Displacement behavior of CH4 adsorbed on coals by injecting pure CO2, N2, and CO2–N2 mixture     

Sohei Shimada  Huoyin Li  Yoshito Oshima  Kazuhide Adachi 《Environmental Geology》2005,49(1):44-52

Gas adsorption isotherms of Akabira coals were established for pure carbon dioxide (CO₂), methane (CH₄), and nitrogen (N₂). Experimental data fit well into the Langmuir model. The ratio of sorption capacity of CO₂, CH₄, and N₂ is 8.5:3.5:1 at a lower pressure (1.2 MPa) regime and becomes 5.5:2:1 when gas pressure increases to 6.0 MPa. The difference in sorption capacity of these three gases is explained by differences in the density of the three gases with increasing pressure. A coal–methane system partially saturated with CH₄ at 2.4 MPa adsorption pressure was experimentally studied. Desorption behavior of CH₄ by injecting pure CO₂ (at 3.0, 4.0, 5.0, and 6.0 MPa), and by injecting the CO₂–N₂ mixture and pure N₂ (at 3.0 and 6.0 MPa) were evaluated. Results indicate that the preferential sorption property of coal for CO₂ is significantly higher than that for CH₄ or N₂. CO₂ injection can displace almost all of the CH₄ adsorbed on coal. When modeling the CH₄–CO₂ binary and CH₂–CO₂–N₂ ternary adsorption system by using the extended Langmuir (EL) equation, the EL model always over-predicted the sorbed CO₂ value with a lower error, while under-predicting the sorbed CH₄ with a higher error. A part of CO₂ may dissolve into the solid organic structure of coal, besides its competitive adsorption with other gases. According to this explanation, the EL coefficients of CO₂ in EL equation were revised. The revised EL model proved to be very accurate in predicting sorbed ratio of multi-component gases on coals.  相似文献   

Book reviews     

J. Thiede  K. Cehak  Stephen G. Warren  A. Zaporozec  Karl W. Butzer  H. Th. Verstappen  Robert A. Creelman  Jan Lundqvist  Xavier de Planhol  G. Kunkel  Wolf Tietze  P. G. Söhnge  K. U. Sirinanda  Owen J. Furuseth  Catharine Nagashima  T. Pioro  Asit K. Biswas  J. -P. Moreau  Hildegard Binder Johnson 《GeoJournal》1980,4(1):91-96

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Crystal chemistry and oxidation state of Fe-rich prehnite from a hydrothermally altered dolerite     

Nagashima  Mariko  Iwasa  Kiyoka  Akasaka  Masahide 《Mineralogy and Petrology》2018,112(2):173-184

Mineralogy and Petrology - Fe-rich prehnite, Ca2(Al,Fe)(AlSi3)O10(OH)2, in a hydrothermally altered dolerite sill from Mitsu, Shimane Peninsula, Japan, was studied using 57Fe Mössbauer...  相似文献   

Al–Mg and Pb–Pb systematics of Allende CAIs: Canonical solar initial Al/Al ratio reinstated     

Benjamin Jacobsen  Qing-zhu Yin  Frederic Moynier  Yuri Amelin  Alexander N. Krot  Kazuhide Nagashima  Ian D. Hutcheon  Herbert Palme 《Earth and Planetary Science Letters》2008,272(1-2):353-364

The precise knowledge of the initial ²⁶Al/²⁷Al ratio [(²⁶Al/²⁷Al)₀] is crucial if we are to use the very first solid objects formed in our Solar System, calcium–aluminum-rich inclusions (CAIs) as the “time zero” age-anchor and guide future work with other short-lived radio-chronometers in the early Solar System, as well as determining the inventory of heat budgets from radioactivities for early planetary differentiation. New high-precision multi-collector inductively-coupled plasma mass spectrometry (MC-ICP-MS) measurements of ²⁷Al/²⁴Mg ratios and Mg-isotopic compositions of nine whole-rock CAIs (six mineralogically characterized fragments and three micro-drilled inclusions) from the CV carbonaceous chondrite, Allende yield a well-defined ²⁶Al–²⁶Mg fossil isochron with an (²⁶Al/²⁷Al)₀ of (5.23 ± 0.13) × 10^− 5. Internal mineral isochrons obtained for three of these CAIs (A44A, AJEF, and A43) are consistent with the whole-rock CAI isochron. The mineral isochron of AJEF with (²⁶Al/²⁷Al)₀ = (4.96 ± 0.25) × 10^− 5, anchored to our precisely determined absolute ²⁰⁷Pb–²⁰⁶Pb age of 4567.60 ± 0.36 Ma for the same mineral separates, reinstate the “canonical” (²⁶Al/²⁷Al)₀ of 5 × 10^− 5 for the early Solar System. The uncertainty in (²⁶Al/²⁷Al)₀ corresponds to a maximum time span of ± 20 Ka (thousand years), suggesting that the Allende CAI formation events were culminated within this time span. Although all Allende CAIs studied experienced multistage formation history, including melting and evaporation in the solar nebula and post-crystallization alteration likely on the asteroidal parent body, the ²⁶Al–²⁶Mg and U–Pb-isotopic systematics of the mineral separates and bulk CAIs behaved largely as closed-system since their formation. Our data do not support the “supra-canonical” ²⁶Al/²⁷Al ratio of individual minerals or their mixtures in CV CAIs, suggesting that the supra-canonical ²⁶Al/²⁷Al ratio in the CV CAIs may have resulted from post-crystallization inter-mineral redistribution of Mg isotopes within an individual inclusion. This redistribution must be volumetrically minor in order to satisfy the mass balance of the precisely defined bulk CAI and bulk mineral data obtained by MC-ICP-MS.The radiogenic ²⁰⁸Pb/²⁰⁶Pb ratio obtained as a by-product from the Pb–Pb age dating is used to estimate time-integrated ²³²Th/²³⁸U ratio (κ value) of CAIs. Limited κ variations among the minerals within a single CAI, contrasted by much larger variations among the bulk CAIs, suggest Th/U fractionation occurred prior to crystallization of igneous CAIs. If interpreted as primordial heterogeneity, the κ value can be used to calculate the mean age of the interstellar dust from which the CAIs condensed.  相似文献   

Characteristics of observed turbulent mixing across the Antarctic Slope Front at 140°E, East Antarctica     

Daisuke Hirano  Yujiro Kitade  Hideki Nagashima  Masaji Matsuyama 《Journal of Oceanography》2010,66(1):95-104

The strength of mixing due to turbulence in the Antarctic Slope Front (ASF) region was investigated using CTD (conductivity-temperature-depth profilers) observations and direct measurements of turbulence conducted off Adélie Land, East Antarctica along 140°E from the 12th–14th February, 2005. The strongest horizontal gradient of the ASF was located below 300 m depth near the 1000 m isobath. The turbulent measurements revealed that the energy dissipation rate frequently exceeded 10^?8 Wkg^?1 on the continental shelf and upper slope regions. Turbulent diffusivities near the shelf break were higher than 10^?3 m²s^?1. Near the ASF the average turbulent heat flux was 5.7 Wm^?2 and 1.1 Wm^?2 across the temperature minimum layer to 250 m and from 300 to 600 m, respectively. The distribution of the high dissipation rate was consistently explained by the characteristic curve of the M2 internal wave emanating from the shelf break and continental slope. The water mass observed in the ASF below 300 m in the continental slope comprised Modified Circumpolar Deep Water and low salinity Shelf Water originating from either the upper layer of the Adélie Depression or the Adélie Bank, and produced by boundary mixing near the shelf break.  相似文献   

Alkalinization and acidification of stream water with changes in atmospheric deposition in a tropical dry evergreen forest of northeastern Thailand          下载免费PDF全文

Hiroyuki Sase  Jesada Luangjame  Hathairatana Garivait  Bopit Kietvuttinon  Thiti Visaratana  Masato Kamisako  Ryo Kobayashi  Seiichi Ohta  Junko Shindo  Kentaro Hayashi  Hideshige Toda  Kazuhide Matsuda 《水文研究》2017,31(4):836-846

Field surveys on atmospheric deposition and stream water chemistry were conducted in an evergreen forest in northeastern Thailand characterized by a tropical savanna climate with distinct dry and wet seasons. Atmospheric deposition of ion constituents by throughfall and stemflow was shown to increase in the beginning and end of the wet season, reflecting the precipitation pattern. The pH and electrical conductivity of stream water increased with alkalinity and base cation concentrations due to mineralization of organic matter by the first rain and retention of anions in soil during the start of the wet season. After initial alkalinization, the pH and alkalinity declined rapidly with the highest SO₄^2? concentration displayed in the middle towards the end of the wet season. The magnitude of peaks in SO₄^2? concentration (13.5–60.6 μmol_c/L) reflects deposition during the first 2 months of the wet season (March and April) in respective years (60.8–170 mol_c/ha). Release of SO₄^2? with H⁺, which is retained in soil during the early wet season, may cause acidification later in the season. The deposition and concentration of SO₄^2? declined over 6 years. However, the pH of stream water declined with increasing concentrations of SO₄^2? and other major ions. The release of materials accumulated in the ecosystem was facilitated by the decrease in SO₄^2? concentration/deposition and increased precipitation in the middle–late wet season. The retention‐release cycle of SO₄^2? largely contributed to both seasonal and interannual variations in stream water chemistry in the tropical savanna climate studied.  相似文献   

Millennial-scale oscillations of the westerly jet path during the last glacial period   总被引：1，自引：0，他引：1  

Kana Nagashima  Ryuji Tada  Atsushi Tani  Youbin Sun  Yuko Isozaki  Shin Toyoda  Hitoshi Hasegawa 《Journal of Asian Earth Sciences》2011,40(6):239-1220

It has been established that East Asian summer monsoon intensity varies with Dansgaard–Oeschger cycles, suggesting a connection between the climates of East Asia and the North Atlantic on a millennial timescale. However, the dynamics of such a connection are still unsolved. Here we demonstrate that temporal changes in the provenance of aeolian dust in Japan Sea sediments, which we interpret to reflect changes in the westerly jet path over East Asia, exhibit variations in harmony with Dansgaard–Oeschger cycles. The dominance of dust with a Mongolian Gobi provenance during stadials suggests a westerly jet axis located to the south of the Himalaya–Tibetan Plateau throughout most of the year, whereas the co-dominance of dust from both the Taklimakan Desert and the Mongolian Gobi during interstadials suggests that the westerly jet axis jumped to the north of the Tibetan Plateau at latest in summer. As the shift of the westerly jet axis to the north of the Tibetan Plateau is closely related to the onset of the East Asian summer monsoon, changes of the westerly jet path apparently critically affect the teleconnection between the climates of Asia and North Atlantic on a millennial timescale.  相似文献   

Interpreting the Helioseismic and Magnetic Imager (HMI) Multi-Height Velocity Measurements     

Kaori Nagashima  Björn Löptien  Laurent Gizon  Aaron C. Birch  Robert Cameron  Sebastien Couvidat  Sanja Danilovic  Bernhard Fleck  Robert Stein 《Solar physics》2014,289(9):3457-3481

The Solar Dynamics Observatory/Helioseismic and Magnetic Imager (SDO/HMI) filtergrams, taken at six wavelengths around the Fe i 6173.3 Å line, contain information about the line-of-sight velocity over a range of heights in the solar atmosphere. Multi-height velocity inferences from these observations can be exploited to study wave motions and energy transport in the atmosphere. Using realistic convection-simulation datasets provided by the STAGGER and MURaM codes, we generate synthetic filtergrams and explore several methods for estimating Dopplergrams. We investigate at which height each synthetic Dopplergram correlates most strongly with the vertical velocity in the model atmospheres. On the basis of the investigation, we propose two Dopplergrams other than the standard HMI-algorithm Dopplergram produced from HMI filtergrams: a line-center Dopplergram and an average-wing Dopplergram. These two Dopplergrams correlate most strongly with vertical velocities at the heights of 30?–?40 km above (line center) and 30?–?40 km below (average wing) the effective height of the HMI-algorithm Dopplergram. Therefore, we can obtain velocity information from two layers separated by about a half of a scale height in the atmosphere, at best. The phase shifts between these multi-height Dopplergrams from observational data as well as those from the simulated data are also consistent with the height-difference estimates in the frequency range above the photospheric acoustic-cutoff frequency.  相似文献   

53Mn‐53Cr dating of aqueously formed carbonates in the CM2 lithology of the Sutter's Mill carbonaceous chondrite     

Christine E. Jilly  Gary R. Huss  Alexander N. Krot  Kazuhide Nagashima  Qing‐Zhu Yin  Naoji Sugiura 《Meteoritics & planetary science》2014,49(11):2104-2117

Radiometric dating of secondary minerals can be used to constrain the timing of aqueous alteration on meteoritic parent bodies. Dolomite is a well‐documented secondary mineral in CM chondrites, and is thought to have formed by precipitation from an aqueous fluid on the CM parent body within several million years of accretion. The petrographic context of crosscutting dolomite veins indicates that aqueous alteration occurred in situ, rather than in the nebular setting. Here, we present ⁵³Mn‐⁵³Cr systematics for dolomite grains in Sutter's Mill section SM51‐1. The Mn‐Cr isotope data show well‐resolved excesses of ⁵³Cr correlated with ⁵⁵Mn/⁵²Cr ratio, which we interpret as evidence for the in situ decay of radioactive ⁵³Mn. After correcting for the relative sensitivities of Mn and Cr using a synthetic Mn‐ and Cr‐bearing calcite standard, the data yield an isochron with slope corresponding to an initial ⁵³Mn/⁵⁵Mn ratio of 3.42 ± 0.86 × 10^?6. The reported error includes systematic uncertainty from the relative sensitivity factor. When calculated relative to the U‐corrected Pb‐Pb absolute age of the D'Orbigny angrite, Sutter's Mill dolomites give a formation age between 4564.8 and 4562.2 Ma (2.4–5.0 Myr after the birth of the solar system). This age is contemporaneous with previously reported ages for secondary carbonates in CM and CI chondrites. Consistent carbonate precipitation ages between the carbonaceous chondrite groups suggest that aqueous alteration was a common process during the early stages of parent body formation, probably occurring via heating from internal ²⁶Al decay. The high‐precision isochron for Sutter's Mill dolomite indicates that late‐stage processing did not reach temperatures that were high enough to further disturb the Mn‐Cr isochron.  相似文献   

Pulsation at the tip of the first giant branch?     

Yoshifusa Ita  Toshihiko Tanabé  Noriyuki Matsunaga  Yasushi Nakajima  Chie Nagashima  Takahiro Nagayama  Daisuke Kato  Mikio Kurita  Tetsuya Nagata  Shuji Sato  Motohide Tamura  Hidehiko Nakaya  Yoshikazu Nakada 《Monthly notices of the Royal Astronomical Society》2002,337(3):L31-L34

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