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71.
Hydrogeochemical characteristics of central Jianghan Plain, China   总被引:2,自引:0,他引:2  
The central Jianghan Plain is the semi-closed basin in the middle reaches of Yangtze River. A total of 78 water samples targeting groundwater were collected from 75 sites in this study site, the area between Yangtze River and Han River, including rivers and lakes for temperature, pH, electrical conductivity (EC), total dissolved solids (TDS) and ion composition measurements. Correlation matrix was used to assess the geochemical and anthropogenic processes. The most confined groundwater was grouped into HCO3–Ca–Mg, while phreatic groundwater and surface water had a more diversified hydrochemistry. The spatial variation in overall water quality as well as comparison with WHO (World Health Organization) standards for drinking water is illustrated. Mn, As and NO3 ? concentrations were found to exceed the allowable limits for drinking water of WHO guidelines, and they also show remarkable spatial variations. Abnormally high nitrate concentration, up to 150–190 mg/l, was found only in phreatic groundwater, which suggested that the nitrate pollution might be caused by agricultural activities. The present study may be helpful in further studies concerning water quality issues in this area where groundwater is a vital source for drinking and other activities.  相似文献   
72.
The dispersal of volcanic ash from the May 18, 1980 eruption of Mount St. Helens (MSH) has been simulated using the Lagrangian ash-tracking model PUFF. Previous applications of the model were limited to smaller, short-lived eruptions with ash dispersal occurring mainly within the troposphere. Two high-resolution atmospheric reanalysis datasets (ERA-40 and NCEP/NCAR-40) allowed MSH ash cloud dispersal to be simulated up to 30 km elevation. The 1980 eruption was divided into two distinct eruptive phases, (1) an initial, relatively short-lived blast/surge phase that injected ash up to 30 km and (2) a subsequent nine-hour plinian phase that maintained an average eruption column height of 16 km. Using PUFF, the two phases of the MSH eruption were modeled separately based on a range of individual input parameters and then combined to produce an integrated simulation of the entire eruption. The trajectory and areal extent of the modeled atmospheric ash cloud best match the actual distribution of MSH ash when input parameters are set to values inferred from satellite and radar data collected on May 18, 1980. The prevailing wind field exerts the strongest control on the advection and ultimate position of the modeled ash cloud, making the maximum column height and the vertical distribution of ash the most sensitive of the PUFF input parameters for this event. The results indicate that the PUFF model works well at simulating the dispersal of ash injected well into the lower stratosphere from a moderate, relatively long-lived eruption, such as MSH. However, attempts to use PUFF to recreate some granulometric aspects of the MSH fallout deposit, such as the maximum particle size as a function of distance from source, were not successful. PUFF consistently predicts much greater fallout distances for small ash particles (< 500 µm) than actually observed in the MSH deposit. The effective settling velocities used by the PUFF model appear to be too slow to accurately predict fallout distances of small ash particles. As a consequence the PUFF model may overestimate the duration of ash loading in the atmosphere associated with the distal fine ash component of explosive eruptions.  相似文献   
73.
This paper examines the impact of contrasting antecedent soil moisture conditions on the hydrochemical response, here the changes in dissolved nitrogen (NO3?, NH4+ and dissolved organic nitrogen (DON)) and dissolved organic carbon (DOC) concentrations, of a first‐order stream during hydrological events. The study was performed in the Hermine, a 5 ha forested watershed of the Canadian Shield. It focused on a series of eight precipitation events (spring, summer and fall) sampled every 2 or 3 h and showing contrasted antecedent moisture conditions. The partition of the eight events between two groups (dry or wet) of antecedent moisture conditions was conducted using a principal component analysis (PCA). The partition was controlled (first axis explained 86% of the variability) by the antecedent streamflow, the streamflow to precipitation ratio Q/P and by the antecedent groundwater depth. The mean H+, NO3?, NH4+, total dissolved nitrogen and DOC concentrations and electrical conductivity values in the stream were significantly higher following dry antecedent conditions than after wetter conditions had prevailed in the Hermine, although the temporal variability was high (17 to 138%). At the event scale, a significantly higher proportion of the changes in DON, NO3?, and DOC concentrations in the stream was explained by temporal variations in discharge compared with the seasonal and annual scales. Two of the key hydrochemical features of the dry events were the synchronous changes in DOC and flow and the frequent negative relationships between discharge and NO3?. The DON concentrations were much less responsive than DOC to changes in discharge, whereas NH was not in phase with streamflow. During wet events, the synchronicity between streamflow and DON or NO3? was higher than during dry events and discharge and NO3? were generally positively linked. Based on these observations, the hydrological behaviour of the Hermine is conceptually compatible with a two‐component model of shallow (DON and DOC rich; variable NO3?) and deep (DON and DOC poor; variable NO3?) subsurface flow. The high NO3? and DOC levels measured at the early stages of dry events reflected the contribution from NO3?‐rich groundwaters. The contribution of rapid surface flow on water‐repellent soil materials located close to the stream channel is hypothesized to explain the DOC levels. An understanding of the complex interactions between antecedent soil moisture conditions, the presence of soil nutrients available for leaching and the dynamics of soil water flow paths during storms is essential to explain the fluxes of dissolved nitrogen and carbon in streams of forested watersheds. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
74.
The phototrophic communities in meromictic, perennially ice-covered Lake A, on Ellesmere Island in the Canadian High Arctic, were characterized by pigment analysis using high performance liquid chromatography. Samples were taken to determine the vertical changes down the water column as well as a variation between years. These analyses showed that Lake A had distinct phototrophic communities in its oxic and anoxic layers. The pigment analyses indicated that phototrophic biomass in the upper, oxic waters was dominated by picocyanobacteria, while in the lower, anoxic layer photosynthetic green sulphur bacteria were dominant. Interannual variation in pigment concentrations was related to the penetration of photosynthetically active radiation in the water column, suggesting that light availability may be limiting the net accumulation of photosynthetic bacterial biomass in Lake A. Pigment analysis of the surface sediments indicated that deposition was dominated by the photosynthetic sulphur bacterial contribution. The sedimentary record of bacterial pigments in polar meromictic lakes offers a promising tool for the reconstruction of past changes in ice cover and therefore in climate.  相似文献   
75.
In this paper a novel series of field measurements are presented, which are the first to elucidate the processes influencing siltation in Botlek Harbour. Botlek Harbour is situated at the limit of saline water intrusion in the Rotterdam Waterway. Normally, after the ebb tide fresher river waters are found in the Rotterdam Waterway at the location of Botlek Harbour. On the flooding tide, the tip of the salt wedge is advected along the Rotterdam Waterway towards the mouth of Botlek Harbour. Hence on flood, a lock-exchange mechanism operates between Botlek Harbour and the Rotterdam Waterway. On the flood tide, when there is a supply of suspended particulate matter (SPM) associated with the presence of the estuarine turbidity maximum (ETM) at the mouth of the harbour, the survey data show exchange of SPM into the harbour. This lock-exchange process is found to be the dominant cause for SPM transport into the harbour. This is further substantiated by an analysis of the mass transport mechanisms. In this analysis, the vertical profiles of the instantaneous velocity, salinity and SPM concentration fields, recorded during the surveys, were decomposed into advective and dispersive transport components. The results of this analysis indicate that the correlation between the lock-exchange mechanism on the flood tide with the availability of SPM for exchange and efficient trapping, dominate the total exchange of SPM (97%). Hence, the increase in measured near-bed SPM concentration within the harbour is ascribed to tidal advection of saline water and the ETM along the Rotterdam Waterway. Tidal advection controls the density difference between the estuary and harbour, as well as the availability of SPM for exchange at the entrance to Botlek Harbour. The location of the ETM at the tip of the salt wedge is a key factor in supplying SPM to Botlek Harbour. Consequently the timing of the availability of SPM at the mouth of the harbour needs to be considered in siltation studies. The survey data suggest that Botlek Harbour basin has a 100% trapping efficiency. Analysis of 5 months of data, from a measuring rig located within the harbour, show excursions of the limit of the salt wedge and ETM. These excursions are likely to affect siltation of upstream harbours. Salinity-induced density gradients control the transport and subsequent trapping of SPM in the estuary in close proximity to the harbour entrance, the exchange of SPM between the estuary and harbour, and the trapping of SPM in the harbour basin.  相似文献   
76.
The coastal plain bordering the southern Venice Lagoon is a reclaimed lowland characterized by high subsidence rate, and ground level and water-table depth below sea level. In this agricultural region, where the surface hydrologic network is entirely artificially controlled by irrigation/drainage canals, salinization problems have long been encountered in soils and groundwaters. Here we use isotopic and geochemical tracers to improve our understanding of the origin of salinization and mineralization of the semi-confined aquifer (0–40 m), and the freshwater inputs to this hydrological system. Water samples have been collected at different seasons in the coastal Adriatic Sea, lagoon, rivers and irrigation canals, as well as in the semi-confined aquifer at depths between 12 and 35 m (14 boreholes), and in the first confined aquifer (three boreholes drilled between 40 and 80 m depth). Stable isotopes (δ18O and δD) and conductivity profiles show that direct saline intrusion from the sea or the lagoon is observed only in a restricted coastal strip, while brackish groundwaters are found over the entire topographic and piezometric depression in the centre of the study area. Fresh groundwaters are found only in the most western zone. The sharp isotopic contrast between the western and central regions suggests disconnected hydrological circulations between these two parts of the shallow aquifer. The border between these two regions also corresponds to the limits of the most strongly subsiding zone.Our results can be interpreted in terms of a four end-member mixing scheme, involving (1) marine water from the lagoon or the open sea, (2) alpine and pre-alpine regional recharge waters carried either by the main rivers Adige, Bacchiglione and Brenta (irrigation waters) or by the regional groundwater circulation, (3) local precipitation, and (4) evaporated waters infiltrated from the surface. Infiltration from the surface is also revealed by the stratification of the electrical conductivity profiles, showing that the brackish groundwaters are overlain by a shallow layer of less saline water all over the central depression. In the first confined aquifer, the groundwaters have isotopic compositions similar to the deep groundwaters of the Venetian confined aquifers (40–400 m depth). The isotopic data and the Br/Cl ratio show that the origin of the salinization of the phreatic aquifer can be ascribed to seawater intrusion alone, with no indication of the involvement of deep brines (identified at 450 m depth) in the process.The chemical composition of the saline and brackish groundwaters is characterized by an excess of sodium and a deficit of calcium compared to conservative mixing between fresh groundwaters and seawater. This suggests that the phreatic aquifer is progressively freshening, as a consequence of the beneficial influence of the extensive irrigation/drainage network, including raised canals acting as a hydraulic barrier along the coast. This freshening tendency may have been lasting since the reclamation in the mid-twentieth century, and has probably been accelerated by the ban on groundwater abstraction since the 1970s.  相似文献   
77.
The size and composition of microartifacts (objects less than 2 mm) and macroartifacts (objects greater than 2 mm) are utilized to interpret the formational processes of an archaeological site. Because grain-size distributions are known to reflect mode of transport and source, the attribute of size is examined by plotting each artifact class (unmodified rock, modified rock, ceramic, concretion, bone/shell, and metal) in size frequency diagrams. the plots allow the agent and mode of transport to be reconstructed, which in turn allows the formational processes of the site to be interpreted. the example used is the Pelts Site (23-DU-29) of southeastern Missouri. the site was chosen for this pilot study because the formation processes can be reconstructed from other data. the size distributions of each artifact class support those reconstructions and allow the proposed method to be evaluated as an interpretive method for other archaeological sites.  相似文献   
78.
The mineralogy and geochemistry of Ceres, as constrained by Dawn's instruments, are broadly consistent with a carbonaceous chondrite (CM/CI) bulk composition. Differences explainable by Ceres’s more advanced alteration include the formation of Mg‐rich serpentine and ammoniated clay; a greater proportion of carbonate and lesser organic matter; amounts of magnetite, sulfide, and carbon that could act as spectral darkening agents; and partial fractionation of water ice and silicates in the interior and regolith. Ceres is not spectrally unique, but is similar to a few other C‐class asteroids, which may also have suffered extensive alteration. All these bodies are among the largest carbonaceous chondrite asteroids, and they orbit in the same part of the Main Belt. Thus, the degree of alteration is apparently related to the size of the body. Although the ammonia now incorporated into clay likely condensed in the outer nebula, we cannot presently determine whether Ceres itself formed in the outer solar system and migrated inward or was assembled within the Main Belt, along with other carbonaceous chondrite bodies.  相似文献   
79.
Unusual late deglacial/early interglacial sedimentation rates following the last two glaciations have been detected from three cores on the eastern Reykjanes Ridge. Morphologic, textural, and mineralogic evidence pinpoint bottom currents as the process responsible for these unusual depositional rates, which rise at first to 10–40 times the regional mean, and then subside slightly to values still 2–5 times the norm. A portion of the lutite excesses in the interglacial sediment of these cores is accounted for by input of fine detritus eroded from subaerially exposed and isostatically uplifted Icelandic basalts. For the most part, however, the extraordinary depositional rates late in the deglacial periods are caused by erosion and redistribution of previously deposited glacialage sediments. We infer that reinitiation of overflow of deep water into the Atlantic due to deglacial removal of the Norwegian Sea ice cover triggered a strong bottom-current flow that dislodged sediment from exposed sites. The deglacial intensification of the deep circulation thus left a major sedimentological imprint on the sediments of the eastern Reykjanes Ridge.  相似文献   
80.
Non-fishery use of artificial reefs has been given attention in recent years. The primary concern associated with non-fishery artificial reefs is their effects to the surrounding ecosystems. This study examined the infaunal communities around two non-fishery artificial reefs (the sunken vessels YO257 and Sea Tiger) in Mamala Bay, Hawaii. Infaunal community structures at these artificial reefs were relatively similar to one at a nearly natural patch reef. A large amount of basalt gravel around YO257 associated with its deployment operation possibly had an effect on the surrounding community by increasing pore space. Polychaete assemblages were compared with existing data throughout the bay, and this revealed that the variation in sediment grain sizes and depths seemed to play some role in structuring the polychaete communities. Nevertheless, the infaunal communities around the artificial reefs were typical and within the range of natural variation in Mamala Bay, supporting their beneficial uses in ecotourism.  相似文献   
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