Oxygen isotope exchange between H₂O and CO₂ at elevated CO₂ pressures: Implications for monitoring of geological CO₂ storage     

G. Johnson  B. Mayer 《Applied Geochemistry》2011,26(7):1184-1191

Traditionally, the application of stable isotopes in Carbon Capture and Storage (CCS) projects has focused on δ¹³C values of CO₂ to trace the migration of injected CO₂ in the subsurface. More recently the use of δ¹⁸O values of both CO₂ and reservoir fluids has been proposed as a method for quantifying in situ CO₂ reservoir saturations due to O isotope exchange between CO₂ and H₂O and subsequent changes in δ¹⁸O_H2O values in the presence of high concentrations of CO₂. To verify that O isotope exchange between CO₂ and H₂O reaches equilibrium within days, and that δ¹⁸O_H2O values indeed change predictably due to the presence of CO₂, a laboratory study was conducted during which the isotope composition of H₂O, CO₂, and dissolved inorganic C (DIC) was determined at representative reservoir conditions (50 °C and up to 19 MPa) and varying CO₂ pressures. Conditions typical for the Pembina Cardium CO₂ Monitoring Pilot in Alberta (Canada) were chosen for the experiments. Results obtained showed that δ¹⁸O values of CO₂ were on average 36.4 ± 2.2‰ (1σ, n = 15) higher than those of water at all pressures up to and including reservoir pressure (19 MPa), in excellent agreement with the theoretically predicted isotope enrichment factor of 35.5‰ for the experimental temperatures of 50 °C. By using ¹⁸O enriched water for the experiments it was demonstrated that changes in the δ¹⁸O values of water were predictably related to the fraction of O in the system sourced from CO₂ in excellent agreement with theoretical predictions. Since the fraction of O sourced from CO₂ is related to the total volumetric saturation of CO₂ and water as a fraction of the total volume of the system, it is concluded that changes in δ¹⁸O values of reservoir fluids can be used to calculate reservoir saturations of CO₂ in CCS settings given that the δ¹⁸O values of CO₂ and water are sufficiently distinct.  相似文献   

The sinkhole enigma in the Alpine Foreland, Southeast Germany: Evidence of impact-induced rock liquefaction processes     

Kord Ernstson  Werner Mayer  Andreas Neumair  Dirk Sudhaus 《Central European Journal of Geosciences》2011,3(4):385-397

Sudden collapse of the Quaternary soil to form sinkholes on the order of meters and tens of meters has been a geologic phenomenon within living memory in a localized area north of Lake Chiemsee in Southeast Germany. Failing a satisfying explanation, a relation with an undefined glaciation process has always been proposed. Excavations and geophysical measurements at three newly affected sites show underground features such as prominent sandy-gravelly intrusions and extrusions typical of rock liquefaction processes well known to occur during strong earthquakes. Since strong earthquakes can reasonably be excluded to have affected the area under discussion, it has been suggested that the observed widespread liquefaction is related with the recently proposed Holocene Chiemgau meteorite impact event. Except for one earlier proposed but unassertive relation between impact and liquefaction, the obviously direct association of both processes in the Chiemgau area emphasizes that observed paleoliquefaction features need not necessarily have originated solely from paleoseismicity but can provide a recognizable regional impact signature.  相似文献   

Shallow site archaeology: Artifact dispersal,stratigraphy, and radiocarbon dating at the Barger Gulch locality B Folsom Site,Middle Park,Colorado     

Todd A. Surovell  Nicole M. Waguespack  James H. Mayer  Marcel Kornfeld  George C. Frison 《Geoarchaeology》2005,20(6):627-649

Shallowly buried archaeological sites are particularly susceptible to surface and subsurface disturbance processes. Yet, because cultural deposition often operates on short time scales relative to geologic deposition, vertical artifact distributions can be used to clarify questions of site formation. In particular, patterns in artifact distributions that cannot be explained by occupation histories must be explained by natural processes that have affected sites. Buried only 10–50 cm beneath the ground surface for 10,450 ¹⁴C yr, the Folsom component at Barger Gulch Locality B (Middle Park, Colorado) exhibits many signs of post‐depositional disturbance. Through examination of variation in the vertical distribution of the artifact assemblage, we are able to establish that only a Folsom component is present. Using vertical artifact distributions, stratigraphy, and radiocarbon dating, we are able to reconstruct the series of events that have impacted the site. The Folsom occupation (˜10,450 ¹⁴C yr B.P.) was likely initially buried in a late‐Pleistocene eolian silt loam. Erosion brought the artifacts to rest on a deflation surface at some time prior to 9400 ¹⁴C yr B.P. A mollic epipedon formed in sediments that accumulated between 9400 and 7000 ¹⁴C yr B.P. Some time after 5200 ¹⁴C yr B.P., this soil was partially truncated, and artifacts that had previously dispersed upward created a secondary lag at its upper contact. This surface was buried again and artifact dispersal continued. © 2005 Wiley Periodicals, Inc.  相似文献   

Nitrogen uptake and denitrification in restored and unrestored streams in urban Maryland, USA   总被引：2，自引：0，他引：2  

Carolyn A. Klocker  Sujay S. Kaushal  Peter M. Groffman  Paul M. Mayer  Raymond P. Morgan 《Aquatic Sciences - Research Across Boundaries》2009,71(4):411-424

There is growing interest in rates of nitrate uptake and denitrification in restored streams to better understand the effects of restoration on nitrogen processing. This study quantified nitrate uptake in two restored and two unrestored streams in Baltimore, Maryland, USA using nitrate additions, denitrification enzyme assays, and a ¹⁵N isotope tracer addition in one of the urban restored streams, Minebank Run. Restoration included either incorporation of stormwater ponds below a storm drain and catch basins to attenuate flow or hydrologic “reconnection” of a stream channel to its floodplain. Stream restoration was conducted for restoring aging sanitary and bridge infrastructure and introducing some stormwater management in watersheds developed prior to current regulations. Denitrification potential in sediments was variable across streams, whereas nitrate uptake length appeared to be significantly correlated to surface water velocity, which was low in the restored streams during summer baseflow conditions. Uptake length of NO₃ ⁻–N in Minebank Run estimated by ¹⁵N tracer addition was 556 m. Whole stream denitrification rates in Minebank Run were 153 mg NO₃ ⁻–N m⁻² day⁻¹, and approximately 40% of the daily load of nitrate was estimated to be removed via denitrification over a distance of 220.5 m in a stream reach designed to be hydrologically “connected” to its floodplain. Increased hydrologic residence time in Minebank Run during baseflow likely influenced rates of whole stream denitrification, suggesting that hydrologic residence time may be a key factor influencing N uptake and denitrification. Restoration approaches that increase hydrologic “connectivity” with hyporheic sediments and increase hydrologic residence time may be useful for stimulating denitrification. More work is necessary, however, to examine changes in denitrification rates in restored streams across different seasons, variable N loads, and in response to the “flashy” hydrologic flow conditions during storms common in urban streams.  相似文献   

Isotopic and geochemical characterization of salinization in the shallow aquifers of a reclaimed subsiding zone: The southern Venice Lagoon coastland   总被引：3，自引：0，他引：3  

Julie C. Gattacceca  Christine Vallet-Coulomb  Adriano Mayer  Christelle Claude  Olivier Radakovitch  Enrico Conchetto  Bruno Hamelin   《Journal of Hydrology》2009,378(1-2):46-61

The coastal plain bordering the southern Venice Lagoon is a reclaimed lowland characterized by high subsidence rate, and ground level and water-table depth below sea level. In this agricultural region, where the surface hydrologic network is entirely artificially controlled by irrigation/drainage canals, salinization problems have long been encountered in soils and groundwaters. Here we use isotopic and geochemical tracers to improve our understanding of the origin of salinization and mineralization of the semi-confined aquifer (0–40 m), and the freshwater inputs to this hydrological system. Water samples have been collected at different seasons in the coastal Adriatic Sea, lagoon, rivers and irrigation canals, as well as in the semi-confined aquifer at depths between 12 and 35 m (14 boreholes), and in the first confined aquifer (three boreholes drilled between 40 and 80 m depth). Stable isotopes (δ¹⁸O and δD) and conductivity profiles show that direct saline intrusion from the sea or the lagoon is observed only in a restricted coastal strip, while brackish groundwaters are found over the entire topographic and piezometric depression in the centre of the study area. Fresh groundwaters are found only in the most western zone. The sharp isotopic contrast between the western and central regions suggests disconnected hydrological circulations between these two parts of the shallow aquifer. The border between these two regions also corresponds to the limits of the most strongly subsiding zone.Our results can be interpreted in terms of a four end-member mixing scheme, involving (1) marine water from the lagoon or the open sea, (2) alpine and pre-alpine regional recharge waters carried either by the main rivers Adige, Bacchiglione and Brenta (irrigation waters) or by the regional groundwater circulation, (3) local precipitation, and (4) evaporated waters infiltrated from the surface. Infiltration from the surface is also revealed by the stratification of the electrical conductivity profiles, showing that the brackish groundwaters are overlain by a shallow layer of less saline water all over the central depression. In the first confined aquifer, the groundwaters have isotopic compositions similar to the deep groundwaters of the Venetian confined aquifers (40–400 m depth). The isotopic data and the Br/Cl ratio show that the origin of the salinization of the phreatic aquifer can be ascribed to seawater intrusion alone, with no indication of the involvement of deep brines (identified at 450 m depth) in the process.The chemical composition of the saline and brackish groundwaters is characterized by an excess of sodium and a deficit of calcium compared to conservative mixing between fresh groundwaters and seawater. This suggests that the phreatic aquifer is progressively freshening, as a consequence of the beneficial influence of the extensive irrigation/drainage network, including raised canals acting as a hydraulic barrier along the coast. This freshening tendency may have been lasting since the reclamation in the mid-twentieth century, and has probably been accelerated by the ban on groundwater abstraction since the 1970s.  相似文献   

Microtopographic evolution of mineral surfaces as a tool to identify and date young fault scarps in bedrock     

Larry Mayer  John Rakovan  Eric Rufe 《Journal of Geodynamics》2000,29(3-5)

Faulting that results in surface ruptures through bedrock can be particularly difficult to date. For example, stratigraphic control on the age of faulting, based on the age of the bedrock, often leaves unacceptably large uncertainty on the age of the faulting. From a paleoseismological perspective, there is a clear need to determine if a bedrock fault scarp is actually a young feature. For young fault ruptures that create fresh mineral surfaces, analysis of microtopography developed by weathering of the mineral surface may provide a quantifiable method for determining the fault age. The direct quantitative measurement of mineral surface microtopography using Atomic Force Microscopy affords a novel method to study the rupture ages of active faults. The method for using microtopographic evolution of mineral surfaces depends on three conditions. The first condition is that freshly exposed mineral cleavage surfaces, which can be described geometrically as planes, are formed during a rupture event. The formation of these fresh surfaces is analogous to the initiation of a weathering ‘clock’ that defines time t=0. Following cleavage formation dissolution of the planar mineral surface occurs. The rate of dissolution for a mineral species under given climatic conditions, governs the rate of mineral surface alteration. Thus as dissolution proceeds, the roughness of the mineral surface increases. We suggest that the progression of microtopographic roughness over time, which can be estimated by computing quantitative statistics derived from digital mineral surface topography, will systematically vary until a steady state surface topography is reached. The fractal dimension, D_f, is one such measure of surface roughness where, D_f at time t=0 is 2. The dissolution of the mineral surface increases the fractal dimension as the removal of material proceeds. We posit that somewhere between D_f=2 and D_f=3, the microtopography reaches a steady state. Therefore, in the pre-steady state stage of surface roughness, the quantitative measure of roughness of the mineral may serve as a measure of time elapsed since faulting. The period of time this initial stage of surface roughening represents is dependent on the mineral and as a consequence, its dissolution rate, in a specific set of environmental conditions. The time elapsed since fault rupture and grain cleavage can also be estimated from the measurement of the volume of material removed through dissolution. If part of the original cleavage surface remains and can be identified then AFM measurements of the surface microtopography can be used to calculate the dissolved volume per unit area.  相似文献   

On the local multiscale determination of the Earth’s disturbing potential from discrete deflections of the vertical     

T. Fehlinger  W. Freeden  C. Mayer  M. Schreiner 《Computational Geosciences》2008,12(4):473-490

As a first approximation, the Earth is a sphere; as a second approximation, it may be considered an ellipsoid of revolution. The deviations of the actual Earth’s gravity field from the ellipsoidal “normal” field are so small that they can be understood to be linear. The splitting of the Earth’s gravity field into a “normal” and a remaining small “disturbing” field considerably simplifies the problem of its determination. Under the assumption of an ellipsoidal Earth model, high observational accuracy is achievable only if the deviation (deflection of the vertical) of the physical plumb line, to which measurements refer, from the ellipsoidal normal is not ignored. Hence, the determination of the disturbing potential from known deflections of the vertical is a central problem of physical geodesy. In this paper, we propose a new, well-promising method for modelling the disturbing potential locally from the deflections of the vertical. Essential tools are integral formulae on the sphere based on Green’s function with respect to the Beltrami operator. The determination of the disturbing potential from deflections of the vertical is formulated as a multiscale procedure involving scale-dependent regularized versions of the surface gradient of the Green function. The modelling process is based on a multiscale framework by use of locally supported surface curl-free vector wavelets.   相似文献   

Radiation balance over low-lying and mountainous areas in south-west Germany     

M. G. Iziomon  H. Mayer  W. Wicke  A. Matzarakis 《Theoretical and Applied Climatology》2001,68(3-4):219-231

Summary  Surface radiative fluxes play a major role in the energy exchange process between the atmosphere and earth surface and are thus very crucial to climatic processes within the atmospheric boundary layer. Based on four years REKLIP (REgio-KLIma-Project) data set of measured radiative fluxes and additional supporting meteorological variables, the surface radiation regime for selected lowland site (Bremgarten 212 m a.s.l.) and mountain sites (Geiersnest at 870 m a.s.l.; Feldberg 1489 m a.s.l.) in the southern Upper Rhine valley region (south-west Germany) has been reported. Time series of radiative fluxes and surface albedo showed significant inter-site differences. Possible reasons for the observed differences have been made. Downward atmospheric radiation A _l at the study sites was parameterised in terms of air temperature, vapour pressure and cloud amount, all of which strongly govern the variation of A _l . Effective terrestrial radiation amounted to about 50% of absorbed shortwave radiation at the study sites annually. During clear sky conditions, global solar irradiance G _s constituted about 76.0% of the incident extraterrestrial solar irradiance at Feldberg mountain site but only 68.5% of that at Bremgarten lowland site. Annual cumulative of net radiative flux R _n amounted to 1722 MJm⁻² yr⁻¹ at the lowland site, while that at Geiersnest and Feldberg mountain sites constituted 84% and 73% respectively of the corresponding magnitude for the lowland site. In the same vein, annual mean of radiation efficiency (defined here as R _n /G _s ) amounted to 0.32 in Feldberg, 0.37 in Geiersnest and 0.41 in Bremgarten. Consequently the annual available energy, of which net radiative flux is representative, was smaller at the mountain ous sites relative to the lowland site during the study period. Inter-annual variability of net radiative flux, its constituent variables and derivatives at the study sites were generally below 10%, with longwave fluxes showing the lowest fluctuation. This renders the measured data quite suitable for modelling purposes. In winter, mean daily sums of R _n showed a slow rise with cloud amount N at the lowland site but a sharp rise with N at Feldberg mountain site. In summer however, mean daily sums of R _n declined significantly with N as well as Linke turbidity factor at the study sites. Received June 24, 1999 Revised November 2, 2000  相似文献   

The structure of the Campanian Plain and the activity of the Neapolitan volcanoes (Italy)     

Roberto Scandone  Francesca Bellucci  Lucio Lirer  Giuseppe Rolandi 《Journal of Volcanology and Geothermal Research》1991,48(1-2)

The central Campanian Plain is dominated by the structural depression of Acerra whose origin is tectonic, but may have been enlarged and further depressed after the eruption of the Campanian Ignimbrite (42-25 ka). The deposits of the Campanian Ignimbrite are possibly the results of multiple eruptions with huge pyroclastic deposits that covered all the Campanian Plain.The more recent activity of Vesuvius, Campi Flegrei and Procida occurred on the borders of Acerra depression and resulted from a reactivation of regional faults after the Campanian Ignimbrite cycle. The activity of Vesuvius produced the building of a stratovolcano mostly by effusive and plinian explosive eruptions. The Campi Flegrei area, on the contrary, was dominated by the eruption of the Neapolitan Yellow Tuff at 12 ka that produced a caldera collapse of the Gulf of Pozzuoli. The caldera formation controlled the emplacement of the recent activity of Campi Flegrei and the new volcanoes were formed only within the caldera or along its rim.  相似文献   

Conditions and formation mechanism of carbon phases in late quarternary geyzerites and travertines of Ol’khon area and Ol’khon Island (Baikal rift zone)     

Yu. V. Danilova  T. G. Shumilova  J. Mayer  B. S. Danilov 《Petrology》2016,24(1):35-48

Late Quaternary geyserite and travertine in Ol’khon Area and Ol’khon Island contain a recently discovered high-temperature association of hydrocarbon and carbonaceous phases, including highly crystalline graphite, α-carbyne, and bitumen, which were produced at temperatures no lower than 400°C. A carbon modification α-carbyne, which was previously found only among experimental products, was first identified in geyserite from the Ol’khon area. Nanometer-sized morphostructures and crystallites were detected on the surface of highly crystalline graphite from the geyserite and travertine. No such structures and crystallites have ever been found on graphite of magmatic, metamorphic, metasomatic, or pneumatolytic origin. The newly formed nanometer-sized morphostructures and crystallites should be regarded as typomorphic features of carbonaceous phases in high-temperature hydrothermal rocks. Graphite was likely produced in the geyserite and travertine by low-pressure polycondenssation of hydrocarbons, at free growth in open space from oversaturated solutions and/or a gas phase.  相似文献