Multiproxy Analyses of Stratigraphy and Palaeoenvironment of the Late Palaeolithic Grabow Floodplain Site,Northern Germany     

Johann Friedrich Tolksdorf  Falko Turner  Knut Kaiser  Eileen Eckmeier  Mareike Stahlschmidt  Rupert A. Housley  Klaus Breest  Stephan Veil 《Geoarchaeology》2013,28(1):50-65

Changing river courses and fluctuations of the water table were some of the most fundamental environmental changes that humans faced during the Late Glacial, particularly as these changes affected areas intensively used for settlement and resource exploitation. Unfortunately, only a few stratigraphies have been documented in the North European plain that show the interaction between river development, vegetation history, and occupation by Late Palaeolithic humans. Here, we present the results of detailed stratigraphical studies (pedology, archaeology, chrono‐, tephra‐, and palynostratigraphy) at the Federmesser site Grabow 15 located in the broad Elbe River valley. The research aimed to produce a model of site formation based on a multiproxy approach, relating the local evidence to the palaeoenvironmental and settlement history of the wider region. After deposition of fluvial sands during the Late Pleniglacial in a braided setting, the river course developed locally toward a meandering system at the transition from the Older Dryas to the Allerød, while periodic flooding led to the deposition of floodplain sediments during the early Allerød. The floodplain was settled by people of the earliest “Federmessergruppen,” who are believed to have chosen this open floodplain area along the river for collecting and processing amber of local origin. Their artifacts became embedded in the aggrading floodplain sediments. In the late Allerød, floodplain sedimentation ceased and a Fluvisol‐type soil developed, indicating a trend toward geomorphic stability. The Fluvisol was then covered by silty floodplain sediments due to a rising water level during the late Younger Dryas resulting in the cessation of human occupation in the area. Subsequent organic‐rich Late Glacial/Holocene sediments preserved the settlement remains to the present.  相似文献   

The L3–6 chondritic regolith breccia Northwest Africa (NWA) 869: (II) Noble gases and cosmogenic radionuclides     

Kees WELTEN  Marc W. CAFFEE  Luitgard FRANKE  A. J. Timothy JULL  Marlene D. LeCLERC  Knut METZLER  Ulrich OTT 《Meteoritics & planetary science》2011,46(7):970-988

Abstract– We measured cosmogenic radionuclides and noble gases in the L3–6 chondrite breccia Northwest Africa (NWA) 869, one of the largest meteorite finds from the Sahara. Concentrations of ¹⁰Be, ²⁶Al, and ³⁶Cl in stone and metal fractions of six fragments of NWA 869 indicate a preatmospheric radius of 2.0–2.5 m. The ¹⁴C and ¹⁰Be concentrations in three fragments yield a terrestrial age of 4.4 ± 0.7 kyr, whereas two fragments show evidence for a recent change in shielding, most likely due to a recent impact on the NWA meteoroid, approximately 10⁵ yr ago, that excavated material up to approximately 80 cm deep and exposed previously shielded material to higher cosmic‐ray fluxes. This scenario is supported by the low cosmogenic ³He/²¹Ne ratios in these two samples, indicating recent loss of cosmogenic ³He. Most NWA samples, except for clasts of petrologic type 4–6, contain significant amounts of solar Ne and Ar, but are virtually free of solar helium, judging from the trapped ⁴He/²⁰Ne ratio of approximately 7. Trapped planetary‐type Kr and Xe are most clearly present in the bulk and matrix samples, where abundances of ¹²⁹Xe from decay of now extinct ¹²⁹I are highest. Cosmogenic ²¹Ne varies between 0.55 and 1.92 × 10^?8 cm³ STP g^?1, with no apparent relationship between cosmogenic and solar Ne contents. Low cosmogenic (²²Ne/²¹Ne)_c ratios in solar gas free specimens are consistent with irradiation in a large body. Combined ¹⁰Be and ²¹Ne concentrations indicate that NWA 869 had a 4π cosmic‐ray exposure (CRE) age of 5 ± 1 Myr, whereas elevated ²¹Ne concentrations in several clasts and bulk samples indicate a previous CRE of 10–30 Myr on the parent body, most probably as individual components in a regolith. Unlike many other large chondrites, NWA 869 does not show clear evidence of CRE as a large boulder near the surface of its parent body. Radiogenic ⁴He concentrations in most NWA 869 samples indicate a major outgassing event approximately 2.8 Gyr ago that may have also resulted in loss of solar helium.  相似文献   

Transferability of hydrological model parameter spaces in the estimation of runoff in ungauged catchments     

Mulugeta B. Zelelew  Knut Alfredsen 《水文科学杂志》2013,58(8):1470-1490

Abstract

In this study, transferability options of the Hydrologiska Byråns Vattenbalansavdelning (HBV) hydrological model parameter (MP) spaces were investigated to estimate ungauged catchment runoff. Three approaches were applied in the study: MP space transfer from single, neighbouring and all potential donor catchments. The model performance was evaluated by a jackknife procedure, where one catchment at a time was treated as if ungauged, and behavioural MP sets from candidate donor catchments were used to estimate the “ungauged” runoff. The results showed that ungauged catchment runoff estimation could not be guaranteed by transferring MP sets from a single physiographically nearest donor catchment. Integrating MP sets typically from one to six donor catchments supplemented the lack of effective MP sets and improved the model performance at the ungauged catchments. In addition, the analysis results revealed that the model performance converged to an average performance when the MP sets of all potential donor catchments were integrated.  相似文献   

Assimilation of ice concentration in a coupled ice–ocean model,using the Ensemble Kalman filter     

Knut Arild?Lis?terEmail author  Julia?Rosanova  Geir?Evensen 《Ocean Dynamics》2003,53(4):368-388

An implementation of the Ensemble Kalman filter (EnKF) with a coupled ice–ocean model is presented. The model system consists of a dynamic–thermodynamic ice model using the elastic-viscous-plastic (EVP) rheology coupled with the HYbrid Coordinate Ocean Model (HYCOM). The observed variable is ice concentration from passive microwave sensor data (SSM/I). The assimilation of ice concentration has the desired effect of reducing the difference between observations and model. Comparison of the assimilation experiment with a free-run experiment shows that there are large differences, especially in summer. In winter the differences are relatively small, partly because the atmospheric forcing used to run the model depends upon SSM/I data. The assimilation has the strongest impact close to the ice edge, where it ensures a correct location of the ice edge throughout the simulation. An inspection of the model ensemble statistics reveals that the error estimates of the model are too small in winter, partly a result of too low model ice-concentration variance in the central ice pack. It is found that the ensemble covariance between ice concentration and sea-surface temperature in the same grid cell is of the same sign (negative) throughout the year. The ensemble covariance between ice concentration and salinity is more dependent upon the physical mechanisms involved, with ice transport and freeze/melt giving different signs of the covariances. The ice-transport and ice-melt mechanisms also impact the ice-concentration variance and the covariance between ice concentration and ice thickness. The ensemble statistics show a high degree of complexity, which to some extent merits the use of computationally expensive assimilation methods, such as the Ensemble Kalman filter. The present study focuses on the assimilation of ice concentration, but it is understood that assimilation of other datasets, such as sea-surface temperature, would be beneficial.Responsible Editor: Jin-Song von Storch  相似文献   

PPP Correction of the IPCC Emission Scenarios – Does it Matter?     

Bjart J. Holtsmark  Knut H. Alfsen 《Climatic change》2005,68(1-2):11-19

Ian Castles and David Henderson have criticized IPCC’s Special Report on Emissions Scenarios (SRES) (IPCC: 2000, Special Report on Emissions Scenarios, Intergovernmental Panel on Climate Change (IPCC), Cambridge University Press, Cambridge, 595 pp. http://www.grida.no/climate/ipcc/emission/index.htm) for using market exchange rates (MER) instead of purchasing power parities (PPP), when converting regional GDP into a common denominator. The consequence is that poor countries generally appear to be poorer than they actually are. An overstated income gap between the rich and poor countries in the base year gives rise to projections of too high economic growth in the poor countries, because the scenarios are constructed with the aim of reducing the income gap. Castles and Henderson claim that overstated economic growth means that greenhouse gas emissions are overstated as well. However, because closure of the emission-intensity gap between the rich and the poor parts of the world is another important driving force in the scenarios, we argue that the use of MER in the SRES scenarios has not caused an overestimation of the global emission growth because, as far as global emissions are concerned, the overstated income gap is effectively neutralized by the overstated emission-intensity gap.  相似文献   

Tracer diffusion of Mg, Ca, Sr, and Ba in Na-aluminosilicate melts     

Knut Roselieb  Albert Jambon 《Geochimica et cosmochimica acta》2002,66(1):109-123

We employed the thin source technique to investigate tracer diffusion of Mg, Ca, Sr, and Ba in glasses and supercooled melts of albite (NaAlSi₃O₈) and jadeite (NaAlSi₂O₆) compositions. The experiments were conducted at 1 bar and at temperatures between 645 and 1025°C. Typical run durations ranged between 30 min and 35 days. The analysis of the diffusion profiles was performed with the electron microprobe. Diffusivities of Ca, Sr, and Ba were found to be independent of either duration t of the experiment or tracer concentration M, initially introduced into the sample. Mg exhibits a diffusivity depending on run time and concentration and tracer diffusivity is derived by extrapolation to M/√t = 0. Temperature dependence of the diffusivity D can be represented by an Arrhenius equation D = D_o exp(−E_a/RT), yielding the following least-squares fit parameters (with D in m²/s and E_a in kJ/mol): D_Mg = 1.8 · 10⁻⁵ exp(−234 ± 20/RT), D_Ca = 3.5 · 10⁻⁶ exp(−159 ± 6/RT), D_Sr = 3.6 · 10⁻⁶ exp(−160 ± 6/RT), and D_Ba = 6.0 · 10⁻⁶ exp(−188 ± 12/RT) for albite; and D_Mg = 8.3 · 10⁻⁶ exp(−207 ± 18/RT), D_Ca = 3.8 · 10⁻⁶ exp(−153 ± 4/RT), D_Sr = 2.3 · 10⁻⁶ exp(−150 ± 4/RT), and D_Ba = 3.7 · 10⁻⁵ exp(−198 ± 4/RT) for jadeite composition. Ca and Sr diffusivities agree within error in both compositions and exhibit the fastest diffusivities, whereas Mg reveals the lowest diffusivity. The relationship between activation energy and radius shows a minimum at Ca and Sr for albite and jadeite compositions extending the relationship already observed elsewhere for alkalies. With increasing substitution of Si by (Na + Al), diffusivities increase, whereas activation energies decrease. Furthermore, a simple model modified from that of Anderson and Stuart (Anderson O. L. and Stuart D. A., “Calculation of activation energy of ionic conductivity in silica glasses by classical methods,” J. Am. Ceram. Soc.37, 573-580, 1954) is discussed for calculating the activation energies.  相似文献   

Fishing vessel profitability and local economic link obligations—the case of Norwegian trawlers     

Ola Flaaten  Knut Heen 《Marine Policy》2004,28(6):1154

This paper investigates to what extent limited entry licence local-link obligations hamper economic performance of Norwegian wet fish trawlers. For 1999 average landing prices, gross revenue, net profit and some other economic indicators are compared for three groups of trawlers: (A) vessels that had local-link licence obligations and complied with them; (B) vessels that had such obligations but did not comply; and (C) vessels without local-link obligations. Average operating profit was highest for Group C. Group B vessels’ operating profit was just above that of Group A, despite significantly higher revenues. For all fish species, except redfish, Group C trawlers received higher prices than the other vessels.  相似文献   

Scour effects in piled structures—A sensitivity analysis     

Dimitris Diamantidis  Knut Arnesen 《Ocean Engineering》1986,13(5)

A sensitivity analysis is presented in this paper to judge the importance of several parameters influencing scour effects on piles of offshore foundations. The decrease of the pile reliability due to scour is also studied by applying the first-order reliability method. Suggestions for lateral pile resistance in design are included.  相似文献   

Dynamics of carbohydrates in the Norwegian Sea inferred from monthly profiles collected during 3 years at 66°N, 2°E     

Sverre M. Myklestad  Knut Yngve Brsheim 《Marine Chemistry》2007,107(4):475-485

Water samples were collected monthly for 3 years at 66°N, 2°E in the Norwegian Sea, 250 nautical miles off the Norwegian coast. Concentrations of mono- and polysaccharides were measured with the 2,4,6-tripyridyl-s-triazine (TPTZ) spectroscopic method. Total dissolved carbohydrates varied from 3.4 to 28.2 μM C of all samples and the ratio of carbohydrate to dissolved organic C (DOC) varied from an average of 14% at 0–25 m depth to 11% at 800–2000 m depth. This indicates that dissolved carbohydrates were a significant constituent of DOC in the Norwegian Sea. Polysaccharides varied from 0.4 to 21.5 μM C and monosaccharides from 0.7 to 11.7 μM C at all depths. The level of monosaccharides was relatively constant at 2.8–3.2 μM C below the euphotic zone, whereas polysaccharides showed more varying concentrations. Dissolved carbohydrates accumulated during the productive season, reaching maximum concentrations during summer although interannual differences were observed. A significant positive correlation between Chl a and soluble carbohydrate was found in one growing season with nutrient analyses. Average values for total carbohydrates were highest in the surface – 0 to 25 m – with 13.3 μM C and decreased to 8.4 μM C at 800–2000 m depth. The ratio of monosaccharides to polysaccharides exhibited a marked seasonal variation, increased from January to a maximum in June of 1.1, and declined to 0.5 in July.  相似文献   

Sandstone diagenesis and porosity modification during basin evolution     

Knut Bjørlykke  Mogens Ramm  Girish C. Saigal 《International Journal of Earth Sciences》1989,78(1):243-268

The properties of sandstones as potential reservoirs and shales as source rocks depend on primary facies relationships and diagenesis. Porostiy loss due to mechanical compation and pressure solution is essentially a function of grain parameters (sorting, packing and composition) and net overburden stress. The porosity loss can be predicted to a certain extent. The importance of secondary porosity caused by dissolution of framework grains and cements has been fully recognized. The discussion has focused on the processes causing such dissolution and to what extent it can cause net increase in porosity.The most critical factor in clastic diagenesis is the nature of porewater flow and the degree of mass transfer taking place as a result of this. In the North Sea reservoir rocks, petrographic and geochemical evidence suggest that most of the leaching of feldspar and mica resulting in the formation of kaolinite occurred early during fresh wather flushing. Recent calculations indicate that »acids« derived from source rocks are inadequate to explain the secondary porosity observed in reservoir rocks. Mathematical modelling suggests that thermal convection is of limited importance in sedimentary basins, except where there are high lateral changes in geothermal gradients. Evidence from porewater geochemistry suggests that porewaters in sedimentary basins are often stratified or compartmentalized in a way which is inconsistent with large scale convection or compactional flow, making it necessary to assume that diagenetic reactions are relatively isochemical during deeper burial.A better understanding of the diagenetic reactions will help us to improve our predictions about porosity/depth relations, pore size, and pore geometry distribution in reservoir rocks.Porosity depth trends from offshore Norway and published data from other basins are discussed. Empirical linear best fit lines are found to illustrate the relationship quite well for depths between one and five km. Within a specific region, the linear porosity gradient is a function of mineral composition and of temperature and pressure gradients. Primary porosity tends to be best preserved in sandstones with high proportions of stable grains (e. g. in quartz arenites) down to about 3 or 4 km. At greater depth, porosity loss is accelerated due to increased pressure solution. Secondary and primary porosity adjacent to feldspar grains then tends to be selectively preserved relative to primary pores between quartz grains.

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Zusammenfassung Die bestimmenden Faktoren von Sandsteinen als mögliche Speichergesteine und von Schiefern als Bildungsort von Kohlenwasserstoffen liegen in den Verhältnissen der primären Fazieausbildungen der Gesteine und deren Diagenesegeschichte. Korn-Parameter (Sortierung, Pakkungsdichte und Zusammensetzung) und Netto-Auflast steuern mechanische Kompaktion und Drucklösung. Diese sind für Porositätsreduzierungen verantwortlich, die bis zu einem bestimmten Grad abgeschätzt werden können. Der Einfluß von Lösungserscheinungen für die Bildung sekundären Porenraums, der hier definiert werden konnte und die Vorgänge, die Lösungsphasen iniziieren, bilden den zentralen Punkt der Diskussion.Größte Bedeutung in der Diagenese klastischer Sedimente kommt dem Charakter der Grundwasserbewegungen und deren Eigenschaft im Bereich des Stofftransportes zu. Daten der Petrographie und der Geochemie ergeben für die Speichergesteine der Nordsee, daß der Hauptanteil der Lösung von Feldspat und Muskovit, ein Vorgang, der zur Bildung von Kaolinit führte, frühdiadenetisch unter Einfluß von Süßwasser stattfand. Aufgrund neuerer Kalkulationen kann die Bedeutung saurer Lösungen, die man von dem Bildungsgestein hergeleitet, für die sekundäre Porosität der Speichergesteine ausgeschlossen werden. Mathematische Berechnungen räumen dem Einfluß thermaler Konvektion in sedimentären Becken meist geringe Bedeutung zu, es sei denn es gibt große laterale Unterschiede des geothermischen Gradienten. Die geochemische Analyse des Porenwassers ergibt vertikale und horizontale Zonierungen im Chemismus des Wassers. Diese Tatsache widerspricht der These einer großräumischen Konvektion, da in diesem Fall die Diagenese-Prozesse unter Bedeckung bei relativ einheitlicher chemischer Zusammensetzung ablaufen würden.Ein besseres Verständnis der diagenetischen Vorgänge wird die Abhängigkeit des Verhältnisses von Porosität zur Tiefe, der Verteilung des Hohlraumvolumens und der Hohlraumgeometrie in Speichergesteinen erleichtern.Diskutiert werden Zusammenhänge von Porosität und Tiefe, die Daten an Stellen vor der Küste Norwegens und anderen Becken entnommen wurden. Für Tiefen zwischen einem und fünf Kilometern scheinen empirische, lineare Geraden am besten die Verhältnisse zu verdeutlichen. Regional begrenzt kann der lineare Porositätsgradient als eine Funktion der Gradienten von Mineralzusammensetzung, Temperatur und Druck beschrieben werden. Primäre Porosität ist am besten in Sandsteinen mit einem hohen Anteil an stabilen Komponenten (z. B. Quatzarenite) bis zu einer Tiefe von drei oder vier Kilometern erhalten.Drucklösungserscheinungen sind für die zunehmende Abnahme der Porosität in größeren Tiefen verantwortlich. Dabei scheinen sekundäre und intergranulare Porenräume zwischen Feldspatkörnern relativ zu primären Porenräumen zwischen Quartzkörnern stabiler zu sein.

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Résumé Les facteurs qui caractérisent des grès en tant que réservoirs potentiels d'hydrocarbures et des shales en tant que roches-mères sont les relations facielles primaires et la diagenèse. La perte de porosité due à la compaction mécanique et aux impressionnements («pressure-solution») est fonction essentiellement des paramètres des grains (classement, ordonnance et composition) et des contraintes dues à la surcharge. La perte de porosité peut être prévue dans une certaine mesure. On connaît l'importance de la porosité secondaire provoquée par la dissolution des grains et des ciments. La discussion est centrée sur les processus responsables de cette dissolution et sur leur incidence dans l'accroissement net de la porosité.Le facteur le plus critique dans la diagenèse des élastiques est la nature du flux d'eau intersticielle et le degré de transfert de matière qui en résulte. Dans les roches-magasins de la Mer du Nord, les observations pétrographiques et géochimiques montrent que la plus grande partie de l'altération en kaolin du feldspath et du mica s'est produite lors du lessivage par de l'eau douce. Selon des calculs récents, les «acides» dérivés des roches-mères ne peuvent expliquer la porosité secondaire des roches-magasins. La modélisation mathématique suggère que la convection thermique ne joue qu'un rôle subordonné dans un bassin de sédimentation, sauf aux endroits de forte variation latérale du gradient géothermique. L'étude géochimique des eaux intersticielles montre que dans les bassins sédimentaires, elles sont souvent stratifiées ou compartimentées d'une manière qui est incompatible avec une convection à grande échelle car un tel phénomène impliquerait des réactions diagénétiques relativement isochimiques.Une meilleure compréhension des réactions diagénétiques doit nous aider à améliorer nos prévisions relatives à la relation porosité/profondeur, et à la répartition de la taille et de la forme des pores dans les roches-magasins.Une discussion est présentée à propos de la relation porosité/profondeur, à partir des données recueillies off-shore en Norvège et de données publiées provenant d'autres bassins. Il apparaît qu'entre 0 et 5 km de profondeur, des courbes empiriques linéaires rendent le mieux compte de ces relations. Dans une région donnée, le gradient linéaire de porosité est fonction de la composition minéralogique et des gradients de pression et de température. La porosité primaire tend à être bien préservée dans les grès riches en grains stables (p. ex. dans les arénites quartziques) jusqu'à une profondeur de 3 à 4 km. Plus bas, la perte de porosité s'accélère en raison des phénomènes d'impressionnement. Dans ces conditions profondes, les pores primaires et secondaires adjacents aux grains de feldspath semblent relativement plus stables que les pores primaires situés entre les grains de quartz.

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