Experimental study of reaction between perovskite and molten iron to 146 GPa and implications for chemically distinct buoyant layer at the top of the core     

Haruka Ozawa  Kei Hirose  Masanori Mitome  Yoshio Bando  Nagayoshi Sata  Yasuo Ohishi 《Physics and Chemistry of Minerals》2009,36(6):355-363

Partitioning of oxygen and silicon between molten iron and (Mg,Fe)SiO₃ perovskite was investigated by a combination of laser-heated diamond-anvil cell (LHDAC) and analytical transmission electron microscope (TEM) to 146 GPa and 3,500 K. The chemical compositions of co-existing quenched molten iron and perovskite were determined quantitatively with energy-dispersive X-ray spectrometry (EDS) and electron energy loss spectroscopy (EELS). The results demonstrate that the quenched liquid iron in contact with perovskite contained substantial amounts of oxygen and silicon at such high pressure and temperature (P–T). The chemical equilibrium between perovskite, ferropericlase, and molten iron at the P–T conditions of the core–mantle boundary (CMB) was calculated in Mg–Fe–Si–O system from these experimental results and previous data on partitioning of oxygen between molten iron and ferropericlase. We found that molten iron should include oxygen and silicon more than required to account for the core density deficit (<10%) when co-existing with both perovskite and ferropericlase at the CMB. This suggests that the very bottom of the mantle may consist of either one of perovskite or ferropericlase. Alternatively, it is also possible that the bulk outer core liquid is not in direct contact with the mantle. Seismological observations of a small P-wave velocity reduction in the topmost core suggest the presence of chemically-distinct buoyant liquid layer. Such layer physically separates the mantle from the bulk outer core liquid, hindering the chemical reaction between them.  相似文献   

Alteration of gene expression profiles in the brain of Japanese medaka (Oryzias latipes) exposed to KC-400 or PCB126     

Kei Nakayama  Naomi Sei  Yuji Oshima  Kosuke Tashiro  Yohei Shimasaki  Tsuneo Honjo 《Marine pollution bulletin》2008,57(6-12):460

Polychlorinated biphenyls (PCBs) are known as neurotoxic chemicals and possibly alter animal behavior. We previously reported that PCB-exposure induced abnormal schooling behavior in Japanese medaka (Oryzias latipes). This abnormal behavior might be caused by the functional alteration of central or terminal nervous system. To understand the mechanism(s) of behavioral change by PCB-exposure, we analyzed the gene expression profiles in the brain of medaka exposed to 3,3′,4,4′,5-pentachlorobiphenyl (PCB126) or a PCB mixture (Kanechlor-400: KC-400) using a cDNA microarray that we constructed. Twelve FLF-II strain medaka (six individuals per treatment) were dietary exposed to PCB126 (0.01 μg/g b.w./day) or KC-400 (1 μg/g b.w./day) for three weeks. For the control, six fish were fed a control diet. After the exposure period, fish were dissected, and the brain samples were collected. The samples from control fish were pooled and used as a common reference in the microarray experiment. Microarray data were normalized by the LOWESS method, and we screened the genes whose expression levels were altered more than 1.5-fold. Gene expression profiling showed 97 down-regulated and 379 up-regulated genes in the brain of medaka exposed to PCB126. KC-400 exposure suppressed 15 genes and induced 266 genes in medaka brain. Among these genes, the expression levels of 7 and 188 genes were commonly down- or up-regulated, respectively in both treatment groups. On the other hand, 31 gene expressions were significantly different between PCB126 and KC-400 treatment groups, and three out of 31 genes were received opposite effects. In addition, the microarray data showed that thyroid hormone-responsive genes were up-regulated by PCB-exposure, which may imply that PCBs or their metabolites mimic thyroid hormone effects in the brain of PCB-exposed medaka.  相似文献   

Alteration of gene expression profiles in the brain of Japanese medaka (Oryzias latipes) exposed to KC-400 or PCB126     

Nakayama K  Sei N  Oshima Y  Tashiro K  Shimasaki Y  Honjo T 《Marine pollution bulletin》2008,57(6-12):460-466

Polychlorinated biphenyls (PCBs) are known as neurotoxic chemicals and possibly alter animal behavior. We previously reported that PCB-exposure induced abnormal schooling behavior in Japanese medaka (Oryzias latipes). This abnormal behavior might be caused by the functional alteration of central or terminal nervous system. To understand the mechanism(s) of behavioral change by PCB-exposure, we analyzed the gene expression profiles in the brain of medaka exposed to 3,3',4,4',5-pentachlorobiphenyl (PCB126) or a PCB mixture (Kanechlor-400: KC-400) using a cDNA microarray that we constructed. Twelve FLF-II strain medaka (six individuals per treatment) were dietary exposed to PCB126 (0.01 microg/g b.w./day) or KC-400 (1 microg/g b.w./day) for three weeks. For the control, six fish were fed a control diet. After the exposure period, fish were dissected, and the brain samples were collected. The samples from control fish were pooled and used as a common reference in the microarray experiment. Microarray data were normalized by the LOWESS method, and we screened the genes whose expression levels were altered more than 1.5-fold. Gene expression profiling showed 97 down-regulated and 379 up-regulated genes in the brain of medaka exposed to PCB126. KC-400 exposure suppressed 15 genes and induced 266 genes in medaka brain. Among these genes, the expression levels of 7 and 188 genes were commonly down- or up-regulated, respectively in both treatment groups. On the other hand, 31 gene expressions were significantly different between PCB126 and KC-400 treatment groups, and three out of 31 genes were received opposite effects. In addition, the microarray data showed that thyroid hormone-responsive genes were up-regulated by PCB-exposure, which may imply that PCBs or their metabolites mimic thyroid hormone effects in the brain of PCB-exposed medaka.  相似文献   

Field measurement and modeling of near-bed sediment transport processes with fluid mud layer in Tokyo Bay     

Yasuyuki Nakagawa  Kazuo Nadaoka  Hiroshi Yagi  Ryuichi Ariji  Haruo Yoneyama  Kazuhiro Shirai 《Ocean Dynamics》2012,62(10-12):1535-1544

Tokyo Bay is one of the estuaries in Japan with a high population of almost 26 million people in the basin area. One of the major concerns for the environment in this water area is the decreasing ecosystem functions including the deterioration of water and sediment qualities caused by various anthropogenic activities. Since the bottom sediments around almost the entire area of the inner bay consist of fine materials with a high organic content, which cause the deterioration of water quality through processes such as hypoxia, an understanding of the fine sediment dynamics in the Bay is crucial for an environmental assessment of the water area. This paper proposes a model for the key processes of fine sediment dynamics, which reflects field data about muddy bed structures and their dynamics obtained during the monitoring campaign in 2007. One of the specific features of the sediment in the Bay at present is the persistent existence of fluid mud layers (water content over 300?%) with a thickness of around a few decimeters, which might be caused by deposition of abundant organic particles due to eutrophication. The present study shows that diffusion flux model delivers quite reliable results for estimating erosion flux from the top of fluid mud layers after calibrating the model parameter against the time series data of vertical flux measured by an acoustic Doppler velocimeter system. This study also derives analytical solutions, based on the Bingham fluid concept, of advection flux in the fluid mud layer on which external shear stress force is applied.  相似文献   

Electrical conductivities of pyrolitic mantle and MORB materials up to the lowermost mantle conditions     

Kenji Ohta  Kei Hirose  Masahiro Ichiki  Katsuya Shimizu  Nagayoshi Sata  Yasuo Ohishi 《Earth and Planetary Science Letters》2010,289(3-4):497-502

The electrical conductivities of natural pyrolitic mantle and MORB materials were measured at high pressure and temperature covering the entire lower mantle conditions up to 133 GPa and 2650 K. In contrast to the previous laboratory-based models, our data demonstrate that the conductivity of pyrolite does not increase monotonically but varies dramatically with depth in the lower mantle; it drops due to high-spin to low-spin transition of iron in both perovskite and ferropericlase in the mid-lower mantle and increases sharply across the perovskite to post-perovskite phase transition at the D″ layer. We also found that the MORB exhibits much higher conductivity than pyrolite. The depth–conductivity profile measured for pyrolite does not match the geomagnetic field data below about 1500-km depth, possibly suggesting the existence of large quantities of subducted MORB crust in the deep lower mantle. The observations of geomagnetic jerks suggest that the electrical conductivity may be laterally heterogeneous in the lowermost mantle with high anomaly underneath Africa and the Pacific, the same regions as large low shear-wave velocity provinces. Such conductivity and shear-wave speed anomalies are also possibly caused by the deep subduction and accumulation of dense MORB crust above the core–mantle boundary.  相似文献   

Development of an operational coastal model of the Seto Inland Sea,Japan     

Kei Sakamoto  Goro Yamanaka  Hiroyuki Tsujino  Hideyuki Nakano  Shogo Urakawa  Norihisa Usui  Mikitoshi Hirabara  Koji Ogawa 《Ocean Dynamics》2016,66(1):77-97

  相似文献   

Gravitational wave background from neutrino-driven gamma-ray bursts     

Takashi Hiramatsu  Kei Kotake  Hideaki Kudoh  Atsushi Taruya 《Monthly notices of the Royal Astronomical Society》2005,364(3):1063-1068

We study cosmic microwave background (CMB) secondary anisotropies produced by inhomogeneous reionization by means of cosmological simulations coupled with the radiative transfer code crash . The reionization history is consistent with the Wilkinson Microwave Anisotropy Probe Thomson optical depth determination. We find that the signal arising from this process dominates over the primary CMB component for   l ≳ 4000  and reaches a maximum amplitude of   l ( l + 1) C_l /2π≃ 1.6 × 10⁻¹³  on arcmin scales (i.e. l as large as several thousands). We then cross-correlate secondary CMB anisotropy maps with neutral hydrogen 21-cm line emission fluctuations obtained from the same simulations. The two signals are highly anticorrelated on angular scales corresponding to the typical size of H  ii regions (including overlapping) at the 21-cm map redshift. We show how the CMB/21-cm cross-correlation can be used: (i) to study the nature of the reionization sources; (ii) to reconstruct the cosmic reionization history; (iii) to infer the mean cosmic ionization level at any redshift. We discuss the feasibility of the proposed experiment with forthcoming facilities.  相似文献   

Discussion of landslide self‐organized criticality and the initiation of debris flow     

Chen Chien‐Yuan  Yu Fan‐Chieh  Lin Sheng‐Chi  Cheung Kei‐Wai 《地球表面变化过程与地形》2007,32(2):197-209

  相似文献   

Space weathered rims found on the surfaces of the Itokawa dust particles     

Takaaki Noguchi  Makoto Kimura  Takahito Hashimoto  Mitsuru Konno  Tomoki Nakamura  Michael E. Zolensky  Ryuji Okazaki  Masahiko Tanaka  Akira Tsuchiyama  Aiko Nakato  Toshinori Ogami  Hatsumi Ishida  Ryosuke Sagae  Shinichi Tsujimoto  Toru Matsumoto  Junya Matsuno  Akio Fujimura  Masanao Abe  Toru Yada  Toshifumi Mukai  Munetaka Ueno  Tatsuaki Okada  Kei Shirai  Yukihiro Ishibashi 《Meteoritics & planetary science》2014,49(2):188-214

On the basis of observations using Cs‐corrected STEM, we identified three types of surface modification probably formed by space weathering on the surfaces of Itokawa particles. They are (1) redeposition rims (2–3 nm), (2) composite rims (30–60 nm), and (3) composite vesicular rims (60–80 nm). These rims are characterized by a combination of three zones. Zone I occupies the outermost part of the surface modification, which contains elements that are not included in the unchanged substrate minerals, suggesting that this zone is composed of sputter deposits and/or impact vapor deposits originating from the surrounding minerals. Redeposition rims are composed only of Zone I and directly attaches to the unchanged minerals (Zone III). Zone I of composite and composite vesicular rims often contains nanophase (Fe,Mg)S. The composite rims and the composite vesicular rims have a two‐layered structure: a combination of Zone I and Zone II, below which Zone III exists. Zone II is the partially amorphized zone. Zone II of ferromagnesian silicates contains abundant nanophase Fe. Radiation‐induced segregation and in situ reduction are the most plausible mechanisms to form nanophase Fe in Zone II. Their lattice fringes indicate that they contain metallic iron, which probably causes the reddening of the reflectance spectra of Itokawa. Zone II of the composite vesicular rims contains vesicles. The vesicles in Zone II were probably formed by segregation of solar wind He implanted in this zone. The textures strongly suggest that solar wind irradiation damage and implantation are the major causes of surface modification and space weathering on Itokawa.  相似文献   

Mineral chemistry of MUSES‐C Regio inferred from analysis of dust particles collected from the first‐ and second‐touchdown sites on asteroid Itokawa     

Tomoki Nakamura  Aiko Nakato  Hatsumi Ishida  Shigeru Wakita  Takaaki Noguchi  Michael E. Zolensky  Masahiko Tanaka  Makoto Kimura  Akira Tshuchiyama  Toshihiro Ogami  Takahito Hashimoto  Mitsuru Konno  Masayuki Uesugi  Toru Yada  Kei Shirai  Akio Fujimura  Ryuji Okazaki  Scott. A. Sandford  Yukihiro Ishibashi  Masanao Abe  Tatsuaki Okada  Munetaka Ueno  Junichiro Kawaguchi 《Meteoritics & planetary science》2014,49(2):215-227

The mineralogy and mineral chemistry of Itokawa dust particles captured during the first and second touchdowns on the MUSES‐C Regio were characterized by synchrotron‐radiation X‐ray diffraction and field‐emission electron microprobe analysis. Olivine and low‐ and high‐Ca pyroxene, plagioclase, and merrillite compositions of the first‐touchdown particles are similar to those of the second‐touchdown particles. The two touchdown sites are separated by approximately 100 meters and therefore the similarity suggests that MUSES‐C Regio is covered with dust particles of uniform mineral chemistry of LL chondrites. Quantitative compositional properties of 48 dust particles, including both first‐ and second‐touchdown samples, indicate that dust particles of MUSES‐C Regio have experienced prolonged thermal metamorphism, but they are not fully equilibrated in terms of chemical composition. This suggests that MUSES‐C particles were heated in a single asteroid at different temperatures. During slow cooling from a peak temperature of approximately 800 °C, chemical compositions of plagioclase and K‐feldspar seem to have been modified: Ab and Or contents changed during cooling, but An did not. This compositional modification is reproduced by a numerical simulation that modeled the cooling process of a 50 km sized Itokawa parent asteroid. After cooling, some particles have been heavily impacted and heated, which resulted in heterogeneous distributions of Na and K within plagioclase crystals. Impact‐induced chemical modification of plagioclase was verified by a comparison to a shock vein in the Kilabo LL6 ordinary chondrite where Na‐K distributions of plagioclase have been disturbed.  相似文献