Global distribution and atmospheric transport of chlorinated hydrocarbons: HCH (BHC) isomers and DDT compounds in the Western Pacific,Eastern Indian and Antarctic Oceans     

Shinsuke Tanabe  Ryo Tatsukawa  Masahide Kawano  Hideo Hidaka 《Journal of Oceanography》1982,38(3):137-148

Concentrations of chlorinated hydrocarbons such as HCH isomers and DDT compounds were determined in air and surface water samples taken from the Western Pacific, Eastern Indian and Antarctic Oceans. The most interesting finding was their presence in measurable concentrations in the Antarctic Ocean. Chlorinated hydrocarbon pesticides are widely distributed in the open ocean environment over both the northern and southern hemispheres, and some characteristic distribution patterns of pesticide species in different oceanic regions were observed both in air and water samples. HCH residues found in the northern hemisphere were much higher in concentration than those in the southern hemisphere. On the other hand, higher concentrations of DDT residues were found in the tropical regions, but their levels were not so different between both the northern and southern hemispheres. HCH isomers found in the northern hemisphere had the following order of concentrations:-HCH> HCH>-HCH, while in the southern hemisphere-HCH was apparently dominant. DDT compound compositions were rather uniform in all the oceans surveyed, and more than 50% wasp,p-DDT. These facts can be explained by the world wide situation regarding pesticide use and the physicochemical properties of the pesticides such as their vapor pressures and water solubilities. In addition, the meridional circulation of the atmosphere, particularly the mass flows of the Hadley and Ferrel cells in the troposphere, also contributes to the atmospheric transport and global distribution of these pesticides.  相似文献   

Time-series observation of dissolved inorganic carbon and nutrients in the northwestern North Pacific     

Hajime Kawakami  Makio C. Honda  Masahide Wakita  Shuichi Watanabe 《Journal of Oceanography》2007,63(6):967-982

Time-series measurements of dissolved inorganic carbon (DIC) and nutrient concentrations were conducted in the northwestern North Pacific from October 2002 to August 2004. Assuming that data obtained in different years represented time-series seasonal data for a single year, vertical distributions of DIC and nutrients showed large seasonal variabilities in the surface layer (∼100 m). Seasonal variabilities in normalized DIC (nDIC) and nitrate concentrations at the sea surface were estimated to be 81–113 μmol kg⁻¹ and 12.7–15.7 μmol kg⁻¹, respectively, in the Western Subarctic Gyre. The variability in nutrients between May and July was generally at least double that in other seasons. In the Western Subarctic Gyre, estimations based on statistical analyses revealed that seasonal new production was 39–61 gC m⁻² and tended to be higher in the southwestern regions or coastal regions. The seasonal new productions in the northwestern North Pacific were two or more times higher than in the North Pacific subtropical gyre and the northeastern North Pacific. It is likely that this difference is due to spatial variations in the concentrations of trace metals and the species of phytoplankton present. In addition, from estimations of surface pCO₂ it was verified that the Western Subarctic Gyre is a source of atmospheric CO₂ between February and May and a sink for CO₂ between July and October.  相似文献   

赤道不稳定波能量收支的数值模拟分析     

陈鲜艳  木本昌秀  胡博  李维京 《热带气象学报》2009,25(3):329-335

最新海表温度卫星观测资料分析表明在赤道东太平洋和大西洋附近存在赤道不稳定波（tropical instability waves）。赤道不稳定波通常于每年春末夏初出现,以约0.6 m/s速度向西传播,周期为20~40天左右,波长约为1 000~2 000 km,可改变赤道附近海洋的热量平衡,并引发强烈的局地海气作用。利用CCSR/NIES/FRCGC AOGCM MIROC 100年的模式输出结果,计算了赤道不稳定波的爆发时间、波长、传播速度、周期,并与观测资料作对比分析,以考察模式对赤道不稳定波的模拟能力。结果表明,模式较好地再现了热带太平洋的海洋内部中尺度动力-热力作用过程,成功模拟了赤道不稳定波的基本特征,发现赤道不稳定波主要存在赤道南北不超过6个纬度的浅层海洋中,除赤道表层外4~6 ?N海洋温跃层中也有赤道不稳定波。对赤道不稳定波的能量进行诊断分析表明其能量主要来自赤道附近洋流经向切变产生的正压不稳定,赤道以北海洋温跃层中赤道不稳定波能量主要来自由浮力作用产生的斜压不稳定,两者的共同作用形成了赤道不稳定波的赤道不对称结构。  相似文献   

New approach for optimal perturbation method in ensemble climate prediction with empirical singular vector     

Jong-Seong Kug  Yoo-Geun Ham  Masahide Kimoto  Fei-Fei Jin  In-Sik Kang 《Climate Dynamics》2010,35(2-3):331-340

In this study, a new method is developed to generate optimal perturbations in ensemble climate prediction. In this method, the optimal perturbation in initial conditions is the 1st leading singular vector, calculated from an empirical linear operator based on a historical model integration. To verify this concept, this method is applied to a hybrid coupled model. It is demonstrated that the 1st leading singular vector from the empirical linear operator, to a large extent, represents the fast-growing mode in the nonlinear integration. Therefore, the forecast skill with the optimal perturbations is improved over most lead times and regions. In particular, the improvement of the forecast skill is significant where the signal-to-noise ratio is small, indicating that the optimal perturbation method is effective when the initial uncertainty is large. Therefore, the new optimal perturbation method has the potential to improve current seasonal prediction with state-of-the-art coupled GCMs.  相似文献   

Ti-rich hydroandradites from the Sanbagawa metamorphic rocks of the Shibukawa area,central Japan     

Hitoshi Onuki  Masahide Akasaka  Takeyoshi Yoshida  Munetomo Nedachi 《Contributions to Mineralogy and Petrology》1982,80(2):183-188

Ti-rich hydroandradite often occurs, though usually as a minor constituent, in serpentinized ultramafic rocks and associated gabbroic rocks of the Sanbagawa metamorphic belt. The chemistry of the host rocks is commonly characterized by undersaturation with SiO₂. Two Ti-rich hydroandradites from metasomatized gabbroic rocks of the Shibukawa area have been chemically analysed by the wet method. Mössbauer experiments indicate the presence of Fe³⁺ and Fe²⁺ in the octahedral sites of these Ti-rich hydroandradites. Wet chemical analyses for total reducing capacity of the present garnets by two different methods together with Mössbauer data imply the presence of octahedral Ti³⁺ in their structure. Ti-rich hydroandratites, apart from their hydrous property, have a similar crystal chemistry to natural Ti-rich andradites. Ti-rich hydroandradites were probably formed in rocks with unusual chemical compositions within a P-T region of 300–400° C and 4–7 kb under limited conditions of relatively low oxygen fugacity and low μCO₂.  相似文献   

El Niño-related sea surface elevation and ocean bottom pressure enhancement associated with the retreat of the Oyashio southeast of Hokkaido,Japan     

Hasegawa  Takuya  Nagano  Akira  Matsumoto  Hiroyuki  Ariyoshi  Keisuke  Wakita  Masahide 《Marine Geophysical Researches》2019,40(4):505-512

  相似文献   

Summertime land–sea thermal contrast and atmospheric circulation over East Asia in a warming climate—Part I: Past changes and future projections     

Youichi Kamae  Masahiro Watanabe  Masahide Kimoto  Hideo Shiogama 《Climate Dynamics》2014,43(9-10):2553-2568

Land–sea surface air temperature (SAT) contrast, an index of tropospheric thermodynamic structure and dynamical circulation, has shown a significant increase in recent decades over East Asia during the boreal summer. In Part I of this two-part paper, observational data and the results of transient warming experiments conducted using coupled atmosphere–ocean general circulation models (GCMs) are analyzed to examine changes in land–sea thermal contrast and the associated atmospheric circulation over East Asia from the past to the future. The interannual variability of the land–sea SAT contrast over the Far East for 1950–2012 was found to be tightly coupled with a characteristic tripolar pattern of tropospheric circulation over East Asia, which manifests as anticyclonic anomalies over the Okhotsk Sea and around the Philippines, and a cyclonic anomaly over Japan during a positive phase, and vice versa. In response to CO₂ increase, the cold northeasterly winds off the east coast of northern Japan and the East Asian rainband were strengthened with the circulation pattern well projected on the observed interannual variability. These results are commonly found in GCMs regardless of future forcing scenarios, indicating the robustness of the East Asian climate response to global warming. The physical mechanisms responsible for the increase of the land–sea contrast are examined in Part II.  相似文献   

A diagnostic study of the impact of El Niño on the precipitation in China   总被引：20，自引：0，他引：20  

Zhang Renhe  Akimasa Sumi  Masahide Kimoto 《大气科学进展》1999,16(2):229-241

The impact of El Niño on the precipitation in China for different seasons are investigated diagnostically. It is found that El Niño can influence the precipitation in China significantly during its mature phase. In the Northern winter, spring and autumn, the positive precipitation anomalies are found in the southern part of China during the El Niño mature phase. In the Northern summer, the patterns of the precipitation anomalies in the El Niño mature phase are different from those in the other seasons. The negative precipitation anomalies appear in both southern and northern parts of China, while in between around the lower reaches of the Yangtze River and the Huaihe River valleys the precipitation anomalies tend to be positive. In the Northern winter, spring and autumn, the physical process by which El Niño affects the precipitation in the southern part of China can be explained by the features of the circulation anomalies over East Asia during the El Niño mature phase (Zhang et al., 1996). The appearance of an anticyclonic anomaly to the north of the maritime continent in the lower troposphere during the El Niño mature phase intensifies the subtropical high in the western Pacific and makes it shift westward. The associated southwesterly flow is responsible for the positive precipitation anomalies in the southern part of China. In the Northern summer, the intensified western Pacific subtropical high covers the southeastern periphery of China so that the precipitation there becomes less. In addition, the weakening of the Indian monsoon provides less moisture inflow to the northern part of China.  相似文献   

Petrology,Geochemistry, and Fluid Inclusion Microthermometry of Sphalerite from the Laloki and Federal Flag Strata‐Bound Massive Sulfide Deposits,Papua New Guinea: Implications for Gold Mineralization     

Hiroharu MATSUEDA  Joseph O. ESPI  Masahide AKASAKA 《Resource Geology》2012,62(2):187-207

The Laloki and Federal Flag deposits are two of the many (over 45) polymetallic massive sulfide deposits that occur in the Astrolabe Mineral Field, Papua New Guinea. New data of the mineralogical compositions, mineral textures, and fluid inclusion studies on sphalerite from Laloki and Federal Flag deposits were investigated to clarify physiochemical conditions of the mineralization at both deposits. The two deposits are located about 2 km apart and they are stratigraphically hosted by siliceous to carbonaceous claystone and rare gray chert of Paleocene–Eocene age. Massive sulfide ore and host rock samples were collected from each deposit for mineralogical, geochemical, and fluid inclusion studies. Mineralization at the Laloki deposit consists of early‐stage massive sulfide mineralization (sphalerite‐barite, chalcopyrite, and pyrite–marcasite) and late‐stage brecciation and remobilization of early‐stage massive sulfides that was accompanied by late‐stage sphalerite mineralization. Occurrence of native gold blebs in early‐stage massive pyrite–marcasite‐chalcopyrite ore with the association of pyrrhotite‐hematite and abundant planktonic foraminifera remnants was due to reduction of hydrothermal fluids by the reaction with organic‐rich sediments and seawater mixing. Precipitation of fine‐grained gold blebs in late‐stage Fe‐rich sphalerite resulted from low temperature and higher salinity ore fluids in sulfur reducing conditions. In contrast, the massive sulfide ores from the Federal Flag deposit contain Fe‐rich sphalerite and subordinate sulfarsenides. Native gold blebs occur as inclusions in Fe‐rich sphalerite, along sphalerite grain boundaries, and in the siliceous‐hematitic matrix. Such occurrences of native gold suggest that gold was initially precipitated from high‐temperature, moderate to highly reduced, low‐sulfur ore fluids. Concentrations of Au and Ag from both Laloki and Federal Flag deposits were within the range (<10 ppm Au and <100 ppm Ag) of massive sulfides at a mid‐ocean ridge setting rather than typical arc‐type massive sulfides. The complex relationship between FeS contents in sphalerite and gold grades of both deposits is probably due to the initial deposition of gold on the seafloor that may have been controlled by factors such as Au complexes, pH, and fO₂ in combination with temperature and sulfur fugacity.  相似文献   

Gold Mineralization of the Gatsuurt Deposit in the North Khentei Gold Belt,Central Northern Mongolia     

Chinbat Khishgee  Masahide Akasaka  Hiroto Ohira  Jargalan Sereenen 《Resource Geology》2014,64(1):1-16

Mineral assemblages, chemical compositions of ore minerals, wall rock alteration and fluid inclusions of the Gatsuurt gold deposit in the North Khentei gold belt of Mongolia were investigated to characterize the gold mineralization, and to clarify the genetic processes of the ore minerals. The gold mineralization of the deposit occurs in separate Central and Main zones, and is characterized by three ore types: (i) low‐grade disseminated and stockwork ores; (ii) moderate‐grade quartz vein ores; and (iii) high‐grade silicified ores, with average Au contents of approximately 1, 3 and 5 g t^?1 Au, respectively. The Au‐rich quartz vein and silicified ore mineralization is surrounded by, or is included within, the disseminated and stockwork Au‐mineralization region. The main ore minerals are pyrite (pyrite‐I and pyrite‐II) and arsenopyrite (arsenopyrite‐I and arsenopyrite‐II). Moderate amounts of galena, tetrahedrite‐tennantite, sphalerite and chalcopyrite, and minor jamesonite, bournonite, boulangerite, geocronite, scheelite, geerite, native gold and zircon are associated. Abundances and grain sizes of the ore minerals are variable in ores with different host rocks. Small grains of native gold occur as fillings or at grain boundaries of pyrite, arsenopyrite, sphalerite, galena and tetrahedrite in the disseminated and stockwork ores and silicified ores, whereas visible native gold of variable size occurs in the quartz vein ores. The ore mineralization is associated with sericitic and siliceous alteration. The disseminated and stockwork mineralization is composed of four distinct stages characterized by crystallization of (i) pyrite‐I + arsenopyrite‐I, (ii) pyrite‐II + arsenopyrite‐II, (iii) galena + tetrahedrite + sphalerite + chalcopyrite + jamesonite + bournonite + scheelite, and iv) boulangerite + native gold, respectively. In the quartz vein ores, four crystallization stages are also recognized: (i) pyrite‐I, (ii) pyrite‐II + arsenopyrite + galena + Ag‐rich tetrahedrite‐tennantite + sphalerite + chalcopyrite + bournonite, (iii) geocronite + geerite + native gold, and (iv) native gold. Two mineralization stages in the silicified ores are characterized by (i) pyrite + arsenopyrite + tetrahedrite + chalcopyrite, and (ii) galena + sphalerite + native gold. Quartz in the disseminated and stockwork ores of the Main zone contains CO₂‐rich, halite‐bearing aqueous fluid inclusions with homogenization temperatures ranging from 194 to 327°C, whereas quartz in the disseminated and stockwork ores of the Central zone contains CO₂‐rich and aqueous fluid inclusions with homogenization temperatures ranging from 254 to 355°C. The textures of the ores, the mineral assemblages present, the mineralization sequences and the fluid inclusion data are consistent with orogenic classification for the Gatsuurt deposit.  相似文献