Calcium isotope constraints on the uptake and sources of Ca in a base-poor forest: A new concept of combining stable (δCa) and radiogenic (ε_Ca) signals     

Juraj Farkaš  Adrien Déjeant  Martin Novák 《Geochimica et cosmochimica acta》2011,75(22):7031-7046

Plant-available reserves of major base cations, Ca²⁺ and Mg²⁺, decreased markedly in soils over the past century, thus posing a potential threat to forest ecosystem health. Trees are thought to obtain dissolved Ca²⁺ ions mainly from an easily accessible soil-water reservoir also termed the ‘exchangeable cation pool’. The status of Ca reserves in this soil pool is sensitive to anthropogenic perturbations such as soil acidification induced by acid rain and/or excessive timber harvesting. Here we show that in a base-poor forest of the northeastern USA (i.e. Wachusett Mountain, Massachusetts) the ‘exchangeable Ca pool’ of deeper mineral soils has a unique isotope signature that is significantly enriched in the radiogenic ⁴⁰Ca, due to the dissolution of K-rich silicate minerals such as biotite. Using a simple isotope mass balance, and assuming that the input of Ca from biotite has a ε_Ca signature of ∼16, the results of our calculation indicate that the weathering of biotite may supply a sizeable fraction, up to 25%, of Ca²⁺ ions into the ‘exchangeable cation pool’ of deeper mineral soils. Importantly, samples of local vegetation (i.e. woody tissues of red oak) show no detectable excess of the radiogenic ⁴⁰Ca, and based on our model the upper limit of a possible biotite-derived Ca contribution in vegetation is estimated at ∼5%. We also found no evidence of the radiogenic ⁴⁰Ca signal in the samples of forest floor and the uppermost organic-rich soils (0-15 cm depth), which in turn suggest that over the long-term development of the forest and its organic matter accumulation, the vegetation growth must have also relied primarily on the non-radiogenic Ca sources. Based on our experimental data, such sources may include (i) wet atmospheric deposition, (ii) the organically-complexed Ca in topsoil horizons, and (iii) chemical weathering and/or fungal-mediated dissolution of apatite and Ca-rich plagioclase. Hence, our stable and radiogenic Ca isotope data indicate that the studied base-poor forest is able to bypass the ‘exchangeable cation pool’ of deeper (i.e. below 15 cm) mineral soils, and still manages to meet its nutritional requirements with respect to Ca. Another important implication of this study is that the organically-complexed Ca in the topsoil horizon (0-15 cm depth) has to be tightly bound to the ion exchange sites, otherwise the large radiogenic ⁴⁰Ca signatures present in the ‘exchangeable cation pool’ of deep mineral soils would be swamped by the downward gravitational flux of non-radiogenic Ca from the decaying organic matter and litterfall. Hence, the limited mobility of the organically-complexed Ca in soils and its tight biological cycling could explain the lack of a significant impact of vegetation on the Ca isotope systematics observed in large rivers.  相似文献   

Spectroscopic Observations of the 2011 Draconids Meteor Shower     

Regina Rudawska  Joe Zender  Peter Jenniskens  Jeremie Vaubaillon  Pavel Koten  Anastasios Margonis  Juraj Tóth  Jonathan McAuliffe  Detlef Koschny 《Earth, Moon, and Planets》2014,112(1-4):45-57

Some past October Draconid shower meteoroids fell apart in a spray of fragments at the end of their trajectory before slowing down, from which it was concluded that these were among the most fragile meteoroids known. In those instances, the dust could not be reliably traced to a particular return of the parent comet 21P/Giaconini-Zinner. On October 8th, 2011, Earth was predicted to transverse the 1900 A.D. dust ejecta of the comet. In 1900, the comet’s perihelion distance first moved significantly inwards to the Sun and ejection conditions could have been unusual. An airborne observing campaign was organized, with several teams contributing imaging and spectrographic cameras to study the manner in which these meteoroids released the volatile element sodium during the ablation process in the Earth’s atmosphere. IMCCE, ESA, and the SETI Institute contributed spectrographic cameras based on low-light WATEC 902H2 Ultimate, low-light LCC1, and GenII XX1332 image intensified cameras. An outburst was observed, much as predicted. Despite a lack of bright meteors, a total of 15 Draconid spectra were recorded. All show evidence of an early release of sodium. The loss of sodium was observed to coincide with the formation of a distinct wake of fragments. The observations show that 21P/Giacobini-Zinner ejected fragile meteoroids during the return in 1900. Those grains may have lost some sodium even before impacting Earth.  相似文献   

Radar Observations of Taurid Complex Meteor Showers in 2003: Activity and Mass Distribution     

P. Pecina  V. Porub–an  D. Pecinová  J. Toth 《Earth, Moon, and Planets》2004,95(1-4):681-688

Results of Ondřejov radar observation of Taurid complex meteor showers, i.e. ζ Perseids, β Taurids, S and N Taurids, performed in 2003, are presented. We have found some mass segregation within ζ Perseid, β Taurid and S Taurid showers. We have also established conspicuous lack of long duration echoes (with T ⩾ 3 s resp. T ⩾ 5 s) in S and N Taurid showers. The lack within remaining showers is not so pronounced but still persists.  相似文献   

Periodicities in the green corona for the sun as a star     

Vojtech Rušin  Juraj Zverko 《Solar physics》1990,128(1):261-268

A coronal index (CI) derived from the limb observations of the 530.3 nm emission corona (green corona) over 1964–1987 was analyzed by the Fourier transform technique (FTT) to find periodicity in this layer of solar atmosphere. As expected, two pronounced periods were indicated: the rotational, about 27 d, and the activity cycle length, 11 years. Beside these there are seen other periodicities of less significancies, namely of about 5,2.2,1 and 0.5 year. The values of these periodicities in individual cycles 20 and 21 slightly differs that could be related to different activity zone depths beneath the photosphere.  相似文献   

Calcium isotope record of Phanerozoic oceans: Implications for chemical evolution of seawater and its causative mechanisms   总被引：1，自引：0，他引：1  

Juraj Farkaš  Florian Böhm  John Blenkinsop  Robert van Geldern  Silke Voigt 《Geochimica et cosmochimica acta》2007,71(21):5117-5134

A total of 280 brachiopods of Ordovician to Cretaceous age, complemented by published data from belemnites and planktonic foraminifera, are used to reconstruct the evolution of calcium isotope composition of seawater (δ^44/40Ca_SW) over the Phanerozoic. The compiled δ^44/40Ca_SW record shows a general increase from ∼1.3‰ (NIST SRM 915a) at the beginning of the Ordovician to ∼2‰ at present. Superimposed on this trend is a major long-term positive excursion from the Early Carboniferous to Early Permian as well as several short-term, mostly negative, oscillations.A numerical model of the global cycles of calcium, carbon, magnesium and strontium was used to estimate whether the recorded δ^44/40Ca_SW variations can be explained by varying magnitudes of input and output fluxes of calcium to the oceans. The model uses the record of marine ⁸⁷Sr/⁸⁶Sr ratios as proxy for seafloor spreading rates, a record of oceanic Mg/Ca ratios to estimate rates of dolomite formation, and reconstructed atmospheric CO₂, discharge and erosion rates to estimate continental weathering fluxes.The model results indicate that varying magnitudes of the calcium input and output fluxes cannot explain the observed δ^44/40Ca_SW trends, suggesting that the isotope signatures of these fluxes must also have changed. As a possible mechanism we suggest variable isotope fractionation in the sedimentary output flux controlled by the dominant mineralogy in marine carbonate deposits, i.e. the oscillating ‘calcite-aragonite seas’. The ultimate control of the calcium isotope budget of the Phanerozoic oceans appears to have been tectonic processes, specifically variable rates of oceanic crust production that modulated the hydrothermal calcium flux and the oceanic Mg/Ca ratio, which in turn controlled the dominant mineralogy of marine carbonates, hence the δ^44/40Ca_SW. As to the causes of the short-term oscillations recorded in the secular δ^44/40Ca_SW trend, we tentatively propose that these are related to variable rates of dolomite formation and/or to changing chemical composition of the riverine flux, in particular and ratios, induced by variable proportions of silicate vs. carbonate weathering rates on the continents.  相似文献   

A New Method for Low‐Temperature Decomposition of Chromites and Dichromium Trioxide using Bromic Acid Evaluated by Chromium Isotope Measurements     

Vladislav Chrastný  Jan Rohovec  Eva Čadková  Jan Pašava  Juraj Farkaš  Martin Novák 《Geostandards and Geoanalytical Research》2014,38(1):103-110

In recent years, routine application of the stable isotope determination of chromium (Cr) in environmental and health protection research has led to the search for simpler chromite decomposition techniques. As the range of Cr isotope abundance ratios in nature is very narrow, conventional chromite decomposition techniques are no longer suitable, due to the relatively high risk of contamination during laboratory procedures. We have developed a protocol for the decomposition of chromites based on oxidation by bromic acid at room temperature. The procedure takes 15 d and requires two doses of bromic acid during the reaction period (day 1 and 8), due to the limited stability of the reagent. Chromium extracted by alkaline oxidative fusion and by bromic acid decomposition yielded statistically indistinguishable δ⁵³Cr values, measured by multi‐collector inductively coupled plasma‐mass spectrometry following addition of a ⁵⁰Cr‐⁵⁴Cr double‐spike.  相似文献   

Trends in the timing and magnitude of floods in Canada   总被引：2，自引：0，他引：2  

Juraj M. Cunderlik  Taha B.M.J. Ouarda 《Journal of Hydrology》2009,375(3-4):471-480

This study investigates trends in the timing and magnitude of seasonal maximum flood events across Canada. A new methodology for analyzing trends in the timing of flood events is developed that takes into account the directional character and multi-modality of flood occurrences. The methodology transforms the directional series of flood occurrences into new series by defining a new location of the origin. A test of flood seasonality (multi-modality) is then applied to identify dominant flood seasons. Floods from the dominant seasons are analyzed separately by a seasonal trend analysis. The Mann–Kendall test in conjunction with the method of pre-whitening is used in the trend analysis. Over 160 streamflow records from one common observation period are analyzed in watersheds with relatively pristine and stable land-use conditions. The results show weak signals of climate variability and/or change present in the timing of floods in Canada during the last three decades. Most of the significant trends in the timing of spring snowmelt floods are negative trends (earlier flood occurrence) found in the southern part of Canada. There are no significant trends identified in the timing of fall rainfall floods. However, the significance of the fall, rainfall-dominated flood season has been increasing in several analyzed watersheds. This may indicate increasing intensity of rainfall events during the recent years. Trends in the magnitude of floods are more pronounced than the trends in the timing of floods. Almost one fifth of all the analyzed stations show significant trends in the magnitude of snowmelt floods. Most of the significant trends are negative trends, suggesting decreasing magnitudes of snowmelt floods in Canada over the last three decades. Significant negative trends are found particularly in southern Ontario, northern Saskatchewan, Alberta and British Columbia. There are no significant trends in the magnitude of rainfall floods found in the analyzed streamflow records. The results support the outcomes of previous streamflow trend studies conducted in Canada.  相似文献   

Arsenic mobility from anthropogenic impoundment sediments – Consequences of contamination to biota, water and sediments, Poša, Eastern Slovakia     

Edgar Hiller  L&#x;ubomír Jurkovi   Jozef Kordík  Igor Slaninka  Michal Jankulr  Juraj Majzlan  Jrg Gttlicher  Ralph Steininger 《Applied Geochemistry》2009,24(11):2175-2185

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Gottfried Konecny:the ambassador of photogrammetry and remote sensing for 75 years     

Charles K.Toth 《地球空间信息科学学报》2021,24(1):27-32

A 90th birthday would be a milestone celebration for any person,but exceptionally rare if the person is still active after 75 years of working and serving the photogrammetric and remote sensing communities worldwide.This unprecedented career is the motivation to reflect on the technological developments of the past 75 years in the light of Gottfried Konecny's lifetime achievements.I started to get to know Gottfried not long before he officially retired from the Institute for Photogrammetry and Engineering Surveys in 1998.Furthermore,I was not even born when he,as a young and talented scholar supported by the Fulbright Scholarship from the US Government,arrived at the Ohio State University(OSU),which has been my professional home for three decades.In the second half of Gottfried's 75-year career,the technological changes have been phenomenal,and,furthermore,shown an accelerating trend in the past few years.It is absolutely remarkable how Gottfried has been able to keep up with these rapid changes and advancing technologies and exploits them for mapping and,in general,for all the users of the geospatial field at large.Additionally,his open-minded and kind personality has been always a major plus to his technical skills and experiences,and ultimately helped him assist many colleagues to advance their careers,and along the way developed and increased the use of geospatial data and systems in support of many countries worldwide.  相似文献   

Potential of time‐lapse photography of snow for hydrological purposes at the small catchment scale     

Juraj Parajka  Peter Haas  Robert Kirnbauer  Josef Jansa  Günter Blöschl 《水文研究》2012,26(22):3327-3337

Time‐lapse photography provides an attractive source of information about snow cover characteristics, especially at the small catchment scale. The objective of this study was to design and test a monitoring system, which allows multi‐resolution observations of snow cover characteristics. The main aim was to simultaneously investigate the spatio‐temporal patterns of snow cover, snow depth and snowfall interception in the area very close to the camera, and the spatio‐temporal patterns of snow cover in the far range. The multi‐resolution design was tested at three sites in the eastern part of the Austrian Alps (Hochschwab‐Rax region). Digital photographs were taken at hourly time steps between 6:00 and 18:00 in the period November, 2004 to December, 2006. The results showed that the time‐lapse photography allows effective mapping of the snow depths at high temporal resolution in the region close to the digital camera at many snow stake locations. It is possible to process a large number of photos by using an automatic procedure for accurate snow depth readings. The digital photographs can also be used to infer the settling characteristics of the snow pack and snow interception during the day. Although it is not possible to directly estimate the snow interception mass, the photos may indeed give very useful information on the snow processes on and beneath the forest canopy. The main advantage of using time‐lapse photography in the far range of the digital camera is to observe the spatio‐temporal patterns of snow cover over different landscape configurations. The results illustrate that digital photographs can be very useful for parameterising processes such as sloughing on steep slopes, snow deposition in gullies and snow erosion on mountain ridges in a distributed snow model. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献