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621.
Mobile Location‐Based Services (mLBS) are an increasingly consumer‐based concept borne from, and continually driven by, technology‐centred development; as opposed to the needs of end users. Where users have been made a focus, the research generally concerns issues of overall system appearance, functionality, information content and interaction methods, with little emphasis on the component geospatial representations. This paper describes the initial stages of a research project aimed at filling this void through the application of a qualitative User‐Centred Design (UCD) methodology for optimising geospatial representations within mLBS applications, in order to support a selected user group: Australian ‘leisure‐based travellers’. Presented in this paper is an account of two UCD activities adopted for the research. The first, user profiling, served to define the target user population in terms of their technological, geospatial and travel experiences, using an online questionnaire. The second, user task analysis, involved in‐depth interviews with a subset of users in order to obtain a deeper understanding of the geospatial goals, tasks, needs and preferences within the population, as well as the range of user differences and variability in tasks present. An overall user assessment, through combined analysis of the two result sets, highlighted considerations for the ongoing research, including a set of specific implications for the design of alternative models for geospatial services, representations and interactions. The themes described in this paper represent an initial and necessary component of UCD, which has been largely overlooked in research relating to mLBS. Whilst the focus here is on a specific user group and context of use, it is envisaged that many of the concepts tested and ratified by the resulting models will be relevant to mLBS applications in general.  相似文献   
622.
Variability of dissolved Fe2+ and ∑H2S concentrations in porewaters were studied, using cathodic stripping voltammetry (CSV) microelectrodes, in sediments overlain by hypoxic waters in the summer from the southeastern region of Corpus Christi Bay, Texas (CCB) and the Mississippi River Bight (MRB), Louisiana. These measurements were complimented by sediment microcosm studies where oxygen concentrations in the overlying water were manipulated. Sulfate reduction rates, benthic oxygen demand, total reduced sulfide, porewater sulfate, and total organic carbon were also determined. Fe2+ and ∑H2S were the major dissolved redox-reactive dissolved species in these sediments. During hypoxic conditions, an upward migration of porewater Fe2+ and ∑H2S occurred, with Fe2+ reaching much higher maximum concentrations than ∑H2S. Statistically significant (p < 0.05) differences in both Fe2+ and ∑H2S occurred between sediments at the CCB and MRB study sites. Although both sites were Fe-dominated, reactive and dissolved iron were higher while ∑H2S was lower at the MRB site. However, there were no statistically significant (p > 0.05) difference in regard to ∑H2S between microcosm and field monitoring studies. Results indicated that, for Fe2+ and ∑H2S, relatively large and rapid changes occurred in both the concentrations and distributions of these important porewater constituents in response to relatively short-term changes in overlying water oxygen content. Model calculations indicated that conditions in the sediments can be responsible for the induction of hypoxic conditions in the formation of hypoxic overlying waters in <6 days at CCB and ~20 days at MRB.  相似文献   
623.
We determined the distribution of macroalgae in Hog Island Bay, a shallow coastal lagoon in Virginia, USA, seasonally at 12 sites from 1998 to 2000 and at 3 representative sites from 2000 to 2002. We analyzed macroalgal biomass, taxonomic richness, and abundance of two non-native species, the cryptic invaderGracilaria vermiculophylla and the conspicuousCodium fragile, with respect to season, location (mainland, mid lagoon, barrier island sites), and elevation (intertidal, subtidal). Taxonomic richness, total algal biomass, and nonnative biomass peaked in the summer months when temperature and light availability were highest. A few stress tolerant and ephemeral algae dominated the algal assemblage.G. vermiculophylla constituted 74% of the entire algal biomass, was the most abundant alga in all seasons, locations, and elevation levels, and was positively correlated with taxonomic richness and abundance of filamentous species.Ulva curvata, Bryopsis plumosa, andC. fragile accounted for an additional 16% of the algal biomass. There are distinct habitats in Hog Island Bay that can be classified into low diversity-low biomass regions near the mainland and barrier islands and high diversity-high biomass regions in the open mid lagoon, where abundant shells for attachment and intermediate levels of water column nutrients and turbidity likely create better growth conditions. Taxonomic richness and biomass were higher in subtidal than intertidal zones, presumably due to lower desiccation stress. This study provides an example of how a single invasive species can dominate an entire assemblage, both in terms of biomass (being most abundant in all seasons, locations, and tidal levels) and species richness (correlating positively with epiphytic filamentous taxa). By adding hard-substratum structural complexity to a relatively homogenous soft-substratum system,G. vermiculophylla increases substratum availability for attachment and entanglement of other algal species and enhances local diversity. Without widespread and abundantG. vermiculophylla, taxa likePolysiphonia, Ceramium, Bryopsis, Ectocarpus, andChampia would likely be much less common. This study also highlights the importance of using DNA analysis of voucher specimens in monitoring programs to accurately identify cryptic invaders.  相似文献   
624.
Lead- and Pb-As-jarosites are minerals common to acidic, sulphate-rich environments, including weathering zones of sulphide ore deposits and acid rock or acid mine drainage (ARD/AMD) sites, and often form on or near galena. The structures of these jarosites are based on linear tetrahedral-octahedral-tetrahedral (T-O-T) sheets, comprised of slightly distorted FeO6 octahedra and SO42− (-AsO43− in Pb-As-jarosites) tetrahedra. To better understand the dissolution mechanisms and products of the break down of Pb- and Pb-As-jarosite, preliminary batch dissolution experiments were conducted on synthetic Pb- and Pb-As-jarosite at pH 2 and 20 °C, to mimic environments affected by ARD/AMD, and at pH 8 and 20 °C, to simulate ARD/AMD environments recently remediated with slaked lime (Ca(OH)2). All four dissolutions are incongruent. Dissolution of Pb-jarosite at pH 2 yields aqueous Pb, Fe and SO42−. The pH 8 Pb-jarosite dissolution yields aqueous Pb, SO42− and poorly crystalline Fe(OH)3, which does not appear to resorb Pb or SO42−, possibly due to the low solution pH (3.44-3.54) at the end of the experiment. The pH 2 and 8 dissolutions of Pb-As-jarosite result in the formation of secondary compounds (poorly crystalline PbSO4 for pH 2 dissolution; poorly crystalline PbSO4 and Fe(OH)3 for pH 8 dissolution), which may act as dissolution inhibitors after 250 to 300 h of dissolution. In the pH 2 dissolution, aqueous Fe, SO42− and AsO43− also form, and in the pH 8 dissolution, Fe(OH)3 precipitates then subsequently resorbs aqueous AsO43−. The dissolutions probably proceed by preferred dissolution of the A- and T-sites, which contain Pb, and SO42− and AsO43−, respectively, rather than Fe, which is sterically remote, within the T-O-T Pb- and Pb-As-jarosite structures. These data provide the foundation necessary for further, more detailed investigations into the dissolution of Pb- and Pb-As-jarosites.  相似文献   
625.
Jarosite [KFe3(SO4)2(OH)6] is a mineral that is common in acidic, sulphate-rich environments, such as acid sulphate soils derived from pyrite-bearing sediments, weathering zones of sulphide ore deposits and acid mine or acid rock drainage (ARD/AMD) sites. The structure of jarosite is based on linear tetrahedral-octahedral-tetrahedral (T-O-T) sheets, made up from slightly distorted FeO6 octahedra and SO4 tetrahedra. Batch dissolution experiments carried out on synthetic jarosite at pH 2, to mimic environments affected by ARD/AMD, and at pH 8, to simulate ARD/AMD environments recently remediated with slaked lime (Ca(OH)2), suggest first order dissolution kinetics. Both dissolution reactions are incongruent, as revealed by non-ideal dissolution of the parent solids and, in the case of the pH 8 dissolution, because a secondary goethite precipitate forms on the surface of the dissolving jarosite grains. The pH 2 dissolution yields only aqueous K, Fe, and SO4. Aqueous, residual solid, and computational modelling of the jarosite structure and surfaces using the GULP and MARVIN codes, respectively, show for the first time that there is selective dissolution of the A- and T-sites, which contain K and SO4, respectively, relative to Fe, which is located deep within the T-O-T jarosite structure. These results have implications for the chemistry of ARD/AMD waters, and for understanding reaction pathways of ARD/AMD mineral dissolution.  相似文献   
626.
Abstract:  This paper examines the culturally specific experiences of belonging within Oruāmo/Beachhaven, a suburb in North Shore City. In-depth interviews with 32 caregivers of young children expose the fact that the ethnic groups represented – Māori, Samoan and Pākehā– vary in their uses and understandings of, as well as feelings for, residential neighbourhood. Examination of the themes of natural environment, social relations, continuity of residence, facilities, organisations and place transformation reveal that, while representatives of all groups had views on these matters, there was a variable degree of engagement with and priority afforded to these concerns.  相似文献   
627.
Groundwater drought denotes the condition and hazard during a prolonged meteorological drought when groundwater resources decline and become unavailable or inaccessible for human use. Groundwater drought risk refers to the combined physical risk and human vulnerability associated with diminished groundwater availability and access during drought. An integrated management support tool, GRiMMS, is presented, for the mapping and assessment of relative groundwater drought risk in the Southern African Development Community (SADC) region. Based on composite mapping analysis of region-wide gridded relative indices of meteorological drought risk, hydrogeological drought proneness and human groundwater drought vulnerability, the mapping results highlight consistent areas across the region with highest groundwater drought risk and populations in the order of 39 million at risk of groundwater drought at present. Projective climate-model results suggest a potentially significant negative impact of climate change on groundwater drought risk. The tool provides a means for further attention to the key, but neglected, role of groundwater in drought management in Africa.  相似文献   
628.

Arsenic (As), iron (Fe), and manganese (Mn) contents were measured in sediment nodules and associated pore waters obtained from sediment cores collected from a salt marsh on Pólvora Island (southern Brazil). Sediment cores were obtained when brackish water dominated the estuary, at two different environments: an unvegetated mudflat colonized by crabs (Neohelice granulata), and a low intertidal stand vegetated by Spartina alterniflora. We determined the percentage of nodules in each depth interval of the cores, along with redox potential, and As, Fe, and Mn contents of the nodules. The mineralogy of the nodules was investigated, and results showed they are mainly composed by quartz, phyllosilicates, and amorphous Fe–Mn oxides/oxyhydroxides. Pore water results showed that bioturbation by local crabs supports oxygen penetration to depths of ca. 25 cm below the salt marsh surface, with lower Fe contents in pore water associated with the brackish period. However, S. alterniflora growth appears to have a greater impact on sediment geochemistry of Fe, Mn, and possibly As due to sulfate reduction and the associated decrease in pore water pH. Higher Fe concentrations were observed in the pore waters during the period of brackish water dominance, which also corresponded to the S. alterniflora growth season. The study demonstrates that differences in geochemical conditions (e.g., Fe content) that can develop in salt marsh sediments owing to different types of bioirrigation processes (i.e., bioirrigation driven by crabs versus that related to the growth of S. alterniflora) play important roles in the biogeochemical cycling of As.

  相似文献   
629.
On August 19, 2020, at 13:18—UTC, a meteor event ended as a meteorite shower in Santa Filomena, a city in the Pernambuco State, northeast Brazil. The heliocentric orbital parameters resulting from images by cameras of the weather broadcasting system were semimajor axis a = 2.1 ± 0.1 au, eccentricity e = 0.55 ± 0.03, and inclination i = 0.15o ± 0.05. The data identified the body as an Apollo object, an Earth-crossing object with a pericenter interior to the Earth's orbit. The chemical, mineralogical, and petrological evaluations, as well as the physical analysis, followed several traditional techniques. The meteorite was identified as a H5-6 S4 W0 ordinary chondrite genomict breccia. The large amount of metal in the meteorite made a metallographic evaluation based on the opaque phases possible. The monocrystalline kamacite crystals suggest a higher petrological type and the distorted Neumann lines imply at least two different shock events. The absence of the plessite phase shows that the meteorite did not reach the highest shock levels S5 and S6. The well-defined polycrystalline taenite is indicative of petrologic types 4 and 5 due to the conserved internal tetrataenite rim at the boundaries. The presence of polycrystalline taenites and the characteristics of the Agrell Effect suggest that the Santa Filomena meteorite did not reheat above 700°C. The absence of martensite confirms reheating temperatures <800°C and a slow cooling rate. The Ni contents and sizes of the zoned taenite particles indicate a slow cooling rate ranging from 1 to 10 K Myr−1.  相似文献   
630.
We assess the future of coal under alternative climate stabilization regimes, investigating how the quantity and location of future coal production, trade and use depends upon five factors: the supply-side constraint of resource depletion, diversification and deepening of international trade, economic growth, trends in energy intensity, and the availability of coal-fired carbon-free electric generation technology (IGCC-CCS). Using the Phoenix computable general equilibrium model of the world economy, we find that coal is sensitive to demand-side assumptions about economic growth and energy-saving structural or technological change. In a 550 ppm stabilization emission tax scenario, the gobal coal industry initially declines sharply and then rebounds, in 2050 reaching roughly the same size as it is today—but only if IGCC-CCS is available by 2020. Under alternative stabilization regimes, IGCC-CCS penetration is a key influence on production and imports in major coal regions, where it interacts with extraction costs driven by the rate of depletion relative to trade partners.  相似文献   
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