Study on the fate of petroleum-derived polycyclic aromatic hydrocarbons (PAHs) and the effect of chemical dispersant using an enclosed ecosystem,mesocosm     

Yamada M  Takada H  Toyoda K  Yoshida A  Shibata A  Nomura H  Wada M  Nishimura M  Okamoto K  Ohwada K 《Marine pollution bulletin》2003,47(1-6):105-113

Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant.  相似文献   

Electric Currents In the Ocean Induced By the Geomagnetic Sq Field and Their Effects On the Estimation of Mantle Conductivity     

Masahiko Takeda 《Geophysical Journal International》1991,104(2):381-385

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Calculation and application of first-order cnoidal wave theory     

Masahiko Isobe 《Coastal Engineering》1985,9(4):309-325

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In situ flash X-ray observation of projectile penetration processes and crater cavity growth in porous gypsum target analogous to low-density asteroids     

Minami Yasui  Masahiko Arakawa  Sunao Hasegawa  Yukihiro Fujita  Toshihiko Kadono 《Icarus》2012,221(2):646-657

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Application of Continuous 222Rn Monitor with Dual Loop System in a Small Lake     

Masahiko Ono  Takahiro Tokunaga  Jun Shimada  Kimpei Ichiyanagi 《Ground water》2013,51(5):706-713

To estimate the spatial distribution of groundwater discharge from the bottom of a small lake of Kumamoto in Japan, we applied continuous radon measurements with a dual loop system and verified the results obtained using the radon method by visual diving surveys. Time‐shifting correction in the dual‐loop system is reasonable to obtain the true radon activity in water. Distributions of radon activity and water temperature in the study area reveal the effects on groundwater discharge and mixing situation of lake water. The estimated discharge zone ascertained using the radon method agrees with the groundwater discharge distribution observed through diving surveys. Although the data resolution of the radon method is much greater than the width of observed discharge zones, the general distribution of groundwater discharge is recognizable. The dual loop system of radon measurement is useful for smaller areas.  相似文献   

Fe–Mg partitioning between post-perovskite and ferropericlase in the lowermost mantle     

Takeshi Sakai  Eiji Ohtani  Hidenori Terasaki  Masaaki Miyahara  Masahiko Nishijima  Naohisa Hirao  Yasuo Ohishi  Nagayoshi Sata 《Physics and Chemistry of Minerals》2010,37(7):487-496

Fe–Mg partitioning between post-perovskite and ferropericlase has been studied using a laser-heated diamond anvil cell at pressures up to 154 GPa and 2,010 K which corresponds to the conditions in the lowermost mantle. The composition of the phases in the recovered samples was determined using analytical transmission electron microscopy. Our results reveal that the Fe–Mg partition coefficient between post-perovskite and ferropericlase (K _D^PPv/Fp) increases with decreasing bulk iron content. The compositional dependence of K _D^PPv/Fp on the bulk iron content explains the inconsistency in previous studies, and the effect of the bulk iron content is the most dominant factor compared to other factors, such as temperature and aluminum content. Iron prefers ferropericlase compared to post-perovskite over a wide compositional range, whereas the iron content of post-perovskite (X _Fe^PPv, the mole fraction) does not exceed a value of 0.10. The iron-rich ferropericlase phase may have significant influence on the physical properties, such as the seismic velocity and electrical conductivity at the core–mantle boundary region.  相似文献   

High‐pressure polymorphs in Yamato‐790729 L6 chondrite and their significance for collisional conditions          下载免费PDF全文

Yukako Kato  Toshimori Sekine  Masahiko Kayama  Masaaki Miyahara  Akira Yamaguchi 《Meteoritics & planetary science》2017,52(12):2570-2585

Shock pressure recorded in Yamato (Y)‐790729, classified as L6 type ordinary chondrite, was evaluated based on high‐pressure polymorph assemblages and cathodoluminescence (CL) spectra of maskelynite. The host‐rock of Y‐790729 consists mainly of olivine, low‐Ca pyroxene, plagioclase, metallic Fe‐Ni, and iron‐sulfide with minor amounts of phosphate and chromite. A shock‐melt vein was observed in the hostrock. Ringwoodite, majorite, akimotoite, lingunite, tuite, and xieite occurred in and around the shock‐melt vein. The shock pressure in the shock‐melt vein is about 14–23 GPa based on the phase equilibrium diagrams of high‐pressure polymorphs. Some plagioclase portions in the host‐rock occurred as maskelynite. Sixteen different CL spectra of maskelynite portions were deconvolved using three assigned emission components (centered at 2.95, 3.26, and 3.88 eV). The intensity of emission component at 2.95 eV was selected as a calibrated barometer to estimate shock pressure, and the results indicate pressures of about 11–19 GPa. The difference in pressure between the shock‐melt vein and host‐rock might suggest heterogeneous shock conditions. Assuming an average shock pressure of 18 GPa, the impact velocity of the parent‐body of Y‐790729 is calculated to be ~1.90 km s^?1. The parent‐body would be at least ~10 km in size based on the incoherent formation mechanism of ringwoodite in Y‐790729.  相似文献