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181.
A self-consistent explanation for the width, strength, and position of spectral features which may be diagnostic of the structure and composition of circumstellar and interstellar silicate grains is presented based on a long series of laboratory experiments using simple oxide analogs. The ratio of the integrated absorption strength of the grains near 10 to that near 20 is shown to decrease monotonically with increased processing (e.g., annealing/hydration) and this ratio may, therefore, be diagnostic of the relative age of the silicate. The oxidation state of iron in the grains is directly related to both the near-infrared grain opacity and enhanced absorption in the ultraviolet. The oxidation state of both iron and silicon is directly related to the rate of nucleation, growth, and processing in a circumstellar outflow, as well as to the processing history of the grain after it reaches the interstellar medium. Other diagnostic indicators of the average silicon oxidation state, degree of structural polymerization and dispersion in the average degree of structural polymerization are discussed.  相似文献   
182.
The fidelity of numerical simulations of the general circulation of the North Atlantic Ocean in basin- to global-scale models have improved considerably in the last several years. This improvement appears to represent a regime shift in the dynamics of the simulated flow as the horizontal grid spacing decreases to around 10 km. Nevertheless, some significant biases in the simulated circulation and substantial uncertainties about the robustness of these results with respect to parameterization choices remain. A growing collection of simulations obtained with the POP primitive equation model allow us to investigate the convergence properties and sensitivity of high resolution numerical simulations of the North Atlantic, with particular attention given to Gulf Stream separation and the subsequent path of the North Atlantic Current into the Northwest Corner. Increases in resolution and reductions in dissipation both contribute to the improvements in the circulation seen in recent studies. We find that our highest resolution eddy-resolving simulations retain an appreciable sensitivity to the closure scheme. Our most realistic simulations of the Gulf Stream are not obtained at the lowest levels of dissipation, while the simulation of the North Atlantic Current continues to improve as dissipation is reduced to near the numerical stability limit. In consequence, there is a limited range of parameter space where both aspects of the simulated circulation can be brought into agreement with observations. This experience gained with the comparatively affordable regional North Atlantic model is now being used to configure the next generation of ocean climate models.  相似文献   
183.
The Levantine Basin circulation derived from recent data consists of a series of sub-basin-scale to mesoscale eddies interconnected by jets. The basin-scale circulation is masked by eddy variability that modulates and modifies it on seasonal and interannual time scales. Long-term qualitative changes in the circulation are reflected in the bifurcation pattterns of ther mid-basin jets, relative strengths of eddies and the hydrographic properties at the core of these eddies. Confinement within the Basin geometry strongly influences the co-evolution of the circulation features.Surface measurements, satellite images and the mass field indicate an entire range of scales of dynamical features in the region. The complexity of the circulation is consistent with the basin-wide and mesoscale heterogeneity of the hydrographic properties. The interannual variability of LIW (Levantine Intermediate Water) formation in the region appears correlated with the changes in the circulation. Wintertime convective overturning of water masses reach intermediate depths and constitute a dominant mechanism of LIW formation, especially in anticyclonic eddies and along the coasts of the northern Levantine Basin.  相似文献   
184.
Arctic warming and permafrost thaw visibly expose changes in the landscape of the Lena River delta, the largest Arctic delta. Determining the past and modern river regime of thick deltaic deposits shaping the Lena River mouth in north-eastern Siberia is critical for understanding the history of delta formation and carbon sequestration. Using a 65 m long sediment core from the delta apex a set of sedimentological techniques is applied to aid in reconstructing the Lena River history. The analysis includes: (i) grain-size measurements and the determination of the bedload composition; (ii) X-ray fluorescence, X-ray diffractometry, and magnetic susceptibility measurements and heavy mineral analysis for tracking mineral change; (iii) pH, electrical conductivity, ionic concentrations, and the δ18O and δD stable isotope composition from ground ice for reconstructing permafrost formation. In addition; (iv) total and dissolved organic carbon is assessed. Chronology is based on; (vi) radiocarbon dating of organic material (accelerator mass spectrometry and conventional) and is complemented by two infrared – optically stimulated luminescence dates. The record stretches back approximately to Marine Isotope Stage 7. It holds periods from traction, over saltation, to suspension load sedimentation. Minerogenic signals do not indicate provenance change over time. They rather reflect the change from high energy to a lower energy regime after Last Glacial Maximum time parallel to the fining-up grain-size trend. A prominent minimum in the ground ice stable isotope record at early Holocene highlights that a river arm migration and an associated refreeze of the underlying river talik has altered the isotopic composition at that time. Fluvial re-routing might be explained by internal dynamics in the Lena River lowland or due to a tectonic movement, since the study area is placed in a zone of seismic activity. At the southern Laptev Sea margin, onshore continental compressional patterns are bordering offshore extensional normal faults.  相似文献   
185.
Impact melt rocks from the 1.9 km diameter, simple bowl‐shaped Tenoumer impact crater in Mauritania have been analyzed chemically and petrologically. They are heterogeneous and can be subdivided into three types based on melt matrix color, occurrence of lithic clast components, amount of vesiculation (melt degassing), different proportions of carbonate melt mingled into silicate melt, and bulk rock chemical composition. These heterogeneities have two main causes (1) due to the small size of the impact crater, there was probably no coherent melt pool where a homogeneous mixture of melts, derived from different target lithologies, could be created; and (2) melt rock heterogeneity occurring at the thin section scale is due to fast cooling during and after the dynamic ejection and emplacement process. The overall period of crystal growth from these diverse melts was extremely short, which provides a further indication that complete chemical equilibration of the phases could not be achieved in such short time. Melt mixing processes involved in the generation of impact melts are, thus, recorded in nonequilibrium growth features. Variable mixing processes between chemically different melt phases and the formation of hybrid melts can be observed even at millimeter scales. Due to extreme cooling rates, different mixing and mingling stages are preserved in the varied parageneses of matrix minerals and in the mineral chemistry of microlites. 40Ar39Ar step‐heating chronology on specimens from three melt rock samples yielded five concordant inverse isochron ages. The inverse isochron plots show that minute amounts of inherited 40Ar* are present in the system. We calculated a weighted mean age of 1.57 ± 0.14 Ma for these new results. This preferred age represents a refinement from the previous range of 21 ka to 2.5 Ma ages based on K/Ar and fission track dating.  相似文献   
186.
Two typical mineral textures of the MG 1 chromitite of the Bushveld Complex, South Africa, were observed; one characterised by abundant orthopyroxene oikocrysts, and the other by coarse-grained granular chromitite with only minor amounts of interstitial material. Oikocrysts form elongate clusters of several crystals aligned parallel to the layering, and typically have subhedral, almost chromite-free, core zones containing remnants of olivine. The core zones are surrounded by poikilitic aureoles overgrowing euhedral to subhedral chromite chadacrysts. Chromite grains show no preferred crystal orientation, whereas orthopyroxene grains forming clusters commonly share the same crystallographic orientation. Oikocryst core zones have lower Mg# and higher concentrations of incompatible trace elements compared to their poikilitic aureoles. Core zones are relatively enriched in REE compared to a postulated parental magma (B1) and did not crystallise in equilibrium with the surrounding minerals, whereas the composition of the poikilitic orthopyroxene is consistent with growth from the B1 magma. These observations cannot be explained by the classic cumulus and post-cumulus models of oikocryst formation. Instead, we suggest that the oikocryst core zones in the MG1 chromitite layer formed by peritectic replacement of olivine primocrysts by reaction with an upwards-percolating melt enriched in incompatible trace elements. Poikilitic overgrowth on oikocryst core zones occurred in equilibrium with a basaltic melt of B1 composition near the magma-crystal mush interface. Finally, adcumulus crystallisation followed by grain growth resulted in the surrounding granular chromitite.  相似文献   
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189.
The objective of moveout parameter inversion is to derive sets of parameter models that can be used for moveout correction and stacking at each common midpoint location to increase the signal-to-noise ratio of the data and to provide insights into the kinematic characteristics of the data amongst other things. In this paper, we introduce a data-driven user-constrained optimization scheme that utilizes manual picks at a point on each reflector within a common midpoint gather to constrain the search space in which an optimization procedure can search for the optimal parameter sets at each reflection. The picks are used to create boundary curves which can be derived approximately via an optimization technique or analytically via the derivation of an analytical bounds function. In this paper, we derive analytical forms of bounds functions for four different moveout cases. These are normal moveout, non-hyperbolic moveout, azimuthally dependent normal moveout and azimuthally dependent non-hyperbolic moveout. The optimization procedure utilized here to search for the optimal moveout parameters is the particle swarm optimization technique. However, any metaheuristic optimization procedure could be modified to account for the constraints introduced in this paper. The technique is tested on two-layer synthetic models based on three of the four moveout cases discussed in this paper. It is also applied to an elastic forward modelled synthetic model called the HESS model, and finally to real 2D land data from Alaska. The resultant stacks show a marked improvement in the signal-to-noise ratio compared to the raw stacks. The results for the normal moveout, non-hyperbolic moveout and azimuthally dependent normal moveout tests suggest that the method is viable for said models. Results demonstrate that our method offers potential as an alternative to conventional parameter picking and inversion schemes, particularly for some cases where the number of parameters in the moveout approximation is 2 or greater.  相似文献   
190.
Trade-wind cumuli constitute the cloud type with the highest frequency of occurrence on Earth, and it has been shown that their sensitivity to changing environmental conditions will critically influence the magnitude and pace of future global warming. Research over the last decade has pointed out the importance of the interplay between clouds, convection and circulation in controling this sensitivity. Numerical models represent this interplay in diverse ways, which translates into different responses of trade-cumuli to climate perturbations. Climate models predict that the area covered by shallow cumuli at cloud base is very sensitive to changes in environmental conditions, while process models suggest the opposite. To understand and resolve this contradiction, we propose to organize a field campaign aimed at quantifying the physical properties of trade-cumuli (e.g., cloud fraction and water content) as a function of the large-scale environment. Beyond a better understanding of clouds-circulation coupling processes, the campaign will provide a reference data set that may be used as a benchmark for advancing the modelling and the satellite remote sensing of clouds and circulation. It will also be an opportunity for complementary investigations such as evaluating model convective parameterizations or studying the role of ocean mesoscale eddies in air–sea interactions and convective organization.  相似文献   
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