Experimental study on the phase equilibria in the join CaMgSi2O6-CaCrCrSiO6 with special reference to the blue diopside     

Ko Ikeda  Kenzo Yagi 《Contributions to Mineralogy and Petrology》1977,61(1):91-106

The behaviour of tetrahedrally coordinated and octahedrally coordinated Cr³⁺ ions in diopside is discussed from the study on the join CaMg-Si₂O₆-CaCrCrSiO₆. The molecule CaCrCrSiO₆ decomposes into uvarovite+eskolaite and its maximum solubility in diopside is 6.7 wt percent at 940 ° C. Crystalline phases are diopside ss (ss is abbreviation of solid solution), uvarovite ss, wollastonite ss, spinel and eskolaite. The diopside ss is blue in colour. Its optical spectra were measured in the wavelenght range of 325–2600 nm, and assigned after tetrahedral configuration Td and octahedral configuration Oh. It is estimated that octahedral Cr³⁺ ions are in high spin state, while tetrahedral Cr³⁺ ions may be probably in low spin state. The _t and B are 10,300–10,370 cm^–1 and 429–432 cm^–1. The CFSE for tetrahedral low spin Cr³⁺ ions is nearly the same as that for octahedral high spin Cr³⁺ ions. The ionic radii of tetrahedral low spin Cr³⁺ ions calculated are 0.47–0.53 Å, shrinked from the radius of octahedral high spin Cr³⁺ ion (0.615 Å) as much as 14–24 percent. Petrologic implications of the result are also discussed.The first half of the D. Sc. dissertation of K. Ikeda presented to Hokkaido University in June, 1976  相似文献   

Long-term variations of North Pacific Tropical Water along the 137°E repeat hydrographic section     

Toshiya Nakano  Tomoyuki Kitamura  Shusaku Sugimoto  Toshio Suga  Masafumi Kamachi 《Journal of Oceanography》2015,71(3):229-238

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Laboratory Enrichment of Radioactive Assemblages and Estimation of Thorium and Uranium Radioactivity in Fractions Separated from Placer Sands in Southeast Bangladesh     

Takayuki Sasaki  Mohammad Rajib  Masafumi Akiyoshi  Taishi Kobayashi  Ikuji Takagi  Toshiyuki Fujii  Md. Mashrur Zaman 《Natural Resources Research》2015,24(2):209-220

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Global shearing modes of galactic disks     

Masanori Iye  Tatsuo Ueda  Masafumi Noguchi  Shinko Aoki 《Astrophysics and Space Science》1983,89(2):363-376

A new scheme has been devised to calculate discrete unstable global shearing spiral modes of gaseous disk models of galaxies. The scheme makes use of the Legendre expansion of eigen functions and the problem of stability analysis is reduced to an eigenvalue problem of an infinite matrix. The spiral patterns of these shearing wave solutions of linearized equations change their form in the course of time due to the differential rotation of the equilibrium disk. These shearing wave solutions are presumed to have intermediate characteristics between so-called density-waves and material arms. Comparison between these shearing modes and the non-shearing normal modes for a series of disk models is presented.  相似文献   

Multiple sulfur isotope chemostratigraphy across the Permian–Triassic boundary at Chaotian,China: Implications for a shoaling model of toxic deep-waters     

Masafumi Saitoh  Yuichiro Ueno  Yukio Isozaki  Naohiro Yoshida 《Island Arc》2021,30(1):e12398

Previous studies on multiple sulfur isotopes (³²S, ³³S, and ³⁴S) in sedimentary pyrite at the end-Permian suggested a shoaling of anoxic/sulfidic deep-water contributing to the extinction. This scenario is based on an assumption that the sedimentary sulfur cycle was largely controlled by benthos activity, though a stratigraphic correlation between the sulfur records and ichnofabrics of the sediments at the end-Permian has not yet been examined. We report the multiple sulfur isotopic composition of pyrite in the Permian–Triassic boundary interval at Chaotian, South China. Our data can be generally explained by a mixing of sulfur in sulfide from two different sources: one produced via sulfate reduction in an open system with respect to sulfate and the other produced in a closed system. In particular, the former with the substantially low δ³⁴S (<−40 ‰) and high ∆³³S (up to +0.100 ‰) values was likely produced via water-mass sulfate reduction or via sulfate reduction in oxic sediments with common burrows. The frequent occurrence of small pyrite framboids (mostly <5 μm in diameter) in the Lopingian (Late Permian) Dalong Formation of deep-water facies supports the enhanced water-mass sulfate reduction in an anoxic deep-water mass. The negative ∆³³S values are observed only in the oxic limestones, and no substantial ∆³³S change is observed across the extinction horizon despite of the disappearance of bioturbation. Our results are apparently inconsistent with the previous shoaling model. We expand the model and infer that, when the deep-water was sulfidic and its shoaling rate was high, a substantial amount of hydrogen sulfide (H₂S) was supplied onto the shelf via the shoaling; that resulted in the positive ∆³³S value of the bulk sediments. The observed ∆³³S variation on a global scale suggests a substantial variation in H₂S concentration and/or in upwelling rate of shoaling deep-waters during the Permian–Triassic transition.  相似文献   

Simulation analyses of buildings damaged in the 1995 Kobe,Japan, earthquake considering soil–structure interaction     

Yasuhiro Hayashi  Kazuo Tamura  Masafumi Mori  Ikuo Takahashi 《地震工程与结构动力学》1999,28(4):371-391

A series of studies was conducted on three buildings of steel reinforced concrete structures with RC shear walls damaged in the 1995 Hyogo-ken Nanbu earthquake. These buildings are located in an area where structural damage centred around. Two of these buildings suffered severe damage, while the third was not structurally damaged. Our studies deal with site inspections, including micro-tremor measurement of buildings, the evaluation of input motions, and the response analyses considering soil–structure interaction. The results of simulation analyses of the two severely damaged buildings correspond to their actual damage state. From the response analyses of the one slender building with no structural damage, it was concluded that uplifting is the main reason it did not suffer any structural damage. Through these studies, the importance of soil–structure interaction and effective input motion is fully understood. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Compression behaviors of distorted rutile-type hydrous phases, MOOH (M?=?Ga, In, Cr) and CrOOD     

Asami Sano-Furukawa  Takehiko Yagi  Taku Okada  Hirotada Gotou  Takumi Kikegawa 《Physics and Chemistry of Minerals》2012,39(5):375-383

X-ray diffraction measurements of distorted rutile-type oxyhydroxides β-GaOOH, InOOH, β-CrOOH, and β-CrOOD were taken at a maximum pressure of up to 35 GPa under quasi-hydrostatic conditions, at ambient temperature. Anomalies in the evolution of the relative lattice constants and the axial ratios of β-GaOOH, InOOH, and β-CrOOD suggest anisotropic stiffening along the a- and/or b-axes where the hydrogen bond is formed. The changes were observed at 15 GPa in β-GaOOH and InOOH and at 4 GPa in β-CrOOD. The pressures were higher in oxyhydroxides that have longer O…O distances of the hydrogen bond at ambient pressure. In contrast, such stiffening behavior was not observed in CrOOH, which has a significant short O…O distance and strong hydrogen bond. The stiffening behaviors observed in the present study can be attributed to the symmetrization of the hydrogen bonds in oxyhydroxides, as was previously found in δ-AlOOH(D).  相似文献   

Elasticity of CaIrO<Subscript>3</Subscript> with perovskite and post-perovskite structure     

Ken?NiwaEmail author  Takehiko?Yagi  Kenya?Ohgushi 《Physics and Chemistry of Minerals》2011,38(1):21-31

Compression behaviors of CaIrO₃ with perovskite (Pv) and post-perovskite (pPv) structures have been investigated up to 31.0(1.0) and 35.3(1) GPa at room temperature, respectively, in a diamond-anvil cell with hydrostatic pressure media. CaIrO₃ Pv and pPv phases were compressed with the axial compressibility of β _a > β _c > β _b and β _b > β _a > β _c, respectively and no phase transition was observed in both phases up to the highest pressure in the present study. The order of axial compressibility for pPv phase is consistent with the crystallographic consideration for layer structured materials and previous experimental results. On the other hand, Pv phase shows anomalous compression behavior in b axis, which exhibit constant or slightly expanded above 13 GPa, although the applied pressure remained hydrostatic. Volume difference between Pv and pPv phases was gradually decreased with increasing pressure and this is consistent with the results of theoretical study based on the ab initio calculation. Present results, combined with theoretical study, suggest that these complicate compression behaviors in CaIrO₃ under high pressure might be caused by the partially filled electron of Ir⁴⁺. Special attention must be paid in case of using CaIrO₃ as analog materials to MgSiO₃, although CaIrO₃ exhibits interesting physical properties under high pressure.  相似文献   

High-pressure phase behavior of MnTiO<Subscript>3</Subscript>: decomposition of perovskite into MnO and MnTi<Subscript>2</Subscript>O<Subscript>5</Subscript>     

Taku Okada  Takehiko Yagi  Daisuke Nishio-Hamane 《Physics and Chemistry of Minerals》2011,38(4):251-258

The phase relations and compression behavior of MnTiO₃ perovskite were examined using a laser-heated diamond-anvil cell, X-ray diffraction, and analytical transmission electron microscopy. The results show that MnTiO₃ perovskite becomes unstable and decomposes into MnO and orthorhombic MnTi₂O₅ phases at above 38 GPa and high temperature. This is the first example of ABO₃ perovskite decomposing into AO + AB₂O₅ phases at high pressure. The compression behavior of volume, axes, and the tilting angle of TiO₆ octahedron of MnTiO₃ perovskite are consistent with those of other A²⁺B⁴⁺O₃ perovskites, although no such decomposition was observed in other perovskites. FeTiO₃ is also known to decompose into two phases, instead of transforming into the CaIrO₃-type post-perovskite phase and we argue that one of the reasons for the peculiar behavior of titanate is the weak covalency of the Ti–O chemical bonds.  相似文献   

Improving strategies with constraints regarding non-Gaussian statistics in a three-dimensional variational assimilation method     

Norihisa?UsuiEmail author  Shiro?Ishizaki  Yosuke?Fujii  Masafumi?Kamachi 《Journal of Oceanography》2011,67(3):253-262

We assess validity of a Gaussian error assumption, the basic assumption in data assimilation theory, and propose two kinds of constraints regarding non-Gaussian statistics. In the mixed water region (MWR) off the east coast of Japan exhibiting complicated frontal structures, a probability density function (PDF) of subsurface temperature shows double peaks corresponding to the Kuroshio and Oyashio waters. The complicated frontal structures characterized by the temperature PDF sometimes cause large innovations, bringing about a non-Gaussianity of errors. It is also revealed that assimilated results with a standard three-dimensional variational (3DVAR) scheme have some issues in MWR, arising from the non-Gaussianity of errors. The Oyashio water sometimes becomes unrealistically cold. The double peaks seen in the observed temperature PDF are too smoothed. To improve the assimilated field in MWR, we introduce two kinds of constraints, J _c1 and J _c2, which model the observed temperature PDF. The constraint J _c1 prevents the unrealistically cold Oyashio water, and J _c2 intends to reproduce the double peaks. The assimilated fields are significantly improved by using these constraints. The constraint J _c1 effectively reduces the unrealistically cold Oyashio water. The double peaks in the observed temperature PDF are successfully reproduced by J _c2. In addition, not only subsurface temperature but also whole level temperature and salinity (T–S) fields are improved by adopting J _c1 and J _c2 to a multivariate 3DVAR scheme with vertical coupled T–S empirical orthogonal function modes.  相似文献