Composition and heterogeneity of anorthositic impact melt at Mistastin Lake crater, Labrador     

Cassandra L. Marion  Paul J. Sylvester 《Planetary and Space Science》2010,58(4):552-573

Anorthositic impact melt rocks, their target rocks (principally anorthosite, mangerite, granodiorite) and zircon clasts from the ∼36-Ma-old, 28-km-wide Mistastin Lake crater of northern Labrador (55°53′N; 63°18′W) have been examined in order to evaluate the scale and origin of compositional heterogeneities in impact melts produced in craters of moderate size. In particular we assess whether and, if so, how the initial composition of the impact melt was modified as it entrained mineral clasts derived from the underlying rocks over which it flowed when it moved away from the shock-induced, central melting zone. A secondary goal was to determine if zircon clasts in the impact melts are present in the proportions of their target rock sources and/or the substrate lithologies over which they flowed. Chemical compositions of bulk samples of 33 melt rocks and 14 target rocks were measured by XRF and SN-ICPMS. Matrix compositions of nine samples of impact melt rocks were determined by EPMA and LA-ICPMS. Zircon grains from four samples of target rock and zircon clasts from three samples of impact melt rock were measured for multi-element composition, U-Pb age and Hf-isotopic composition by LA-(MC)-ICPMS.The data reveal compositional heterogeneities in the impact melts on the scales of both bulk samples and matrices. Bulk samples can be divided into compositions with high and low concentrations of high-field-strength elements (HFSE; Ti, Zr, Nb) and Fe, Ba, Ce and Y. High HFSE-type melt rocks formed when impact melt entrained large quantities of clasts from mangerite, which is rich in HFSE. Matrix compositions of bulk samples do not show the HFSE distinction but are affected by the introduction of low-temperature melts from the clasts to form dispersed, micron-scale silica-rich heterogeneities.The best estimate of sources of the initial impact melt is ∼73% anorthosite, ∼7% mangerite and ∼20% granodiorite, based on least-squares modeling of major-element compositions of the matrices of thinner flows. Zircon derived from anorthosite can be distinguished from zircon from mangerite and granodiorite by higher Nb/Ta and Eu/Eu* ratios and more negative initial ε Hf values. Zircon clasts >40 mm in size in the impact melt rocks are dominantly or exclusively derived from mangerite and granodiorite rather than from anorthosite. Because anorthosite was the principal source of impact melt at Mistastin, zircon may be a poor provenance indicator for anorthosite contributions to impact melts, particularly where grains smaller than 40 microns are not analyzed.  相似文献   

Distribution and chronology of Pleistocene permafrost features in France: Database and first results     

Pascal Bertran  Eric Andrieux  Pierre Antoine  Sylvie Coutard  Laurent Deschodt  Philippe Gardère  Marion Hernandez  Claude Legentil  Arnaud Lenoble  Morgane Liard  Norbert Mercier  Olivier Moine  Luca Sitzia  Brigitte Van Vliet‐Lanoë 《Boreas: An International Journal of Quaternary Research》2014,43(3):699-711

Numerous periglacial features (polygons, nets, soil stripes, ice‐wedge pseudomorphs and sand‐wedge casts, involutions) have been recorded in France by examining bibliographical sources and aerial photographs. These data show that a large part of France was affected by permafrost during the Pleistocene and only the southern Aquitaine Basin and Languedoc seem to have been beyond its maximum extent. The first OSL ages obtained from the aeolian infill of wedge structures indicate that at least two phases of thermal contraction cracking occurred in southwestern France between ～25 and 36 ka. Chronostratigraphical data from loess in northern France indicate that these episodes correspond to the formation of ice‐wedge networks associated with tundra gleys. In the latter region, two additional permafrost episodes probably occurred during the Last Glacial, the older one corresponding to the end of Marine Isotope Stage (MIS) 4 around 60 ka and the more recent one to MIS 2 around 19–16 ka. Although stratigraphical data indicate that these episodes were relatively short (about one millennium), relict permafrost may have existed for longer periods in northern France.  相似文献   

High resolution U‐Pb ages of Ca‐phosphates in Apollo 14 breccias: Implications for the age of the Imbrium impact     

R. E. Merle  A. A. Nemchin  M. L. Grange  M. J. Whitehouse  R. T. Pidgeon 《Meteoritics & planetary science》2014,49(12):2241-2251

Previous age estimates of the Imbrium impact range from 3770 to 3920 Ma, with the latter being the most commonly accepted age of this basin‐forming event. The occurrence of Ca‐phosphates in Apollo 14 breccias, interpreted to represent ejecta formed by this impact, provides a new opportunity to date the Imbrium event as well as refining the impact history of the Moon. We present new precise U‐Pb analyses of Ca‐phosphates from impact breccia sample 14311 that are concordant and give a reliable weighted average age of 3938 ± 4 Ma (2σ). Comparison with previously published U‐Pb data on phosphate from Apollo 14 samples indicate that all ages are statistically similar and suggest phosphates could have been formed by the same impact at 3934 Ma ± 3 Ma (2σ). However, this age is older than the 3770 to 3920 Ma range determined for other samples and also interpreted as formed during the Imbrium impact. This suggests that several impacts occurred during a 20–30 Ma period around 3900 Ma and formed breccias sampled by the Apollo missions.  相似文献   

First alkaline magmatism during Iberia–Newfoundland rifting     

Marion Grange  Urs Schärer  Guy Cornen  Jacques Girardeau 《地学学报》2008,20(6):494-503

The age and origin of alkaline rocks emplaced into the sediments of the rift‐related continental Lusitanian basin were investigated to constrain earliest magmatic activity occurring prior to oceanic plate formation between Iberia and Newfoundland. The U–Pb titanite ages are 146.5 ± 1.6 (2σSTERR), 145.3 ± 1.4 and 142.3 ± 1.0 Ma, and initial Pb isotopic ratios of feldspars lie at 18.418–18.978 for ²⁰⁶Pb/²⁰⁴Pb, at 15.594–15.925 for ²⁰⁷Pb/²⁰⁴Pb and at 37.105–39.216 for ²⁰⁸Pb/²⁰⁴Pb. Initial ⁸⁷Sr/⁸⁶Sr ratios measured in the same feldspar fractions lie at 0.705409–0.706462. This episode of magmatic activity lasting for at least 4.2 ± 2.6 Myr most likely marks a phase of maximum lithospheric thinning during which zones of weakness were created to allow deep magmas to reach the surface. Such zones are preferentially re‐activated Palaeozoic faults of the Iberian plate. The isotope data suggest that the dominant volume of alkaline magmas was generated by partial melting of the metasomatized subcontinental Iberian mantle.  相似文献   

The influence of climate,hydrology and permafrost on Holocene peat accumulation at 3500 m on the eastern Qinghai–Tibetan Plateau     

David J. Large  Baruch Spiro  Marion Ferrat  Michaela Shopland  Malin Kylander  Kerry Gallagher  Xiangdong Li  Chengde Shen  Goran Possnert  Gan Zhang  W. George Darling  Dominik Weiss 《Quaternary Science Reviews》2009,28(27-28):3303-3314

Peatland of the eastern Qinghai–Tibetan Plateau lies at the convergence of the East Asian and Indian monsoon systems in eastern Asia. To understand the evolution of this peatland and its potential to provide new insights into the Holocene evolution of the East Asian monsoon a 6 m peat core was collected from the undisturbed central part of a peat deposit near Hongyuan. The age-depth profile was determined using 16 ¹⁴C-AMS age dates, the peat analysed for a range of environmental variables including carbon, nitrogen and hydrogen concentration, bulk density, δ¹³C and the associated spring water analysed for hydrogen and oxygen isotopes. The age-depth profile of the recovered peat sequence covers the period from 9.6 to 0.3 kyr BP and is linear indicating that the conditions governing productivity and decay varied little over the Holocene. Using changes in carbon density, organic carbon content and its δ¹³C, cold dry periods of permafrost characterised by low density and impeded surface drainage were identified. The low δ¹⁸O and δD values of the spring water emanating around the peat deposit, down to ?13.8 and ?102‰ (VSMOW), respectively, with an inverse relationship between electrical conductivity and isotopic composition indicate precipitation under colder and drier conditions relative to the present day. In view of the current annual mean air temperature of 1 °C this suggests conditions in the past have been conducive to permafrost. Inferred periods of permafrost correspond to independently recognised cold periods in other Holocene records from across China at 8.6, 8.2–7.8, 5.6–4.2, 3.1 and 1.8–1.5 kyr BP. The transition to a cold dry climate appears to be more rapid than the subsequent recovery and cold dry periods at Hongyuan are of longer duration than equivalent cold dry periods over central and eastern China. Light–dark banding peat on a scale of 15–30 years from 9.6 to 5.5 kyr BP may indicate a strong influence of decadal oscillations possibly the Pacific Decadal Oscillation and a potential link between near simultaneous climatic changes in the northwest Pacific, ENSO, movement of the Intertropical Convergence Zone and the East Asian Monsoon.  相似文献   

REDD herrings or REDD menace: Response to Beymer-Farris and Bassett     

Neil D. Burgess  Shadrack Mwakalila  Pantaleo Munishi  Marion Pfeifer  Simon Willcock  Deo Shirima  Seki Hamidu  George B. Bulenga  Jason Rubens  Haji Machano  Rob Marchant 《Global Environmental Change》2013,23(5):1349-1354

Norwegian funded REDD+ projects in Tanzania have attracted a lot of attention, as has the wider REDD+ policy that aims to reduce deforestation and degradation and enhance carbon storage in forests of the developing countries. One of these REDD+ projects, managed by WWF Tanzania, was criticised in a scientific paper published in GEC, and consequently in the global media, for being linked to attempted evictions of communities living in the Rufiji delta mangroves by the Government of Tanzania, allegedly to make the area ‘ready for REDD’. In this response, we show how this eviction event in Rufiji mangroves has a history stretching back over 100 years, has nothing to do with REDD+ or any policy changes by government, and is not in any way linked to the work of any WWF project in Tanzania. We also outline some of the broader challenges faced by REDD+ in Tanzania.  相似文献   

Restored Eelgrass (<Emphasis Type="Italic">Zostera marina</Emphasis> L.) as a Refuge for Epifaunal Biodiversity in Mid-Western Atlantic Coastal Bays     

Jonathan S. Lefcheck  Scott R. Marion  Robert J. Orth 《Estuaries and Coasts》2017,40(1):200-212

As nearshore ecosystems are increasingly degraded by human activities, active restoration is a critical strategy in ensuring the continued provision of goods and services by coastal habitats. After being absent for nearly six decades, over 1800 ha of the foundational species eelgrass (Zostera marina L.) has been successfully re-established in the coastal bays of the mid-western Atlantic, USA, but nothing is known about the recovery of associated animal communities in this region. Here, we determine the patterns and drivers of functional recovery in epifaunal invertebrates associated with the restored eelgrass habitat from 2001 to 2013. After less than a decade, the invertebrate community in the restored bed was richer, more even, and exhibited greater variation in functional traits than a nearby reference bed. Analysis of a suite of environmental and physical variables using random forests revealed these differences were primarily due to the increasing area and density of eelgrass, a direct consequence of ongoing restoration efforts. Based on analysis of functional traits, we propose that the rapid life histories of constituent organisms may have played a key role in their successful recovery. We also speculate that diverse epifaunal communities may have contributed to the restoration success through a well-described mutualism with eelgrass. Given that restored eelgrass now make up 32 % of total seagrass cover in the mid-Atlantic coastal bays, this restoration may conserve regional biodiversity by providing new and pristine habitat, particularly given the general decline of existing eelgrass in this region.  相似文献   

Nitrile,Latex, Neoprene and Vinyl Gloves: A Primary Source of Contamination for Trace Element and Zn Isotopic Analyses in Geological and Biological Samples          下载免费PDF全文

Marion Garçon  Lucie Sauzéat  Richard W. Carlson  Steven B. Shirey  Mélanie Simon  Vincent Balter  Maud Boyet 《Geostandards and Geoanalytical Research》2017,41(3):367-380

Exogenic contamination is of primary concern for geochemical and biological clean laboratories working with sample sizes at the nanogram or even subpicogram level. Here, we determined sixty trace elements in fifteen different types of gloves from major suppliers world‐wide to evaluate whether gloves could be potential sources of contamination for routine trace element and isotope measurements. We found that all gloves contain some trace elements that can be easily mobilised in significant amounts. In weak acid at room temperature, the tested gloves released up to 17 mg of Zn, more than 1 μg of Mg, Ti, Mn, Fe, Rb, Sr, Zr, Sn, Hf and Pb and between 100 and 1000 ng of Li, Sc, V, Cr, Ni, Cu, Ga, As, Se, Y, Ag, Ba, La, Ce, Nd, Tl and Th. Vinyl gloves released lower quantities of biologically and geologically important elements, with the exception of In and Sn. Isotopic analyses indicate that all gloves share roughly the same Zn isotopic composition (average δ⁶⁶Zn = +0.10 ± 0.32‰ (2s)). A single contact between glove and labware releases an average of ~ 6 ng of Zn and hence can significantly shift δ⁶⁶Zn above the precision level when the amount of Zn determined is below 500 ng.  相似文献   

The impact of climate changes during the Holocene on vegetation in northern French Guiana     

Vincent Freycon  Marion Krencker  Robert Nasi 《Quaternary Research》2010,73(2):220-225

The impact of climatic changes that occurred during the last glacial maximum and the Holocene on vegetation changes in the Amazon Basin and the Guiana Shield are still widely debated. The aim of our study was to investigate whether major changes in vegetation (i.e. transitions between rainforests and C₄ savannas) occurred in northern French Guiana during the Holocene. We measured variations in the δ¹³C of soil organic matter at eight sites now occupied by forest or savannah. The forest sites were selected to cover two regions (forest refugia and peneplains) which are thought to have experienced different intensities of disturbance during the latest Pleistocene and the Holocene. We found that none of the forest sites underwent major disturbances during the Holocene, i.e. they were not replaced by C₄ savannahs or C₄ forest savannahs for long periods. Our results thus suggest that tropical rainforests in northern French Guiana were resilient to drier climatic conditions during the Holocene. Nevertheless, geographical and vertical variations in the ¹³C of SOM were compatible with minor changes in vegetation, variations in soil processes or in soil physical properties.  相似文献   

Non-isoprenoid macrocyclic glycerol diethers associated with authigenic carbonates     

Marion Baudrand  Vincent Grossi  Richard Pancost  Giovanni Aloisi   《Organic Geochemistry》2010,41(12):1341-1344

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