Petrological and Geochemical Characteristics of Intrusive Rocks Related to Porphyry Copper Mineralization and the Implications for the Genesis of Deposits in the Namosi area, Viti Levu, Republic of the Fiji Islands     

Takayuki Tanaka  Akira Imai  Saori Egashira  Sachihiro Sakomoto  Kentaro Yasunaga    Katsuhiko Maeda 《Resource Geology》2010,60(1):35-51

In the Namosi district, of Viti Levu Island, Republic of the Fiji Islands, we conducted chemical analysis on intrusive rocks and attempted to clarify the relationship between petrological characteristics and mineralization. Samples were collected from the Waisoi copper deposit, Waivaka corridor, Waisomo, Wailutelevu and Wainabama Southwest localities. The intrusive rocks in the district show the overall characteristics of calc-alkaline magnetite series. Using the normative composition diagram for granite classification, most of the intrusive rocks plot in the tonalite, granodiorite, quartz monzodiorite and quartz diorite fields. Rare earth element (REE) analysis revealed that at Waisoi the intrusive rocks tend towards an Eu positive anomaly, whereas most of those at Waisomo tend to have a negative anomaly. The (Ce_cn/Yb_cn)/Yb_cn ratio shows that the intrusive rocks in the Namosi district may be derived from a mantle origin magma possibly contaminated by crustal materials. Waisoi rocks have less contamination with continental crust and show higher gold content compared to those of the Waivaka corridor. The observed differences between Waisoi and Waivaka corridor in the Cu/Au ratio might also be caused by varying amounts of contamination by crustal materials. There is no clear correlation between the La/Yb ratio and K–Ar ages, however, the La/Yb ratio of the Waivaka corridor rocks has a wide range, suggesting a variable amount of crustal contamination of the magma from 7 to 5 Ma. The less crustal contamination and generation of relatively high silica contents under relatively oxidized conditions in the Waisoi magmas is correlated with Au-rich porphyry copper mineralization and in contrast more crustal contamination produced Au-poor porphyry copper mineralization at the Waivaka Corridor in the Namosi district.  相似文献   

Alkalinization and acidification of stream water with changes in atmospheric deposition in a tropical dry evergreen forest of northeastern Thailand          下载免费PDF全文

Hiroyuki Sase  Jesada Luangjame  Hathairatana Garivait  Bopit Kietvuttinon  Thiti Visaratana  Masato Kamisako  Ryo Kobayashi  Seiichi Ohta  Junko Shindo  Kentaro Hayashi  Hideshige Toda  Kazuhide Matsuda 《水文研究》2017,31(4):836-846

Field surveys on atmospheric deposition and stream water chemistry were conducted in an evergreen forest in northeastern Thailand characterized by a tropical savanna climate with distinct dry and wet seasons. Atmospheric deposition of ion constituents by throughfall and stemflow was shown to increase in the beginning and end of the wet season, reflecting the precipitation pattern. The pH and electrical conductivity of stream water increased with alkalinity and base cation concentrations due to mineralization of organic matter by the first rain and retention of anions in soil during the start of the wet season. After initial alkalinization, the pH and alkalinity declined rapidly with the highest SO₄^2? concentration displayed in the middle towards the end of the wet season. The magnitude of peaks in SO₄^2? concentration (13.5–60.6 μmol_c/L) reflects deposition during the first 2 months of the wet season (March and April) in respective years (60.8–170 mol_c/ha). Release of SO₄^2? with H⁺, which is retained in soil during the early wet season, may cause acidification later in the season. The deposition and concentration of SO₄^2? declined over 6 years. However, the pH of stream water declined with increasing concentrations of SO₄^2? and other major ions. The release of materials accumulated in the ecosystem was facilitated by the decrease in SO₄^2? concentration/deposition and increased precipitation in the middle–late wet season. The retention‐release cycle of SO₄^2? largely contributed to both seasonal and interannual variations in stream water chemistry in the tropical savanna climate studied.  相似文献   

Stability of a circular tunnel in cohesive-frictional soil subjected to surcharge loading     

Kentaro Yamamoto  Andrei V. Lyamin  Daniel W. Wilson  Scott W. Sloan  Andrew J. Abbo 《Computers and Geotechnics》2011

The stability of circular tunnels in cohesive-frictional soils subjected to surcharge loading has been investigated theoretically and numerically assuming plane strain conditions. Despite the importance of this problem, previous research on the subject is very limited. At present, no generally accepted design or analysis method is available to evaluate the stability of tunnels/openings in cohesive-frictional soils. In this study, continuous loading is applied to the ground surface, and both smooth and rough interface conditions are modelled. For a series of tunnel diameter-to-depth ratios and material properties, rigorous lower- and upper-bound solutions for the ultimate surcharge loading are obtained by applying finite element limit analysis techniques. For practical use, the results are presented in the form of dimensionless stability charts with the actual tunnel stability numbers being closely bracketed from above and below. As an additional check on the solutions, upper-bound rigid-block mechanisms have been developed and the predicted collapse loads from these are compared with those from finite element limit analysis. Finally, an expression that approximates the ultimate surcharge load has been devised which is convenient for use by practising engineers.  相似文献   

Flux‐Free Fusion of Silicate Rock Preceding Acid Digestion for ICP‐MS Bulk Analysis     

Kenji Shimizu  Qing Chang  Kentaro Nakamura 《Geostandards and Geoanalytical Research》2011,35(1):45-55

We present a new method for the decomposition of silicate rocks by flux‐free fusion in preparation for whole‐rock trace element determination (Sc, Rb, Sr, Y, Zr, Nb, Cs, Ba, rare earth elements and Hf) that is especially applicable to zircon‐bearing felsic rocks. The method was verified by analyses of RMs of mafic (JB‐1a, JB‐2, JGb‐1) and felsic rocks (JG‐3, JR‐3, JSd‐1, GSP‐2, G‐2). Pellets of powdered sample (up to 500 mg) without flux were weighed and placed in a clean platinum crucible. The samples were then fused in a Siliconit® tube furnace and quenched to room temperature. The optimum condition for the fusion of granitic rock was determined to be heating for 2–3 min at 1600 °C. The fused glass in the platinum crucible after heating was decomposed using HF and HClO₄ in a Teflon® beaker. Decomposed and diluted sample solutions were analysed using a quadrupole inductively coupled plasma‐mass spectrometer. Replicate analyses (n = 4 or 5) of the RMs revealed that analytical uncertainties were generally < 3% for all elements except Zr and Hf (～ 6%) in JG‐3. These higher uncertainties may be attributed to sample heterogeneity. Our analytical results for the RMs agreed well with recommended concentrations and recently published concentrations, indicating complete decomposition of our rock samples during fusion.  相似文献   

Juxtaposition of adakite, boninite, high-TiO₂ and low-TiO₂ basalts in the Devonian southern Altay, Xinjiang, NW China   总被引：1，自引：0，他引：1  

Hecai Niu  Hiroaki Sato  Haixiang Zhang  Jun'ichi Ito  Xueyuan Yu  Takashi Nagao  Kentaro Terada  Qi Zhang 《Journal of Asian Earth Sciences》2006,28(4-6):439-456

We present petrographic and geochemical data on representative samples of the Devonian adakite, boninite, low-TiO₂ and high-TiO₂ basalts and associated rocks in the southern Altay areas, Xinjiang, NW China. These volcanic rocks mostly occur as tectonic blocks within suture zones between the Siberian and Junggar plates. Adakite occurs in the Suoerkuduke area ca. 40 km south of Fuyun, and actually represents a poorly-sorted massive volcaniclastic deposit, mostly consisting of a suite of hornblende andesite to pyroxene andesite. The geochemical features of the adakite suggest its generation by melting of subducted oceanic crust. Boninite occurs in the Saerbulake area ca. 20 km southwest of Fuyun, as pillowed lava or pillowed breccia. It is associated with high-TiO₂ basalt/gabbro and low-TiO₂ basalt. The boninites are metamorphosed, but contain relict clinopyroxene with Mg# (=100*Mg/(Mg+Fe)) of 90–92, and Cr₂O₃ contents of 0.5–0.7 wt% and chromian spinel with Cr/(Cr+Al) ratio of 0.84. The bulk rock compositions of the boninites are characterized by low and U-shaped REE with variable La/Yb ratios. They are classified as high-Ca boninite. The Cr-rich cpx phenocryst and Chromian spinel suggests that the boninites were formed by melting of mildly refractory mantle peridotite fluxed by a slab-derived fluid component under normal mantle potential temperature conditions. Basaltic rocks occur as massive flows, pillowed lavas, tuff breccia, lapilli tuff and blocks in tectonic mélanges. Together with gabbros, the basaltic rocks are classified into high-TiO₂ (>1.7 wt%) and low-TiO₂ (<1.5 wt%) types. They show variable trace element compositions, from MORB-type through transitional back-arc basin basalt to arc tholeiite, or within plate alkalic basalt. A notable feature of the Devonian formations in the southern Altay is the juxtaposition of volcanic rocks of various origins even within a limited area; i.e. the adakite and the boninites are associated with high-TiO₂ and low-TiO₂ basalts and/or gabbros, respectively. This is most likely produced by complex accretion and tectonic processes during the convergence in the Devonian–Carboniferous paleo-Asian Ocean between the Siberian and Junggar plates.  相似文献   

Terrestrial heat flow at Hirabayashi on Awaji Island, south-west Japan   总被引：1，自引：0，他引：1  

Taku Kitajima  Yoji Kobayashi  Ryuji Ikeda  Yoshihisa Iio  Kentaro Omura 《Island Arc》2001,10(3-4):318-325

Abstract Terrestrial heat flow at Hirabayashi in Awaji Island, south-west Japan, was investigated using the deep borehole penetrating through the Nojima Fault, which was activated during the 1995 Hyogo-ken Nanbu earthquake, by measuring the thermal conductivity of basement rocks. Using the temperature logging data, the value of terrestrial heat flow in Hirabayashi was found to be 56.6 ± 5.2 mW/m². The relationship between cut-off depth of aftershocks of the Hyogo-ken Nanbu earthquake in Hirabayashi and terrestrial heat flow are discussed. The cut-off depth roughly corresponds to isotherms of 300°C.  相似文献   

Carbonate Minerals in the Warrawoona Group, Pilbara Craton: Implications for Continental Crust, Life, and Global Carbon Cycle in the Early Archean     

Kentaro NAKAMURA  Yasuhiro KATO 《Resource Geology》2002,52(2):91-100

Abstract: The occurrences of the Early Archean carbonate minerals are compiled and their precipitation processes are investigated for the Warrawoona Group, Pilbara Craton. Sedimentary carbonate rocks such as limestone and dolostone are very rare, and only a small amount of sedimentary carbonate minerals are sometimes contained in the hydrothermal bedded chert, implying that a sink of CO₂ was minor in the Early Archean sediments. Moreover, it is very likely that the activity of cyanobacteria forming stromatolites was considerably low in the Early Archean. Microfossils and carbonaceous matter in the hydrothermal cherts are probably derived from a non-photosynthetic microorganisms related to the seafloor hydrothermal activity. Their preservation in sediments may play a very minor role in carbon sink of the Earth's surface.
On the other hand, carbonatized volcanic rocks subjected to seafloor hydrothermal alteration occur ubiquitously in the Early Archean greenstone belts such as the Warrawoona Group, suggesting that the hydrothermally altered oceanic crust had large amounts of CO₂ as carbonate minerals. Global carbon cycle in the Early Archean is considered to have been controlled by the intense seafloor hydrothermal alteration. Large amounts of CO₂ were sunk into the oceanic crust by the alteration. The carbonatized oceanic crust was partly accreted to the continents and/or island–arcs, and partly subducted into the mantle without decomposition. Significant amounts of carbonate minerals in the carbonatized oceanic crust were very likely to store in the accretionary prisms and mantle, consequently giving rise to a decrease of atmospheric and oceanic CO₂.  相似文献   

A review of Pacific salmon hatchery programmes on Hokkaido Island, Japan     

Morita  Kentaro; Saito  Toshihiko; Miyakoshi  Yasuyuki; Fukuwaka  Masa-aki; Nagasawa  Toru; Kaeriyama  Masahide 《ICES Journal of Marine Science》2006,63(7):1353-1363

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Coastal upwelling along the north coast of Papua New Guinea and El Niño events during 1981–2005     

Takuya Hasegawa  Kentaro Ando  Keisuke Mizuno  Roger Lukas  Bunmei Taguchi  Hideharu Sasaki 《Ocean Dynamics》2010,60(5):1255-1269

We investigate the relationship between sea surface temperature (SST) cooling and upwelling along Papua New Guinea’s (PNG) north coast before the onset of El Niño events using a hindcast experiment with a high-resolution ocean general circulation model. Coastal upwelling and related SST cooling appear along PNG north coast during the boreal winter before the onsets of six El Niño events occurring during 1981–2005. Relatively cool SSTs appear along PNG north coast during that time, when anomalous northwesterly surface wind stress, which can cause coastal upwelling by offshore Ekman transport appearing over the region. In addition, anomalous cooling tendencies of SST are observed, accompanying anomalous upward velocities at the base of the mixed layer and shallow anomalies of 27°C isotherm depth. It is also shown that entrainment cooling plays an important role in the cooling of the mixed layer temperature in this region.  相似文献   

Geochemical constraints on the depositional environment of the 1.84 Ga Embury Lake Formation,Flin Flon Belt,Canada     

Kento Motomura  Shoichi Kiyokawa  Minoru Ikehara  Kentaro Tanaka  Yuji Sano 《Island Arc》2020,29(1)

The Flin Flon Belt of Canada contains Paleoproterozoic volcanic–sedimentary sequences that are related to the Trans‐Hudson Orogeny. The sequences include island arc volcanic and volcaniclastic rocks (Amisk Group) that are unconformably overlain by subaerial sedimentary rocks (Missi Group), and younger deep facies sediments. In the Flin Flon area, several north–south trending faults divide the sequences into blocks and obscure the depositional environment of the deep facies sediments. Locally, within the Flin Flon area, the Embury Lake Formation is in fault contact with island arc volcanic–sedimentary sequences of the Amisk and Missi Groups. To identify the depositional environment of the Embury Lake Formation, we used lithologic and geochemical approaches. Here, we report carbon isotopic values in organic matter (δ¹³C_org) and sulfur isotopes (δ³⁴S), as well as total organic carbon and total sulfur measurements for the black shale in the formation. Samples were taken from a drill core that contains alternating bands of sandstone and black shale. Pyrite in the black shale is divided into four textural types: euhedral, vein‐type, elliptical, and microcrystalline. Microcrystalline pyrite is typically generated by microbially mediated sulfate reduction. An extremely low S/C ratio (avg. = 0.04) is consistent with lacustrine deposition. The ranges of δ¹³C_org (?36 ‰ to ?27 ‰) and δ³⁴S (+3.0 ‰ to +7.7 ‰) values can be explained by bacterial photosynthesis that involved Calvin cycle and acetyl CoA pathways, and sulfate reduction in a low‐sulfate environment. Considering the depositional age reported in a previous study of < 1.84 Ga, the Embury Lake Formation was likely emplaced in a lacustrine setting during the Trans‐Hudson Orogeny.  相似文献