Secondary Ion Mass Spectrometry Bias on Isotope Ratios in Dolomite–Ankerite,Part II: δ13C Matrix Effects          下载免费PDF全文

Maciej G. Śliwiński  Kouki Kitajima  Reinhard Kozdon  Michael J. Spicuzza  John H. Fournelle  Adam Denny  John W. Valley 《Geostandards and Geoanalytical Research》2016,40(2):173-184

This study is Part II of a series that documents the development of a suite of calibration reference materials for in situ SIMS analysis of stable isotope ratios in Ca‐Mg‐Fe carbonates. Part I explored the effects of Fe²⁺ substitution on SIMS δ¹⁸O bias measured from the dolomite–ankerite solid solution series [CaMg(CO₃)₂–CaFe(CO₃)₂], whereas this complementary work explores the compositional dependence of SIMS δ¹³C bias (calibrated range: Fe# = 0.004–0.789, where Fe# = molar Fe/(Mg+Fe)). Under routine operating conditions for carbonate δ¹³C analysis at WiscSIMS (CAMECA IMS 1280), the magnitude of instrumental bias increased exponentially by 2.5–5.5‰ (session‐specific) with increasing Fe‐content in the dolomite structure, but appeared insensitive to minor Mn substitution [< 2.6 mole % Mn/(Ca+Mg+Fe+Mn)]. The compositional dependence of bias (i.e., the matrix effect) was expressed using the Hill equation, yielding calibration residual values ≤ 0.3‰ relative to CRM NBS‐19 for eleven carbonate reference materials (6‐μm‐diameter spot size measurements). Based on the spot‐to‐spot repeatability of a drift monitor material that ‘bracketed’ each set of ten sample‐spot analyses, the analytical precision was ± 0.6–1.2‰ (2s, standard deviations). The analytical uncertainty for individual sample analyses was approximated by combining the precision and calibration residual values (propagated in quadrature), suggesting an uncertainty of ± 1.0–1.5‰ (2s).  相似文献   

Sikhote Alin' meteoroid: A contribution to the story of its fragmentation and fragment scattering     

Bruno Lang  Maciej Kowalski 《Earth and Planetary Science Letters》1973,21(1):85-90

The correlation of the size and spatial distribution of fragments from the Sikhote Alin' meteoroid, 1947, was examined.With Frost's logarithmic rule of spatial sorting of meteorite fragments, supported by an ad hoc developed averaging procedure, a new approach to the size distribution was made possible.It was found that the meteoroid has been originally broken into several - presumably 5–6 - large fragments unequal in size, which further fragmented with various efficiency and speed.The conclusions are compatible with the reports of the witnesses of the fall of the meteorite.  相似文献   

Oil/source rock correlations in the Polish Flysch Carpathians and Mesozoic basement and organic facies of the Oligocene Menilite Shales: insights from hydrous pyrolysis experiments     

John B. Curtis  Maciej J. Kotarba  Michael D. Lewan  Dariusz Wi&#x;c&#x;aw 《Organic Geochemistry》2004,35(11-12):1573

The Oligocene Menilite Shales in the study area in the Polish Flysch Carpathians are organic-rich and contain varying mixtures of Type-II, Type-IIS and Type-III kerogen. The kerogens are thermally immature to marginally mature based on atomic H/C ratios and Rock-Eval data. This study defined three organic facies, i.e., sedimentary strata with differing hydrocarbon-generation potentials due to varying types and concentrations of organic matter. These facies correspond to the Silesian Unit and the eastern and western portions of the Skole Unit. Analysis of oils generated by hydrous pyrolysis of outcrop samples of Menilite Shales demonstrates that natural crude oils reservoired in the flysch sediments appear to have been generated from the Menilite Shales. Natural oils reservoired in the Mesozoic basement of the Carpathian Foredeep appear to be predominantly derived and migrated from Menilite Shales, with a minor contribution from at least one other source rock most probably within Middle Jurassic strata. Definition of organic facies may have been influenced by the heterogeneous distribution of suitable Menilite Shales outcrops and producing wells, and subsequent sample selection during the analytical phases of the study.  相似文献   

Large wood clogging during floods in a gravel‐bed river: the Długopole bridge in the Czarny Dunajec River,Poland          下载免费PDF全文

Virginia Ruiz‐Villanueva  Bartłomiej Wyżga  Paweł Mikuś  Maciej Hajdukiewicz  Markus Stoffel 《地球表面变化过程与地形》2017,42(3):516-530

During floods, large quantities of wood can be mobilized and transported downstream. At critical sections, such as bridges, the transported wood might be entrapped and a quick succession of backwater effects can occur as a result of the reduction of the cross‐sectional area. The aim of this work is to explore large wood‐related hazards during floods in the gravel‐bed river Czarny Dunajec (Polish Carpathians), where the river flows through the village of D?ugopole. This work is based on the numerical modelling of large wood transport together with flow dynamics in which inlet and boundary conditions were designed based on field observations. The exploratory approach developed in this study uses multiple scenarios (193) to analyse the factors controlling bridge clogging: wood size, wood supply, flow conditions, morphology and obstacles in the riverbed. Results highlighted the strong control of log length (stronger than that of log diameter) on potential blockage probability; however, according to our results the main factor controlling bridge clogging was the flood discharge. River morphology and wood supply play an important role as well. The river morphology may reduce bridge blockage, as it influences flow velocity and depth, and creates natural retention zones for wood. In addition, the impacts of bridge blockage were analysed in terms of afflux depth and length, and flooded area. Results showed that bridge blockage may result in a significant increase in water depth (up to 0.7 m) and flooded area (up to 33% more), therefore increasing flood risk in the village. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Anisotropy of magnetic susceptibility as an indicator for palaeocurrent analysis in folded turbidites (Outer Western Carpathians,Poland)     

Aleksandra Stachowska  Maciej Łoziński  Michał Śmigielski  Anna Wysocka  Leszek Jankowski  Piotr Ziółkowski 《Sedimentology》2020,67(7):3783-3808

The anisotropy of magnetic susceptibility is a well-known geological proxy in revealing the directional tectonic and sedimentological features of rocks, although it can be ambiguous in situations where these two factors co-occur. This paper demonstrates the usefulness of the anisotropy of magnetic susceptibility in determining palaeotransport directions in turbiditic rocks that underwent subsequent thrusting and folding. This study demonstrates that the magnetic lineation is largely unsuitable as a palaeocurrent direction proxy, and suggests that the imbrication of magnetic foliation is better in such cases. Moreover, the anisotropy of magnetic susceptibility results were analyzed in reference to a joint and fold study within the framework of the regional structural geology. Magnetic fabric investigations were conducted in the eastern part of the Outer Western Carpathians (south-east Poland). During the study, a total of 191 oriented palaeomagnetic samples were collected from three outcrops (Nasiczne, Dwernik and Hoczew) in the Krosno Beds, Silesian Unit. For the purpose of sedimentological analysis, 121 m of turbidite successions were documented and 126 directional sedimentary structures were measured. The magnetic anisotropy of sandstones revealed typical sedimentary fabrics, often overprinted by variably intense tectonic deformation. Oblate susceptibility ellipsoids from Nasiczne showed tilt coherent with the palaeoflow direction, whereas the rocks from Dwernik and Hoczew contained triaxial magnetic fabric developed during compressional palaeostress. This paper suggests that medium-grained and coarse-grained sandstones, preferably with high mica content, are the most suitable for palaeotransport reconstructions among the studied lithologies.  相似文献   

Correlation between Loess profiles on the basis of mineralogical,malacological, and anthropogenic indicators: A case study from Moravany-Lopata,western Slovakia     

Maciej Pawlikowski  Witold P. Alexandrowicz  Ladislav Banesz  Josef Hromada  Janusz K. Kozlowski  Krzysztof Sobczyk  Barbara Kazior 《Geoarchaeology》1998,13(6):565-594

Moravany-Lopata, located in the complex of sites in the middle Vah basin, dates to the period immediately preceding the LGM. The authors use this site to demonstrate the usefulness of mineralogical, sedimentological, palaeomalacological, and anthropogenic criteria for the correlation of loess profiles. This analysis is especially concerned with sites in loess territories where the loess layers covering archaeological levels are not thick. Such sites occur frequently on the plateaus of the northern part of Central Europe, though they appear most notably in the areas in which the last loess cover, corresponding to the period after the last Pleniglacial and/or Late Glacial postloess sediments, is absent. The archaeological levels dated to before or directly after the LGM occur in the upper portion of the loess, overlain by the Holocene soil. The investigations at the Moravany-Lopata site have confirmed the usefulness of the anthropogenic indicators in the 0.1–1.0 mm fraction for the identification of occupation levels extending even beyond the area of occurrence of macrofinds and evident type structures. On this basis, a relationship could be established between two occupational levels and two ice-wedge generations in the period from 21.4 to 20 ky. Gravettian settlement in western Slovakia seems to have persisted up to the maximum of the LGM. Population groups representing the end of the shouldered points horizon (pointes à cran) appeared in western Slovakia in the intervals between the formation of large networks of ice wedges. The next settlement phase in that territory falls at about 18–17 ky B.P. This is the Epigravettian settlement, which is culturally unrelated to the shouldered points horizon. © 1998 John Wiley & Sons, Inc.  相似文献   

Analysis of trophic networks and carbon flows in south-eastern Baltic coastal ecosystems     

Maciej T. Tomczak  Brbel Müller-Karulis  Leili Jrv  Jonne Kotta  Georg Martin  Atis Minde  Arno Pllume  Arturas Razinkovas  Solvita Strake  Martynas Bucas  Thorsten Blenckner 《Progress in Oceanography》2009,81(1-4):111

Carbon flows in five south-eastern Baltic coastal ecosystems (Puck Bay, Curonian Lagoon, Lithuanian coast, Gulf of Riga coast and Pärnu Bay) were compared on the basis of ECOPATH models using 12 common functional groups. The studied systems ranged from the hypertrophic Curonian Lagoon to the mesotrophic Gulf of Riga coast. Interestingly, we found that macrophytes were not consumed by grazers, but rather channelled into the detritus food chain. In all ecosystems fisheries had far reaching impacts on their target species and on the food-web in general. In particular, benthic food-webs were partly affected by indirect fisheries effects. For example, fisheries tend to change the biomass of piscivorous fish, causing a cascading effect on benthivorous fish and macrozoobenthos. These cascades are ecosystem specific and need to be considered when using benthic invertebrates as productivity and eutrophication indicators. Odum’s maturity attributes allowed a ranking of costal ecosystems according to their maturity. Namely, the community development decreased in the following order: Pärnu Bay > Gulf of Riga coast > Lithuanian coast > Puck Bay > Curonian Lagoon.  相似文献   

Deep‐burial alteration of early‐diagenetic carbonate concretions formed in Palaeozoic deep‐marine greywackes and mudstones (Bardo Unit,Sudetes Mountains,Poland)     

Maciej J. Bojanowski  Andrzej Barczuk  Andreas Wetzel 《Sedimentology》2014,61(5):1211-1239

Carbonate concretions formed in bathyal and deeper settings have been studied less frequently than those formed in shallow‐marine deposits. Similarly, concretions affected by catagenetic conditions have rarely been reported. Calcite concretions in deep‐marine mudstones and greywackes of the Bardo Unit (Sudetes Mountains, Poland) formed during early diagenesis and were buried to significant depths. Petrographic and geochemical (elemental and stable C and O isotopic) analyses document their formation close to the sediment–water interface, prior to mechanical compaction within the sulphate reduction zone and their later burial below the oil window. Although the concretions were fully formed during early diagenesis, the effects of increased temperature and interaction with late‐diagenetic interstitial fluids can be discerned. During maximum burial, the concretions underwent thorough recrystallization that caused alteration of fabric and elemental and O isotope composition. The initial finely crystalline cement was replaced by more coarsely crystalline, sheaf‐like, poikilotopic calcite in the concretions. These large calcite crystals engulf and partially replace unstable detrital constituents. The extremely low δ¹⁸O values (down to ?21·2‰ Vienna Pee Dee Belemnite) in the concretions are the result of the increased temperature in combination with alteration of volcanic glass, both causing a significant ¹⁸O‐depletion of bicarbonate dissolved in the interstitial fluids. Recrystallization led to uniform O isotope ratios in the concretions, but did not affect the C isotope signature. The δ¹³C values of the late‐diagenetic cements precipitated in the greywacke and in cracks cutting through concretions imply crystallization in the catagenetic zone and decarboxylation as a source of the bicarbonate. These late‐diagenetic processes took place in a supposedly overpressured setting, as suggested by clastic dykes and hydrofractures that cut through both concretions and host rock. All of these features show how the effects of early and late diagenesis can be distinguished in such rocks.  相似文献   

Estimation of Solar Prominence Magnetic Fields Based on the Reconstructed 3D Trajectories of Prominence Knots     

Maciej Zapiór  Pawe? Rudawy 《Solar physics》2012,280(2):445-456

We present an estimation of the lower limits of local magnetic field strengths in quiescent, activated, and active (surges) prominences, based on reconstructed three-dimensional (3D) trajectories of individual prominence knots. The 3D trajectories, velocities, tangential and centripetal accelerations of the knots were reconstructed using observational data collected with a single ground-based telescope equipped with a Multi-channel Subtractive Double Pass imaging spectrograph. Lower limits of magnetic fields channeling observed plasma flows were estimated under assumption of the equipartition principle. Assuming approximate electron densities of the plasma n _e=5×10¹¹?cm^?3 in surges and n _e=5×10¹⁰?cm^?3 in quiescent/activated prominences, we found that the magnetic fields channeling two observed surges range from 16 to 40?Gauss, while in quiescent and activated prominences they were less than 10?Gauss. Our results are consistent with previous detections of weak local magnetic fields in the solar prominences.  相似文献   

On the importance of training methods and ensemble aggregation for runoff prediction by means of artificial neural networks     

Adam P. Piotrowski  Jaroslaw J. Napiorkowski  Marzena Osuch  Maciej J. Napiorkowski 《水文科学杂志》2013,58(10):1903-1925

ABSTRACT

Artificial neural networks (ANNs) become widely used for runoff forecasting in numerous studies. Usually classical gradient-based methods are applied in ANN training and a single ANN model is used. To improve the modelling performance, in some papers ensemble aggregation approaches are used whilst in others, novel training methods are proposed. In this study, the usefulness of both concepts is analysed. First, the applicability of a large number of population-based metaheuristics to ANN training for runoff forecasting is tested on data collected from four catchments, namely upper Annapolis (Nova Scotia, Canada), Biala Tarnowska (Poland), upper Allier (France) and Axe Creek (Victoria, Australia). Then, the importance of the search for novel training methods is compared with the importance of the use of a very simple ANN ensemble aggregation approach. It is shown that although some metaheuristics may slightly outperform the classical gradient-based Levenberg-Marquardt algorithm for a specific catchment, none performs better for the majority of the tested ones. One may also point out a few metaheuristics that do not suit ANN training at all. On the other hand, application of even the simplest ensemble aggregation approach clearly improves the results when the ensemble members are trained by any suitable algorithms.