A Mini‐Review of E‐Waste Management in Brazil: Perspectives and Challenges     

Jos Francisco de Oliveira Neto  Maisa Mendona Silva  Simone Machado Santos 《洁净——土壤、空气、水》2019,47(9)

The accelerated production and replacement of new electrical and electronic equipment demonstrates a tendency for the proportional increase in the generation of e‐waste. Developing countries experience similar social and environmental consequences from this trend, which compounds the other challenges associated with the already poor solid waste management in these regions. Moreover, the dangerous composition of some e‐waste amplifies the problems related to managing these materials. This mini‐review presents a brief overview of e‐waste management in Brazil, including technical aspects, scientific studies, and the challenges ahead. With the Brazilian National Policy of Solid Waste already in place, technical and scientific studies endorse measures that range from incorporating the informal recycling sector into the e‐waste management sector to encouraging the expansion of the recycling industry. All such actions, combined with an intensified commitment of electronic equipment manufacturers to reverse logistics, can improve e‐waste management in Brazil.  相似文献   

500 Years of rainfall variability and extreme hydrological events in southeastern Spain drylands     

M.J. Machado  G. Benito  M. Barriendos  F.S. Rodrigo 《Journal of Arid Environments》2011,75(12):1244-1253

The semiarid SE fringe of the Iberian Peninsula is considered one of the most sensitive to extreme floods and droughts in the western Mediterranean area. The controlling climatic mechanisms are nevertheless difficult to predict and model. A combined documentary-sedimentary-instrumental 500 years comprehensive register of climatic data (rainfall and flooding) was collated for analysing the decadal to centennial scale hydrological response. Wet years are closely linked to the presence of autumn (SON) positive anomalies (e.g. early 18th century). However, continuous, decadal wet periods seem to correspond in time to both autumn and spring (MAM) positive rainfall anomaly years (e.g. 1570/90, 1830/40, 1870/1900). High frequencies of large floods were registered during the late Medieval Warm Period (AD 950–1200), and during some decades of the Little Ice Age with an average of 0.22 floods/year (1440–1490, 1520–1570, 1600–1740, 1770–1800, 1820–1840, 1870–1900), but flood frequency decreased in the 20th Century (1945–1973; 0.14 floods/year). During wet phases (e.g. late 19th century), large floods occurred during all seasons, whereas a predominantly autumn extreme flooding (>70%) is linked to a rainfall patterns with higher inter-annual variability (e.g. 1945–1973). The recurrence of dry phases is higher since early 17th century, and the frequency of continuous wetter phases lower than the ones with marked annual variability. This results in a trend with less frequent high magnitude catastrophic floods. This study confirms a shift from autumn rainfall maxima towards winter since the early 1990's. The tendency towards longer dry periods and increased inter-annual variability (with 1–3 years maximum wet spells) and a changing seasonal rainfall distribution are thought to be key in modelling projections for this specific arid Mediterranean region.  相似文献   

Distributions of total,inorganic and organic phosphorus in surface and recent sediments of the sub-tropical and semi-pristine Guaratuba Bay estuary,SE Brazil     

Luiz Carlos Cotovicz Junior  Eunice da Costa Machado  Nilva Brandini  Rafaela Cristine Zem  Bastiaan Adriaan Knoppers 《Environmental Earth Sciences》2014,72(2):373-386

This study addresses the distribution of total phosphorus (TP) and its inorganic (IP) and organic (OP) fractions, grain-size and organic matter of surface and recent sediments, coupled to the behavior of total and dissolved inorganic phosphorus (TP and DIP) of the water column, of the semi-pristine Guaratuba Bay estuary, SE Brazil. Surface sediment samples were taken at 43 sites spread along the estuarine gradient and recent sediments from 3 short (35 cm long) cores from the upper, central and lower portions of the estuary, respectively. Highest TP and IP concentrations of surface sediments were detected within the upper sector and the transition zone between the upper and central sectors, all characterized by fine sediments, low salinities and water depths. In contrast, the lower sector and its narrow and deep tidal channel, subject to more intense tidal forcing, exhibited a higher fraction of sandy sediments with lower TP, IP and OP contents. In spite of the spatial variability in sediment grain size, IP corresponded to the major fraction of TP in all estuarine sectors and both TP and IP correlated significantly with the fine sedimentary (silt + clay) grain-size fraction. The fine surface sediments acted as a trap for IP at the fresh water–low salinity interface, which also corresponded to the region of a DIP sink in surface waters. In general, the short sediment cores showed that TP and IP contents increased from 15 cm depths to the top layer. Published sedimentation rates from additional cores taken at the sites of the short cores of this study, implied that depositional alterations of TP and IP increased during the early 1970s, which corresponded to the onset of anthropogenic disturbances from crop plantations in the lowland plains of the river end-member and urbanization at the estuary’s mouth and along the adjacent coast.  相似文献   

Interactive flare sites within an active region complex     

G. Poletto  G. A. Gary  M. E. Machado 《Solar physics》1993,144(1):113-140

The problem of physical relationships between different active regions has been dealt with only rarely and mainly in connection with flares. How sympathetic activity can be triggered between distant regions is therefore, so far, largely unknown. Soft X-ray images of large-scale coronal structures connecting different active regions were obtained by Skylab nearly 20 years ago, while SMM, more recently, did not provide any clear evidence for this kind of loop. As a consequence, we do not know how common these features are nor how they form nor whether they represent the only means by which distant active regions may be linked. In the latter case, however, interconnecting loops should be detected by analyzing the interaction between different active regions. We examine here a set of images of an active region complex, acquired on June 24-25, 1980, by the Hard X-ray Imaging Spectrometer on SMM, with the purpose of establishing whether there was any interplay between the frequent activity observed at different sites in the activity center and, in such a case, how the interaction was established. By analyzing both quiet and active orbits we show that, as a rule, activity originating in one region triggers the other region's activity. However, we find little unambiguous evidence for the presence of large-scale interconnecting loops. A comparison of X-ray images with magnetic field observations suggested that we interpret the active region behavior in terms of the interaction between different loop systems, in a scenario quite analogous to the interacting bipole representation of individual flares. We conclude that active region interplay provides an easily observable case to study the time-dependent topology and the mechanisms for the spreading of activity in transient events over all energy scales.  相似文献   

Flare model chromospheres and photospheres     

Marcos E. Machado  Jeffrey L. Linsky 《Solar physics》1975,42(2):395-420

Homogeneous plane-parallel model atmospheres for solar flares have been constructed to approximately simulate observations of flares. The wings of the Ca II lines have been used to derive flare upper photosphere models, which indicate temperature increases of ～100 K over the temperature distribution in the pre-existing facula at a height of 300 km above τ₅₀₀₀ = 1. In the case of flares covering sunspots the temperature rise seems to occur much higher in the atmosphere. We solve the transfer and statistical equilibrium equations for a three-level hydrogen atom and a five-level calcium atom in order to obtain the chromospheric flare models. The general properties of flares, including n _e, N ₂, linear thickness, and Lyman continuum intensity are approximately reproduced. We find that with increasing flare importance the height of the upper chromosphere and transition region occur lower in the solar atmosphere, accounting for the factor of 60–600 increase in pressure in these regions relative to the quiet Sun. The Ca II line profiles agree with observations only by assuming a macro-velocity distribution that increases with height. Also the chromospheric parts of flares appear to be highly inhomogeneous. We show that shock and particle heated flare models do not agree with the observations and propose a thermal response model for flares. In particular, it appears that heating in the photosphere is an essential aspect of flares.  相似文献   

Relative Response of Biological and Non-Biological Monitors in a Coastal Environment     

A. Machado  M. C. Freitas  A. M. G. Pacheco 《Journal of Atmospheric Chemistry》2004,49(1-3):161-173

A field study was carried out in the spring and summer of 2003 (2 months each), to assess the efficiency of alternative exposure modes of biological monitors – lichen biomass and tree-bark biomass – together with prospective, non-biological monitors – cellulose acetate and Chelex-100 resin – versus conventional transplants of the same species. After exposure to the marine atmosphere of Sines (SW Portugal), saline elements (Cl, Na, K, Mg) contents were determined in all samples by instrumental neutron activation analysis (INAA). Manganese was used as the crustal reference for data normalisation. As a whole, the results pointed to a consistent elemental accumulation regardless of the season (spring, summer), and to some fair reproducibility of data. There were good correlations between Cl and Na in terms of both raw and normalised data, for either the biomonitors or the cellulose acetate. Elemental ratios generally agreed with the average relative composition of bulk seawater. The degree of association between Cl and Na appeared rather unaffected by the normalisation procedure, which suggests that (i) both elements most likely had an almost exclusive marine origin; and (ii) accounting for crustal inputs via Mn did not bias the results. Other sources than the sea-spray might contribute to the Mg levels, though, as only Mn-normalised data showed intrinsic (correlation) and extrinsic (ratio) consistency. The performance of the Chelex-100 resin was rather disappointing when compared to the other monitors.  相似文献   

Marine sediment contamination of an industrial site at Port of Bagnoli, Gulf of Naples, Southern Italy   总被引：1，自引：0，他引：1  

Romano E  Ausili A  Zharova N  Celia Magno M  Pavoni B  Gabellini M 《Marine pollution bulletin》2004,49(5-6):487-495

For almost one century an important steel plant has been active at the Bagnoli industrial area (Naples, Southern Italy). The environmental survey of near shore and offshore sediments has been carried out as fundamental part of a clean up project. The characteristics of the area, supposed type of pollution, national and international protocols in force were taken into consideration in designing sampling schemes and selecting analytical parameters. For this work, sediment grain size, PAHs, PCBs, trace elements, total hydrocarbons and organic matter were considered. Factor analysis evidenced two main types of pollution in the proximity of the industrial plant, both probably attributable to the activity of the industrial site. The first one, due to Cd, Pb, Zn and Mn seems determined by localised activities at the southern part of the plant. The second one, due to Fe and Mn, appears directly linked to the whole contaminated area.  相似文献   

Evidence for the photospheric origin of the flare optical continuum     

Marcos E. Machado 《Solar physics》1971,17(2):389-391

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Environmental influences on the demersal fish assemblages in the Sepetiba Bay, Brazil   总被引：1，自引：0，他引：1  

Francisco Gerson Araújo  Márcia Cristina Costa de Azevedo  Márico de Araújo Silva  André Luiz Machado Pessanha  Iracema David Gomes  Antônio Gomes da Cruz-Filho 《Estuaries and Coasts》2002,25(3):441-450

The structure of the demersal fish assemblage in Sepetiba Bay, southeast Brazil (22°54′–23°04′S, 43°34′–44°10′W) was described and related to environmental variables. A 3-yr long trawl survey (from July 1993 to June 1996) was conducted using a stratified random sampling strategy at 158 stations. One hundred and seven species of fishes in 80 genera and 44 families were identified. Gerreidae and Ariidae made up 30.5% and 28.6%, and 19.8% and 28.1% of the total number and weight, respectively. Sciaenidae, Engraulididae, Sparidae, and Carangidae were other prominent families. Three assemblages existed in the bay: one inhabited shallow, less saline and less transparent water in the inner zone (depth <5 m, transparency <2 m, salinity <30 psu, and slightly higher temperature); another in the outer zone with the opposite situation (depth >10 m, transparency >3 m, salinity >30 psu, and slightly lower temperature); and a third assemblage in the middle zone likely to prefer average values or show no clear preferences. Most species decreased in abundance over the 3-yr period of study. No seasonal change was detected in the assemblage structure, but many species were rare, indicating high spatial and temporal patchiness. Canonical correlation analyses were used to describe and compare the fish assemblages in the three different habitats. The outer zone had the greatest number of species recorded, lowest abundance, highest diversity and evenness, and was comprised mainly byCynossion leiarchus, Prionotus punctatus, Anchoa tricolor, Haemulon steindachneri, Diplectrum radiale, Etropus crossotus, andSphoeroides greeleyi; the inner zone had the lowest number of species recorded but the greatest number of species per sample, highest abundance, lowest diversity and evenness, being comprised mainly byDiapterus rhombeus, Genidens genidens, Cathrops spixii, Chloroschombrus chrysurus, Sciadeichthyes luniscutis, Cetengraulis edentulus, andArchorsargus rhomboidalis; while the third group had the lowest number of species per sample, being comprised by species widely distributed asGerres aprion, G. genidens, Gerres gula, andMicropogonias furnieri. Depth, followed by transparency and salinity, were the primary factors influencing assemblage distribution.  相似文献   

SERMIN1 and VIDAC18: Two Proposed Reference Materials for Rare Earth Element Determination in Groundwater     

Rui Santos  M.J. Canto Machado  Leopoldo Cortez 《Geostandards and Geoanalytical Research》2008,32(2):181-191

In this work, homogeneous samples of two Portuguese mineral waters, SERMIN1 and VIDAC18, have been analysed for their REE contents. The participation of twenty international laboratories made it possible to evaluate the data by robust statistical procedures. Eighty-one percent of the participants used ICP-QMS for REE determination in these two candidate reference materials. Assigned values are reported for SERMIN1, covering the fourteen naturally occurring lanthanides (La-Lu). For VIDAC18, assigned values are presented only for ten REE, since accurate assigned values for La, Ce, Tb and Eu need further analytical work to improve data quality.  相似文献