Chemical and physical weathering in a hot‐arid,tectonically active alluvial system of Anza Borrego Desert,California          下载免费PDF全文

Young Ji Joo  Megan E. Elwood Madden  Gerilyn S. Soreghan 《Sedimentology》2016,63(5):1065-1083

Investigation of chemical and physical weathering of bedrock and alluvial sediment in the Anza Borrego Desert, California, sheds light on weathering processes in hot‐arid systems and clarifies interpretations of climate from alluvial sediment. All of the alluvial sediment in the study area emanates from Cretaceous tonalite of the Peninsular Range, enabling exploration of the effects of external variables – climate, transport distance and tectonics – on the physical and chemical properties of the sediment. Chemical weathering in this area is dominated by plagioclase alteration observed in both bedrock outcrops and sediment, evinced most clearly by changes in the Eu anomaly. Biotite chemical weathering, manifested by interlayer K⁺ loss, is not evident in bedrock, but clearly observed in the sediment. Despite the weak intensity of chemical weathering (Chemical Index of Alteration = 56 to 62), fine‐grained (<63 μm) sediment displays a clear weathering trend in A–CN–K space and contains up to 25% clay minerals. Physical abrasion and grain‐size reduction in biotite during transport predominates in the sediment, whereas physical (insolation) weathering affecting bedrock is inferred from estimates of differential thermal expansion of mineral phases in response to extreme temperature changes in the study area. Chemical alteration and Brunauer–Emmett–Teller surface area both increase within the active Elsinore fault zone at the distal end of the depositional transect, reflecting tectonic‐induced fracturing and associated accelerated weathering. Extensive fracturing, together with a more humid Pleistocene climate, probably facilitated in situ bedrock weathering, preceding arid alluvial deposition in the Holocene. This study demonstrates that both climate and tectonic processes can affect chemical and physical weathering, resulting in alteration of plagioclase, leaching of K⁺ from biotite in the sediment and formation of clay minerals, even in hot, arid systems.  相似文献   

GIS applications for military operations in coastal zones     

S. Fleming  T. Jordan  M. Madden  E.L. Usery  R. Welch 《ISPRS Journal of Photogrammetry and Remote Sensing》2009,64(2):213-222

In order to successfully support current and future US military operations in coastal zones, geospatial information must be rapidly integrated and analyzed to meet ongoing force structure evolution and new mission directives. Coastal zones in a military-operational environment are complex regions that include sea, land and air features that demand high-volume databases of extreme detail within relatively narrow geographic corridors. Static products in the form of analog maps at varying scales traditionally have been used by military commanders and their operational planners. The rapidly changing battlefield of 21st Century warfare, however, demands dynamic mapping solutions. Commercial geographic information system (GIS) software for military-specific applications is now being developed and employed with digital databases to provide customized digital maps of variable scale, content and symbolization tailored to unique demands of military units. Research conducted by the Center for Remote Sensing and Mapping Science at the University of Georgia demonstrated the utility of GIS-based analysis and digital map creation when developing large-scale (1:10,000) products from littoral warfare databases. The methodology employed–selection of data sources (including high resolution commercial images and Lidar), establishment of analysis/modeling parameters, conduct of vehicle mobility analysis, development of models and generation of products (such as a continuous sea–land DEM and geo-visualization of changing shorelines with tidal levels)–is discussed. Based on observations and identified needs from the National Geospatial-Intelligence Agency, formerly the National Imagery and Mapping Agency, and the Department of Defense, prototype GIS models for military operations in sea, land and air environments were created from multiple data sets of a study area at US Marine Corps Base Camp Lejeune, North Carolina. Results of these models, along with methodologies for developing large-scale littoral warfare databases, aid the National Geospatial-Intelligence Agency in meeting littoral warfare analysis, modeling and map generation requirements for US military organizations.  相似文献   

The names of urban dispossession: a concluding commentary     

David J. Madden 《Urban geography》2019,40(6):888-892

ABSTRACT

This concluding commentary discusses some of the ways in which branded renaming reflects conflicts over ownership, authority, property and power. Practices of sponsored renaming and place branding are not monolithic, but this special issue shows that they are deeply rooted within neoliberal urbanism. It should therefore not be surprising that place branding is almost always contested, and often a flashpoint in struggles over urban space.  相似文献   

Coupled biotic-abiotic Mn(II) oxidation pathway mediates the formation and structural evolution of biogenic Mn oxides     

D.R. Learman  S.M. Webb  A.S. Madden 《Geochimica et cosmochimica acta》2011,75(20):6048-6063

Manganese (Mn) oxides are among the strongest oxidants and sorbents in the environment, impacting the transport and speciation of metals, cycling of carbon, and flow of electrons within soils and sediments. The oxidation of Mn(II) to Mn(III/IV) oxides has been primarily attributed to biological processes, due in part to the faster rates of bacterial Mn(II) oxidation compared to observed mineral-induced and other abiotic rates. Here we explore the reactivity of biogenic Mn oxides formed by a common marine bacterium (Roseobacter sp. AzwK-3b), which has been previously shown to oxidize Mn(II) via the production of extracellular superoxide. Oxidation of Mn(II) by superoxide results in the formation of highly reactive colloidal birnessite with hexagonal symmetry. The colloidal oxides induce the rapid oxidation of Mn(II), with dramatically accelerated rates in the presence of organics, presumably due to mineral surface-catalyzed organic radical generation. Mn(II) oxidation by the colloids is further accelerated in presence of both organics and light, implicating reactive oxygen species in aiding abiotic oxidation. Indeed, the enhancement of Mn(II) oxidation is negated when the colloids are reacted with Mn(II) in the presence of superoxide dismutase, an enzyme that scavenges the reactive oxygen species (ROS) superoxide. The reactivity of the colloidal phase is short-lived due to the rapid evolution of the birnessite from hexagonal to pseudo-orthogonal symmetry. The secondary particulate triclinic birnessite phase exhibits a distinct lack of Mn(II) oxidation and subsequent Mn oxide formation. Thus, the evolution of initial reactive hexagonal birnessite to non-reactive triclinic birnessite imposes the need for continuous production of new colloidal hexagonal particles for Mn(II) oxidation to be sustained, illustrating an intimate dependency of enzymatic and mineral-based reactions in Mn(II) oxidation. Further, the coupled enzymatic and mineral-induced pathways are linked such that enzymatic formation of Mn oxide is requisite for the mineral-induced pathway to occur. Here, we show that Mn(II) oxidation involves a complex network of abiotic and biotic processes, including enzymatically produced superoxide, mineral catalysis, organic reactions with mineral surfaces, and likely photo-production of ROS. The complexity of coupled reactions involved in Mn(II) oxidation here highlights the need for further investigations of microbially-mediated Mn oxide formation, including identifying the role of Mn oxide surfaces, organics, reactive oxygen species, and light in Mn(II) oxidation and Mn oxide phase evolution.  相似文献   

Application of inverse path distance weighting for high-density spatial mapping of coastal water quality patterns     

Joseph Stachelek  Christopher J. Madden 《International journal of geographical information science》2013,27(7):1240-1250

One of the primary goals of coastal water quality monitoring is to characterize spatial variation. Generally, this monitoring takes place at a limited number of fixed sampling points. The alternative sampling methodology explored in this paper involves high-density sampling from an on-board flow-through water analysis system (Dataflow). Dataflow (West Palm Beach, FL, USA) has the potential to provide better spatial resolution of water quality features because it generates many closely spaced (<10 m) measurements. Regardless of the measurement technique, parameter values at unsampled locations must be interpolated from nearby measurement points in order to generate a comprehensive picture of spatial variations. Standard Euclidean interpolations in coastal settings tend to yield inaccurate results because they extend through barriers in the landscape such as peninsulas, islands, and submerged banks. We recently developed a method for non-Euclidean interpolation by inverse path distance weighting (IPDW) in order to account for these barriers. The algorithms were implemented as part of an R package and made available from R repositories. The combination of IPDW with Dataflow provided more accurate estimates of salinity patterning relative to Euclidean inverse distance weighting (IDW). IPDW was notably more accurate than IDW in the presence of intense spatial gradients.  相似文献   

Shock re‐equilibration of fluid inclusions in crystalline basement rocks from the Ries crater,Germany     

Megan E. Elwood Madden  David A. Kring  Robert J. Bodnar 《Meteoritics & planetary science》2006,41(2):247-262

Abstract— This study examines the effects of shock metamorphism on fluid inclusions in crystalline basement target rocks from the Ries crater, Germany. The occurrence of two‐phase fluid inclusions decreases from shock stage 0 to shock stage 1, while single‐phase inclusions increase, likely as a result of re‐equilibration. In shock stages 2 and 3, both two‐phase and single‐phase inclusions decrease with increasing shock stage, indicating that fluid inclusion vesicles are destroyed due to plastic deformation and phase changes in the host minerals. However, quartz clasts entrained in shock stage 4 melts contain both single‐phase and two‐phase inclusions, demonstrating the rapid quenching of the melt and the heterogeneous nature of impact deformation. Inclusions in naturally shocked polycrystalline samples survive at higher shock pressures than those in single crystal shock experiments. However, fluid inclusions in both experimental and natural samples follow a similar trend in re‐equilibration at low to moderate shock pressures leading to destruction of inclusion vesicles in higher shock stages. This suggests that shock processing may lead to the destruction of fluid inclusions in many planetary materials and likely contributed to shock devolatilization of early planetesimals.  相似文献   

Effects of a Beach Nourishment Project in Jamaica Bay,New York,on Horseshoe Crab (<Emphasis Type="Italic">Limulus polyphemus</Emphasis>) Spawning Activity and Egg Deposition     

Mark L. Botton  Christina P. Colón  John Rowden  Susan Elbin  Debra Kriensky  Kim McKown  Matthew Sclafani  Robert Madden 《Estuaries and Coasts》2018,41(4):974-987

Restoration of horseshoe crab spawning habitats through beach nourishment may be considered as a potential strategy to enhance reproductive success in areas where estuarine beaches have been lost to coastal erosion and development. The US Army Corps of Engineers performed a beach nourishment project at Plumb Beach (Jamaica Bay, Brooklyn, NY) in 2012 to stabilize the shoreline. While the addition of sand was done to protect infrastructure, it created an opportunity to examine the responses of American horseshoe crabs (Limulus polyphemus) to beach nourishment using a BACI (before-after control impact) design. During Spring 2012, before beach nourishment, horseshoe crabs made minimal use of the highly degraded western section of Plumb Beach in comparison to a nearby reference site, as quantified by numbers of spawning adults at high tide and densities of horseshoe crab eggs in core samples. In the first post-nourishment field season (Spring 2013), there was no detectable increase in horseshoe crab spawning activity on the newly restored beach. In 2014 and 2015, the density of spawning females began to increase at the nourished beach, although their numbers and especially the density of horseshoe crab eggs remained much lower than at the reference site. Three years after beach nourishment, differences in sediments texture (mean grain diameter, percent gravel, sorting, skewness, and hardness) were still evident between the nourishment and reference sites. Our results suggest that (1) at this site, beach nourishment appeared to bring about only slow increases in horseshoe crab spawning density after several seasons and (2) subtle differences in beach geomorphology over relatively short distances can be detected by horseshoe crabs and may underlie their selection of specific nesting sites.  相似文献   

Contrasting effects of Al substitution on microbial reduction of Fe(III) (hydr)oxides     

Eileen B. Ekstrom  Andrew S. Madden 《Geochimica et cosmochimica acta》2010,74(24):7086-7099

Aluminum, one of the most abundant elements in soils and sediments, is commonly found co-precipitated with Fe in natural Fe(III) (hydr)oxides; yet, little is known about how Al substitution impacts bacterial Fe(III) reduction. Accordingly, we investigated the reduction of Al substituted (0-13 mol% Al) goethite, lepidocrocite, and ferrihydrite by the model dissimilatory Fe(III)-reducing bacterium (DIRB), Shewanella putrefaciens CN32. Here we reveal that the impact of Al on microbial reduction varies with Fe(III) (hydr)oxide type. No significant difference in Fe(III) reduction was observed for either goethite or lepidocrocite as a function of Al substitution. In contrast, Fe(III) reduction rates significantly decreased with increasing Al substitution of ferrihydrite, with reduction rates of 13% Al-ferrihydrite more than 50% lower than pure ferrihydrite. Although Al substitution changed the minerals’ surface area, particle size, structural disorder, and abiotic dissolution rates, we did not observe a direct correlation between any of these physiochemical properties and the trends in bacterial Fe(III) reduction. Based on projected Al-dependent Fe(III) reduction rates, reduction rates of ferrihydrite fall below those of lepidocrocite and goethite at substitution levels equal to or greater than 18 mol% Al. Given the prevalence of Al substitution in natural Fe(III) (hydr)oxides, our results bring into question the conventional assumptions about Fe (hydr)oxide bioavailability and suggest a more prominent role of natural lepidocrocite and goethite phases in impacting DIRB activity in soils and sediments.  相似文献   

Reduced sulfur–carbon–water systems on Mars may yield shallow methane hydrate reservoirs     

M.E. Elwood Madden  J.R. Leeman  M.J. Root  S. Gainey 《Planetary and Space Science》2011,59(2-3):203-206

Methane clathrate hydrate reservoirs capped by overlying permafrost have been proposed as potential sources of atmospheric methane plumes on Mars. However, the surface flux of methane from hydrate dissociation is limited by the diffusion rate of methane through the overlying ice. Assuming hydrates underlay the entire plume footprint, the maximum diffusion path length is expected to be less than 15 m, depths too shallow to stabilize pure methane hydrates under Mars geothermal and lithostatic conditions at low to mid latitudes. Therefore, pure methane hydrates confined within permafrost could not produce methane surface fluxes of the magnitude observed near the equator. However, the addition of 10% H₂S, a secondary gas commonly associated with methane production on Earth, expands the hydrate stability field, with clathrates expected within 10 m of the surface at the equator and at depths less than 1 m at higher latitudes. This indicates that H₂S would also be expected to be released as well as methane if the plumes have a confined hydrate reservoir source.  相似文献   

A multiwavelength infrared study of NGC 891     

C. H. Whaley  J. A. Irwin  S. C. Madden  F. Galliano  G. J. Bendo 《Monthly notices of the Royal Astronomical Society》2009,395(1):97-113

We present a multiwavlength infrared (IR) study of the nearby, edge-on, spiral galaxy NGC 891. We have examined 20 independent, spatially resolved IR images of this galaxy, 14 of which are newly reduced and/or previously unpublished images. These images span a wavelength regime from  λ 1.2 μ  m in which the emission is dominated by cool stars, through the mid-IR, in which emission is dominated by polycyclic aromatic hydrocarbons (PAHs), to λ 850 μm, in which emission is dominated by cold dust in thermal equilibrium with the radiation field. The changing morphology of the galaxy with wavelength illustrates the changing dominant components. We detect extraplanar dust emission in this galaxy, consistent with previously published results, but now show that PAH emission is also in the halo, to a vertical distance of   z ≥ 2.5 kpc  . We compare the vertical extents of various components and find that the PAHs (from λ 7.7 and 8 μm data) and warm dust (λ 24 μm) extend to smaller z heights than the cool dust (λ 450 μm). For six locations in the galaxy for which the signal-to-noise ratio was sufficient, we present spectral energy distributions (SEDs) of the IR emission, including two in the halo – the first time a halo SED in an external galaxy has been presented. We have modelled these SEDs and find that the PAH fraction, f _PAH, is similar to Galactic values (within a factor of 2), with the lowest value at the galaxy's centre, consistent with independent results of other galaxies. In the halo environment, the fraction of dust exposed to a colder radiation field, f _cold, is of the order of unity, consistent with an environment in which there is no star formation. The source of excitation is likely from photons escaping from the disc.  相似文献