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The hyper-arid conditions prevailing in Agua Verde aquifer in northern Chile make this system the most important water source for nearby towns and mining industries. Due to the growing demand for water in this region, recharge is investigated along with the impact of intense pumping activity in this aquifer. A conceptual model of the hydrogeological system is developed and implemented into a two-dimensional groundwater-flow numerical model. To assess the impact of climate change and groundwater extraction, several scenarios are simulated considering variations in both aquifer recharge and withdrawals. The estimated average groundwater lateral recharge from Precordillera (pre-mountain range) is about 4,482 m3/day. The scenarios that consider an increase of water withdrawal show a non-sustainable groundwater consumption leading to an over-exploitation of the resource, because the outflows surpasses inflows, causing storage depletion. The greater the depletion, the larger the impact of recharge reduction caused by the considered future climate change. This result indicates that the combined effects of such factors may have a severe impact on groundwater availability as found in other groundwater-dependent regions located in arid environments. Furthermore, the scenarios that consider a reduction of the extraction flow rate show that it may be possible to partially alleviate the damage already caused to the aquifer by the continuous extractions since 1974, and it can partially counteract climate change impacts on future groundwater availability caused by a decrease in precipitation (and so in recharge), if the desalination plant in Taltal increases its capacity.  相似文献   
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Cadmium, chromium, nickel, and lead were evaluated in the particulate fraction at one of the most industrialized estuaries at the Southwestern Atlantic Ocean, through Geographic Information System (GIS). Concentrations were analyzed at 21 stations during 2008–2010. The highest metal concentrations (Cd: 8,9; Cr: 256,49; Ni: 27,02; Pb: 78,43 µg g??1 d. w.) were recorded at the stations located near industrial and urban discharges situated along the estuary. In addition, Pb presented a different seasonal and spatial behavior in comparison with Cd, Cr and Ni. Winter and spring presented the higher concentrations of Pb, and the inner stations presented the higher values. The estuary is considered a moderate to strongly polluted and significantly polluted according to the Index of geoaccumulation (Igeo) and the Enrichment Factor of Cd, respectively. The Multidimensional Scaling plot showed three groups of stations: the inner, associated to low levels of metals (G1), middle stations (G2) with intermediate levels and the outer (G3) with the highest ones. In addition, this work reveals the usefulness of the GIS-mapping techniques in the distribution of pollutants along an estuarine environment and the environmental quality assessment of estuarine systems.  相似文献   
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The Buenos Aires (Argentina) and Venice (Italy) coastlands have experienced significant saltwater contamination of the phreatic aquifer, coastal erosion, hydrodynamic changes and relative sea level rise processes due to natural and man-induced factors. These factors expose coastal areas to morpho-hydro-geological hazards, such as soil desertification, frequency and degree of flooding, littoral erosion, and the silting of river mouths and channels. Man-made interventions and actions, such as beach mining, construction of coastal structures and exploitation of aquifers without an adequate knowledge of the hydrology setting and an adequate management program, worsen these natural hazards. Uncontrolled human activity induces environmental damage to the overall coastal plains. The coastal plains play an important role in the social/economic development of the two regions based on land use, such as agriculture, horticulture, breeding, and tourism, as well as industry. Results of investigations on saltwater contamination, sea level rise and morphological changes recently performed in these two coastal areas are presented here.  相似文献   
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This article points out some particular features conditioning seismic hazard assessments (SHA) in Spain, a region with low–moderate seismicity. Although sized earthquakes occurred in the past, as evidenced by historical documents and neotectonic studies, no large events occurred during the last decades. The absence of strong motion records corresponding to earthquakes with magnitude larger than 5.5 is an important obstacle for the development of ground motion models constrained by local data, with the consequent difficulty in SHA studies. In this paper, some recent developments aiming at providing solutions to these difficulties are presented. Specifically, a strong motion databank containing a massive collection of accelerograms and response spectra from different configurations source-path-site corresponding to earthquakes all over the world is introduced, together with software utilities for its management. A first application of this databank is the development of specific ground motion models for Spain and for the Mediterranean region that predict peak ground accelerations as a function of several definitions of magnitude, distance and soil class. The predictive power of these ground motion models is tested by contrasting their estimates with recently recorded ground motions. The comparison between our ground-motion models with others proposed in the literature for other areas reveals a regular overestimation of the expected ground motions at Spanish sites by the non-local models. Consequently, SHA studies based in external models may overestimate the predicted hazard at the Iberian sites. In the last part of the paper a method for checking whether the response spectra proposed in the Spanish Building Code (NCSE-02) are consistent with actual accelerometric data from recent low magnitude earthquakes is applied. The spectral shapes of the Spanish Building Code NCSE-02 are compared with the response spectral shapes deduced from the available accelerograms by normalising the response spectra with the recorded PGA. It is appreciated that the NCSE-02 spectral shapes are exceeded by a large number of actual spectral shapes for short periods (around 0.2 s), a result to be taken into account in further revisions of the NCSE-02 code. The issues tackled in this work constitute not only an improvement for ground-motion characterisation in Spain, but also provide guidelines of general interest for potential applications in other regions with similar seismicity.  相似文献   
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 The structural behavior of synthetic gahnite (ZnAl2O4) has been investigated by X-ray powder diffraction at high pressure (0–43 GPa) and room temperature, on the ID9 beamline at ESRF. The equation of state of gahnite has been derived using the models of Birch–Murnaghan, Vinet and Poirier–Tarantola, and the results have been mutually compared (the elastic bulk modulus and its derivatives versus P determined by the third-order Birch–Murnaghan equation of state are K 0=201.7(±0.9) GPa, K 0=7.62(±0.09) and K 0=−0.1022 GPa−1 (implied value). The compressibilities of the tetrahedral and octahedral bond lengths [0.00188(8) and 0.00142(5) GPa−1 at P=0, respectively], and the␣polyhedral volume compressibilities of the four-␣and␣sixfold coordination sites [0.0057(2) and 0.0041(2) GPa−1 at P=0, respectively] are discussed. Received: 15 January 2001 / Accepted: 23 April 2001  相似文献   
40.
 Synchrotron X-ray powder diffraction experiments at high pressure conditions (0.0001–13 GPa) were performed at ESRF (Grenoble-F), on the beamline ID9, to investigate the bulk elastic properties of natural P2/n-omphacites, with quasi-ideal composition. The monoclinic cell parameters a, b, c and β were determined as a function of pressure, and their compressibility coefficients are 0.00277(7), 0.00313(8), 0.00292(5) and 0.00116(4) GPa−1, respectively. The third-order Birch-Murnaghan equation of state was used to interpolate the experimental PV data, obtaining K 0=116.6(±2.5) GPa and K0=6.03(±0.60). K 0 was also determined by means of the axial and angular compressibilities [122.5(±1.7) GPa], and of the finite Lagrangian strain theory [121.5(±1.0) GPa]. The discrepancies on K 0 are discussed in the light of a comparison between techniques to determine the bulk modulus of crystalline materials from static compression diffraction data. Received: 22 February 2000 / Accepted: 10 July 2000  相似文献   
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