Groundwater,Acid and Carbon Dioxide Dynamics Along a Coastal Wetland,Lake and Estuary Continuum     

Luke C. Jeffrey  Damien T. Maher  Isaac R. Santos  Ashly McMahon  Douglas R. Tait 《Estuaries and Coasts》2016,39(5):1325-1344

Coastal wetlands are hotspots for biodiversity and biological productivity, yet the hydrology and carbon cycling within these systems remains poorly understood due to their complex nature. By using a novel spatiotemporal approach, this study quantified groundwater discharge and the related inputs of acidity and CO₂ along a continuum of a modified coastal acid sulphate soil (CASS) wetland, a coastal lake and an estuary under highly contrasting hydrological conditions. To increase the resolution of spatiotemporal data and advance upon previous methodologies, we relied on automated observations from four simultaneous time-series stations to develop multiple radon mass balance models to estimate groundwater discharge and related groundwater inputs of acidity and dissolved inorganic carbon (DIC), along with surface water to atmosphere CO₂ fluxes. Spatial surveys indicated distinct acid hotspots with minimum surface water pH of 2.91 (dry conditions) and 2.67 (flood conditions) near a non-remediated (drained) CASS area. Under flood conditions, groundwater discharge accounted for ～14.5 % of surface water entering the lake. During the same period, acid discharge from the acid sulphate soil section of the continuum produced ～4.8 kg H₂SO₄?ha^?1 day^?1, a rate much higher than previous studies in similar systems. During baseflow conditions, the low pH water was rapidly buffered within the estuarine lake, with the pH increasing from 4.22 to 6.07 over a distance of ～250 m. The CO₂ evasion rates within the CASS were extremely high, averaging 2163?±?125 mmol m^?2 day^?1 in the dry period and 4061?±?259 mmol m^?2 day^?1 under flood conditions. Groundwater input of DIC could only account for 0.4 % of this evasion in the dry conditions and ～5 % during the flood conditions. We demonstrated that by utilising a spatiotemporal (multiple time-series stations) approach, the study was able to isolate distinct zones of differing hydrology and biogeochemistry, whilst providing more reasonable groundwater acid input estimates and air–water CO₂ flux estimates than some traditional sampling designs. This study highlights the notion that modified CASS wetlands can release large amounts of CO₂ to the atmosphere because of high groundwater acid inputs and extremely low surface water pH.  相似文献   

Enhanced Dissolved Organic Matter Recovery from Saltwater Samples with Electrodialysis     

Luke R. Chambers  Ellery D. Ingall  Emily M. Saad  Amelia F. Longo  Masayuki Takeuchi  Yuanzhi Tang  Claudia Benitez-Nelson  Sheean T. Haley  Sonya T. Dyhrman  Jay Brandes  Aron Stubbins 《Aquatic Geochemistry》2016,22(5-6):555-572

Complexities associated with dissolved organic matter (DOM) isolation from seawater have hampered compositional characterization of this key component of global carbon and nutrient cycles. DOM isolation efficiency by electrodialysis (ED) from salt-containing waters was optimized and evaluated on samples including coastal ocean seawater, open ocean seawater, artificial seawater from axenic cultures of marine phytoplankton, and artificial seawater samples containing standard compounds of different molecular sizes and charge. ED was performed with a system optimized for processing 2–10 L sample volumes. Additionally, the combination of ED and solid-phase extraction, using Bond Elut PPL exchange resin, was evaluated. Using only ED, the following DOC recoveries were achieved: coastal seawater, 71.3 ± 6.5 %; open ocean, 50.5 ± 3.1 %; phytoplankton cultures, 70.3 ± 12.5 %; glucose, 90.2 ± 2.1 %; EDTA, 67.5 ± 9.9 %; and vitamin B₁₂, 98.3 ± 1.6 %. With the combination of PPL and ED techniques, an average DOC recovery of 76.7 ± 2.6 % was obtained for coastal seawater, but this recovery was not statistically different from seawater recoveries using only ED. Comparison of C/N ratios and fluorescence excitation emission matrices taken at the beginning and end of the recovery process for coastal samples processed using only ED indicated that the final recovered material was representative of the DOM present in the original samples. Typical recoveries using combined PPL and ED exceed those of previous isolation methods.  相似文献   

Bypassing the ‘ratification straitjacket’: reviewing US legal participation in a climate agreement     

Luke Kemp 《Climate Policy》2016,16(8):1011-1028

The issue of US ratification of international environmental treaties is a recurring obstacle for environmental multilateralism, including the climate regime. Despite the perceived importance of the role of the US to the success of any future international climate agreement, there has been little direct coverage in terms of how an effective agreement can specifically address US legal participation. This article explores potential ways of allowing for US legal participation in an effective climate treaty. Possible routes forward include the use of domestic legislation such as section 115 (S115) of the Clean Air Act (CAA) and the use of sole–executive agreements, instead of Senate ratification. Legal participation from the US through sole–executive agreements is possible if the international architecture is designed to allow for their use. Architectural elements such as varying legality and participation across an agreement (variable geometry) could allow for the use of sole–executive agreements. Two broader models for a 2015 agreement with legal participation through sole–executive agreements are constructed based upon these options: a modified pledge and review system and a form of variable geometry composed of number of opt-out, voting-based protocols on specific issues accompanied by bilateral agreements on mitigation commitments with other major emitters through the use of S115 and sole–executive agreements under the Montreal Protocol and Chicago Convention (‘Critical Mass Governance'). While there is no single solution, Critical Mass Governance appears to provide the optimum combination of tools to effectively allow for US legal participation whilst ensuring an effective treaty.

Policy relevance

This article provides some recommendations on how to create an effective, legally binding treaty that allow for US legal participation without Senate approval. Given the recent election of a Republican majority in the US Senate and Congress, increasing willingness of the President to utilize his executive powers, as well as a strong shift in negotiations to appease US interests, the insights of this research are timely and relevant to delegations and other United Nations Framework Convention on Climate Change (UNFCCC) actors. It will also be of use to domestic US actors involved with climate policy by illustrating how to allow for effective and sustainable US multilateral engagement that bypasses domestic political gridlock.  相似文献   

Extreme heat in New Zealand: a synthesis     

Harrington  Luke J.  Frame  Dave 《Climatic change》2022,170(1):1-31

Climatic Change - The usefulness of global integrated assessment model (IAM) results for policy recommendation in specific regions has not been fully assessed to date. This study presents the...  相似文献   

Conceptualising the Migration–Food Security Nexus: Lessons from Nepal and Vanuatu     

Luke K. Craven  Hom N. Gartaula 《The Australian geographer》2015,46(4):455-471

In the past decade, international development practitioners have increasingly argued that migration improves the food security of households at origin, by providing the capital necessary for agricultural intensification or food purchase. These debates have occurred largely in isolation from a discussion of the values that underpin food production and consumption in the communities that migrants call home. We question the assumption that a shift from an agricultural-based economy to an economy based on remittances increases the ability of communities to secure access to food in the face of rapid economic and cultural change. In this paper, we present two independently conducted studies from Nepal and Vanuatu that investigate the impact of out-migration on local perceptions of agricultural and residential land and the meaning given to food security. Our data reveal that the value changes associated with large-scale out-migration have the potential to make the agricultural sector at origin more vulnerable, unproductive, unsustainable or unattractive, leaving a longer-term impact on food security. We offer some reflections on the implications of these findings for the structure of the migration–food security nexus.  相似文献   

Cryogenic Tests of Volume-Phase Holographic Gratings: I. Results at 200 K     

N. Tamura  G. J. Murray  P. Luke  C. Blackburn  D. J. Robertson  N. A. Dipper  R. M. Sharples  J. R. Allington-Smith 《Experimental Astronomy》2003,15(1):1-12

We present results from cryogenic tests of a Volume-Phase Holographic(VPH) grating at 200 K measured at near-infrared wavelengths. The aims of these tests were to see whether the diffraction efficiency and angular dispersion of a VPH grating are significantly different at a low temperature from those at a room temperature, and to see how many cooling and heating cycles the grating can withstand. We have completed 5 cycles between room temperature and 200 K, and find that the performance is nearly independent of temperature, at least over the temperature range which we are investigating. In future, we will not only try more cycles between these temperatures but also perform measurements at a much lower temperature (e.g., ∼80 K).  相似文献   

Production limits — who benefits?     

Hugh Cameron  Luke Georghiou 《Marine Policy》1981,5(3):267-270

One of the main issues contributing to the US-instigated hiatus in negotiations on the Draft Convention for the Law of the Sea has been the question of production controls for manganese nodule mining. As the text stands, production controls cover both the total amount of metals produced from nodules in any year and also the maximum quantity which any single operator will be licensed to produce annually. Both types of control use the nickel content of nodules mined as the specified limit. The overall controls relate production to projected growth in world nickel consumption. In this note, some of the implications of the methods used to calculate production ceilings are explored. The likely success of the regulations in achieving their stated objectives can then be discussed.  相似文献   

Japanese new technology: Creating future marine industries     

Luke Georghiou  Glyn Ford  Michael Gibbons  Glyn Jones 《Marine Policy》1983,7(4):239-253

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SOLAR ENERGETIC ION AND ELECTRON LIMITS FROM HIREGS OBSERVATIONS     

Feffer  P. T.  Lin  R. P.  Slassi-Sennou  S.  McBride  S.  Primbsch  J. H.  Zimmer  G.  Pelling  R. M.  Pehl  R.  Madden  N.  Malone  D.  Cork  C.  Luke  P.  Vedrenne  G.  Cotin  F. 《Solar physics》1997,171(2):419-445

The HIgh-REsolution Gamma-ray and hard X-ray Spectrometer (HIREGS) consists of an actively shielded array of twelve liquid-nitrogen-cooled germanium detectors designed to provide unprecedented spectral resolution and narrow-line sensitivity for solar gamma-ray line observations. Two long-duration, circumpolar balloon flights of HIREGS in Antarctica (10–24 January, 1992 and 31 December, 1992–10 January, 1993) provided 90.9 and 20.4 hours of solar observations, respectively. During the observations, eleven soft X-ray bursts at C levels and above (largest M1.7) occurred, and three small solar hard X-ray bursts were detected by the Compton Gamma-Ray Observatory. HIREGS detected a significant increase above 30 keV in one. No solar gamma-ray line emission was detected. Limits on the 2.223-MeV line and the hard X-ray emission are used to estimate the relative contribution of protons and electrons to the energy in flares, and to coronal heating. For the 2.223-MeV line, the upper limit fluence is 0.8 ph cm^-2 in the flares, and the upper limit flux is 1.8 × 10^-4 ph s^-1 cm^-2 in the absence of flares. These limits imply that 6 × 10³⁰ (2) protons above 30 MeV were accelerated in the flares, assuming standard photospheric abundances and a thick target model. The total energy contained in the accelerated protons >30 MeV is 4 × 10²⁶ ergs, but this limit can be more than 10³⁰ ergs if the spectrum extends down to 1 MeV. The upper limit on the total energy in accelerated electrons during the observed flares can also exceed 10³⁰ ergs if the spectrum goes down to 7 keV. Quiet-Sun observations indicate that 10²⁶erg s^-1 are deposited by energetic protons >1 MeV, well below the10²⁷ –10²⁸ erg s^-1 required for coronal heating, while <3 × 10²⁷ erg s^-1 are deposited by energetic electrons, which does not exclude the possibility of coronal heating by quiet-time accelerated electrons. The quiet-Sun observations also suggest that if protons stored in the corona are to supply the energy for flares, as suggested by Elliot (1964), the proton spectrum must extend down to at least 2 MeV. However, collisional losses at typical coronal-loop densities prevent those low-energy protons from being stored for 10⁴ s. It therefore seems unlikely that the energy for flares could come from energetic protons stored over long periods.  相似文献   

Wake studies of a 1/30th scale horizontal axis marine current turbine   总被引：1，自引：0，他引：1  

Luke Myers  A.S. Bahaj 《Ocean Engineering》2007,34(5-6):758-762

A 0.4 m diameter (1:30th scale) horizontal axis marine current turbine (MCT) was tested in a circulating water channel. The turbine performance and wake characteristics were determined over a range of flow speeds and rotor thrust coefficients. Measurements of the water surface elevation profiles indicated increasing variation and surface turbulence with increasing flow speeds. Blockage-type effects (where the measured point velocity was greater than the inflow velocity) occurred around the sides of the rotor for all flow speeds. Although the effects were exaggerated at model scale, it is expected that reasonable variations in water level and flow velocity could also occur over a full scale MCT array.  相似文献