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11.
The cumulene carbenes are important components of hydrocarbon chemistry in low-mass star-forming cores. Here we report the first astronomical detection of the long-chain cumulene carbene H2C6 in the interstellar cloud TMC-1, from observations of two of its rotational transitions: J(K,K') = 7(1,7) --> 6(1,6) at 18.8 GHz and 8(1,8) --> 7(1,7) at 21.5 GHz, using NASA's Deep Space Network 70 m antenna at Goldstone, California. In addition we also observed the shorter cumulene carbene H2C4 at the same position. The fractional abundance of H2C6 relative to H2 is about 4.7 x 10(-11) and that of H2C4 is about 4.1 x 10(-9). The abundance of H2C6 is in fairly good agreement with gas-phase chemical models for young molecular cloud cores, but the abundance of H2C4 is significantly larger than predicted.  相似文献   
12.
13.
The northern section of the molecular cloud complex NGC 6334 has been mapped in the CO and CS spectral line emission and in continuum emission at a wavelength of 1300 μm. Our observations highlight the two dominant sources, I and I(N), and a host of weaker sources. NGC 6334 I is associated with a cometary ultracompact H  ii region and a hot, compact core ≤10 arcsec in size. Mid-infrared and CH3OH observations indicate that it is also associated with at least two protostellar sources, each of which may drive a molecular outflow. For region I we confirm the extreme high-velocity outflow first discovered by Bachiller & Cernicharo and find that it is very energetic with a mechanical luminosity of 390 L. A dynamical age for the outflow is ∼3000 yr. We also find a weaker outflow originating from the vicinity of NGC 6334 I. In CO and CS this outflow is quite prominent to the north-west, but much less so on the eastern side of I, where there is very little molecular gas. Spectral survey data show a molecular environment at position I which is rich in methanol, methyl formate and dimethyl ether, with lines ranging in energy up to 900 K above the ground state. NGC 6334 I(N) is more dense than I, but cooler, and has none of the high-excitation lines observed toward I. I(N) also has an associated outflow, but it is less energetic than the outflow from I. The fully sampled continuum map shows a network of filaments, voids and cores, many of which are likely to be sites of star formation. A striking feature is a narrow, linear ridge which defines the western boundary. It is unclear if there is a connection between this filament and the many potential sites of star formation, or if the filament existed prior to the star formation activity.  相似文献   
14.
For several reasons the fate and effects of oil pollution are not easily studied in natural ecosystems. Furthermore, the results of laboratory tests cannot easily be extrapolated to natural systems. A logical objective of ecotoxicological research is, therefore, to simulate natural systems in model ecosystem experiments. A one-year feasibility study was carried out with MOdel TIdal Flat ecosystems (MOTIFs), designed to represent tidal flat systems typical of the Wadden Sea and other temperate estuarine areas. During the first 6 months the 4 MOTIFs studied developed very similarly. After this period an oil spill was simulated by exposing two of the four MOTIFs to a floating oil mousse for one week. During this week part of the oil was buried in the sediment by bioturbation. This sediment-bound fraction caused a prolonged exposure of the MOTIFs to oil compounds. Short- and long-term effects resulted in large differences between oil-treated and control MOTIFs. These differences persisted to the end of the experiment, 7 months after the removal of most of the oil.  相似文献   
15.
At eight different areas on the shores of the lower part of Lake Zürich sphaeriids were collected at depths of 3, 6, 9, 12 and 15 m. 368 samples, each 1/16 m2 in size, contained 19,780 individuals, which belong to 14 species. The following points were examined: depth distributions of the species, associations between different species and the dependence of their abundance on environmental factors. Over the period of one year fish were kept away from test-sites in order to estimate their influence on the sphaeriid fauna.  相似文献   
16.
Isolated type III radio burst activity was observed at Clark Lake Radio Observatory in March and the first part of April, 1971, to occur in discrete regions of the corona above certain active regions. When these regions were examined under high resolution in H all the type III events appeared to have associated activity in H. The potential coronal magnetic field in these regions appeared to be either open or diverging, whereas the field over a rather active region which did not have radio burst activity was closed in a magnetic arcade. The latter feature has been associated with streamers. Streamers have also been associated with dark filaments. The occurrence of a stable dark filament in an active region appeared to have an inhibiting effect on type III activity. It is suggested that a streamer field configuration is not favorable to the escape of isolated type III exciters.  相似文献   
17.
A carbonaceous chondrite was recovered immediately after the fall near the village of Diepenveen in the Netherlands on October 27, 1873, but came to light only in 2012. Analysis of sodium and poly‐aromatic hydrocarbon content suggests little contamination from handling. Diepenveen is a regolith breccia with an overall petrology consistent with a CM classification. Unlike most other CM chondrites, the bulk oxygen isotopes are extremely 16O rich, apparently dominated by the signature of anhydrous minerals, distributed on a steep slope pointing to the domain of intrinsic CM water. A small subset plots closer to the normal CM regime, on a parallel line 2 ‰ lower in δ17O. Different lithologies in Diepenveen experienced varying levels of aqueous alteration processing, being less aqueously altered at places rather than more heated. The presence of an agglutinate grain and the properties of methanol‐soluble organic compounds point to active impact processing of some of the clasts. Diepenveen belongs to a CM clan with ~5 Ma CRE age, longer than most other CM chondrites, and has a relatively young K‐Ar resetting age of ~1.5 Ga. As a CM chondrite, Diepenveen may be representative of samples soon to be returned from the surface of asteroid (162173) Ryugu by the Hayabusa2 spacecraft.  相似文献   
18.
The Pannonian Basin, originating during the Early Miocene, is a large extensional basin incorporated between Alpine, Carpathian and Dinaride fold-thrust belts. Back-arc extensional tectonics triggered deposition of up to 500-m-thick continental fluvio-lacustrine deposits distributed in numerous sub-basins of the Southern Pannonian Basin. Extensive andesitic and dacitic volcanism accompanied the syn-rift deposition and caused a number of pyroclastic intercalations. Here, we analyze two volcanic ash layers located at the base and top of the continental series. The lowermost ash from Mt. Kalnik yielded an 40Ar/39Ar age of 18.07?±?0.07?Ma. This indicates that the marine-continental transition in the Slovenia-Zagorje Basin, coinciding with the onset of rifting tectonics in the Southern Pannonian Basin, occurs roughly at the Eggenburgian/Ottnangian boundary of the regional Paratethys time scale. This age proves the synchronicity of initial rifting in the Southern Pannonian Basin with the beginning of sedimentation in the Dinaride Lake System. Beside geodynamic evolution, the two regions also share a biotic evolutionary history: both belong to the same ecoregion, which we designate here as the Illyrian Bioprovince. The youngest volcanic ash level is sampled at the Glina and Karlovac sub-depressions, and both sites yield the same 40Ar/39Ar age of 15.91?±?0.06 and 16.03?±?0.06?Ma, respectively. This indicates that lacustrine sedimentation in the Southern Pannonian Basin continued at least until the earliest Badenian. The present results provide not only important bench marks on duration of initial synrift in the Pannonian Basin System, but also deliver substantial backbone data for paleogeographic reconstructions in Central and Southeastern Europe around the Early–Middle Miocene transition.  相似文献   
19.
In this paper we present new 40Ar/39Ar data of volcanic ash layers intercalated in the astronomically dated sections of Monte dei Corvi and Monte Gibliscemi (Italy) to obtain better radioisotopic time constraints on the Serravallian/Tortonian boundary and to confirm the intercalibration of radioisotopic and astronomical time proposed by Kuiper et al. [2004 ; Fish Canyon Tuff (FCT)-sanidine at 28.21 ± 0.03 Ma]. The latter intercalibration is supported by astronomically calibrated FCT sanidine ages for two ash layers at Monte Gibliscemi (GiF-1: 28.28 ± 0.04; GiD-3: 28.16 ± 0.04 Ma; ±1 SE). As a consequence, our results support the astronomically calibrated age of 11.608 Ma for the Tortonian Global Stratotype Section and Point and, hence, the tuning of the Serravallian/Tortonian boundary interval. The Ancona and Respighi levels at Monte dei Corvi give a more diffuse picture, possibly because of contamination with detrital or xenocrystic material and the inferior quality of biotite for intercalibration purposes.  相似文献   
20.
The principal dynamical properties of the planetary and satellite systems listed in Section 2 require these bodies to have condensed in highly-flattened nebulae which provided the dissipation forces that produced the common directions of orbital motion, and the lowe andi values. Minimum masses of these nebulae can be estimated on the assumption that the initial solar abundances apply, starting from the empirical data on present planetary and satellite compositions and masses. The asteroids and comets are assumed to be direct condensations and accretion products in their respective zones (2–4 AU and 20–50 AU), without the benefit of gravitational instability in the solar nebula, owing to the comparatively low density there; with gravitational instability accelerating and ultimately dominating the accretion of the planets and major satellites, in zones approaching and exceeding the local Roche density. Only in the case of Jupiter, gravitational instability appears to have dominated from the outset; the other planets are regarded as hybrid structures, having started from limited accretions. In Section 3 the empirical information on protostars is reviewed. ‘Globules’ are described, found to have the typical range of stellar masses and with gaseous compositions now well known thanks largely to radio astronomy. They contain also particulate matter identified as silicates, ice, and probably graphite and other carbon compounds. The measured internal velocities would predict a spread of total angular momenta compatible with the known distribution of semi-major axes in double stars. The planetary system is regarded as an ‘unsuccessful’ binary star, in which the secondary mass formed a nebula instead of a single stellar companion, with 1–2% of the solar mass. This mass fraction gives a basis for an estimate of thefrequency of planetary systems. The later phases of the globules are not well known empirically for the smaller masses of solar type; while available theoretical predictions are mostly made for non-rotating pre-stellar masses. Section 5 reviews current knowledge of the degree of stability of the planetary orbits over the past 4.5×109 yr, preparatory to estimates of their original locations and modes of origin. The results of the Brouwer and Van Woerkom theory and of recent numerical integrations by Cohenet al. indicate no drastic changes in Δa/a over the entire post-formation history of the planets. Unpublished numerical integrations by Dr P. E. Nacozy show the remarkable stability of the Jupiter-Saturn system as long as the planetary masses are well below 29 times their actual values. Numerical values of Δa/a are collected for all planets. The near resonances found for both pairs of planets and of satellites are briefly reviewed. Section 6 cites the statistics on the frequency and masses of asteroids and information on the Kirkwood gaps, both empirical and theoretical. An analogous discussion is made for the Rings of Saturn, including its extension observed in 1966 to the fourth Saturn satellite, Dione. The reality, or lack of it, of the divisions in the Rings are considered. The numbers of Trojan asteroids are reviewed, as is the curious, yet unexplained, bimodal distribution of their orbital inclinations. Important information comes from the periods of rotation of the asteroids and the orientation of their rotational axes. The major Hirayama families are considered as remnants of original asteroid clusterings whose membership has suffered decreases through planetary perturbations. Other families with fewer large members may be due to collisions. The three main classes of meteorites, irons, stones, and carbonaceous chondrites all appear to be of asteroidal origin and they yield the most direct evidence on the early thermal history of the solar system. While opinion on this subject is still divided, the author sees in the evidence definite confirmation of thecold origin of the planetary system, followed by ahot phase due to the evolving sun that caused the dissolution of the solar nebula. This massive outward ejection, that included the smaller planetesimals, appears to have caused the surface melting of the asteroids by intense impact, with the splashing responsible for the formation of the chondrules. The deep interiors of the asteroids are presumably similar to the C1 meteorites which have recently been found to be more numerous in space by two orders of magnitude than previously supposed.  相似文献   
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