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931.
Curtis M. Oldenburg 《Environmental Geology》2008,54(8):1687-1694
A screening and ranking framework (SRF) has been developed to evaluate potential geologic carbon dioxide (CO2) storage sites on the basis of health, safety, and environmental (HSE) risk arising from CO2 leakage. The approach is based on the assumption that CO2 leakage risk is dependent on three basic characteristics of a geologic CO2 storage site: (1) the potential for primary containment by the target formation; (2) the potential for secondary containment
if the primary formation leaks; and (3) the potential for attenuation and dispersion of leaking CO2 if the primary formation leaks and secondary containment fails. The framework is implemented in a spreadsheet in which users
enter numerical scores representing expert opinions or published information along with estimates of uncertainty. Applications
to three sites in California demonstrate the approach. Refinements and extensions are possible through the use of more detailed
data or model results in place of property proxies. 相似文献
932.
Eleven surface soil samples from calcareous soils of industrial areas in Hamadan Province, western Iran were analyzed for
total concentrations of Zn, Cd, Ni, Cu and Pb and were sequentially extracted into six fractions to determine the bioavailability
of various heavy metal forms. Total Zn, Cd, Ni, Cu and Pb concentrations of the contaminated soils were 658 (57–5,803), 125.8
(1.18–1,361), 45.6 (30.7–64.4), 29.7 (11.7–83.5) and 2,419 (66–24,850) mg kg−1, respectively. The soils were polluted with Zn, Pb, and Cu to some extent and heavily polluted with Cd. Nickel values were
not above regulatory limits. Copper existed in soil mainly in residual (RES) and organic (OM) fractions (about 42 and 33%,
respectively), whereas Zn occurred essentially as RES fraction (about 69%). The considerable presence of Cd (30.8%) and Pb
(39%) in the CARB fraction suggests these elements have high potential biavailability and leachability in soils from contaminated
soils. The mobile and bioavailable (EXCH and CARB) fractions of Zn, Cd, Ni, Cu, and Pb in contaminated soils averaged (7.3,
40.4, 16, 12.9 and 40.8%), respectively, which suggests that the mobility and bioavailability of the five metals probably
decline in the following order: Cd = Pb > Ni > Cu > Zn. 相似文献
933.
R. K. Prasad N. C. Mondal Pallavi Banerjee M. V. Nandakumar V. S. Singh 《Environmental Geology》2008,55(3):467-475
Remote Sensing and Geographic Information System has become one of the leading tools in the field of hydrogeological science,
which helps in assessing, monitoring and conserving groundwater resources. It allows manipulation and analysis of individual
layer of spatial data. It is used for analysing and modelling the interrelationship between the layers. This paper mainly
deals with the integrated approach of Remote Sensing and geographical information system (GIS) to delineate groundwater potential
zones in hard rock terrain. The remotely sensed data at the scale of 1:50,000 and topographical information from available
maps, have been used for the preparation of ground water prospective map by integrating geology, geomorphology, slope, drainage-density
and lineaments map of the study area. Further, the data on yield of aquifer, as observed from existing bore wells in the area,
has been used to validate the groundwater potential map. The final result depicts the favourable prospective zones in the
study area and can be helpful in better planning and management of groundwater resources especially in hard rock terrains. 相似文献
934.
The Hill Country of Central Texas, USA, is undergoing rapid socioeconomic development, but environmental management of this
region is hampered by misconceptions about local bedrock, soils, terrain, and hydrologic processes. The Hill Country is underlain
mostly by Glen Rose Limestone (Lower Cretaceous) and exhibits a stepped terrain, which has been incorrectly attributed to
alternating hard and soft bedrock strata. Other characteristics mistakenly attributed to this landscape include thin soils
with scant water-retention capabilities, and rapid runoff as the dominant hydrologic process. This report presents new findings:
unweathered bedrock is well indurated, but interbeds exhibit variable weathering rates. Recessive slopes (“risers”) on this
stepped terrain result from rapid deterioration of strata having generally heterogeneous depositional fabrics (bioturbation
and irregular clay partings) in contrast to ledge-forming strata having homogeneous fabrics. A stony regolith is thus formed
beneath risers, providing porous and permeable ground that retards runoff and promotes the formation of moderately deep to
deep (two-tiered) regolith/soil zones. These surficial materials on local steep slopes compose important natural environmental
buffers; they support diverse biota and enhanced geochemical cycling of nutrients; they also exhibit significant water retention
and enhanced erosion abatement. Proper land management demands recognition of these attributes in the siting, design, and
construction of facilities. 相似文献
935.
S. Miko G. Koch S. Mesić M. Šparica-Miko M. Šparica R. Čepelak A. Bačani P. Vreča T. Dolenec S. Bergant 《Environmental Geology》2008,55(3):517-537
Due to their balneotherapeutic features, the organic-rich sediments in Makirina Cove are an important source of healing mud.
An environmental geochemistry approach using normalization techniques was applied to evaluate the anthropogenic contribution
of trace metals to sediments used as healing mud. Sediment geochemistry was found to be associated with land-use change and
storm events, as well as with proximity of a road with heavy traffic in the summer months. Local valley topography preferentially
channels lithogenic and pollutant transport to the cove. Concentrations and distribution of trace metals indicate lithogenic
(Ni, Cr, Co) and anthropogenic (Pb, Cu, Zn and Se) contributions to the sediments. The calculation of enrichment factors indicates
a moderate (EFs between 2–3.5) input of anthropogenic Cu and Pb in surficial sediments to a depth of 10 cm. Patients using
the Makirina Cove sediments as healing mud could be to some extent exposed to enhanced uptake of metals from anthropogenic
sources via dermal contact. 相似文献
936.
The aim of this interdisciplinary study is to examine a component of the hydrological cycle in Galapagos by characterizing
soil properties. Nine soil profiles were sampled on two islands. Their physical and hydrodynamic properties were analyzed,
along with their mineralogical composition. Two groups of soils were identified, with major differences between them. The
first group consists of soils located in the highlands (>350 m a.s.l.), characterized by low hydraulic conductivity (<10−5 m s−1) and low porosity (<25%). These soils are thick (several meters) and homogeneous without coarse components. Their clay fraction
is considerable and dominated by gibbsite. The second group includes soils located in the low parts of the islands (<300 m
a.s.l.). These soils are characterized by high hydraulic conductivity (>10−3 m s−1) and high porosity (>35%). The structure of these soils is heterogeneous and includes coarse materials. The physical properties
of the soils are in good agreement with the variations of the rainfall according to the elevation, which appears as the main
factor controlling the soil development. The clayey alteration products constrain soils physical and hydrodynamic properties
by reducing the porosity and consequently the permeability and also by increasing water retention. 相似文献
937.
M. Irfan Yesilnacar Erkan Sahinkaya Muhsin Naz Bestamin Ozkaya 《Environmental Geology》2008,56(1):19-25
Monitoring groundwater quality by cost-effective techniques is important as the aquifers are vulnerable to contamination from
the uncontrolled discharge of sewage, agricultural and industrial activities. Faulty planning and mismanagement of irrigation
schemes are the principle reasons of groundwater quality deterioration. This study presents an artificial neural network (ANN)
model predicting concentration of nitrate, the most common pollutant in shallow aquifers, in groundwater of Harran Plain.
The samples from 24 observation wells were monthly analysed for 1 year. Nitrate was found in almost all groundwater samples
to be significantly above the maximum allowable concentration of 50 mg/L, probably due to the excessive use of artificial
fertilizers in intensive agricultural activities. Easily measurable parameters such as temperature, electrical conductivity,
groundwater level and pH were used as input parameters in the ANN-based nitrate prediction. The best back-propagation (BP)
algorithm and neuron numbers were determined for optimization of the model architecture. The Levenberg–Marquardt algorithm
was selected as the best of 12 BP algorithms and optimal neuron number was determined as 25. The model tracked the experimental
data very closely (R = 0.93). Hence, it is possible to manage groundwater resources in a more cost-effective and easier way with the proposed
model application. 相似文献
938.
The Cu–Co–Ni Texeo mine has been the most important source of Cu in NW Spain since Roman times and now, approximately 40,000 m3 of wastes from mine and metallurgical operations, containing average concentrations of 9,263 mg kg−1 Cu, 1,100 mg kg−1 As, 549 mg kg−1 Co, and 840 mg kg−1 Ni, remain on-site. Since the cessation of the activity, the abandoned works, facilities and waste piles have been posing
a threat to the environment, derived from the release of toxic elements. In order to assess the potential environmental pollution
caused by the mining operations, a sequential sampling strategy was undertaken in wastes, soil, surface and groundwater, and
sediments. First, screening field tools were used to identify hotspots, before defining formal sampling strategies; so, in
the areas where anomalies were detected in a first sampling stage, a second detailed sampling campaign was undertaken. Metal
concentrations in the soils are highly above the local background, reaching up to 9,921 mg kg−1 Cu, 1,373 mg kg−1 As, 685 mg kg−1 Co, and 1,040 mg kg−1 Ni, among others. Copper concentrations downstream of the mine works reach values up to 1,869 μg l−1 and 240 mg kg−1 in surface water and stream sediments, respectively. Computer-based risk assessment for the site gives a carcinogenic risk
associated with the presence of As in surface waters and soils, and a health risk for long exposures; so, trigger levels of
these elements are high enough to warrant further investigation. 相似文献
939.
Regional distribution pattern of groundwater heavy metals resulting from agricultural activities 总被引:18,自引:0,他引:18
Contaminations of groundwater by heavy metals due to agricultural activities are growing recently. The objective of this study
was to evaluate and map regional patterns of heavy metals (Cd, Zn and Cu) in groundwater on a plain with high agricultural
activities. The study was conducted to investigate the concentration of heavy metals and distribution in groundwater in regions
of Shush Danial and Andimeshk aquifers in the southern part of Iran. Presently, groundwater is the only appropriate and widely
used source of drinking water for rural and urban communities in this region. The region covers an area of 1,100 km2 between the Dez and Karkhe rivers, which lead to the Persian Gulf. For this study, the region was divided into four sub-regions
A, B, C and D. Additionally, 168 groundwater samples were collected from 42 water wells during the earlier months of 2004.
The flame atomic absorption spectrometry (AAS-Flame) was used to measure the concentration of heavy metals in water samples
and the Surfer software was used for determination of the contour map of metal distribution. The results demonstrated that
in all of the samples, Cd and Zn concentrations were below the EPA MCLG and EPA secondary standard, respectively. However,
the Cu contents of 4.8 % of all samples were higher than EPA MCL. It is also indicated that the concentrations of metals were
more pronounced at the southern part of the studied region than at the others. The analysis of fertilizers applied for agricultural
activities at this region also indicated that a great majority of the above-mentioned heavy metals were discharged into the
environment. Absence of confining layers, proximity to land surface, excess agricultural activities in the southern part and
groundwater flow direction that is generally from the north to the southern parts in this area make the southern region of
the Shush plain especially vulnerable to pollution by heavy metals than by other contaminants. 相似文献
940.
A Triassic carbonate unit has been intensively drained by zinc and lead ore mines and numerous borehole fields since the nineteenth
century. Its groundwater recharge has increased due to: pumping of water from boreholes, mining activity, and urbanization.
An approach to determine the amounts of the recharge at a variety of spatial scales is presented in the paper. Different methods
were used to identify and quantify recharge components on a regional and local scale: mathematical modelling was performed
for four aquifers included in an aquifer system, an analytical estimation based on the assumption that an average recharge
is equal to the average discharge of the hydrogeological system—for six man-made drainage centres, and the method of water
level fluctuation (WLF) was applied in one observation borehole. Results of modelling have been supplemented by observation
of environmental tracers (δ18O, δ2H, 3H), noble gases temperatures, and 4Heexc in groundwater. The regional aquifer’s current recharge according to estimations performed by means of modelling varies from
39 to 101 mm/year on average. Depending on the aquifer site the average precipitation ranges from 779 to 864 mm/year. In the
confined part of the aquifer average recharge ranges from 26 to 61 mm/year. Within outcrops average recharge varies from 96
to 370 mm/year. Current recharge estimated by the analytical method for man-made drainage centres varies from 158 up to 440 mm/year.
High values are caused by different recharge sources like precipitation, induced leakage from shallow aquifers, and water
losses from streams, water mains and sewer systems. Pumping of water, mining and municipal activities constitute additional
factors accounting for the intensified recharge. 相似文献