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131.
Pesticide runoff from agriculture poses a threat to water quality in the world heritage listed Great Barrier Reef (GBR) and sensitive monitoring tools are needed to detect these pollutants. This study investigated the utility of passive samplers in this role through deployment during a wet and dry season at river mouths, two near-shore regions and an offshore region. The nearshore marine environment was shown to be contaminated with pesticides in both the dry and wet seasons (average water concentrations of 1.3-3.8 ng L−1 and 2.2-6.4 ng L−1, respectively), while no pesticides were detected further offshore. Continuous monitoring of two rivers over 13 months showed waters flowing to the GBR were contaminated with herbicides (diuron, atrazine, hexazinone) year round, with highest average concentrations present during summer (350 ng L−1). The use of passive samplers has enabled identification of insecticides in GBR waters which have not been reported in the literature previously.  相似文献   
132.
A temporary seismic network composed of 11 stations was installed in the city of Potenza (Southern Italy) to record local and regional seismicity within the context of a national project funded by the Italian Department of Civil Protection (DPC). Some stations were moved after a certain time in order to increase the number of measurement points, leading to a total of 14 sites within the city by the end of the experiment. Recordings from 26 local earthquakes (Ml 2.2−3.8 ) were analyzed to compute the site responses at the 14 sites by applying both reference and non-reference site techniques. Furthermore, the Spectral Intensity (SI) for each local earthquake, as well as their ratios with respect to the values obtained at a reference site, were also calculated. In addition, a field survey of 233 single station noise measurements within the city was carried out to increase the information available at localities different from the 14 monitoring sites. By using the results of the correlation analysis between the horizontal-to-vertical spectral ratios computed from noise recordings (NHV) at the 14 selected sites and those derived by the single station noise measurements within the town as a proxy, the spectral intensity correction factors for site amplification obtained from earthquake analysis were extended to the entire city area. This procedure allowed us to provide a microzonation map of the urban area that can be directly used when calculating risk scenarios for civil defence purposes. The amplification factors estimated following this approach show values increasing along the main valley toward east where the detrital and alluvial complexes reach their maximum thickness.  相似文献   
133.
The Pisco earthquake ( M w 8.0; 2007 August 15) occurred offshore of Peru's southern coast at the subduction interface between the Nazca and South American plates. It ruptured a previously identified seismic gap along the Peruvian margin. We use Wide Swath InSAR observations acquired by the Envisat satellite in descending and ascending orbits to constrain coseismic slip distribution of this subduction earthquake. The data show movement of the coastal regions by as much as 85 cm in the line-of-sight of the satellite. Distributed-slip model indicates that the coseismic slip reaches values of about 5.5 m at a depth of ∼18–20 km. The slip is confined to less than 40 km depth, with most of the moment release located on the shallow parts of the interface above 30 km depth. The region with maximum coseismic slip in the InSAR model is located offshore, close to the seismic moment centroid location. The geodetic estimate of seismic moment is 1.23 × 1021 Nm ( M w 8.06), consistent with seismic estimates. The slip model inferred from the InSAR observations suggests that the Pisco earthquake ruptured only a portion of the seismic gap zone in Peru between 13.5° S and 14.5° S, hence there is still a significant seismic gap to the south of the 2007 event that has not experienced a large earthquake since at least 1687.  相似文献   
134.
Photosystem II (PSII) herbicides are used in large quantities on agricultural lands adjoining the Great Barrier Reef (GBR). Routine monitoring at 14 sites in inshore waters of the GBR using passive sampling techniques detected diuron (32-94% of sampling periods) at maximum concentrations of 1.7-430ng L(-1) in the relatively pristine Cape York Region to the Mackay Whitsunday Region, respectively. A PSII herbicide equivalent (PSII-HEq) index developed as an indicator for reporting was dominated by diuron (average contribution 89%) and typically increased during the wet season. The maximum PSII-HEq indicates the potential for photosynthetic inhibition of diatoms, seagrass and coral-symbionts. PSII herbicides were significantly positively correlated with remotely sensed coloured dissolved organic matter, a proxy for freshwater extent. Combining these methods provides for the first time the potential to cost-effectively monitor improvements in water quality entering the GBR with respect to exposure to PSII herbicides.  相似文献   
135.
The effects of the photosystem II (PSII) herbicide diuron was assessed on thirteen tropical foraminifera hosting diatom, dinoflagellate, red or green algae endosymbionts. Inhibition of photosynthesis (reduced ΔF/F(m)(')) by diuron depended on both symbiont type and test ultrastructure, with greatest sensitivity observed for diatom- and chlorophyte-hosting species (24h IC(25) 2.5-4μg L(-1)). Inhibition kinetics was slow (24-48h until maximum inhibition) in comparison with corals, suggesting structural differences may influence herbicide uptake and transport. Although foraminifera were generally less sensitive to direct effects of diuron (inhibition ΔF/F(m)(')) than other marine phototrophs, damage to PSII (reduction F(v)/F(m)) occurred at concentrations lower than observed for other organisms (24h IC(25) 3-12μg L(-1)). Damage to PSII was highly light dependent and occurred at very low light intensities indicating limited photoprotective capacity. The high diversity, widespread occurrence and relative sensitivity make foraminifera good bioindicator organisms to evaluate phytotoxic stress on coral reefs.  相似文献   
136.
Based on our experience in the project REAKT, we present a methodological framework to evaluate the potential benefits and costs of using earthquake early warning (EEW) and operational earthquake forecasting (OEF) for real-time mitigation of seismic risk at nuclear facilities. We focus on evaluating the reliability, significance and usefulness of the aforementioned real-time risk-mitigation tools and on the communication of real-time earthquake information to end-users. We find that EEW and OEF have significant potential for the reduction of seismic risk at nuclear plants, although much scientific research and testing is still necessary to optimise their operation for these sensitive and highly-regulated facilities. While our test bed was Switzerland, the methodology presented here is of general interest to the community of EEW researchers and end-users and its scope is significantly beyond its specific application within REAKT.  相似文献   
137.
138.
This paper discusses the mineralogy, whole-rock geochemistry and elemental mass balance of the hydrothermal alteration zones within the Batu Hijau porphyry copper-gold deposit, Sumbawa Island, Indonesia. The hydrothermal alteration and mineralisation developed in four stages, namely (i) the early stage consisting of a central copper-gold-bearing biotite (potassic), proximal actinolite (inner propylitic) and the distal chlorite-epidote (outer propylitic) zones; (ii) the transitional stage represented by the chlorite-sericite (intermediate argillic) zone; (iii) the late stages distinguished into the sericite-paragonite (argillic) and pyrophyllite-andalusite (advanced argillic) zones; and (iv) the very late stage typified by the illite-sericite zone. In general, major elements (particularly Ca, Mg, Na and K) and some minor and rare earth elements decrease from the least altered rocks towards the late alteration zones as a consequence of the breakdown of Ca-bearing hornblende, biotite and plagioclase. Chemical discrimination by means of millicationic R1-R2 diagram indicates that R1 [4Si − 11(Na + K) − 2(Fe + Ti)] increases while R2[6Ca + 2Mg + Al] decreases with increasing alteration intensity, from least-altered, through early, transitional, to late alteration zones. Rare earth elements-chondrite (C1) normalised patterns also exhibit the depletion of the elements through the subsequent alteration zones. These results are consistent with the elemental mass balance calculation using the isocon method which shows that the degree of mass and volume depletion systematically increases during alteration. A decrease of the elements as well as mass and volume from early, through transitional to late alteration stages may imply a general decrease of the element activities in hydrothermal fluids during the formation of the alteration zones.  相似文献   
139.
The interactions between groundwater and surface water have been significantly affected by human activities in the semi-arid Hailiutu catchment, northwest China. Several methods were used to investigate the spatial and temporal interactions between groundwater and surface water. Isotopic and chemical analyses of water samples determined that groundwater discharges to the Hailiutu River, and mass balance equations were employed to estimate groundwater seepage rates along the river using chemical profiles. The hydrograph separation method was used to estimate temporal variations of groundwater discharges to the river. A numerical groundwater model was constructed to simulate groundwater discharges along the river and to analyze effects of water use in the catchment. The simulated seepage rates along the river compare reasonably well with the seepage estimates derived from a chemical profile in 2012. The impacts of human activities (river-water diversion and groundwater abstraction) on the river discharge were analyzed by calculating the differences between the simulated natural groundwater discharge and the measured river discharge. Water use associated with the Hailiutu River increased from 1986 to 1991, reached its highest level from 1992 to 2000, and decreased from 2001 onwards. The reduction of river discharge might have negative impacts on the riparian ecosystem and the water availability for downstream users. The interactions between groundwater and surface water as well as the consequences of human activities should be taken into account when implementing sustainable water resources management in the Hailiutu catchment.  相似文献   
140.
The increased availability of multi-sensor data, and elevation information in particular, leads to the need of advanced processing methods. In the context of landscape modeling tasks, we concentrate on one central component, the extraction of terrain surface from a Digital Surface Model (DSM). In contrast to conventional mathematical grey value morphology approaches (filtering methods) or to stochastical procedures, we propose an alternative methodology for this task by applying a region-based and multi-scale approach. It consists of segmentation and follow-up fuzzy logic classification based on several features derived from elevation and multi-spectral image data. The satisfying results obtained with a multi-sensor as well as with other datasets show the applicability of the approach.  相似文献   
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