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991.
Corinne Casiot Marc Leblanc Odile Bruneel Jean-Christian Personné Kouadio Koffi Françoise Elbaz-Poulichet 《Aquatic Geochemistry》2003,9(4):273-290
The distribution of arsenic (As(III), As(V)) and iron (Fe(II), Fe(III)) species was monitored during 1 year in a borehole drilled in the Carnoulès tailings impoundment which contains As-rich pyrite. The concentrations of total As and Fe in subsurface waters exhibited strong variations over one year, which were controlled by dissolved oxygen concentrations. At high oxygen levels, extremely high As (up to 162 mM) and Fe (up to 364 mM) concentrations were reached in the borehole, with the oxidised species predominant. As and Fe concentrations decreased 10-fold under oxygen-deficient conditions, as a result of pH increase and subsequent precipitation of As(V) and Fe(III). From drill core sections, it appeared that at low dissolved oxygen levels, As(III) was primarily released into water by the oxidation of As-rich pyrite in the unsaturated zone. Subsequent As and Fe precipitation was promoted during transport to the saturated zone; this reaction resulted in As enrichments in the sediment below the water table compared to the original content in pyrite, together with the formation of As-rich (up to 35 wt% As) ferruginous material in the unsaturated zone. High amounts of As(V) were released from these secondary phases during leaching experiments with oxygenated acid sulfate-rich waters; this process is believed to contribute to As(V) enrichment in the subsurface waters of the Carnoulès tailings during periods of high dissolved oxygen level. 相似文献
992.
Climatic significance of seasonal trace element and stable isotope variations in a modern freshwater tufa 总被引:1,自引:0,他引:1
Christian Ihlenfeld Marc D. Norman Russell N. Drysdale John Webb 《Geochimica et cosmochimica acta》2003,67(13):2341-2357
We present a continuous ∼14-yr-long (1985 to 1999) high-resolution record of trace element (Mg, Sr, Ba, U) and stable isotope (δ13C, δ18O) variations in a modern freshwater tufa from northwestern Queensland, Australia. By utilizing the temperature dependence of the δ18O signal, an accurate chronology was developed for the sampled profile, which allowed a comparison of the chemical records with hydrological and meteorological observations. As a consequence, it was possible to constrain the relevant geochemical processes relating climate variables, such as temperature and precipitation, to their chemical proxies in the tufa record. Temperatures calculated from the Mg concentrations of the tufa samples provide close approximations of average annual water temperature variations. Furthermore, we demonstrate that temporal changes in (Mg/Ca)water can be estimated using an empirically derived equation relating (Mg/Ca)water to the (Sr/Ba) ratio measured in the tufa samples. By means of this relationship, it is theoretically possible to determine the (Mg/Ca) ratio of paleowaters, and hence to derive reliable estimates of former water temperatures from the Mg concentrations of fossil tufas from the study area. Sympathetic variations in Sr, Ba, and δ13C along the sampled profile record changes in water chemistry, which are most probably caused by variable amounts of calcite precipitation within the vadose zone of the karst aquifer. This process is thought to be markedly subdued whenever the amount of wet-season precipitation exceeds a given threshold. Accordingly, distinct minima in Sr, Ba, and δ13C are interpreted to reflect years with above-average rainfall. The pronounced seasonal and annual variability of the U concentration along the profile is thought to primarily record changes in the U flux from the soil to the water table. We suggest that during intensive rain events U is transported to the phreatic zone by complexing organic colloids, giving rise to conspicuous U maxima in the tufa after above-average wet seasons. This study demonstrates the potential of freshwater tufas to provide valuable information on seasonal temperature and rainfall variations. If tufa deposits turn out to be reasonably resistant to secondary processes, combined investigation of speleothems and tufas from the same area could become a promising approach in future research. While speleothems offer continuous records of long-term paleoenvironmental changes, tufas could provide high-resolution time windows into selected periods of the past. 相似文献
993.
Michael R. Savina Michael J. Pellin Igor V. Veryovkin Andrew M. Davis 《Geochimica et cosmochimica acta》2003,67(17):3215-3225
Isotopic analysis of heavy elements in individual stardust grains is important in testing and constraining theories of stellar nucleosynthesis. These analyses are challenging in that the grains are very small, the largest being perhaps a few microns in diameter, and contain only trace concentrations of heavy elements, generally on the order of ppm. In addition, isotopic analysis requires the suppression of isobaric interferences. We describe a unique instrument, based on resonant ionization mass spectrometry, that has successfully characterized such grains for the past several years, and report on some recent upgrades that significantly enhance the instrumental capabilities. The fundamental principles and operational details are discussed, along with illustrative results and plans for future modifications. 相似文献
994.
Michael R. Savina Andrew M. Davis C.Emil Tripa Michael J. Pellin Roy S. Lewis Roberto Gallino 《Geochimica et cosmochimica acta》2003,67(17):3201-3214
Barium isotopic compositions of single 2.3-5.3 μm presolar SiC grains from the Murchison meteorite were measured by resonant ionization mass spectrometry. Mainstream SiC grains are enriched in s-process barium and show a spread in isotopic composition from solar to dominantly s-process. In the relatively coarse grain size fraction analyzed, there are large grain-to-grain variations of barium isotopic composition. Comparison of single grain data with models of nucleosynthesis in asymptotic giant branch (AGB) stars indicates that the grains most likely come from low mass carbon-rich AGB stars (1.5 to 3 solar masses) of about solar metallicity and with approximately solar initial proportions of r- and s-process isotopes. Measurements of single grains imply a wide variety of neutron-to-seed ratios, in agreement with previous measurements of strontium, zirconium and molybdenum isotopic compositions of single presolar SiC grains. 相似文献
995.
996.
Integration of ground-penetrating radar and microgravimetric methods to map shallow caves 总被引:1,自引:0,他引:1
Ground-penetrating radar (GPR) and microgravimetric surveys have been conducted in the southern Jura mountains of western Switzerland in order to map subsurface karstic features. The study site, La Grande Rolaz cave, is an extensive system in which many portions have been mapped. By using small station spacing and careful processing for the geophysical data, and by modeling these data with topographic information from within the cave, accurate interpretations have been achieved.The constraints on the interpreted geologic models are better when combining the geophysical methods than when using only one of the methods, despite the general limitations of two-dimensional (2D) profiling. For example, microgravimetry can complement GPR methods for accurately delineating a shallow cave section approximately 10×10 m2 in size. Conversely, GPR methods can be complementary in determining cavity depths and in verifying the presence of off-line features and numerous areas of small cavities and fractures, which may be difficult to resolve in microgravimetric data. 相似文献
997.
I. P. Vaughan P. A. Davis A. E. Walsby 《Aquatic Sciences - Research Across Boundaries》2001,63(3):350-362
The relationship between photosynthesis and irradiance was investigated in a strain of the cyanobacterium Planktothrix rubescens isolated from Lake Zürich, using cultures grown on a 12:12-h light-dark cycle. From the photosynthesis-irradiance (P/I) curves, values of the light-affinity coefficient, f, and the maximum rate of photosynthesis, Pm, were determined: in different cultures f ranged from 0.02-0.08 7mol mg-1 h-1 (7mol m-2 s-1)-1 and Pm from 0.6-2.6 7mol mg-1 h-1 (rates of O2 production related to dry biomass). Comparisons made at different phases of the light-dark cycle in individual cultures showed that in the first hour of the light phase f rose by an average of 21 % and Pm by 7 %. In cultures that had been grown in many light-dark cycles, however, the rise occurred only if light was given at the beginning of the notional light phase; cultures kept in darkness showed no rise. It is concluded that the observed increases in f and Pm after dawn were in response to the exogenous irradiance rather than due to endogenous rhythms. These findings are discussed in relation to diel variations in the photosynthetic coefficients of natural populations of P. rubescens in Lake Zürich. 相似文献
998.
Detailed studies of seasonal patterns of karst processes are rare in remote regions with limited winter access. An important aspect of erosional and environmental processes is how these change over time, and how they relate to annual cycles of temperature, precipitation and runoff. Such measurements have consistently proved difficult in remote alpine areas, resulting in a paucity of continuous data from these environments. An automated data‐logger installation designed to perform under difficult conditions, including limited sunlight for solar recharge, heavy snowfall and disturbance by bears, has provided four years of data at a 2‐hour sampling interval of electrical conductivity (used to predict solute concentration), water level (used to predict discharge) and temperature, at the Marble Mountains karst resurgence, California, USA. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
999.
Marc D. Norman Vickie C. BennettGraham Ryder 《Earth and Planetary Science Letters》2002,202(2):217-228
Highly siderophile element compositions of lunar impact melt breccias provide a unique record of the asteroid population responsible for large cratering events in the inner Solar System. Melt breccias associated with the 3.89 Ga Serenitatis impact basin resolve at least two separate impact events. KREEP-rich melt breccias representing the Apollo 17 poikilitic suite are enriched in highly siderophile elements (3.6-15.8 ppb Ir) with CI-normalized patterns that are elevated in Re, Ru and Pd relative to Ir and Pt. The restricted range of lithophile element compositions combined with the coherent siderophile element signatures indicate formation of these breccias in a single impact event involving an EH chondrite asteroid, probably as melt sheet deposits from the Serenitatis Basin. One exceptional sample, a split from melt breccia 77035, has a distinctive lithophile element composition and a siderophile element signature more like that of ordinary chondrites, indicating a discrete impact event. The recognition of multiple impact events, and the clear signatures of specific types of meteoritic impactors in the Apollo 17 melt breccias, shows that the lunar crust was not comprehensively reworked by prior impacts from 3.9 to 4.5 Ga, an observation more consistent with a late cataclysm than a smoothly declining accretionary flux. Late accretion of enstatite chondrites during a 3.8-4.0 Ga cataclysm may have contributed to siderophile element heterogeneity on the Earth, but would not have made a significant contribution to the volatile budget of the Earth or oxidation of the terrestrial mantle. Siderophile element patterns of Apollo 17 poikilitic breccias become more fractionated with decreasing concentrations, trending away from known meteorite compositions to higher Re/Ir and Pd/Pt ratios. The compositions of these breccias may be explained by a two-stage impact melting process involving: (1) deep penetration of the Serenitatis impactor into meteorite-free lower crust, followed by (2) incorporation of upper crustal lithologies moderately contaminated by prior meteoritic infall into the melt sheet. Trends to higher Re/Ir with decreasing siderophile element concentrations may indicate an endogenous lunar crustal component, or a non-chondritic late accretionary veneer in the pre-Serenitatis upper crust. 相似文献
1000.
Sarah Brown Paul Bierman Andrea Lini P. Thompson Davis John Southon 《Journal of Paleolimnology》2002,28(2):219-236
Four sediment cores and twenty-five 14C ages from Ritterbush Pond in northern Vermont provide a detailed and continuous temporal record of Holocene lake and watershed dynamics. Using visual logs, carbon content, magnetic susceptibility, stable isotope signatures, and X-radiography, all measured at 1-cm scale, we identify and date discrete layers of terrestrially-derived sediment in the organic-rich, lacustrine gyttja. These inorganic layers range in thickness from <1 mm to >10 cm and range in grain size and sorting from homogeneous silt to graded sand. AMS radiocarbon ages both from macrofossils within the thickest layers, and gyttja bracketing these layers, provide the basis for correlation among the cores, the dating of 52 basin-wide sedimentation events, and the development of a detailed sedimentation chronology for the Holocene.Physical, chemical, and isotopic analyses suggest the inorganic layers are terrestrially derived and result from hydrologic events large enough to erode and transport sediment from the watershed into the pond. The temporal and spatial distribution of the inorganic layers suggests changing basin-wide sedimentation and thus erosion dynamics since deglaciation over 12,000 years ago. Specifically, for intervals lasting 400 to 1000 years, during the early (>8600 cal yBP), middle (6400 to 6800 cal yBP) and late Holocene (1800 to 2600 cal yBP), the Ritterbush Pond watershed eroded more rapidly than at other times and terrestrially derived material poured into the pond. Analysis of Ritterbush Pond sediments demonstrates the potential for North American lakes to preserve a record of drainage basin dynamics. 相似文献