Travel time controls the magnitude of nitrate discharge in groundwater bypassing the riparian zone to a stream on Virginia's coastal plain     

Samuel A. Flewelling  Janet S. Herman  George M. Hornberger  Aaron L. Mills 《水文研究》2012,26(8):1242-1253

Groundwater that bypasses the riparian zone by travelling along deep flow paths may deliver high concentrations of fertilizer‐derived NO₃^? to streams, or it may be impacted by the NO₃^? removal process of denitrification in streambed sediments. In a study of a small agricultural catchment on the Atlantic coastal plain of Virginia's eastern shore, we used seepage meters deployed in the streambed to measure specific discharge of groundwater and its solute concentrations for various locations and dates. We used values of Cl^? concentration to discriminate between bypass water recharged distal to the stream and that contained high NO₃^? but low Cl^? concentrations and riparian‐influenced water recharged proximal to the stream that contained low NO₃^? and high Cl^? concentrations. The travel time required for bypass water to transit the 30‐cm‐thick, microbially active denitrifying zone in the streambed determined the extent of NO₃^? removal, and hydraulic conductivity determined travel time through the streambed sediments. At all travel times greater than 2 days, NO₃^? removal was virtually complete. Comparison of the timescales for reaction and transport through the streambed sediments in this system confirmed that the predominant control on nitrate flux was travel time rather than denitrification rate coefficients. We conclude that extensive denitrification can occur in groundwater that bypasses the riparian zone, but a residence time in biologically active streambed sediments sufficient to remove a large fraction of the NO₃^? is only achieved in relatively low‐conductivity porous media. Instead of viewing them as separate, the streambed and riparian zone should be considered an integrated NO₃^? removal unit. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

On the transfer of stratospheric ozone into the troposphere near the north pole     

Samuel J. Oltmans  Wolfgang E. Raatz  Walter D. Komhyr 《Journal of Atmospheric Chemistry》1989,9(1-3):245-253

A series of nearly daily ozone vertical profiles obtained at station T-3 on Fletcher's Ice Island (85°N, 90°W) during the period January-March 1971 shows several significant ozone intrusions into the troposphere. These intrusions are not only associated with enhanced ozone amounts in the stratosphere but also require tropopause folding events to transport ozone into the troposphere. These folds in the Arctic tropopause appear to be capable of contributing significantly to the ozone budget of the Arctic troposphere during the late winter and spring seasons. The importance of tropopause folding for bringing ozone into the troposphere seen in the daily ozone profiles confirms the results found in the Arctic Gas and Aerosol Sampling Program aircraft flights.  相似文献   

Mise en évidence expérimentale des facteurs nutritifs limitants de la production du micro-nanoplancton et de l'ultraplancton dans une eau côtière de la Méditerranée orientale (Haïfa,Israël)     

D. J. Bonin  M. C. Bonin  T. Berman 《Aquatic Sciences - Research Across Boundaries》1989,51(2):129-152

Enrichment experiments were carried out on seawater samples from the Israeli coast to characterise the nature of nutrient limitation. Phytoplankton chlorophyll, ATP, PC, PN, PP and bicarbonate and orthophosphate uptake rates indicate that phosphorus limitation is more extreme than that of nitrogen. A large increase in total nitrogen observed with P enrichment suggests that a substantial nitrogen fixation is mediated by picocyanobacteria in this kind of oligotrophic mediterranean waters.

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Comparison Between Pump and Treat, Biorestoration, and Biorestoration/ Pump and Treat Combined: Lessons from Computer Modeling     

Samuel A. Marquis Jr.  Dennis Dineen 《Ground Water Monitoring & Remediation》1994,14(2):105-119

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An intercomparison of seawater filtration procedures     

J.M. Bewers  P.A. Yeats  S. Westerlund  B. Magnusson  D. Schmidt  H. Zehle  S.S. Berman  A. Mykytiuk  J.C. Duinker  R.F. Nolting  R.G. Smith  H.L. Windom 《Marine pollution bulletin》1985,16(7):277-281

Filtration systems, used for the preparation of coastal seawater samples for trace analysis, have been intercompared to determine the extent of contamination arising during the filtration process. The results show that all the systems intercompared are able to provide uncontaminated filtrates for copper, nickel, cobalt and manganese and, with two exceptions, for cadmium and iron, at levels that would be encountered in uncontaminated coastal waters.  相似文献   

Carbon,hydrogen and nitrogen isotopes in solvent-extractable organic matter from carbonaceous chondrites     

Richard H Becker  Samuel Epstein 《Geochimica et cosmochimica acta》1982,46(1):97-103

Solvent extractions were done on the carbonaceous chondrites Murray, Murchison, Orgueil and Renazzo, using CCl₄ and CH₃OH. Between 2 and 10% of the total carbon in these meteorites is extractable by ordinary techniques, most of it in CH₃OH. After demineralization with HF, perhaps as much as 30% of the total carbon in Murray may be extractable with CH₃OH. The extracts from Renazzo have isotopic ratios which suggest that they are mainly terrestrial organic matter, with lesser contributions from indigenous organics. The CH₃OH-soluble organic matter from Murchison and both untreated and HF-treated Murray has δ¹³C values of about +5 to + 10%. and δ¹⁵N values of about +90 to +100%., both of which are significantly higher than the bulk meteorite values. The Orgueil CH₃OH-extract also has a δ¹⁵N value well above the value in residual organic matter. Values for δD of +300 to +500%. are found for the CH₃OH-soluble organic matter. The combined data for C, H and N isotopes makes it highly unlikely that the CH₃OH-soluble components are derivable from, or simply related to, the insoluble organic polymer found in the same meteorites. A relationship is suggested between the event that formed hydrous minerals in CI1 and CM2 meteorites and the introduction of water-soluble (methanol-soluble) organic compounds. Organic matter soluble in CCl₄ has essentially no nitrogen, and δ³C and δD values are lower than for CH₃OH-soluble phases. Either there are large isotopic fractionations for carbon and hydrogen between different soluble organic phases, or the less polar components are partially of terrestrial origin.  相似文献   

Processes controlling precipitation of carbonate cement and dissolution of silica in reef and near-reef settings     

Samuel A. Epstein  Gerald M. Friedman 《Sedimentary Geology》1982,33(3):157-171

Carbonate cementation in the surface layer of reefs and beachrock eliminates porosity and partially replaces detrital quartz grains. The uptake and release of CO₂ by photosynthesis and respiration in reef communities cause a shift in the carbonate buffer system of seawater. Field studies and experimentation simulating the natural settings show minimum values of CO₂ (1.9 mmoles 1^?1) and HCO₃^? (2.4 meq 1^?1) in association with maximum values of pH (9.8) and O₂ (> 100% oxygen saturation) in waters covering corals and algae prior to sunset. The converse is true for these variables prior to sunrise, when minimum values of pH (7.6) and O₂ (<66% oxygen saturation) occur with maximum values of CO₂ (2.7 mmoles 1^?1) and HCO₃^? (2.7 meq 1^?1). Experimental tanks containing plain seawater showed almost no diurnal variability in pH (a constant 7.5–7.6) or O₂ (80–90% oxygen saturation) measurements. Seawater adjacent to reef biomass, with elevated pH and supersaturated with calcium carbonate, is periodically pumped into the underlying reef and beach sediments due to pressure-buildups between the reef framework or algal zones and open waters. Carbonate precipitation and quartz dissolution follow. As the system equilibrates, pH values progressively decrease.  相似文献   

Stable isotopes,proceedings of the fourth international conference: edited by H.-L. Schmidt,H. Forstel and K. Heinzinger,Elsevier, 1982, 775 p. $175     

Samuel M. Savin 《Geochimica et cosmochimica acta》1983,47(4):850-851

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The Collision Manifold of the Collinear One-Bumper Two-Body Problem     

Samuel R. Kaplan 《Celestial Mechanics and Dynamical Astronomy》2001,79(1):1-14

We present a special model which is a caricature of the collinear three-body problem. Near triple-collision behavior for the model is governed by the collision manifold. We study the bifurcations of the dynamics on this manifold as we vary the ratio of masses. Both analytic and numerical results are presented.This revised version was published online in October 2005 with corrections to the Cover Date.  相似文献   

Simulated precipitation response to SST forcing and potential predictability in the region of the South Atlantic convergence zone     

Marcelo Barreiro  Ping Chang  R. Saravanan 《Climate Dynamics》2005,24(1):105-114

The sensitivity of the precipitation response in the South Atlantic convergence zone (SACZ) to sea surface temperature (SST) anomaly is investigated by an inter-model comparison study of ensembles of multidecadal integrations of two atmospheric general circulation models (AGCMs)—version 1 of the NASA Seasonal-to-Interannual Prediction Project (NSIPP-1) model, and the NCAR community climate model (CCM3) version 3.6.6. Despite the different physical parameterizations, the two models consistently show an SST-forced signal located mainly over the oceanic portion of the SACZ. The signal has interannual-to-decadal timescales, and consists of a shift and strengthening of the SACZ toward anomalous warm waters. A potential predictability analysis reveals that the maximum predictable variance is about 50% of the total SACZ variance over the ocean, but the signal attenuates rapidly toward the South American continent. This result implies that the land portion of the SACZ is primarily dominated by the internal variability, thereby having a limited potential predictability at seasonal timescales.  相似文献