Bioreduction of hematite nanoparticles by the dissimilatory iron reducing bacterium Shewanella oneidensis MR-1     

Saumyaditya Bose  Michael F. Hochella Jr.  David W. Kennedy  Andrew S. Madden 《Geochimica et cosmochimica acta》2009,73(4):962-976

We examined the reduction of different size hematite (α-Fe₂O₃) nanoparticles (average diameter of 11, 12, 30, 43, and 99 nm) by the dissimilatory iron reducing bacteria (DIRB), Shewanella oneidensis MR-1, to determine how S. oneidensis MR-1 may utilize these environmentally relevant solid-phase electron acceptors. The surface-area-normalized-bacterial Fe(III) reduction rate for the larger nanoparticles (99 nm) was one order of magnitude higher than the rate observed for the smallest nanoparticles (11 nm). The Fe(III) reduction rates for the 12, 30, and 43 nm nanoparticles fell between these two extremes. Whole-cell TEM images showed that the mode of Fe₂O₃ nanoparticle attachment to bacterial cells was different for the aggregated, pseudo-hexagonal/irregular and platey 11, 12, and 99 nm nanoparticles compared to the non-aggregated 30 and 43 nm rhombohedral nanoparticles. Due to differences in aggregation, the 11, 12, and 99 nm nanoparticles exhibited less cell contact and less cell coverage than did the 30 and 43 nm nanoparticles. We hypothesize that S. oneidensis MR-1 employs both indirect and direct mechanisms of electron transfer to Fe(III)-oxide nanoparticles and that the bioreduction mechanisms employed and Fe(III) reduction rates depend on the nanoparticles’ aggregation state, size, shape and exposed crystal faces.  相似文献   

Long-Period Magnetotelluric Measurements Near the Central California Coast: A Land-Locked View of the Conductivity Structure Under the Pacific Ocean   总被引：2，自引：0，他引：2  

R. L. Mackie  B. R. Bennett  T. R. Madden 《Geophysical Journal International》1988,95(1):181-194

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Observations of OCS and a search for OC3S in the interstellar medium     

Matthews HE  MacLeod JM  Broten NW  Madden SC  Friberg P 《The Astrophysical journal》1987,315(2):646-653

Observations of OCS and a search for OC3S are reported, with particular reference to cold dust clouds. OCS has been detected for the first time in dark clouds with a mean fractional abundance relative to hydrogen of approximately 3 x 10(-9); this is approximately 4 times greater than that observed for giant molecular clouds. This results is discussed in the context of molecule formation mechanisms. Observations of the J = 1 --> 0 transition of OCS indicate that this transition is amplifying the background continuum radiation in the direction of Sgr B2.  相似文献   

Near‐infrared spectroscopy of a hydroecological indicator: new tool for determining sustainable yield for Floridan aquifer system     

Sydney T. Bacchus  Douglas D. Archibald  George A. Brook  Kerry O. Britton  Bruce L. Haines  Stephen L. Rathbun  Marguerite Madden 《水文研究》2003,17(9):1785-1809

Pond‐cypress (Taxodium ascendens Brong.) is a dominant canopy species in depressional wetlands of the south‐eastern Coastal Plain. Unsustainable withdrawals from the karst Floridan aquifer system have caused premature decline and death of pond‐cypress trees, presumably owing to altered hydroperiods (which alter the flow of water and nutrients in trees). There has been no scientifically based means to determine sustainable yield from this regional aquifer system or to detect early stages of physical/ecological damage associated with groundwater mining and aquifer storage and recovery (ASR, which also can alter natural hydroperiods). In this study, the relationship between visual symptoms (indicators) of stress or premature decline, and spectral reflectance was evaluated using dried, milled branch tips collected from natural stands of mature pond‐cypress. Depressional systems evaluated represented four of the six aquifer system subregions where subsurface perturbations from groundwater mining: (i) were presumed not to be occurring (reference wetlands); (ii) may be occurring but are not documented; and (iii) have been confirmed. Sampled trees were assigned to one of three stress classes (1, no/minimal; 2, moderate; 3, severe) based on the visual indicators. Partial least squares–linear discriminant analysis of second derivative spectral transformations in the visible/shortwave near‐infrared (NIR) region (400–1100 nm) and the NIR region (1100–2500 nm) was used to evaluate the samples in assigned classes. Class 1 samples were discriminated from combined class 2 and 3 samples in the NIR region with 100% and 97% accuracy for consecutive winter sample periods (before bud‐break). The percentage of correctly classified samples in this spectral region was lower (85%) for summer samples (full leaf‐out). Second‐derivative models for the NIR region developed from the winter data sets predicted assigned classes for alternate winter's samples with an accuracy of 97% and 100%. High correlation between spectral reflectance of dried, milled branch tips collected from mature pond‐cypress in winter and visual indicators of premature decline suggests in situ pond‐cypress are hydroecological indicators of anthropogenic subsurface hydroperiod perturbations. This approach provides objective means for early detection of unsustainable aquifer yield and adverse impacts from ASR activities in the south‐eastern Coastal Plain. Used in conjunction with hydrological monitoring and modelling, the hydroecological indicators should provide the means with which sustainable yield in the south‐eastern Coastal Plain can be achieved and maintained. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Hierarchical Bayesian modeling of spatio-temporal patterns of lung cancer incidence risk in Georgia,USA: 2000–2007     

Ping Yin  Lan Mu  Marguerite Madden  John E. Vena 《Journal of Geographical Systems》2014,16(4):387-407

Lung cancer is the second most commonly diagnosed cancer in both men and women in Georgia, USA. However, the spatio-temporal patterns of lung cancer risk in Georgia have not been fully studied. Hierarchical Bayesian models are used here to explore the spatio-temporal patterns of lung cancer incidence risk by race and gender in Georgia for the period of 2000–2007. With the census tract level as the spatial scale and the 2-year period aggregation as the temporal scale, we compare a total of seven Bayesian spatio-temporal models including two under a separate modeling framework and five under a joint modeling framework. One joint model outperforms others based on the deviance information criterion. Results show that the northwest region of Georgia has consistently high lung cancer incidence risk for all population groups during the study period. In addition, there are inverse relationships between the socioeconomic status and the lung cancer incidence risk among all Georgian population groups, and the relationships in males are stronger than those in females. By mapping more reliable variations in lung cancer incidence risk at a relatively fine spatio-temporal scale for different Georgian population groups, our study aims to better support healthcare performance assessment, etiological hypothesis generation, and health policy making.  相似文献   

Potential effects of obliquity change on gas hydrate stability zones on Mars     

Margaret J. Root  Megan E. Elwood Madden 《Icarus》2012,218(1):534-544

Methane hydrate dissociation due to obliquity-driven temperature change has been suggested as a potential source of atmospheric methane plumes recently observed on Mars. This work uses both equilibrium and time-dependent models to determine how geothermal gradients change on Mars as a result of obliquity and predict how these changes affect gas hydrate stability zones (HSZs). The models predict that the depth to the HSZ decreases with increasing latitude for both CO₂ and CH₄ hydrate, with CO₂ hydrate occurring at shallower depths than CH₄ hydrate over all latitudes. The depth of the HSZ increases as surface temperatures warm and decreases as surface temperatures cool with changing obliquity, with the largest change in HSZ volume predicted near the equator and the poles. Therefore, changes in the depth to the HSZ may cause hydrate dissociation near the equator and poles as the geothermal gradient moves in and out of the hydrate stability field over hundreds of thousands of years. Sublimation of overlying ice containing diffused methane could account for recent observations of seasonal methane plumes on Mars. In addition, near-surface gas hydrate reservoirs may be preserved at mid-latitudes due to minimal changes in surface temperature with obliquity over geologic time scales. Comparisons of the predicted changes in the HSZ with hydrate dissociation and diffusion rates reveal that metastable hydrate may also remain in the near subsurface, especially at high latitudes, for millions to billions of years. The presence of methane hydrate in the near subsurface at midlatitudes could be an important analytical target for future Mars missions, as well as serving as a source of fuel for future spacecraft.  相似文献   

Photo's from Proceedings of the Third MicroQuasar Workshop; Granada Worshop on Galactic Relativistic Jet Sources – Granada,Spain, 11–13 September 2000     

Herbert W. Schnopper  Eric Silver  Stephen Murray  Suzanne Romaine  Simon Bandler  Christine Jones  William Forman  Norman Madden  Jeffery Beeman  Eugene Haller  Finn Christensen  Niels Westergaard  Juan Fabregat  Victor Reglero  Alvaro Gimenez  Noah Brosch  Elia Liebowitz  Hagai Netzer  Marco Barbera  Alfonso Collura  Salvatore Sciortino 《Astrophysics and Space Science》2001,276(1):49-65

The X-Ray Spectroscopic Explorer (XRASE) has a unique combination of features that will make it possible to address many of NASA's scientific goals. These include how galaxy clusters form, the physics and chemistry of the ISM, the heating of stellar coronae, the amount and content of intergalactic baryonic matter, the mass of black holes and the formation of disks and jets in AGN and galactic binaries. XRASE has a thin foil, multilayered telescope with a large collecting area up to 10 keV, especially in the Fe K region (1100 cm²). Its microcalorimeter array combines high energy resolution (7 eV at 6 keV) and efficiency with a field-of-view of 26 arcmin² . A deep orbit allows for long, continuous observations. Monitoring instruments in the optical (WOM-X), UV (TAUVEX) and hard X-RAY (GRAM) bands will offer exceptional opportunities to make simultaneous multi-wavelength observations.  相似文献   

Intraseasonal oscillations in 15 atmospheric general circulation models: results from an AMIP diagnostic subproject   总被引：16，自引：1，他引：16  

J. M. Slingo  K. R. Sperber  J. S. Boyle  J.-P. Ceron  M. Dix  B. Dugas  W. Ebisuzaki  J. Fyfe  D. Gregory  J.-F. Gueremy  J. Hack  A. Harzallah  P. Inness  A. Kitoh  W. K.-M. Lau  B. McAvaney  R. Madden  A. Matthews  T. N. Palmer  C.-K. Parkas  D. Randall  N. Renno 《Climate Dynamics》1996,12(5):325-357

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Quartz latite rheoignimbrite flows of the Etendeka Formation,north-western Namibia     

SC Milner  AR Duncan  A Ewart 《Bulletin of Volcanology》1992,54(3):200-219

The Etendeka Formation of north-western Namibia consists of a sequence of interbedded quartz latites and tholeiitic basalts and forms part of the Karoo Igneous Province in southern Africa. The age of the Etendeka Formation is approximately 130–135 Ma. The quartz latites make up a significant proportion of the stratigraphic succession (<25% of the total stratigraphic thickness) and form as much as 60% of the outcrop area in the southern Etendeka. Apart from some systematic differences between pitchstones and devitrified quartz latite, largely explained by alteration processes, individual quartz latite units exhibit remarkably uniform compositions with no significant vertical or lateral variation. Geochemistry can be used as a primary criterion for the correlation of major quartz latite units over much of the southern Etendeka area enabling the reconstruction of the Etendeka Formation stratigraphy in this region. Individual quartz latite units occur as voluminous (400–2600 km³), widespread (up to 8800 km²), sheet-like deposits typically between 40 and 300 m thick. Each unit consists of basal, main and upper zones. The main zone generally constitutes over 70% of the thickness of the unit and typically consists of texturally featureless devitrified quartz latite. In contrast the basal and upper zones of the flow are characterised by flow banding, pitchstone lenses and breccia, with rare occurrences of pyroclastic textures. The quartz latites are sparsely porphyritic (<10% phenocrysts) with glassy or devitrified groundmass textures. The phenocrysts consist of plagioclase, pyroxene, titanomagnetite and rare ilmenite. Pyroxene geothermometry indicates high (1000–1100°C) temperatures of crystallisation which, coupled with the absence or primary hydrous phases, indicates that the quartz latites were relatively hot, H₂O-undersaturated magmas. The quartz latites display features common to both rhyolite lavas and ignimbrites and are clearly the products of an unusual eruption style. The local preservation of pyroclastic textures and the broad areal extent of these units lead to the conclusion that the quartz latites are high-temperature rheomorphic ignimbrites (i.e. rheoignimbrites). A combination of high eruption temperature and relatively low viscosity helps to explain the often completely welded and homogeneous textures observed in most quartz latite outcrops in the Etendeka area.  相似文献   

Motions at core surface in the geostrophic approximation     

J.L. Le Mouël  C. Gire  T. Madden 《Physics of the Earth and Planetary Interiors》1985,39(4):270-287

Motions at the top of the core which generate the observed Secular Variation (S.V.) field are computed. To reduce the well known ambiguity of the solution, two constraints are added: the flow is a large scale one and is geostrophic. The computed flow then has a very simple geometry; its poloïdal part is roughly axisymmetrical with respect to an equatorial diameter. This geometry is almost unchanged from 1970 to 1980 while the intensity of the velocity is nearly doubled.  相似文献