Partitioning of metals (Fe,Pb, Cu,Zn) in urban run‐off from the Kaikorai Valley,Dunedin, New Zealand     

Luke M. Mosley  Barrie M. Peake 《新西兰海洋与淡水研究杂志》2013,47(3):615-624

Urban run‐off from a catchment in Dunedin, New Zealand was sampled and chemically characterised (iron (Fe), lead (Pb), copper (Cu), zinc (Zn) in total and <0.4 (im fractions, suspended solids, nitrogen (N), phosphorus (P), dissolved organic carbon, major ions, pH) during base flows, and storm flows from five rainfall events. Fe and Pb were found to be predominantly particle‐associated (>0.4 μm) and their concentrations increased significantly at the beginning of storm run‐off. In contrast, the majority of Cu and Zn was found in the <0.4μm fraction before rainfall events but during the initial period of storm flows a significant proportion of Cu and Zn was also present in the >0.4 μm fraction. The results indicate that Cu and Zn may be more bio‐available, and more difficult to remove by storm‐water treatment, than Pb. The pH level and the concentration of major ions (Ca⁺², Na⁺, Mg⁺², K⁺), dissolved reactive phosphorus, and nitrate generally decreased during storm flows as a result of dilution by rainwater. Concentrations of total N and P often increased during the initial period of storm run‐off, which was likely because of wash‐off of particulate plant material.  相似文献   

Clay‐coat diversity in marginal marine sediments     

Luke J. Wooldridge  Richard H. Worden  Joshua Griffiths  James E. P. Utley 《Sedimentology》2019,66(3):1118-1138

The specific mineralogy of clay grain coats controls the ability of the coat to inhibit quartz cementation in sandstones during prolonged burial and heating. How and why clay‐coat mineralogy varies across marginal marine systems is poorly understood, even though these eogenetic phenomena strongly influence subsequent mesodiagenesis and reservoir quality. The novel development of the ability to predict the distribution of clay‐coat mineralogy would represent an important development for sandstone reservoir quality prediction. In marginal marine sediments, clay minerals occur as grain‐coats, floccules, mud intraclasts, clay‐rich rock fragments or as dispersed material. However, the relationships between clay mineralogy, the amount of clay, and its distribution is poorly understood. This study focused on the Ravenglass Estuary, UK. The key aim was to develop and apply a novel methodology utilising scanning electron microscope – energy dispersive spectrometry, for the first time, on grain coats in modern sediments, to differentiate the clay‐coat mineral signature from that of the bulk sediment, and reveal the distribution of clay minerals across marginal marine sediments. The study showed that marginal marine sediments principally have their clay mineral assemblage present as clay‐coats on sand grains. These clay‐coats have a mixed clay mineralogy and are spatially heterogeneous across the range of marginal‐marine depositional environments. The study further showed that clay‐coat mineralogy is governed initially by the hydrologically‐controlled segregation of the clay minerals within inner estuarine depositional environments, and subsequently by the selective abrasive removal of specific clay mineral types during reworking and transport into the outer estuary and the marine environment. The highest relative abundance of grain‐coating chlorite was in sand‐flat and tidal‐bar depositional environments. The availability of an analogue data set, and an understanding of the controlling processes of clay‐coat mineralogy, offer crucial steps in building a predictive capability for clay‐coat derived elevated reservoir quality in deeply buried sandstones.  相似文献   

HST Multicolor (255-1042 nm) Photometry of Saturn's Main Rings: I: Radial Profiles, Phase and Opening Angle Variations, and Regional Spectra     

Jeffrey N. CuzziRichard G. French  Luke Dones 《Icarus》2002,158(1):199-223

The main rings of Saturn were observed with the Planetary Camera of the WFPC2 instrument on the Hubble Space Telescope (HST) from September 1996 to December 2000 as the ring opening angle to Earth and Sun increased from 4° to 24°, with a spread of phase angles between 0.3° and 6° at each opening angle. The rings were routinely observed in the five HST wideband UBVRI filters (F336W, F439W, F555W, F675W, and F814W) and occasionally in the F255W, F785LP, and F1042M filters. The emphasis in this series of papers will be on radial color (implying compositional) variations. In this first paper we describe the analysis technique and calibration procedure, note revisions in a previously published Voyager ring color data analysis, and present new results based on over 100 HST images.In the 300-600 nm spectral range where the rings are red, the 555/336-nm ratio increases by about 14% as the phase angle increases from 0.3° to 6°. This effect, never reported previously for the rings, is significantly larger than the phase reddening which characterizes other icy objects, primarily because of the redness of the rings. However, there is no discernible tendency for color to vary with ring opening angle at a given phase angle, and there is no phase variation of color where the spectrum is flat. We infer from this combination of facts that multiple intraparticle scattering, either in a regolith or between facts of an unusually rough surface, is important in these geometries, but that multiple interparticle scattering in a vertically extended layer is not. Voyager color ratios at a phase angle of 14° are compatible with this trend, but calibration uncertainties prevent their use in quantitative modeling.Overall ring average spectra are compatible with those of earlier work within calibration uncertainties, but ring spectra vary noticeably with region. We refine and subdivide the regions previously defined by others. The variation seen between radial profiles of ratios between different wavelengths suggests the presence of multiple compositional components with different radial distributions. We present new radial profiles of far-UV color ratio (F336W/F255W) showing substantial global variations having a different radial structure than seen between 555 and 336 nm. We constrain radial variation in the strength of a putative 850-nm spectral feature to be at the percent level or less. There seem to be real variations in the shape of regional ring spectra between 800 and 1000 nm.  相似文献   

Hydrology and dynamics of a polythermal (mostly cold) High Arctic glacier     

Robert G. Bingham  Peter W. Nienow  Martin J. Sharp  Luke Copland 《地球表面变化过程与地形》2006,31(12):1463-1479

To improve our understanding of the interactions between hydrology and dynamics in mostly cold glaciers (in which water flow is limited by thermal regime), we analyse short‐term (every two days) variations in glacier flow in the ablation zone of polythermal John Evans Glacier, High Arctic Canada. We monitor the spatial and temporal propagation of high‐velocity events, and examine their impacts upon supraglacial drainage processes and evolving subglacial drainage system structure. Each year, in response to the rapid establishment of supraglacial–subglacial drainage connections in the mid‐ablation zone, a ‘spring event’ of high horizontal surface velocities and high residual vertical motion propagates downglacier over two to four days from the mid‐ablation zone to the terminus. Subsequently, horizontal velocities fall relative to the spring event but remain higher than over winter, reflecting channelization of subglacial drainage but continued supraglacial meltwater forcing. Further transient high‐velocity events occur later in each melt season in response to melt‐induced rising supraglacial meltwater inputs to the glacier bed, but the dynamic response of the glacier contrasts with that recorded during the spring event, with the degree of spatial propagation a function of the degree to which the subglacial drainage system has become channelized. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Partially to fully saturated flow through smooth,clean, open fractures: qualitative experimental studies     

Brendon?R.?Jones  Luke?B.?Brouwers  Matthys?A.?DippenaarEmail author 《Hydrogeology Journal》2018,26(3):945-961

Fractures are both rough and irregular but can be expressed by a simple model concept of two smooth parallel plates and the associated cubic law governing discharge through saturated fractures. However, in natural conditions and in the intermediate vadose zone, these assumptions are likely violated. This paper presents a qualitative experimental study investigating the cubic law under variable saturation in initially dry free-draining discrete fractures. The study comprised flow visualisation experiments conducted on transparent replicas of smooth parallel plates with inlet conditions of constant pressure and differing flow rates over both vertical and horizontal inclination. Flow conditions were altered to investigate the influence of intermittent and continuous influx scenarios. Findings from this research proved, for instance, that saturated laminar flow is not likely achieved, especially in nonhorizontal fractures. In vertical fractures, preferential flow occupies the minority of cross-sectional area despite the water supply. Movement of water through the fractured vadose zone therefore becomes a matter of the continuity principle, whereby water should theoretically be transported downward at significantly higher flow rates given the very low degree of water saturation. Current techniques that aim to quantify discrete fracture flow, notably at partial saturation, are questionable. Inspired by the results of this study, it is therefore hypothetically improbable to achieve saturation in vertical fractures under free-draining wetting conditions. It does become possible under extremely excessive water inflows or when not free-draining; however, the converse is not true, as a wet vertical fracture can be drained.  相似文献   

Women,Gender Norms,and Natural Disasters in Bangladesh          下载免费PDF全文

Luke Juran  Jennifer Trivedi 《Geographical review》2015,105(4):601-611

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Nitrate sources and sinks in Elkhorn Slough,California: Results from long-term continuous in situ nitrate analyzers     

Thomas?P.?ChapinEmail author  Jane?M.?Caffrey  Hans?W.?Jannasch  Luke?J.?Coletti  John?C.?Haskins  Kenneth?S.?Johnson 《Estuaries and Coasts》2004,27(5):882-894

Nitrate and water quality parameters (temperature, salinity, dissolved oxygen, turbidity, and depth) were measured continuously with in situ NO₃ analyzers and water quality sondes at two sites in Elkhorn Slough in Central California. The Main Channel site near the mouth of Elkhorn Slough was sampled from February to September 2001. Azevedo Pond, a shallow tidal pond bordering agricultural fields further inland, was sampled from December 1999 to July 2001. Nitrate concentrations were recorded hourly while salinity, temperature, depth, oxygen, and turbidity were recorded every 30 min. Nitrate concentrations at the Main Channel site ranged from 5 to 65 μM. The propagation of an internal wave carrying water from ≈100 m depth up the Monterey Submarine Canyon and into the lower section of Elkhorn Slough on every rising tide was a major source of nitrate, accounting for 80–90% of the nitrogen load during the dry summer period. Nitrate concentrations in Azevedo Pond ranged from 0–20 μM during the dry summer months. Nitrate in Azevedo Pond increased to over 450 μM during a heavy winter precipitation event, and interannual variability driven by differences in precipitation was observed. At both sites, tidal cycling was the dominant forcing, often changing nitrate concentrations by 5-fold or more within a few hours. Water volume flux estimates were combined with observed nitrate concentrations to obtain nitrate fluxes. Nitrate flux calculations indicated a loss of 4 mmol NO₃ m^?2 d^?1 for the entire Elkhorn Slough and 1 mmol NO₃ m^?2 d^?1 at Azevedo Pond. These results suggested that the waters of Elkhorn Slough were not a major source of nitrate to Monterey Bay but actually a nitrate sink during the dry season. The limited winter data at the Main Channel site suggest that nitrate was exported from Elkhorn Slough during the wet season. Export of ammonium or dissolved organic nitrogen, which we did not monitor, may balance some or all of the NO₃ flux.  相似文献   

Analogue models of the effect of long-term basement fault movement on volcanic edifices     

Luke Wooller  Benjamin van Wyk de Vries  Emmanuelle Cecchi  Hazel Rymer 《Bulletin of Volcanology》2009,71(10):1111-1131

Long-term fault movement under volcanoes can control the edifice structure and can generate collapse events. To study faulting effects, we explore a wide range of fault geometries and motions, from normal, through vertical to reverse and dip-slip to strike-slip, using simple analogue models. We explore the effect of cumulative sub-volcanic fault motions and find that there is a strong influence on the structural evolution and potential instability of volcanoes. The variety of fault types and geometries are tested with realistically scaled displacements, demonstrating a general tendency to produce regions of instability parallel to fault strike, whatever the fault motion. Where there is oblique-slip faulting, the instability is always on the downthrown side and usually in the volcano flank sector facing the strike-slip sense of motion. Different positions of the fault beneath the volcano change the location, type and magnitude of the instability produced. For example, the further the fault is from the central axis, the larger the destabilised sector. Also, with greater fault offset from the central axis larger unstable volumes are generated. Such failures are normal to fault strike. Using simple geometric dimensionless numbers, such as the fault dip, degree of oblique motion (angle of obliquity), and the fault position, we graphically display the geometry of structures produced. The models are applied to volcanoes with known underlying faults, and we demonstrate the importance of these faults in determining volcanic structures and slope instability. Using the knowledge of fault patterns gained from these experiments, geological mapping on volcanoes can locate fault influence and unstable zones, and hence monitoring of unstable flanks could be carried out to determine the actual response to faulting in specific cases.  相似文献   

Mapping groundwater discharge to a coastal lagoon using combined spatial airborne thermal imaging,radon (222Rn) and multiple physicochemical variables     

Katie Coluccio  Isaac Santos  Luke C. Jeffrey  Marwan Katurji  Steve Coluccio  Leanne K. Morgan 《水文研究》2020,34(24):4592-4608

Coastal lagoons are significant wetland environments found on coastlines throughout the world. Groundwater seepage may be a key component of lagoon water balances, though only a few studies have investigated large (>100 km²) coastal lagoons. In this study, we combined airborne thermal infrared imagery with continuous measurements of radon (²²²Rn—a natural groundwater tracer), conductivity, water temperature and dissolved oxygen to map groundwater seepage to a large coastal lagoon in New Zealand. We found evidence of seepage along the margins of the lagoon but not away from the margins. Our findings confirmed previously known seepage zones and identified new potential locations of groundwater inflow. Both point source and diffuse seepage occurred on the western and northwestern margins of the lagoon and parallel to the barrier between the lagoon and sea. These observations imply geologic controls on seepage. The combination of remote sensing and in-situ radon measurements allowed us to effectively map groundwater discharge areas across the entire lagoon. Combined, broad-scale qualitative methods built confidence in our interpretation of groundwater discharge locations in a large, dynamic coastal lagoon.  相似文献   

A study of candidate marine target impact craters in Arabia Terra,Mars     

Germari de VILLIERS  David T. KING Jr.  Luke J. MARZEN 《Meteoritics & planetary science》2010,45(6):947-964

Abstract– Previous workers have proposed that a northern ocean existed early during Martian geologic history and the shorelines of that ocean would coincide roughly with the crustal dichotomy that divides the smooth, northern lowlands with the cratered, southern highlands. Arabia Terra is a region on Mars that straddles the crustal dichotomy, and several proposed shorelines are located in the area. Shallow marine impact craters on Mars likely would exhibit features like those on Earth, including characteristic morphological features that are distinctly different from that of craters formed on land. Common attributes of terrestrial marine impact craters include features of wet mass movement such as gravity slumps and debris flows; radial gullies leading into the crater depression; resurge deposits and blocks of dislocated materials; crater rim collapse or breaching of the crater wall; a central peak terrace or peak ring terrace; and subdued topography (an indicator of both age and possible flood inundation immediately following impact). In this article, these features have been used to evaluate craters on Mars as to a possible marine origin. This study used a simple quantification system to approximately judge and rank shallow marine impact crater candidates based on features observed in terrestrial analogs. Based on the quantification system, 77 potential shallow marine impact craters were found within an area bounded by 20°N and 40°N as well as 20°W and 20°E. Nine exemplary candidates were ranked with total scores of 70% or more. In a second, smaller study area, impact craters of approximately similar size and age were evaluated as a comparison and average total scores are 35%, indicating that there is some morphological difference between craters inside and outside the proposed shorelines. Results of this type of study are useful in helping to develop a general means of classification and characterization of potential marine craters.  相似文献