Neural network prediction of nitrate in groundwater of Harran Plain, Turkey   总被引：2，自引：0，他引：2  

M. Irfan Yesilnacar  Erkan Sahinkaya  Muhsin Naz  Bestamin Ozkaya 《Environmental Geology》2008,56(1):19-25

Monitoring groundwater quality by cost-effective techniques is important as the aquifers are vulnerable to contamination from the uncontrolled discharge of sewage, agricultural and industrial activities. Faulty planning and mismanagement of irrigation schemes are the principle reasons of groundwater quality deterioration. This study presents an artificial neural network (ANN) model predicting concentration of nitrate, the most common pollutant in shallow aquifers, in groundwater of Harran Plain. The samples from 24 observation wells were monthly analysed for 1 year. Nitrate was found in almost all groundwater samples to be significantly above the maximum allowable concentration of 50 mg/L, probably due to the excessive use of artificial fertilizers in intensive agricultural activities. Easily measurable parameters such as temperature, electrical conductivity, groundwater level and pH were used as input parameters in the ANN-based nitrate prediction. The best back-propagation (BP) algorithm and neuron numbers were determined for optimization of the model architecture. The Levenberg–Marquardt algorithm was selected as the best of 12 BP algorithms and optimal neuron number was determined as 25. The model tracked the experimental data very closely (R = 0.93). Hence, it is possible to manage groundwater resources in a more cost-effective and easier way with the proposed model application.  相似文献   

Mineralogy and geochemistry of the Texeo Cu–Co mine site (NW Spain): screening tools for environmental assessment     

J. Loredo  R. Álvarez  A. Ordóñez  T. Bros 《Environmental Geology》2008,55(6):1299-1310

The Cu–Co–Ni Texeo mine has been the most important source of Cu in NW Spain since Roman times and now, approximately 40,000 m³ of wastes from mine and metallurgical operations, containing average concentrations of 9,263 mg kg⁻¹ Cu, 1,100 mg kg⁻¹ As, 549 mg kg⁻¹ Co, and 840 mg kg⁻¹ Ni, remain on-site. Since the cessation of the activity, the abandoned works, facilities and waste piles have been posing a threat to the environment, derived from the release of toxic elements. In order to assess the potential environmental pollution caused by the mining operations, a sequential sampling strategy was undertaken in wastes, soil, surface and groundwater, and sediments. First, screening field tools were used to identify hotspots, before defining formal sampling strategies; so, in the areas where anomalies were detected in a first sampling stage, a second detailed sampling campaign was undertaken. Metal concentrations in the soils are highly above the local background, reaching up to 9,921 mg kg⁻¹ Cu, 1,373 mg kg⁻¹ As, 685 mg kg⁻¹ Co, and 1,040 mg kg⁻¹ Ni, among others. Copper concentrations downstream of the mine works reach values up to 1,869 μg l⁻¹ and 240 mg kg⁻¹ in surface water and stream sediments, respectively. Computer-based risk assessment for the site gives a carcinogenic risk associated with the presence of As in surface waters and soils, and a health risk for long exposures; so, trigger levels of these elements are high enough to warrant further investigation.  相似文献   

Regional distribution pattern of groundwater heavy metals resulting from agricultural activities   总被引：18，自引：0，他引：18  

J. Nouri  A. H. Mahvi  G. R. Jahed  A. A. Babaei 《Environmental Geology》2008,55(6):1337-1343

Contaminations of groundwater by heavy metals due to agricultural activities are growing recently. The objective of this study was to evaluate and map regional patterns of heavy metals (Cd, Zn and Cu) in groundwater on a plain with high agricultural activities. The study was conducted to investigate the concentration of heavy metals and distribution in groundwater in regions of Shush Danial and Andimeshk aquifers in the southern part of Iran. Presently, groundwater is the only appropriate and widely used source of drinking water for rural and urban communities in this region. The region covers an area of 1,100 km² between the Dez and Karkhe rivers, which lead to the Persian Gulf. For this study, the region was divided into four sub-regions A, B, C and D. Additionally, 168 groundwater samples were collected from 42 water wells during the earlier months of 2004. The flame atomic absorption spectrometry (AAS-Flame) was used to measure the concentration of heavy metals in water samples and the Surfer software was used for determination of the contour map of metal distribution. The results demonstrated that in all of the samples, Cd and Zn concentrations were below the EPA MCLG and EPA secondary standard, respectively. However, the Cu contents of 4.8 % of all samples were higher than EPA MCL. It is also indicated that the concentrations of metals were more pronounced at the southern part of the studied region than at the others. The analysis of fertilizers applied for agricultural activities at this region also indicated that a great majority of the above-mentioned heavy metals were discharged into the environment. Absence of confining layers, proximity to land surface, excess agricultural activities in the southern part and groundwater flow direction that is generally from the north to the southern parts in this area make the southern region of the Shush plain especially vulnerable to pollution by heavy metals than by other contaminants.  相似文献   

Environmental risk evaluation of the use of mine spoils and treated sewage sludge in the ecological restoration of limestone quarries     

M. M. Jordán  S. Pina  F. García-Orenes  M. B. Almendro-Candel  E. García-Sánchez 《Environmental Geology》2008,55(2):453-462

The ecologic restoration criteria in areas degraded from extraction activities require making use of their mine spoils. These materials do not meet fertility conditions to guarantee restoration success and therefore, need the incorporation of organic amendments to obtain efficient substratum. Reducing the deficiencies in the organic material and restoration material nutrients with the contribution of treated sewage sludge is proposed in this work. This experiment was based on a controlled study using columns. The work was conducted with two mine spoils, both very rich in calcium carbonate. The first mineral, of poor quality, came from the formation of aggregates of crushed limestone (Z). The other residual material examined originated in limestone extraction, formed by the levels of interspersed non-limestone materials and the remains of stripped soils (D). Two treatments were undertaken (30,000 and 90,000 kg/ha of sewage sludge), in addition to a control treatment. The water contribution was carried out with a device that simulated either short-duration rain or a flooding irrigation system in order to cover the surface and then percolate through the soil. The collection of leached water took place 24 h after the applications. Different parameters of the leached water were determined, including pH, electrical conductivity, nitrate anions, ammonium, phosphates, sulphates and chlorides. The values obtained for each irrigation application are discussed, and the nitrate values obtained were very elevated.  相似文献   

A GPR study of subsidence-creep-fault processes in Morelia, Michoacán, Mexico     

Jorge A. Avila-Olivera  Víctor H. Garduo-Monroy 《Engineering Geology》2008,100(1-2):69-81

In 1983, inhabitants of the City of Morelia, Michoacán, Mexico, began to observe a series of differential settlements causing damages to constructions along linear trends parallel to a system of regional faults. The same phenomenon occurs in others cities of the Mexican Volcanic Belt (MVB), such as Celaya, Aguascalientes, and Querétaro, and is linked to a structurally controlled subsidence, caused by groundwater withdrawal, and the presence of geological faults. We define this subsidence type as Subsidence-Creep-Fault Processes (SCFP), based on the necessary elements for their generation, and we studied them through geophysical and geotechnical techniques. In Morelia, the geophysical investigations have been carried out using ground-penetrating radar (GPR). GPR profiles, perpendicular to the axis of the surface fault generated by the SCFP were carried out. The common-offset single-fold profiling was used, with a central frequency of 50 MHz. In all cases it has been possible to visualize a fault plane dividing two blocks, the presence of synthetic and antithetic faults, influence zones from 20 m to 40 m, and a maximum “net throw” of 4 m. Exploration trenches followed the same direction of the profiles obtained with GPR (perpendicular to the axis of the surface fault). These trenches exposed a fault plane dividing two blocks with different lithology, generating a maximum “net throw” of 4.40 m; as well they help in the determination of influence zones that varied from 14 m to 40 m.  相似文献   

Design of shallow foundations under tensile loading for transmission line towers: An overview     

M.P. Pacheco  F.A.B. Danziger  C. Pereira Pinto   《Engineering Geology》2008,101(3-4):226-235

Tensioned foundations are common in civil engineering applications such as transmission towers, harbors, offshore structures, basement slabs under pressure, industrial equipment, etc. Procedures for the design of tensioned foundations are discussed in this paper, including specific recommendations for more common transmission tower foundations. Starting from a distinction between shallow and deep modes of failure, the paper presents the most common failure mechanisms for shallow failure in tension, including procedures for calculation of foundation tensile capacity under vertical and inclined loading. Emphasis is given to the influence of the strength of the compacted backfill compared to the strength of the natural soil, including presentation of results of full-scale loading tests.  相似文献   

Discussion on “Experimental study on fracture toughness and tensile strength of a clay” [Engineering Geology 94 (2007) 64–75]     

M.R. Lakshmikantha  P.C. Prat  A. Ledesma 《Engineering Geology》2008,101(3-4):295-296

The paper [Wang, J.-J., Zhu, J.-G., Chiu, C.F., Zhang, H., 2007. Experimental study on fracture toughness and tensile strength of a clay. Engineering Geology 94, 64–75.] focuses on two important fracture parameters of soils: tensile strength and fracture toughness. These parameters control the behaviour of soils in a wide range of situations, from the design of a simple footing to much complicated fracture behaviour of clay liners or covers. The authors have done extensive laboratory work to determine these two parameters and their laborious and complicated experimental program needs praise. However, some of the points raised in their conclusions, based on the analysis and comparison with the data from the literature, need to be discussed.  相似文献   

Composition, P-T parameters, and metasomatic transformations of mafic schists of the Svyatoi Nos Peninsula, Eastern Baikal Area     

V. A. Makrygina  Z. I. Petrova  A. A. Koneva  L. F. Suvorova 《Geochemistry International》2008,46(2):140-155

The paper reports data on rock and mineral compositions from the Svyatonosskaya Formation, which is a continuation of the Ol’khon Series in the northern part of the Svyatoi Nos Peninsula, eastern shore of Lake Baikal. The pyroxene-amphibole-plagioclase schists (metagabbro) are replaced there by the garnet-biotite-quartz assemblage, which was formed, according to the data of various geothermometers and calculations by the THERMOCALC computer program, under conditions corresponding to the transition from the granulite (848–811°C) to high grades of the amphibolite (715–670°C) facies under high pressures (8.7 ±1.6 kbar). In petrogenetic grids, these conditions fall onto the line of the onset of eclogitization. In nature these rocks are a continuation of the Chernorudskaya-Barakchinskaya zone of elevated pressures in the Ol’khon area. The metasomatic rocks were formed simultaneously with strike-slip faulting, when coupled zones of relatively high-(eclogite-like) and low-pressure (quartzite-marble melange) developed at the inflow of SiO₂ and K₂O and the removal of MgO and CaO. Analogous compositional changes in gneisses and schists in tectonic extension zones in Ol’khon Island and neighboring areas occurred during the development of migmatites. The migmatization of the gneisses was likely coupled with the garnetization of mafic schists in high-pressure zones and the formation of eclogite-like rocks replacing marbles. The accompanying graphitization of this block suggests that the metasomatic fluid had a hydrocarbon-hydrogen composition.  相似文献   

Diamond formation in sulfide pyrrhotite-carbon melts: Experiments at 6.0–7.1 GPa and application to natural conditions     

A. V. Shushkanova  Yu. A. Litvin 《Geochemistry International》2008,46(1):37-47

Experiments at 6.0–7.1 GPa and 1500–1700°C were carried out to explore the boundary conditions of diamond nucleation and growth in pyrrhotite-carbon melt-solutions. Pyrrhotite is one of the main sulfide minerals of the pyrrhotite-pentlandite-chalcopyrite assemblage of mantle rocks and primary inclusions in diamond. Solutions of carbon in sulfide melts oversaturated with respect to diamond at the expense of the dissolution of starting graphite (thermodynamically unstable phase) are formed owing to the difference between the solubilities of graphite and diamond, which increases under the influence of temperature gradients in experimental samples. We determined the fields of carbon solutions in pyrrhotite melt showing labile and metastable oversaturation with respect to diamond, which correspond to the spontaneous nucleation of the diamond phase and diamond growth on seeds, respectively. The linear growth rate of diamond in sulfide-carbon melts is rather high (on average, 10 μ/min during the first 1–2 min from the onset of spontaneous crystallization). The nucleation density is estimated as 180 grains per cubic centimeter. Diamonds crystallized from sulfide melts show octahedral and spinel twin shapes. Diamond polycrystals were synthesized for the first time from a sulfide medium as intergrowths of skeletal (edge) or “cryptocrystalline” microdiamonds, from 1 to 100 μm in size, their spinel twins and, occasionally, polysynthetic (star-shaped) twins. During diamond growth from sulfidecarbon melts on smooth faces of cuboctahedral diamond seeds synthesized in metal systems, smooth-faced layer-by-layer step-like growth was observed on their octahedral (111) faces, whereas growth on the (100) cubic faces produced rough-surfaced layers of intergrown micropyramids, whose axes were oriented normal to the (100) face. The obtained experimental results were applied to the problem of diamond genesis under the conditions of the Earth’s mantle in the framework of the model of carbonate-silicate parental melts with blebs of immiscible sulfide melts.  相似文献   

Geochemistry of late stage medium to high-K calc-alkaline and shoshonitic dykes in the Ulukişla Basin (Central Anatolia, Turkey): Petrogenesis and tectonic setting     

M. A. Kurt  M. Alpaslan  M. C. Göncüoǧlu  A. Temel 《Geochemistry International》2008,46(11):1145-1163

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