2) If the QBO phase is taken into account, the correlations improve.3) Even if the correlations improves with increasing length of the subintervals into which the individual winter periods (January-February) were derived, their statistical significance declines.  相似文献   

Densities of Huanghe River estuary and Bohai Bay waters     

陈国华  季荣  谢式南  张力军 《中国海洋湖沼学报》1994,12(2):130-135

The densities of 36 water samples from the Huanghe River estuary and Bohai Bay were determinedby a magnetic float densimcter under three temperatures from 15℃ to 25℃.All the measured densities ofsamples were greater than that of the values calculated from the International Equation of State of Seawater.The differences between the measured and calculated densities increased with the decrease of salinities.The dif-ferences appeared exponentially correlated with[Ca~(2+)]/s,[Mg~(2+)]/s and[SO_4~(2-)]/s,and had"s"type curverelationship with the alkalinity in all salinity range.But in the salinity ranging from 25.72 to 31.57,therelationships were all linear.The density difference can be estimated from the equation △ρ（10~3kg·m~(-3)）=（-2.79+236.5([Ca~(2+)]/s)/(-9.7464×10~（-3）+[Ca~(2+)]/s).It was the high alkalinity and[Ca~(2+)]/s that resulted in the measured densi-ties of seawaters being higher than the calculated densities in the Huanghe estuary and Bohai Bay.  相似文献   

Magnetic properties,self-reversal remanence and thermal alteration products of smythite     

Miroslav Krs  František Novák  Marta Krsová  Petr Pruner  Jiří Jansa 《Studia Geophysica et Geodaetica》1993,37(4):382-400

Summary This study is a follow up of the investigation of some magnetic properties and metastability of greigite in samples obtained from Miocene claystones in the Kruné hory (Erzgebirge) Piedmont basins (Bohemia). Three different methods of upgrading the smythite were applied; the magnetic properties of the concentrates are compared. The thermal conversion of smythite sets in at 200°C while greigite converts at 250°C. The first intermediate products to be formed are iron sulphides, marcasite clearly dominating over pyrite and pyrrhotite. Apart from a Fe³⁺ sulphate with a composition of Fe₂(SO₄)₃, oxidation of these sulphides gives rise to -Fe₂O₃. The result of the subsequent decomposition of the mentioned sulphate is the formation of -Fe₂O₃, which retains the sulphate structure. The final product of the thermal decomposition at 800°C is -Fe₂O₃. In the smythite concentrate the conversion to Fe³⁺ sulphate and -Fe₂O₃ is about twice as intensive as in greigite. No direct conversion to -Fe₂O₃ was found. During the thermal process self-reversals of remanence were observed, in various samples as many as four reversals in the temperature interval from 340 to 590°C. The occurrences of self-reversals of remanence were only observed at high degrees of thermal demagnetization, of the order of 10^–2 down to 10^–3 in the temperature interval of sulphide origin (below 400°C), and of the order of 10^–4 down to 10^–6 in the temperature interval of Fe-oxides origin (above 400°C).Presented at the 3rd Conference on New Trends in Geomagnetism, Castle of Smolenice, Czechoslovakia, June 22–29, 1992  相似文献   

Dust particle and solar radiation     

J. Klačka  J. Kaufmannová 《Earth, Moon, and Planets》1993,61(1):63-65

Influence of the solar radiation (electromagnetic and corpuscular - solar wind) on the motion of the interplanetary dust particle is investigated. The ratio time of inspiralling toward the Sun: time of inspiralling neglecting the change of mass of the particle is presented as a function of initial eccentricities.  相似文献   

The effect of an optically thin region on stability of an accretion disk around a supermassive black hole     

B. F. Liu  G. Z. Xie  K. F. Ji 《Astrophysics and Space Science》1995,225(2):299-314

We analyse conditions of the innermost portion of an accretion disk and establish a set of equations for this region. A stable innermost region may exist, which can probably explain the observed UV and X-ray spectra, avoiding the unstable emission. We then discuss the detailed radial structure of a disk around a black hole for typical AGN parameters and obtain different kinds of- relationships for different regions of a disk. On the basis of this, we discuss the stability. A new type of cycle is present, which we call a double S shaped cycle. In this cycle, the extent of accretion rate variability is much larger than that in dwarf nova cycles. This probably solves the problem of violent variability of AGN. In the meantime, the very high accretion rate at the hottest state in limit cycles in the unstable region may provide continuous injection of matter to the jet and power the relativistic motion of the jet.  相似文献   

Containment of an adiabatic plasma on magnetic lines of force by a self-generated electrostatic field     

A. Hruška 《Astrophysics and Space Science》1977,50(1):153-161

One component of a three-fluid adiabatic plasma is under certain conditions contained in a restricted region of space by a large-scale electrostatic field generated within the plasma. The containment is discussed here for plasma consisting of ions and two populations of electrons characterized by different pitch angle distribution functions.The bouncing motion of electrons along open fieldlines between a magnetic mirror and an electrostatic mirror produces a velocity distribution function similar to that generated by bouncing particles on closed fieldlines.  相似文献   

Problems connected with the tangential metric coefficient in the Schwarzschild metric: A possible solution     

Pavel Voráček 《Astrophysics and Space Science》1982,81(1-2):85-94

Four situations are shown where the Schwarzschild metric cannot be used or is subject to unsurmountable problems. The first is the question of a metric useful for PPN-formalism checking different gravitational theories. The second problem occurs in connection with Mach's principle, when the flatness of the spacetime inside a massive hollow sphere is a generally accepted solution. The metrical discontinuity on the same spherical shell is a third problem. The fourth one is the anisotropy of the mass-energy of a test particle in the gravitational field. Three principles for solution are proposed:

1. The space is not dilated, but rather contracted, in the gravitational field; then the measurement-rods are shorter and measured distances have greater magnitudes.
2. The potential energy is to be related to a potential level where a stationary observer is placed and the general relativistic potential must be used.
3. A new metric must be introduced which is distinct from the Schwarzschild metric, so that the space in the gravitational field is warped isotropically.

Then the problems stated are shown to be easily solvable.  相似文献   

TheoreticalPKIKP magnitude determination     

J. Janský  M. Kvasnička 《Studia Geophysica et Geodaetica》1992,36(1):20-25

Summary The estimation of the theoretical magnitude for deep foci based on the vertica component of medium-period PKIKP waves, Earth model PREM and source spectra is presented. The given graphs are valid for period T ranging from 1·6 s to 10 s, source depth of 25 km to 600 km and distance range of 16 500 km to 19 800 km. A simplified method of representing calibration curves is used.  相似文献   

Investigation of the instability of graveyard orbits due to the earth's gravitational perturbations     

Jan Kostelecký  Jaroslav Klokočník 《Studia Geophysica et Geodaetica》1992,36(4):297-301

Summary The Banach theorem is applied to the Lagrange planetary equation for the semimajor axis of a geostationary satellite orbit to estimate the stability of near-geostationary satellite orbits. To achieve a graveyard (disposal) orbit, which will not interfere (=cross) the initial geostationary orbit, the geostationary semi-major axis a_g have to be increased at least by 50 km. Numerical results for a variety of graveyard orbits show that the increase of a_g by about 100 km will yield sufficiently stable orbits (accounting for the Earth's gravitational perturbations only) during the next 150 years.Dedicated to the 75th Birthday of Professor Academician Tibor Kolbenheyer  相似文献