Adsorption of aluminium by a latosol as affected by phosphate and glutamic acid     

Jie Wen Yang  Rong Fa Guo  Sheng Qi Chen 《Environmental Geology》2006,50(6):867-871

The effect of phosphate and glutamic acid on adsorption of aluminium onto a latosol was investigated as a function of pH and ligand concentrations through batch equilibrium experiments. The results showed that adsorption of aluminium by the soil was enhanced after addition of phosphate at low pH, and this promotive effect was gradually eliminated with the increase in pH. The positive effect of phosphate on aluminium adsorption onto latosol was attributed to phosphate-induced surface negative charge and formation of ternary surface complexes involving aluminium and phosphate. While using silica as adsorbent, the inactive surfaces for phosphate, promotion of adsorption of aluminium by phosphate was also found. Then it was proposed that additional aluminium might bind to the phosphate adsorbed onto the silica in the form of surface complexes silica–aluminium–phosphate again, and the mechanism might operate in the soil systems as well. Glutamic acid exhibited no influence on the adsorption of aluminium by the soil at low pH. After increasing the pH, adsorption of aluminium was inhibited especially with the highest addition of glutamic acid, probably owing to weak affinity of complexes between glutamic acid and aluminium to the soil.  相似文献   

Equation of state of MgGeO3 perovskite to 65 GPa: comparison with the post-perovskite phase     

C. E. Runge  A. Kubo  B. Kiefer  Y. Meng  V. B. Prakapenka  G. Shen  R. J. Cava  T. S. Duffy 《Physics and Chemistry of Minerals》2006,33(10):699-709

The equation of state of MgGeO₃ perovskite was determined between 25 and 66 GPa using synchrotron X-ray diffraction with the laser-heated diamond anvil cell. The data were fit to a third-order Birch–Murnaghan equation of state and yielded a zero-pressure volume (V ₀) of 182.2 ± 0.3 Å³ and bulk modulus (K ₀) of 229 ± 3 GPa, with the pressure derivative (K′₀ = (?K ₀/?P) _T ) fixed at 3.7. Differential stresses were evaluated using lattice strain theory and found to be typically less than about 1.5 GPa. Theoretical calculations were also carried out using density functional theory from 0 to 205 GPa. The equation of state parameters from theory (V ₀ = 180.2 Å³, K ₀ = 221.3 GPa, and K′₀ = 3.90) are in agreement with experiment, although theoretically calculated volumes are systematically lower than experiment. The properties of the perovskite phase were compared to MgGeO₃ post-perovskite phase near the observed phase transition pressure (～65 GPa). Across the transition, the density increased by 2.0(0.7)%. This is in excellent agreement with the theoretically determined density change of 1.9%; however both values are larger than those for the (Mg,Fe)SiO₃ phase transition. The bulk sound velocity change across the transition is small and is likely to be negative [?0.5(1.6)% from experiment and ?1.2% from theory]. These results are similar to previous findings for the (Mg,Fe)SiO₃ system. A linearized Birch–Murnaghan equation of state fit to each axis yielded zero-pressure compressibilities of 0.0022, 0.0009, and 0.0016 GPa^?1 for the a, b, and c axis, respectively. Magnesium germanate appears to be a good analog system for studying the properties of the perovskite and post-perovskite phases in silicates.  相似文献   

Influence of sedimentary environments on mechanical properties of clastic rocks     

Zhaoping Meng  Jincai Zhang  Suping Peng 《Environmental Geology》2006,51(1):113-120

The sedimentary environments are the intrinsic factor controlling the mechanical properties of clastic rocks. Examining the relationship between rock sedimentary environments and rock mechanical properties gives a better understanding of rock deformation and failure mechanisms. In this study, more than 55 samples in coal measures were taken from seven different lithologic formations in eastern China. Using the optical microscope the sedimentary characteristics, such as components of clastic rocks and sizes of clastic grains were quantitatively tested and analyzed. The corresponding mechanical parameters were tested using the servo-controlled testing system. Different lithologic attributes in the sedimentary rocks sampled different stress–strain behaviors and failure characteristics under different confining pressures, mainly due to different compositions and textures. Results demonstrate that clastic rocks have the linear best-fit for Mohr-Coulomb failure criterion. The elastic moduli in clastic rocks are highly dependent upon confining pressures, unlike hard rocks. The envelope lines of the mechanical properties versus the contents of quartz, detritus of the grain diameter of more than 0.03 mm, and grain size in clastic rocks are given. The compressive strength or elastic modulus and the grain diameter have a non-monotonic relation and demonstrate the “grain-diameter softening” effect.  相似文献   

VSP资料约束地层反滤波研究   总被引：2，自引：0，他引：2  

WANG Yu HAN Li-guo CUI Jie College of GeoExploration Science  Technology  Jilin University  Changchun  China 《吉林大学学报(地球科学版)》2006,(Z2)

浅地表的低速带和地层滤波作用导致地震信号的能量衰减,地震子波的高频快速衰减,速度频散的子波变形,对地震底层分析带来了严重的影响。地层反滤波算法就是为了消除地层对子波的影响,利用VSP中的直达下行波推算出每个地层滤波算子,计算出各个地层滤波算子的反算子,然后利用这些反算子恢复出地表记录中损失掉的高频成分,减弱地层滤波对波形的影响,增加地表记录的频率成分和波形的准确度。分析实际地震资料表明,经过地层反滤波处理后的记录频率成分明显提升,地质构造更加准确、清晰。  相似文献   

在“国土资源信息化建设成果展览”剪彩仪式上的讲话     

孟宪来 《国土资源信息化》2005,(4):10-10

各位来宾,各位代表,同志们:国土资源信息化建设成果展览,今天在美丽的昆明市隆重开幕了。我谨代表国土资源部,对展览的成功举办表示热烈的祝贺!向参与这次展览的各界代表和朋友们表示诚挚的问候!向各位来宾和同志们表示衷心的感谢!  相似文献   

Land-Parcel Land-Use History as a Key to Site Selection for Documenting Soil Contamination Risk： a Case Study from Australian Suburbia     

YU Jie Ursula Pietrzak Jim Peterson 《地球空间信息科学学报》2005,8(4):257-261

In that orcharding in early-to-mid twentieth century southeastern Australia involved use of certain heavy metal and As compounds in regular pest-control spray procedures, some interest attaches to the possibility that these landparcels are underlain by soils with above-background Cu, Pb and As levels. Interpreta- tion of Land-cover changes allowed land parcels previously occupied by orchards to be identified in the 1950s through time-series air-photos. A comparison of soil analysis results referring to soil samples from control sites, and from land parcels formerly occupied by orchardists, shows that contamination （above-background） levels of cations in the pesticides can be found in the top 6 cm of former orchard soils. It is clear that digital spatial data handling and culturally-informed air photo interpretation has a place in soil contamination studies, land-use planning （with particular reference to re-development） and in administration of public health.  相似文献   

中国MODIS卫星影像彩色镶嵌图制作     

马慧云刘良明  鄢俊洁孟令奎 《四川测绘》2005,28(2):71-73

本文介绍了大范围卫星影像彩色镶嵌图的制作流程．对于大范围卫星影像彩色镶嵌图制作的技术难点（去云、拼接、调色），文章进行了重点介绍并提出技术解决办法．利用MODIS卫星数据制作了两幅全国彩色影像镶嵌图：一幅为红波段（B1）、绿波段（B4）和蓝波段（B3）构成的真彩色合成影像：一幅为红波段（B1）．近红外波段（B2）和蓝波段（B3）构成的假彩色合成影像．两幅影像色彩精美，信息量丰富．  相似文献   

数码相机的畸变差检测研究   总被引：4，自引：0，他引：4  

林宗坚  崔红霞  孙杰  刘丽 《武汉大学学报(信息科学版)》2005,30(2):122-125

提出了一种检测面阵CCD数码相机畸变差的方法。首先利用标准三维检校场测定面阵CCD数码相机的内方位元素和系统畸变系数．然后依据投影几何中空间直线经中心投影变换后仍是直线的原理．提出了对面阵CCD数码相机随机畸变的检测和改正方法。利用该方法对UAVRS-Ⅱ系统中的面阵数码相机的畸变进行了检校，获取了满意的结果。  相似文献   

GPS辅助空中三角测量在新疆基础测绘中的应用     

严海英  石洁  孙艳新 《测绘通报》2005,(5):33-35,66

简要介绍在新疆巴州测区基础测绘生产中采用GPS辅助空中三角测量的技术方案,并对GPS辅助光束法区域网平差成果进行精度分析.  相似文献   

北京市区春季燃烧源大气颗粒物的污染水平和影响因素   总被引：17，自引：6，他引：17  

刘大锰  马永胜  高少鹏  黄杰  安祥华 《现代地质》2005,19(4):627-633

以大气中PM2.5和PM10为研究对象,于2005-03-13—25共7天的时间内,在中国地质大学(北京)测试楼顶、首钢焦化厂和首钢东门设立3个采样点进行采样监测。结果表明:PM2.5和PM10质量浓度的日变化呈现一定规律性,在不同时段PM2.5和PM10的质量浓度不尽相同,且变化较大,在特定时刻出现峰值,主要受污染源排放和气象因素的控制;PM2.5和PM10质量浓度随气温的升高而降低,这与高温有利于颗粒物扩散、低温容易形成逆温层有关;在一定的相对湿度范围内(以大气中水汽不发生重力沉降为界限),PM2.5和PM10质量浓度与相对湿度呈正相关关系;而当发生降水时,由于水滴的冲刷和附带作用,PM2.5和PM10质量浓度降低;PM2.5和PM10质量浓度与风级呈明显的负相关关系。通过北京市与国内8个省会城市的PM2.5和PM10质量浓度的对比,发现北京市PM2.5和PM10污染比较严重,PM2.5和PM10质量浓度分别超过了1996年中国制定的PM10排放标准和1997年美国EPA制定的PM2.5排放标准。  相似文献