Response of surface water chemistry to reduced levels of acid precipitation: comparison of trends in two regions of New York,USA     

Douglas A. Burns  Michael R. McHale  Charles T. Driscoll  Karen M. Roy 《水文研究》2006,20(7):1611-1627

In light of recent reductions in sulphur (S) and nitrogen (N) emissions mandated by Title IV of the Clean Air Act Amendments of 1990, temporal trends and trend coherence in precipitation (1984–2001 and 1992–2001) and surface water chemistry (1992–2001) were determined in two of the most acid‐sensitive regions of North America, i.e. the Catskill and Adirondack Mountains of New York. Precipitation chemistry data from six sites located near these regions showed decreasing sulphate (SO₄^2?), nitrate (NO₃^?), and base cation (C_B) concentrations and increasing pH during 1984–2001, but few significant trends during 1992–2001. Data from five Catskill streams and 12 Adirondack lakes showed decreasing trends in SO₄^2? concentrations at all sites, and decreasing trends in NO₃^?, C_B, and H⁺ concentrations and increasing trends in dissolved organic carbon at most sites. In contrast, acid‐neutralizing capacity (ANC) increased significantly at only about half the Adirondack lakes and in one of the Catskill streams. Flow correction prior to trend analysis did not change any trend directions and had little effect on SO₄^2? trends, but it caused several significant non‐flow‐corrected trends in NO₃^? and ANC to become non‐significant, suggesting that trend results for flow‐sensitive constituents are affected by flow‐related climate variation. SO₄^2? concentrations showed high temporal coherence in precipitation, surface waters, and in precipitation–surface water comparisons, reflecting a strong link between S emissions, precipitation SO₄^2? concentrations, and the processes that affect S cycling within these regions. NO₃^? and H⁺ concentrations and ANC generally showed weak coherence, especially in surface waters and in precipitation–surface water comparisons, indicating that variation in local‐scale processes driven by factors such as climate are affecting trends in acid–base chemistry in these two regions. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Fluid inclusion evidence for impact‐related hydrothermal fluid and hydrocarbon migration in Creataceous sediments of the ICDP‐Chicxulub drill core Yax‐1     

Volker Lüders  Karen Rickers 《Meteoritics & planetary science》2004,39(7):1187-1197

Fluid inclusions studies in quartz and calcite in samples from the ICDP‐Chicxulub drill core Yaxcopoil‐1 (Yax‐1) have revealed compelling evidence for impact‐induced hydrothermal alteration. Fluid circulation through the melt breccia and the underlying sedimentary rocks was not homogeneous in time and space. The formation of euhedral quartz crystals in vugs hosted by Cretaceous limestones is related to the migration of hot (>200 °C), highly saline, metal‐rich, hydrocarbon‐bearing brines. Hydrocarbons present in some inclusions in quartz are assumed to derive from cracking of pre‐impact organic matter. The center of the crater is assumed to be the source of the hot quartz‐forming brines. Fluid inclusions in abundant newly‐formed calcite indicate lower cyrstallization temperatures (75–100 °C). Calcite crystallization is likely related to a later stage of hydrothermal alteration. Calcite precipitated from saline fluids, most probably from formation water. Carbon and oxygen isotope compositions and REE distributions in calcites and carbonate host rocks suggest that the calcite‐forming fluids have achieved close equilibrium conditions with the Cretaceous limestones. The precipitation of calcite may be related to the convection of local pore fluids, possibly triggered by impact‐induced conductive heating of the sediments.  相似文献   

Arenigian and Llanvirnian Conodonts from Ja¨mtland,Northern Sweden | Anita Lo¨fgren, 1978. Fossils and Strata,No. 13. Universitetsforlaget,Oslo, 192 pp., 41 figs., NKr. 150.00, U.S. $ 30.00     

W. Ziegler 《Earth》1979,15(2):174-175

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A geochemical record of the mining history of the Erme Estuary, south Devon, UK     

Price GD  Winkle K  Gehrels WR 《Marine pollution bulletin》2005,50(12):1706-1712

The concentration of selected trace metals (Cu, Pb and Zn) in salt-marsh sediments from within the Erme Estuary have been measured in order to assess possible historical sources of pollution. The Erme Estuary, south Devon, UK is an Area of Outstanding Natural Beauty and has remained largely unaffected by industrialisation, although a number of small silver–lead mines were in operation in the 1800s. Five cores reveal comparable geochemical profiles. An increase of lead at 40 cm depth is observed, reaching maximum values of 427 ppm. Less distinct trends are revealed by zinc and copper, probably reflecting the lack of widespread mining for ores of these elements within the catchment and possible post-depositional mobility rendering the metal concentrations non-contemporaneous with the chemostratigraphy of lead. The geochemical analysis of the salt-marsh sediments provides a fairly robust chemostratigraphic scheme and the likely sources of mine waste can be pinpointed within the catchment. Based upon reference to the historical mining record of these mines chemostratigraphic dating of the sediments can be achieved in order to provide an estimate of salt-marsh accretion rates and sea-level rise.  相似文献   

An analysis of carrier phase differential kinematic GPS positioning using DynaPos     

Karen?M.?CoveEmail author  Marcelo?C.?Santos 《GPS Solutions》2004,8(4):210-216

A series of activities have been carried out at the University of New Brunswick in an effort to evaluate advances in long-range marine kinematic differential positioning. These activities involved processing and analysis of GPS carrier phase kinematic data sets. Some of the data was collected by UNB and some was provided by The XYZs of GPS Inc. Data were collected using Trimble 5700 and Ashtech Z-12 receivers. The data sets were processed using the software DynaPos provided by the The XYZs of GPS Inc. The best results obtained in our analysis indicate an agreement of 5 cm RMS for the horizontal component and 12 cm RMS for the vertical component between two ionospheric-delay free solutions, in baselines varying from 40 to 100 km.  相似文献   

A case study of coping strategies and landslides in two villages of Central-Eastern Nepal     

Karen Sudmeier-Rieux  Stephanie Jaquet 《Applied geography (Sevenoaks, England)》2012,32(2):680-690

Landslides are an increasing problem in Nepal’s Middle Hills due to both natural and human phenomena: mainly increasingly intense monsoon rains and a boom in rural road construction. This problem has largely been neglected due to underreporting of losses and the dispersed nature of landslides. Understanding how populations cope with landslides is a first step toward developing more effective landslide risk management programs. The present research focuses on two villages in Central-Eastern Nepal, both affected by active landslides but with different coping strategies. Research methods are interdisciplinary, based on a geological assessment of landslide risk and a socio-economic study of the villages using household questionnaires, focus group discussions and transect walks. Community risk maps are compared with geological landslide risk maps to better understand and communicate community risk perceptions, priorities and coping strategies. A modified typology of coping strategies is presented, based on previous work by Burton, Kates, and White (1993) that is useful for decision-makers for designing more effective programs for landslide mitigation. Main findings underscore that coping strategies, mainly seeking external assistance and outmigration, are closely linked to access to resources, ethnicity/social status and levels of community organization. Conclusions include the importance of investing in organizational skills, while building on local knowledge about landslide mitigation for reducing landslide risk. There is great potential to increase coping strategies by incorporating skills training on landslide mitigation in existing agricultural outreach and community forest user group training.  相似文献   

Effects of observed and experimental climate change on terrestrial ecosystems in northern Canada: results from the Canadian IPY program   总被引：1，自引：0，他引：1  

Gregory H. R. Henry  Karen A. Harper  Wenjun Chen  Julie R. Deslippe  Robert F. Grant  Peter M. Lafleur  Esther Lévesque  Steven D. Siciliano  Suzanne W. Simard 《Climatic change》2012,115(1):207-234

Tundra and taiga ecosystems comprise nearly 40?% of the terrestrial landscapes of Canada. These permafrost ecosystems have supported humans for more than 4500?years, and are currently home to ca. 115,000 people, the majority of whom are First Nations, Inuit and Métis. The responses of these ecosystems to the regional warming over the past 30?C50?years were the focus of four Canadian IPY projects. Northern residents and researchers reported changes in climate and weather patterns and noted shifts in vegetation and other environmental variables. In forest-tundra areas tree growth and reproductive effort correlated with temperature, but seedling establishment was often hindered by other factors resulting in site-specific responses. Increased shrub cover has occurred in sites across the Arctic at the plot and landscape scale, and this was supported by results from experimental warming. Experimental warming increased vegetation cover and nutrient availability in most tundra soils; however, resistance to warming was also found. Soil microbial diversity in tundra was no different than in other biomes, although there were shifts in mycorrhizal diversity in warming experiments. All sites measured were sinks for carbon during the growing season, with expected seasonal and latitudinal patterns. Modeled responses of a mesic tundra system to climate change showed that the sink status will likely continue for the next 50?C100?years, after which these tundra systems will likely become a net source of carbon dioxide to the atmosphere. These IPY studies were the first comprehensive assessment of the state and change in Canadian northern terrestrial ecosystems and showed that the inherent variability in these systems is reflected in their site-specific responses to changes in climate. They also showed the importance of using local traditional knowledge and science, and provided extensive data sets, sites and researchers needed to study and manage the inevitable changes in the Canadian North.  相似文献   

Impact of stratospheric variability on tropospheric climate change     

Mauro Dall’Amico  Peter A. Stott  Adam A. Scaife  Lesley J. Gray  Karen H. Rosenlof  Alexey Yu. Karpechko 《Climate Dynamics》2010,34(2-3):399-417

An improved stratospheric representation has been included in simulations with the Hadley Centre HadGEM1 coupled ocean atmosphere model with natural and anthropogenic forcings for the period 1979–2003. An improved stratospheric ozone dataset is employed that includes natural variations in ozone as well as the usual anthropogenic trends. In addition, in a second set of simulations the quasi biennial oscillation (QBO) of stratospheric equatorial zonal wind is also imposed using a relaxation towards ERA-40 zonal wind values. The resulting impact on tropospheric variability and trends is described. We show that the modelled cooling rate at the tropopause is enhanced by the improved ozone dataset and this improvement is even more marked when the QBO is also included. The same applies to warming trends in the upper tropical troposphere which are slightly reduced. Our stratospheric improvements produce a significant increase of internal variability but no change in the positive trend of annual mean global mean near-surface temperature. Warming rates are increased significantly over a large portion of the Arctic Ocean. The improved stratospheric representation, especially the QBO relaxation, causes a substantial reduction in near-surface temperature and precipitation response to the El Chichón eruption, especially in the tropical region. The winter increase in the phase of the northern annular mode observed in the aftermath of the two major recent volcanic eruptions is partly captured, especially after the El Chichón eruption. The positive trend in the southern annular mode (SAM) is increased and becomes statistically significant which demonstrates that the observed increase in the SAM is largely subject to internal variability in the stratosphere. The possible inclusion in simulations for future assessments of full ozone chemistry and a gravity wave scheme to internally generate a QBO is discussed.  相似文献   

Climate feedbacks determined using radiative kernels in a multi-thousand member ensemble of AOGCMs     

Benjamin M. Sanderson  Karen M. Shell  William Ingram 《Climate Dynamics》2010,35(7-8):1219-1236

The use of radiative kernels to diagnose climate feedbacks is a recent development that may be applied to existing climate change simulations. We apply the radiative kernel technique to transient simulations from a multi-thousand member perturbed physics ensemble of coupled atmosphere-ocean general circulation models, comparing distributions of model feedbacks with those taken from the CMIP-3 multi GCM ensemble. Although the range of clear sky longwave feedbacks in the perturbed physics ensemble is similar to that seen in the multi-GCM ensemble, the kernel technique underestimates the net clear-sky feedbacks (or the radiative forcing) in some perturbed models with significantly altered humidity distributions. In addition, the compensating relationship between global mean atmospheric lapse rate feedback and water vapor feedback is found to hold in the perturbed physics ensemble, but large differences in relative humidity distributions in the ensemble prevent the compensation from holding at a regional scale. Both ensembles show a similar range of response of global mean net cloud feedback, but the mean of the perturbed physics ensemble is shifted towards more positive values such that none of the perturbed models exhibit a net negative cloud feedback. The perturbed physics ensemble contains fewer models with strong negative shortwave cloud feedbacks and has stronger compensating positive longwave feedbacks. A principal component analysis used to identify dominant modes of feedback variation reveals that the perturbed physics ensemble produces very different modes of climate response to the multi-model ensemble, suggesting that one may not be used as an analog for the other in estimates of uncertainty in future response. Whereas in the multi-model ensemble, the first order variation in cloud feedbacks shows compensation between longwave and shortwave components, in the perturbed physics ensemble the shortwave feedbacks are uncompensated, possibly explaining the larger range of climate sensitivities observed in the perturbed simulations. Regression analysis suggests that the parameters governing cloud formation, convection strength and ice fall speed are the most significant in altering climate feedbacks. Perturbations of oceanic and sulfur cycle parameters have relatively little effect on the atmospheric feedbacks diagnosed by the kernel technique.  相似文献   

Inverse kinetic isotope fractionation during bacterial nitrite oxidation   总被引：4，自引：0，他引：4  

Karen L. Casciotti 《Geochimica et cosmochimica acta》2009,73(7):2061-2076

Natural abundance stable isotopes in nitrate (), nitrite (), and nitrous oxide (N₂O) have been used to better understand the cycling of nitrogen in marine and terrestrial environments. However, in order to extract the greatest information from the distributions of these isotopic species, the kinetic isotope effects for each of the relevant microbial reactions are needed. To date, kinetic isotope effects for nitrite oxidation and anaerobic ammonium oxidation (anammox) have not been reported. In this study, the nitrogen isotope effect was measured for microbial nitrite oxidation to nitrate. Nitrite oxidation is the second step in the nitrification process, and it plays a key role in the regeneration of nitrate in the ocean. Surprisingly, nitrite oxidation occurred with an inverse kinetic isotope effect, such that the residual nitrite became progressively depleted in ¹⁵N as the reaction proceeded. Three potential explanations for this apparent inverse kinetic isotope effect were explored: (1) isotope exchange equilibrium between nitrite and nitrous acid prior to reaction, (2) reaction reversibility at the enzyme level, and (3) true inverse kinetic fractionation. Comparison of experimental data to ab initio calculations and theoretical predictions leads to the conclusion that the fractionation is most likely inverse at the enzyme level. Inverse kinetic isotope effects are rare, but the experimental observations reported here agree with kinetic isotope theory for this simple N-O bond-forming reaction. Nitrite oxidation is therefore fundamentally different from all other microbial processes in which N isotope fractionation has been studied. The unique kinetic isotope effect for nitrite oxidation should help to better identify its role in the cycling of nitrite in ocean suboxic zones, and other environments in which nitrite accumulates.  相似文献