A preliminary investigation of siliceous microfossil succession in late Quaternary sediments from Lake Baikal, Siberia     

M. L. Julius  E. F. Stoermer  S. M. Colman  T. C. Moore 《Journal of Paleolimnology》1997,18(2):189-206

Siliceous microfossil assemblage succession was analyzed in a 100 m sediment core from Lake Baikal, Siberia. The core was recovered from the lake's central basin at a water depth of 365 m. Microfossil abundance varied greatly within the intervals sampled, ranging from samples devoid of siliceous microfossils to samples with up to 3.49 × 10¹¹ microfossils g^-1 sediment. Fluctuations in abundance appear to reflect trends in the marine ¹⁸O record, with peak microfossil levels generally representing climate optima. Microfossil taxa present in sampled intervals changed considerably with core depth. Within each sample a small number of endemic diatom species dominated the assemblage. Changes in dominant endemic taxa between sampled intervals ranged from extirpation of some taxa, to shifts in quantitative abundance. Differences in microfossil composition and the association of variations in abundance with climate fluctuations suggest rapid speciation in response to major climatic excursions.  相似文献   

Production of methyl bromide and methyl chloride in laboratory cultures of marine phytoplankton II     

M. G. Scarratt  R. M. Moore 《Marine Chemistry》1998,59(3-4)

Methyl halides (monohalomethanes), especially methyl bromide, are known to contribute significantly to ozone destruction in the stratosphere. Budgets of natural and anthropogenic methyl bromide suggest that marine organisms may be the source of a significant proportion of the total global production. Since phytoplankton are abundant in surface waters, they are obvious candidates. Cultures of nine phytoplankton species were grown in CO₂-enriched, nitrate-limited medium in sealed glass vessels. Species tested include Chaetoceros calcitrans, Isochrysis sp., Porphyridium sp., Synechococcus sp., Phaeodactylum tricornutum, Tetraselmis sp., Prorocentrum sp., Emiliania huxleyi and Phaeocystis sp. Methyl bromide (CH₃Br) and methyl chloride (CH₃Cl) concentrations were determined by bubbling the cultures with high-purity air, cryotrapping the effluent and analyzing it on a gas chromatograph with an electron capture detector. The Phaeocystis sp. samples were monitored with GCMS. Cell population, bacterial population, Chl a, pH, and nitrate concentration were monitored for periods of at least two weeks. CH₃Cl was produced by all cultures. CH₃Br was absent in Tetraselmis sp. and Isochrysis sp. cultures, but present in all the others. Methyl iodide (CH₃I) was present in most cultures but could not be quantified due to analytical limitations. CH₃I and CH₃Br production was fastest in stationary phase and continued long after cell division had ceased. Axeic cultures of Phaeocystis sp. achieved almost identical production rates of CH₃Cl and CH₃Br as xenic cultures of the same species. Species from tropical waters had faster CH₃Cl and CH₃Br production rates than temperate species. Scaling the observed production rates using global standing stock estimates for Chl a and particulate nitrogen indicate that phytoplankton can account for only a fraction of the CH₃Cl and CH₃Br believed to be produced in the ocean. Calculations based on the estimated global biomass of Phaeocystis sp. and E. huxleyi blooms show that their contribution is insignificantly small.  相似文献   

Radiogenic Isotope Geology,by Alan P. Dickin,Cambridge University Press,Cambridge, UK, 1995 (paperback edition, 1997), $95.00 (U.S., cloth), ISBN 0 521 43151 4, $44.96 (U.S., paper), ISBN 0 521 59891 5     

Moore  Willard S. 《Mathematical Geosciences》1999,31(4):487-489

Mathematical Geosciences -  相似文献   

Pre‐drill Groundwater Geochemistry in the Karoo Basin,South Africa          下载免费PDF全文

Jennifer S. Harkness  Kelley Swana  William K. Eymold  Jodie Miller  Ricky Murray  Siep Talma  Colin J. Whyte  Myles T. Moore  Erica L. Maletic  Avner Vengosh  Thomas H. Darrah 《Ground water》2018,56(2):187-203

Enhanced production of unconventional hydrocarbons in the United States has driven interest in natural gas development globally, but simultaneously raised concerns regarding water quantity and quality impacts associated with hydrocarbon extraction. We conducted a pre‐development assessment of groundwater geochemistry in the critically water‐restricted Karoo Basin, South Africa. Twenty‐two springs and groundwater samples were analyzed for major dissolved ions, trace elements, water stable isotopes, strontium and boron isotopes, hydrocarbons and helium composition. The data revealed three end‐members: a deep, saline groundwater with a sodium‐chloride composition, an old, deep freshwater with a sodium‐bicarbonate‐chloride composition and a shallow, calcium‐bicarbonate freshwater. In a few cases, we identified direct mixing of the deep saline water and shallow groundwater. Stable water isotopes indicate that the shallow groundwater was controlled by evaporation in arid conditions, while the saline waters were diluted by apparently fossil meteoric water originated under wetter climatic conditions. These geochemical and isotopic data, in combination with elevated helium levels, suggest that exogenous fluids are the source of the saline groundwater and originated from remnant seawater prior to dilution by old meteoric water combined with further modification by water‐rock interactions. Samples with elevated methane concentrations (>14 ccSTP/kg) were strongly associated with the sodium‐chloride water located near dolerite intrusions, which likely provide a preferential pathway for vertical migration of deeply sourced hydrocarbon‐rich saline waters to the surface. This pre‐drill evaluation indicates that the natural migration of methane‐ and salt‐rich waters provides a source of geogenic contamination to shallow aquifers prior to shale gas development in the Karoo Basin.  相似文献   

Geologic sources and geographic distribution of sand tempers in prehistoric potsherds from the Mariana Islands     

William R. Dickinson  Brian M. Butler  Darlene R. Moore  Marilyn Swift 《Geoarchaeology》2001,16(8):827-854

Temper sands in prehistoric potsherds of the Mariana Islands include terrigenous detritus derived from Paleogene volcanic bedrock and calcareous grains derived chiefly from modern fringing reefs, but also in part from uplifted Neogene limestones overlying volcanic bedrock. Calcareous sands are nondiagnostic of island of origin, but volcanic sands and the terrigenous component of hybrid sands composed of mixed terrigenous and calcareous grain types can be traced to geologic sources on Saipan and Guam, the only occupied islands where volcanic bedrock is extensively exposed. Quartzose tempers of several types were derived exclusively from dacitic volcanic rocks on Saipan. Nonquartzose tempers of andesitic parentage derive from both Saipan and Guam, but abundance of orthopyroxene as well as clinopyroxene is diagnostic of Saipan andesitic tempers, the presence of olivine is diagnostic of selected tempers from Guam, and placer temper sands rich in heavy ferromagnesian minerals occur only in sherds on Guam. Temper analysis documents widespread ceramic transfer from Saipan to other islands throughout Mariana prehistory, and more restricted ceramic transfer from Guam to nearby Rota, although the origin of some andesitic temper types is petrographically indeterminate. © 2001 John Wiley & Sons, Inc.  相似文献   

A first look at the effects of ionospheric signal bending on a globally processed GPS network     

Elizabeth J. Petrie  Matt A. King  Philip Moore  David A. Lavallée 《Journal of Geodesy》2010,84(8):491-499

This study provides a first attempt at quantifying potential signal bending effects on the GPS reference frame, coordinates and zenith tropospheric delays (ZTDs). To do this, we homogeneously reanalysed data from a global network of GPS sites spanning 14 years (1995.0–2009.0). Satellite, Earth orientation, tropospheric and ground station coordinate parameters were all estimated. We tested the effect of geometric bending and dTEC bending corrections, which were modelled at the observation level based, in part, on parameters from the International Reference Ionosphere 2007 model. Combined, the two bending corrections appear to have a minimal effect on site coordinates and ZTDs except for low latitude sites. Considering five days (DOY 301–305, 28 October–1 November 2001) near ionospheric maximum in detail, they affect mean ZTDs by up to ~1.7 mm at low latitudes, reducing to negligible levels at high latitudes. Examining the effect on coordinates in terms of power-spectra revealed the difference to be almost entirely white noise, with noise amplitude ranging from 0.3 mm (high latitudes) to 2.4 mm (low latitudes). The limited effect on station coordinates is probably due to the similarity in the elevation dependence of the bending term with that of tropospheric mapping functions. The smoothed z-translation from the GPS reference frame to ITRF2005 changes by less than 2 mm, though the effect combines positively with that from the second order ionospheric refractive index term. We conclude that, at the present time, and for most practical purposes, the geometric and dTEC bending corrections are probably negligible at current GPS/reference frame precisions.  相似文献   

Mineralogical approaches to sourcing pipes and figurines from the eastern woodlands,U.S.A.     

Sarah U. Wisseman  Duane M. Moore  Randall E. Hughes  Mary R. Hynes  Thomas E. Emerson 《Geoarchaeology》2002,17(7):689-715

Provenance studies of stone artifacts often rely heavily upon chemical techniques such as neutron activation analysis. However, stone specimens with very similar chemical composition can have different mineralogies (distinctive crystalline structures as well as variations within the same mineral) that are not revealed by multielemental techniques. Because mineralogical techniques are often cheap and usually nondestructive, beginning with mineralogy allows the researcher to gain valuable information and then to be selective about how many samples are submitted for expensive and somewhat destructive chemical analysis, thus conserving both valuable samples and funds. Our University of Illinois team of archaeologists and geologists employs Portable Infrared Mineral Analyzer (PIMA) spectroscopy, X‐ray diffraction (XRD), and Sequential acid dissolution/XRD/Inductively coupled plasma (SAD‐XRD‐ICP) analyses. Two case studies of Hopewellian pipes and Mississippian figurines illustrate this mineralogical approach. The results for both studies identify sources relatively close to the sites where the artifacts were recovered: Sterling, Illinois (rather than Ohio) for the (Hopewell) pipes and Missouri (rather than Arkansas or Oklahoma) for the Cahokia figurines. © 2002 Wiley Periodicals, Inc.  相似文献   

Recent shifts in coastline change and shoreline stabilization linked to storm climate change   总被引：1，自引：0，他引：1       下载免费PDF全文

Jennifer M. Johnson  Laura J. Moore  Kenneth Ells  A. Brad Murray  Peter N. Adams  Richard A. MacKenzie III  John M. Jaeger 《地球表面变化过程与地形》2015,40(5):569-585

Since cuspate coastlines are especially sensitive to changes in wave climate, they serve as potential indicators of initial responses to changing wave conditions. Previous work demonstrates that Cape Hatteras and Cape Lookout, North Carolina, which are largely unaffected by shoreline stabilization efforts, have become increasingly asymmetric over the past 30 years, consistent with model predictions for coastline response to increases in Atlantic Ocean summer wave heights and resulting changes in the distribution of wave‐approach angles. Historic and recent shoreline change observations for Cape Fear, North Carolina, and model simulations of coastline response to an increasingly asymmetric wave climate in the presence of beach nourishment, produce comparable differences in shoreline change rates in response to changes in wave climate. Results suggest that the effect of beach nourishment is to compensate for – and therefore to mask – natural responses to wave climate change that might otherwise be discernible in patterns of shoreline change alone. Therefore, this case study suggests that the effects of wave climate change on human‐modified coastlines may be detectable in the spatial and temporal patterns of shoreline stabilization activities. Similar analyses of cuspate features in areas where the change in wave climate is less pronounced (i.e. Fishing Point, Maryland/Virginia) and where local geology appears to exert control on coastline shape (i.e. Cape Canaveral, Florida), suggest that changes in shoreline configuration that may be arising from shifting wave climate are currently limited to sandy wave‐dominated coastlines where the change in wave climate has been most pronounced. However, if hurricane‐generated wave heights continue to increase, large‐scale shifts in patterns of erosion and accretion will likely extend beyond sensitive cuspate features as the larger‐scale coastline shape comes into equilibrium with changing wave conditions. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Heterogeneous distributions of CO2 may be more important for dissolution and karstification in coastal eogenetic limestone than mixing dissolution          下载免费PDF全文

Jason D. Gulley  Jonathon B. Martin  Paul J. Moore  Amy Brown  Patricia D. Spellman  John Ezell 《地球表面变化过程与地形》2015,40(8):1057-1071

Mixing dissolution, a process whereby mixtures of two waters with different chemical compositions drive undersaturation with respect to carbonate minerals, is commonly considered to form cavernous macroporosity (e.g. flank margin caves and banana holes) in eogenetic karst aquifers. On small islands, macroporosity commonly originates when focused dissolution forms globular chambers lacking entrances to the surface, suggesting that dissolution processes are decoupled from surface hydrology. Mixing dissolution has been thought to be the primary dissolution process because meteoric water would equilibrate rapidly with calcium carbonate as it infiltrates through matrix porosity and because pCO₂ was assumed to be homogeneously distributed within the phreatic zone. Here, we report data from two abandoned well fields in an eogenetic karst aquifer on San Salvador Island, Bahamas, that demonstrate pCO₂ in the phreatic zone is distributed heterogeneously. The pCO₂ varied from less than log ?2.0 to more than log ?1.0 atm over distances of less than 30 m, generating dissolution in the subsurface where water flows from regions of low to high pCO₂ and cementation where water flows from regions of high to low pCO_2. Using simple geochemical models, we show dissolution caused by heterogeneously distributed pCO₂ can dissolve 2.5 to 10 times more calcite than the maximum amount possible by mixing of freshwater and seawater. Dissolution resulting from spatial variability in pCO₂ forms isolated, globular chambers lacking initial entrances to the surface, a morphology that is characteristic of flank margin caves and banana holes, both of which have entrances that form by erosion or collapse after cave formation. Our results indicate that heterogeneous pCO₂, rather than mixing dissolution, may be the dominant mechanism for observed spatial distribution of dissolution, cementation and macroporosity generation in eogenetic karst aquifers and for landscape development in these settings. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Reservoir construction from the Newberry Volcano EGS Demonstration     

Trenton T Cladouhos  Susan Petty  Yini Nordin  Michael Moore  Kyla Grasso  Matt Uddenberg  Michael W Swyer 《地下水科学与工程》2014,2(3):1-7

The Newberry Volcano EGS Demonstration in central Oregon tests recent technological advances designed to reduce the cost of power generated by EGS in a hot, dry well (NWG 55-29) drilled in 2008. An EGS reservoir was created by injecting large volumes of cold water, causing existing fractures to slip in shear (known as hydroshearing) generating the seismic waves that can be used to map fracture location and size. At the Newberry Demonstration the final injectivity ranged between 1.4 and 1.7 L/s/MPa a ~6x improvement over the initial injectivity of the well. The injectivity improvement and seismic analysis indicate that previously impermeable fractures were enhanced during the NWG 55-29 stimulation.  相似文献