滇东北麻栗坪铅锌矿床微量元素分布与赋存状态:LA-ICPMS研究   总被引：4，自引：2，他引：2  

胡宇思  叶霖  黄智龙  李珍立  韦晨  Danyushevskiy Leonid 《岩石学报》2019,35(11):3477-3492

位于扬子板块西南缘的"川滇黔接壤铅锌矿集区"是我国西南大面积低温成矿域的重要组成部分,麻栗坪铅锌矿床位于该矿集区昭通-曲靖成矿带中段,是近年来滇东北地区新发现的铅锌矿床。本文以麻栗坪铅锌矿不同硫化物为研究对象,通过LA-ICPMS原位点测试和元素Mapping分析,尝试揭示该矿床中Ge、Cd和In等微量元素在不同硫化物中分布规律与赋存状态。本次研究发现,麻栗坪矿床不同硫化物中富集的微量元素明显不同,闪锌矿主要富集Mn、Cu、Sn、Cd、In和Ge,而方铅矿主要富集Ag、Sb和Se,黄铁矿则富集As、Co和Ni。闪锌矿是分散元素Ge、In和Cd的主要载体矿物,且Cd、Ge、In、Mn、As、Sb和Ag以类质同象形式赋存于闪锌矿中;而Cu则主要以类质同象形式存在,部分Cu以黄铜矿的显微包裹体形式赋存于闪锌矿中,其中以类质同象赋存于闪锌矿中Cu和Ge呈现明显的相关性,可能暗示其与Zn的置换方式为:3Zn2+Ge4++2Cu+。总体上,该矿床闪锌矿以富集Cd、Ge,贫Fe、Mn、Co、Sn为特征,这些微量元素组成与典型MVT型矿床基本一致,明显有别于喷流沉积和岩浆热液型矿床,而与中低温条件下形成的闪锌矿微量元素组成相似。结合该矿床后生成矿特征明显等地质地球化学研究成果,我们认为该矿床应属于MVT型铅锌矿床。值得注意的是,该矿床闪锌矿相对富集In,可能暗示其形成具有特殊性,这可能与其成矿流体在长距离运移过程中所流经地层有关,该类流体活化萃取了基底地层的中-酸性岩浆岩或火山碎屑岩中的In,致使矿床中闪锌矿相对富集In。  相似文献   

Geochemistry of zircons from basic rocks of the Korosten anorthosite-mangerite-charnockite-granite complex,north-western region of the Ukrainian Shield     

Shumlyanskyy  Leonid  Belousova  Elena  Petrenko  Oksana 《Mineralogy and Petrology》2017,111(4):459-466

Mineralogy and Petrology - The concentrations of 26 trace elements have been determined by laser ablation ICP-MS in zircons from four samples of basic rocks of the Korosten...  相似文献   

Magneto-ionospheric effects of the solar eclipse of March 20, 2015, over Kharkov     

L.?F.?ChernogorEmail author  K.?P.?Garmash 《Geomagnetism and Aeronomy》2017,57(1):72-83

The results of observations of disturbances in the lower and middle ionosphere and in the geomagnetic field accompanying the partial solar eclipse over Kharkov are presented. The ionospheric effects have been studied with the use of an ionosonde and measurements of the phase and amplitude of a radio signal with a frequency of 66.(6) kHz on the Moscow–Kharkov route, and the effects in the magnetic field have been analyzed with the help of a magnetometer–fluxmeter in the range of periods from 1 to 1000 s. Disturbances in both the lower and middle ionosphere, as well as in the geomagnetic field, have been detected. The observation results have been compared with the results of a simulation of physical processes accompanying the solar eclipse. A good agreement has been found between observational and modeling results.  相似文献   

Simultaneous volume measurements of post-perovskite and perovskite in MgSiO3 and their thermal equations of state     

Tetsuya Komabayashi  Kei Hirose  Emiko Sugimura  Nagayoshi Sata  Yasuo Ohishi  Leonid S. Dubrovinsky 《Earth and Planetary Science Letters》2008,265(3-4):515-524

Simultaneous volume measurements of MgSiO₃ post-perovskite (PPv) and perovskite (Pv) were performed in a diamond anvil cell (DAC) combined with synchrotron X-rays. An externally-heated DAC was used in addition to a laser-heated DAC for the volume measurement experiment at high temperatures. The volume data were collected in the stability field of post-perovskite from 115 to 130 GPa. The temperature generated in the externally-heated and the laser-heated DACs for the volume measurement were up to 832 and 2330 K, respectively. Using two different but complementary heating techniques, we collected the data at a wide temperature range from 300 to 2330 K. The obtained P-V-T data for PPv and Pv were fitted to a third-ordered Birch-Murnaghan equation of state (EOS). For a precise comparison of the volume between the two phases, the EOSs were constructed based on the same pressure scale of MgO. The simultaneous volume measurements and the volumes calculated from the determined EOSs demonstrate that the volume difference between PPv and Pv of about 1.5% is almost constant with increasing temperature to 4000 K at the transition. At the base of the mantle, this density difference corresponds to a temperature anomaly of 1300 K without the phase transition due to the very small thermal expansivity of minerals, which has a significant effect on mantle dynamics. The thermal expansivity contrast between the top and the bottom of the mantle is a factor of 3.6. From a mantle convection study, this value suggests that huge and hot plumes are formed at the core–mantle boundary.  相似文献   

Fate of the Black Sea Acartia clausi and Acartia tonsa (Copepoda) penetrating into the Marmara Sea through the Bosphorus     

Elena Hubareva  Leonid Svetlichny  Ahmet Kideys  Melek Isinibilir 《Estuarine, Coastal and Shelf Science》2008

In October 2005 spatial distribution of live and dead Acartia clausi and Acartia tonsa was studied in the Black and Marmara Seas and near the Marmara Sea inlet of the Bosphorus, in order to understand their fate upon transportation between two seas. The morphometric characteristics in both species from all studied areas, and the decreased abundance of A. clausi and A. tonsa from the Black Sea towards the Marmara Sea indicate that the Marmara Sea Acartia populations are formed by recruitment from the Black Sea. We observed mass mortality of A. clausi in the Marmara Sea near the Prince Islands. The majority of carcasses (66% of total A. clausi numbers in the Marmara Sea) were found in the salinity gradient layer.  相似文献   

‘Invisible gold’ in bismuth chalcogenides   总被引：1，自引：0，他引：1  

Cristiana L. Ciobanu  Nigel J. Cook  Joël Brugger  Leonid V. Danyushevsky 《Geochimica et cosmochimica acta》2009,73(7):1970-1999

Gold concentrations have been determined by LA-ICPMS in bismuth chalcogenides (tellurides and sulfosalts, minerals with modular structures; chalcogen X = Te, Se, and S) from 27 occurrences. Deposit types include epithermal, skarn, intrusion-related and orogenic gold. The samples comprised minerals of the tetradymite group, aleksite series, bismuth sulfosalts (cosalite, lillianite, hodrushite, bismuthinite, and aikinite), and accompanying altaite. Gold concentrations in phases of the tetradymite group range from <0.1 to 2527 ppm. Phases in which Bi > X tend to contain lower gold concentrations than Bi₂X₃ minerals (tellurobismuthite and tetradymite). Cosalite and lillianite contain Au concentrations ranging up to 574 and 3115 ppm, respectively. Bismuthinite derivatives have lower Au concentrations: <2 ppm in bismuthinite and up to 542 ppm in aikinite. In our samples, Au concentrations in altaite range from <0.2 to 1662 ppm.Smoother parts of the LA-ICPMS profiles suggest lattice-bound gold, whereas irregularities on the profiles are best explained by the presence of gold particles (?1 μm in diameter). Plotting Au vs. Ag for the entire dataset gives a wedge-shaped distribution, suggesting that Ag underpins Au uptake in both bismuth tellurides and sulfosalts. In the tellurides, correlation trends suggest statistical substitution of Ag(Au), together with Pb, into the octahedral site in the layers. In sulfosalts, Au follows coupled substitutions in which M¹⁺ (Ag, Cu) enters the structure. In tellurides, the presence of van der Waals gaps at chalcogen-chalcogen contacts provides for p-type semi-conductive properties critical for gold scavenging from fluids. Such weak bonds may also act as sites for nucleation of Au (nano)particles. In sulfosalts, contacts between different species that replace one another are also highly predictable to act as traps for (nano)particulate gold.Invisible gold in Bi-chalcogenides is useful to (i) identify trends of orefield zonation, (ii) discriminate between ‘melt’ and ‘fluid-driven’ scavenging, and (iii) interpret replacement and remobilisation processes. Bismuth chalcogenides have the potential to be significant Au carriers in sulfide-poor Au systems, e.g., intrusion-related gold, with impact on the overall Au budget if mean Au concentrations are high enough and the minerals are sufficiently abundant.  相似文献   

Melting relations of multicomponent carbonate MgCO3–FeCO3–CaCO3–Na2CO3 system at 12–26 GPa: application to deeper mantle diamond formation     

Anna Spivak  Natalia Solopova  Leonid Dubrovinsky  Yuriy Litvin 《Physics and Chemistry of Minerals》2015,42(10):817-824

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Atomic arrangements around the O3 site in Al- and Cr-rich oxy-tourmalines: a combined EMP,SREF, FTIR and Raman study     

Ferdinando Bosi  Henrik Skogby  Peter Lazor  Leonid Reznitskii 《Physics and Chemistry of Minerals》2015,42(6):441-453

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An experimental study of the effects of melt composition on plagioclase-melt equilibria at 5 and 10 kbar: implications for the origin of magmatic high-An plagioclase   总被引：3，自引：2，他引：3  

Yuenyong Panjasawatwong  Leonid V. Danyushevsky  Anthony J. Crawford  Keith L. Harris 《Contributions to Mineralogy and Petrology》1995,118(4):420-432

An experimental investigation of plagioclase crystallization in broadly basaltic/andesitic melts of variable Ca# (Ca/(Ca+Na)*100) and Al# (Al/(Al+Si)*100) values and H₂O contents has been carried out at high pressures (5 and 10 kbar) in a solid media piston-cylinder apparatus. The H₂O contents of glasses coexisting with liquidus or near-liquidus plagioclases in each experiment were determined via an FTIR spectroscopic technique. This study has shown that melt Ca# and Al#, H₂O content and crystallization pressure all control the composition of liquidus plagioclase. Increasing melt Ca# and Al# increase An content of plagioclase, whereas the effect of increasing pressure is the opposite. However, the importance of the role played by each of these factors during crystallization of natural magmas varies. Melt Ca# has the strongest control on plagioclase An content, but melt Al# also exerts a significant control. H₂O content can notably increase the An content of plagioclase, up to 10 mol % for H₂O-undersaturated melts, and 20 mol % for H₂O-saturated melts. Exceptionally calcic plagioclases (up to An₁₀₀) in some primitive subduction-related boninitic and related rocks cannot be attributed to the presence of the demonstrated amounts of H₂O (up to 3 wt %). Rather, they must be due to the involvement of extremely refractory (CaO/Na₂O>18) magmas in the petrogenesis of these rocks. Despite the refractory nature of some primitive MORB glasses, none are in equilibrium with the most calcic plagioclase (An₉₄) found in MORB. These plagioclases were likely produced from more refractory melts with CaO/Na₂O = 12–15, or from melts with exceptionally high Al₂O₃(>18%). Magmas of appropriate compositions to crystallize these most calcic plagioclases are sometimes found as melt inclusions in near liquidus phenocrysts from these rocks, but are not known among wholerock or glass compositions. The fact that such melts are not erupted as discrete magma batches indicates that they are effectively mixed and homogenized with volumetrically dominant, less refractory magmas. The high H₂O contents (∼ 6 wt%) in some high-Al basaltic arc magmas may be responsible for the existence of plagioclases up to An₉₅ in arc lavas. However, an alternative possibility is that petrogenesis involving melts with abnormally high CaO/Na₂O values (> 8) may account for the presence of highly anorthitic plagioclases in these rocks. Received: 31 August 1993 / Accepted: 20 May 1994  相似文献   

A Set of Sedimentary Rock Reference Samples: Gpos     

Leonid A. BERKOVITS  Valentina G. OBOLYANINOVA 《Geostandards and Geoanalytical Research》1991,15(1):77-83

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