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151.
Geological mapping, petrography, geochemistry, and isotope studies enable the division of the Pelotas Batholith into six granitic suites: Pinheiro Machado (PMS), Erval (ES), Viamão (VS), Encruzilhada do Sul (ESS), Cordilheira (CS), and Dom Feliciano (DFS). The rocks of the PMS show a large compositional range (granite through granodiorite to tonalite), and the suite is considered pre- to syncollisional. Other suites show restricted compositional variations (granite to granodiorite) and are late to postcollisional. In general, the suites are metaluminous to slightly peraluminous (PMS, ES, and VS) or peraluminous (CS) or have alkaline tendencies (ESS and DFS). The magmatic evolution corresponds to high-K calc-alkaline to alkaline magmatism. The suites are enriched in K, Rb, and REE compared with rocks of typical calc-alkaline series. Initial 87Sr/86Sr ratios vary from 0.705 to 0.716, except in the CS, where they attain values of 0.732–0.740. Sm–Nd TDM model ages vary between 0.98 and 2.0 Ga, with initial εNd values ranging from −0.3 to −10. U–Pb zircon dates of samples from PMS, VS, and ESS suggest an age between 0.63 and 0.59 Ga for magmatism. Rb–Sr dates of samples of alkaline granites from DFS present ages between 0.57 and 0.55 Ga. The main tectonic controls of the magmatism of the Pelotas Batholith are high-dip sinistral shear zones.  相似文献   
152.
Isotope data and trace elements concentrations are presented for volcanic and plutonic rocks from the Livingston, Greenwich, Robert, King George and Ardley islands (South Shetland arc, Antarctica). These islands were formed during subduction of the Phoenix Plate under the Antarctica Plate from Cretaceous to Tertiary. Isotopically (87Sr/86Sr)o ratios vary from 0.7033 to 0.7046 and (143Nd/144Nd)o ratios from 0.5127 to 0.5129. εNd values vary from +2.71 to +7.30 that indicate asthenospheric mantle source for the analysed samples. 208Pb/204Pb ratios vary from 38.12 to 38.70, 207Pb/204Pb ratios are between 15.49 and 15.68, and 206Pb/204Pb from 18.28 to 18.81. The South Shetland rocks are thought to be derived from a depleted MORB mantle source (DMM) modified by mixtures of two enriched mantle components such as slab-derived melts and/or fluids and small fractions of oceanic sediment (EM I and EM II). The isotopic compositions of the subduction component can be explained by mixing between at least 4 wt.% of sediment and 96 wt.% of melts and/or fluids derived from altered MORB.  相似文献   
153.
The ca. 790–600 Ma Rio Negro Complex (RNC) of the Ribeira belt (Brazil) consists of a plutonic portion of a magmatic arc built by the E-vergent subduction of the ESE border of the São Francisco paleoplate during the amalgamation of Western Gondwana.The plutonic series comprises low- to medium-K granitoids (ca. 790–620 Ma) and high-K granitoids and shoshonite rocks (ca. 610–605). The age span of 185 m.y. is suggestive of a long history of arc-related magmatism, continuously or not in time. The Nd isotopic signatures of the RNC consist of εNd(t) ratios from ? 3 to + 5 for the medium-K series shoshonite series and from ? 14 to ? 3 for the younger high-K group. This time-dependent trend of Nd isotopes is indicative of progressive maturity of the arc over time. The same evolution is indicated by Sr data, as the medium-K rocks have 87Sr/86Sr initial ratios < 0.705 while the high-K rocks yield values between 0.705 and 0.710. The predominance of intermediate rocks over mafic ones suggests an initial intra-oceanic to transitional stage, possibly developed in a distal portion of a passive margin, such as the Japanese arc, evolving to a more developed, differentiated felsic rock associations.The role of transform fault zones, such as the Luanda shear zone, is emphasized in order to explain the consumption of a wide oceanic plate in the inner portion of Western Gondwana.  相似文献   
154.
A sediment core from Guanabara Bay (Brazil) was analyzed for 210Pb dating, grain size, total organic carbon (TOC) and total nitrogen, carbon stable isotope ratio (δ13C), nitrogen stable isotope ratio (δ15N) and the metals Fe, Mn, Ni, Co, Cu, Pb, V and Zn, to assess the influence of land use changes on the aquatic system in a region for which large industrial and urban development is expected in the next few decades. To obtain baseline data for improving the monitoring of the expected increase in anthropogenic impacts from surrounding drainage basins, a multivariate analysis of data from different sediment layers was carried out to evaluate the dated sediment record. The geochemical data suggested three different sedimentary phases along the last 200 years. Before the 1880s, the highest clay and TOC contents were observed, where the C/N ratios and the δ13C values suggested a mixture of algal and terrestrial organic matter and the lowest concentrations of Co, Cu, Pb, V and Zn, for which background levels were estimated (4.6, 2.7, 14.9, 24.3 and 70.2 mg kg−1, respectively). From the 1880s to the 1950s, the metal concentrations and sand particles increased, but no change in organic matter quality was observed, reflecting a period of land use change, still without significant sewage input. After the 1950s, the sedimentation rate increased from 0.42 to 0.77 cm year−1 and increasing urban sewage input was evidenced by lower C/N ratios, higher δ15N, decrease of Fe and Mn concentrations and increased fluxes of metals and TOC, which showed a good relationship with population growth data.  相似文献   
155.
156.
Nitrate removal from water has been accomplished by heterotrophic biofilms using organic carbon as a source of reducing power. To overcome the natural limitation in organic carbon in water, a poly-ε-caprolactone based biofilm carrier that serves simultaneously as a biofilm carrier and as a source of organic carbon was developed and tested in the present work. The feasibility of the new biofilm carrier for nitrate removal from water was evaluated in a packed bed reactor. The combination of size and structure provided a carrier element having high surface area and void volume, 1,170 m2/m3 and 67 %, respectively. A maximum denitrification rate of 4.4 mg N–NO3 ?/(L.h) (9.2 mg N–NO3 ?/(m2.h)) was achieved in the packed bed reactor at 20 °C and pH 7.0. Main advantages of the biofilm carrier developed in the present work are its mechanical stability in water even after biofilm formation and controlled release of organic carbon by enzymatic reactions. The proposed biotechnology to remove nitrate from groundwater is robust and easy to operate.  相似文献   
157.
The uncertainty of some commonly used spectral wave parameters resulting from the spectral estimation procedure is assessed. It is observed that the methods of spectral estimation produce a significant uncertainty for all parameters examined, but this is of considerable importance only for the peak period, which is one of the most important parameters to model the wave climate.  相似文献   
158.
This paper describes a study conducted by the National Laboratory for Civil Engineering of Portugal (LNEC), in cooperation with the Defense University Center at the Spanish Naval Academy and “La Sapienza,” University of Rome, to assess the health and safety conditions of the Noble Hall floor in the São Carlos National Theater (Lisbon, Portugal). In a multidisciplinary approach, extensive fieldwork was carried out. The survey included the location and characterization of beams in the various areas of the floor by using two ground penetrating radar (GPR) systems equipped with two different ground- or air-coupled antennas, local inspection openings to visually assess the geometry, timber species and conservation state of structural members, and an assessment of the conservation state of the timber beam ends using drilling equipment. All the tests performed and the results obtained are presented. The potential of using non-destructive tests for the inspection of timber cultural heritage structures, particularly GPR, is discussed, and some practical recommendations are made.  相似文献   
159.
The combined effects of urbanization and extreme climatic events were examined on the ghost crab Ocypode quadrata, a well‐recognized ecological indicator in sandy beaches. The effect of storm waves was assessed before and after these climate events in beaches with different levels of urbanization in the coast of Brazil, Tropical Atlantic Ocean. The number of burrows was used as a metric for the population size of O. quadrata and the number of humans along the beaches as a proxy for the urbanization level. Significant differences were recorded in this species’ population density according to the human pressure. Our core modelling approach showed that the number of O. quadrata burrows was lower after storm waves in urbanized zones, compared to non‐urbanized ones. The interaction between storm waves and urbanization impacted the number of O. quadrata burrows negatively, and suggest that species’ populations are more vulnerable to the combined effects of extreme climatic events and urbanization. Extreme events are predicted to increase in frequency in the next few decades, and may modify or impair ecosystem functioning in sandy beaches by reducing populations of the O. quadrata, an important beach scavenger, which markedly contribute to the flux of energy in coastal trophic webs.  相似文献   
160.
Distribution of wave crests in a non-Gaussian sea   总被引:2,自引:0,他引:2  
The sea elevation at a fixed point is modelled as a quadratic form of a vector valued Gaussian process with arbitrary mean. With this model, saddlepoint methods are used to approximate the mean upcrossing intensity with which the sea level crosses upwards at a certain height. This estimated intensity is further used to determine the probability distribution of wave crests. The use of saddlepoint technique is particularly important here because it can approximate the crest distribution without the need to perform simulations or use fitted distributions. Several numerical examples are given, including two with measured data. In the cases of real data, the results obtained with the saddlepoint technique are also compared with the results obtained with well known methods commonly used in the industry.  相似文献   
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