Analysis of the seismicity in the central part of the Pyrenees (France), and tectonic implications     

Alexis?RigoEmail author  Annie?Souriau  Noalwenn?Dubos  Matthieu?Sylvander  Christian?Ponsolles 《Journal of Seismology》2005,9(2):211-222

Two temporary seismological networks have been set up in 2000 and 2002 in the central part of the Pyrenees, in a region, which appears as a transition between two domains where both the seismic activity and the tectonic regime are different. Together with the permanent networks, they allowed us to obtain precise hypocenter locations for more than 400 events with local magnitudes ranging from 1.5 to 4.6, as well as 30 new focal mechanisms. The seismicity is distributed in several clusters, which are not located along the North Pyrenean Fault, considered as the major tectonic accident resulting from the suture of the Iberian and Eurasian convergent plates when the range formed. Several small fault segments dipping to the north are identified. The maximum focal depth varies from 10 to 20 km, with variations which are roughly parallel to those of the Moho, indicating a thickening of the seismogenic layer to the east of the studied area. The obtained focal solutions reveal a predominance of normal faulting to the West and reverse faulting to the East, with strike-slip motions in between. The largest fault segment to the East, with a length of about 20 km, could possibly be related to a large historical event which occurred in 1660, with intensity IX, close to cities which have become since then important touristic centres.  相似文献   

Synthetic coprecipitates of exopolysaccharides and ferrihydrite. Part II: Siderophore-promoted dissolution     

Christian Mikutta  Ruben Kretzschmar 《Geochimica et cosmochimica acta》2008,72(4):1128-1142

Ferrihydrite (Fh) coprecipitated with exopolymers of plants and microbes may differ in its geochemical reactivity from its abiotic counterpart. We synthesized Fh in the presence and absence of acid polysaccharides (polygalacturonic acid (PGA), alginate, xanthan) and characterized the physical and structural properties of the precipitates formed [Mikutta C., Mikutta R., Bonneville S., Wagner F., Voegelin A., Christl I. and Kretzschmar R. (2008) Synthetic coprecipitates of exopolysaccharides and ferrihydrite. Part I: Characterization. Geochim. Cosmochim. Acta]. In this paper, we focus on the reactivity of PGA and alginate coprecipitates and pure Fh, and studied their interaction with the microbial siderophore desferrioxamine B (DFOB) in the presence and absence of low molecular weight organic (LMWO) acid anions (malate, citrate). Batch adsorption and dissolution experiments were performed in the dark at pH 7 in 10 mM NaClO₄ background electrolyte. In the dissolution experiments, different modes of ligand addition were applied (single, simultaneous, stepwise). With an estimated Langmuir sorption maximum of 15 mmol/mol Fe, a PGA coprecipitate with 11% C_org sorbed about four times as much DFOB as pure Fh, and the amount of DFOB sorbed was ∼4-fold larger than estimated from the sum of DFOB sorption to pure Fh and PGA alone. The apparent initial dissolution rates, R_app-initial, and pseudo-first order rate coefficients, k, of the coprecipitates exceeded those of pure Fh by up to two orders of magnitude. Citrate and malate exerted a strong synergistic effect on the DFOB-promoted dissolution of pure Fh, whereas synergistic effects of both anions were absent or negligible for the coprecipitates. R_app-initial of the citrate and DFOB-promoted dissolution of PGA coprecipitates increased with increasing molar C/Fe ratio of the coprecipitates, independent of the charge of the LMWO ligand. Our results indicate that polyuronates stabilize Fh particles sterically and /or electrostatically, thus increasing the mineral surface area accessible to LMWO ligands. In contrast, pure Fh was coagulated at pH 7 (pH_iep of Fh = 7.1), and hence only a small fraction of the Fh surface underwent dissolution. The increase in ligand-accessible surface area of Fh upon coprecipitation with acid polysaccharides seems to primarily control the kinetics of the ligand-promoted dissolution at neutral pH. In pH environments where the solubility of Fe(III) is very low, dissolution rates of Fe(III) (hydr)oxides in such coprecipitates may therefore exceed those of pure minerals by several orders of magnitude, despite a similar crystallinity of the minerals.  相似文献   

Quantifying initial and wind forcing uncertainties in the Gulf of Mexico   总被引：1，自引：0，他引：1  

Guotu Li  Mohamed Iskandarani  Matthieu Le Hénaff  Justin Winokur  Olivier P. Le Maître  Omar M. Knio 《Computational Geosciences》2016,20(5):1133-1153

This study aims at analyzing the combined impact of uncertainties in initial conditions and wind forcing fields in ocean general circulation models (OGCM) using polynomial chaos (PC) expansions. Empirical orthogonal functions (EOF) are used to formulate both spatial perturbations to initial conditions and space-time wind forcing perturbations, namely in the form of a superposition of modal components with uniformly distributed random amplitudes. The forward deterministic HYbrid Coordinate Ocean Model (HYCOM) is used to propagate input uncertainties in the Gulf of Mexico (GoM) in spring 2010, during the Deepwater Horizon oil spill, and to generate the ensemble of model realizations based on which PC surrogate models are constructed for both localized and field quantities of interest (QoIs), focusing specifically on sea surface height (SSH) and mixed layer depth (MLD). These PC surrogate models are constructed using basis pursuit denoising methodology, and their performance is assessed through various statistical measures. A global sensitivity analysis is then performed to quantify the impact of individual modes as well as their interactions. It shows that the local SSH at the edge of the GoM main current—the Loop Current—is mostly sensitive to perturbations of the initial conditions affecting the current front, whereas the local MLD in the area of the Deepwater Horizon oil spill is more sensitive to wind forcing perturbations. At the basin scale, the SSH in the deep GoM is mostly sensitive to initial condition perturbations, while over the shelf it is sensitive to wind forcing perturbations. On the other hand, the basin MLD is almost exclusively sensitive to wind perturbations. For both quantities, the two sources of uncertainty have limited interactions. Finally, the computations indicate that whereas local quantities can exhibit complex behavior that necessitates a large number of realizations, the modal analysis of field sensitivities can be suitably achieved with a moderate size ensemble.  相似文献   

Assessment of observational networks with the Representer Matrix Spectra method—application to a 3D coastal model of the Bay of Biscay     

Matthieu Le Hénaff  Pierre De Mey  Patrick Marsaleix 《Ocean Dynamics》2009,59(1):3-20

The development of coastal ocean modeling in the recent years has allowed an improved representation of the associated complex physics. Such models have become more realistic, to the point that they can now be used to design observation networks in coastal areas, with the idea that a “good” network is a network that controls model state error. To test this ability without performing data assimilation, we set up a technique called Representer Matrix Spectra (RMS) technique that combines the model state and observation error covariance matrices into a single scaled representer matrix. Examination of the spectrum and the eigenvectors of that matrix informs us on which model state error modes a network can detect and constrain amidst the observation error background. We applied our technique to a 3D coastal model in the Bay of Biscay, with a focus on mesoscale activity, and tested the performance of various altimetry networks and an in situ array deployment strategy. It appears that a single nadir altimeter is not efficient enough at capturing coastal mesoscale physics, while a wide swath altimeter would do a much better job. Testing various local in situ array configurations confirms that adding a current meter to a vertical temperature measurement array improves the detection of secondary variability modes, while shifting the array higher on the shelf break would obviously enhance the model constraint along the coast. The RMS technique is easily set up and used as a “black box,” but the utility of its results is maximized by previous knowledge of model state error physics. The technique provides both quantitative (eigenvalues) and qualitative (eigenvectors) tools to study and compare various network options. The qualitative approach is essential to discard possibly inconsistent modes.  相似文献   

Solar EUV/FUV irradiance variations: analysis and observational strategy     

Matthieu Kretzschmar  Thierry Dudok de Wit  Jean Lilensten  Jean-Francois Hochedez  Jean Aboudarham  Pierre-Olivier Amblard  Frederic Auchère  Said Moussaoui 《Acta Geophysica》2009,57(1):42-51

The knowledge of solar extreme and far ultraviolet (EUV) irradiance variations is essential for the characterization of the Earth’s upper atmosphere. For a long time, this knowledge has been based on empirical models, which are themselves based on proxies of the solar activity. However, the accurate modeling and prediction of the Earth’s upper atmosphere necessitate to improve the precision on the irradiance and its variations below about 200 nm. Here, we present a review of recent works made by the authors that aim at quantifying the irradiance variability at these wavelengths, and that lead to new way of monitoring the solar EUV/FUV irradiance spectrum. In more details, it is shown that the quantification of the high level of redundancy in the solar spectrum variability allows to envisage measuring only a small portion of the spectrum without losing essential knowledge. Finally, we discuss what should and could be measured in order to retrieve the solar extreme and far ultraviolet spectrum.  相似文献   

Voluminous lava flows at Oldoinyo Lengai in 2006: chronology of events and insights into the shallow magmatic system     

Matthieu Kervyn  Gerald G. J. Ernst  Jurgis Klaudius  Jörg Keller  François Kervyn  Hannes B. Mattsson  Frederic Belton  Evelyne Mbede  Patric Jacobs 《Bulletin of Volcanology》2008,70(9):1069-1086

The largest natrocarbonatite lava flow eruption ever documented at Oldoinyo Lengai, NW Tanzania, occurred from March 25 to April 5, 2006, in two main phases. It was associated with hornito collapse, rapid extrusion of lava covering a third of the crater and emplacement of a 3-km long compound rubbly pahoehoe to blocky aa-like flow on the W flank. The eruption was followed by rapid enlargement of a pit crater. The erupted natrocarbonatite lava has high silica content (3% SiO₂). The eruption chronology is reconstructed from eyewitness and news media reports and Moderate Resolution Imaging Spectroradiometer (MODIS) satellite data, which provide the most reliable evidence to constrain the eruption’s onset and variations in activity. The eruption products were mapped in the field and the total erupted lava volume estimated at 9.2 ± 3.0 × 10⁵ m³. The event chronology and field evidence are consistent with vent construct instability causing magma mixing and rapid extrusion from shallow reservoirs. It provides new insights into and highlights the evolution of the shallow magmatic system at this unique natrocarbonatite volcano.  相似文献   

Developing a Complex Independent Component Analysis (CICA) Technique to Extract Non-stationary Patterns from Geophysical Time Series     

Ehsan Forootan  Jürgen Kusche  Matthieu Talpe  C. K. Shum  Michael Schmidt 《Surveys in Geophysics》2018,39(3):435-465

In recent decades, decomposition techniques have enabled increasingly more applications for dimension reduction, as well as extraction of additional information from geophysical time series. Traditionally, the principal component analysis (PCA)/empirical orthogonal function (EOF) method and more recently the independent component analysis (ICA) have been applied to extract, statistical orthogonal (uncorrelated), and independent modes that represent the maximum variance of time series, respectively. PCA and ICA can be classified as stationary signal decomposition techniques since they are based on decomposing the autocovariance matrix and diagonalizing higher (than two) order statistical tensors from centered time series, respectively. However, the stationarity assumption in these techniques is not justified for many geophysical and climate variables even after removing cyclic components, e.g., the commonly removed dominant seasonal cycles. In this paper, we present a novel decomposition method, the complex independent component analysis (CICA), which can be applied to extract non-stationary (changing in space and time) patterns from geophysical time series. Here, CICA is derived as an extension of real-valued ICA, where (a) we first define a new complex dataset that contains the observed time series in its real part, and their Hilbert transformed series as its imaginary part, (b) an ICA algorithm based on diagonalization of fourth-order cumulants is then applied to decompose the new complex dataset in (a), and finally, (c) the dominant independent complex modes are extracted and used to represent the dominant space and time amplitudes and associated phase propagation patterns. The performance of CICA is examined by analyzing synthetic data constructed from multiple physically meaningful modes in a simulation framework, with known truth. Next, global terrestrial water storage (TWS) data from the Gravity Recovery And Climate Experiment (GRACE) gravimetry mission (2003–2016), and satellite radiometric sea surface temperature (SST) data (1982–2016) over the Atlantic and Pacific Oceans are used with the aim of demonstrating signal separations of the North Atlantic Oscillation (NAO) from the Atlantic Multi-decadal Oscillation (AMO), and the El Niño Southern Oscillation (ENSO) from the Pacific Decadal Oscillation (PDO). CICA results indicate that ENSO-related patterns can be extracted from the Gravity Recovery And Climate Experiment Terrestrial Water Storage (GRACE TWS) with an accuracy of 0.5–1 cm in terms of equivalent water height (EWH). The magnitude of errors in extracting NAO or AMO from SST data using the complex EOF (CEOF) approach reaches up to ~50% of the signal itself, while it is reduced to ~16% when applying CICA. Larger errors with magnitudes of ~100% and ~30% of the signal itself are found while separating ENSO from PDO using CEOF and CICA, respectively. We thus conclude that the CICA is more effective than CEOF in separating non-stationary patterns.  相似文献   

Chondrule trace element geochemistry at the mineral scale     

Emmanuel JACQUET  Olivier ALARD  Matthieu GOUNELLE 《Meteoritics & planetary science》2012,47(11):1695-1714

Abstract– We report trace element analyses from mineral phases in chondrules from carbonaceous chondrites (Vigarano, Renazzo, and Acfer 187), carried out by laser ablation inductively coupled plasma‐mass spectrometry. Results are similar in all three meteorites. Mesostasis has rare earth element (REE) concentrations of 10–20 × CI. Low‐Ca pyroxene has light REE (LREE) concentrations near 0.1 × CI and heavy REE (HREE) near 1 × CI, respectively. Olivine has HREE concentrations at 0.1–1 × CI and LREE around 10^?2 × CI. The coarsest olivine crystals tend to have the most fractionated REE patterns, indicative of equilibrium partitioning. Low‐Ca pyroxene in the most pyroxene‐rich chondrules tends to have the lowest REE concentrations. Type I chondrules seem to have undergone a significant degree of batch crystallization (as opposed to fractional crystallization), which requires cooling rates slower than 1–100 K h^?1. This would fill the gap between igneous calcium‐aluminum‐rich inclusions (CAIs) and type II chondrules. The anticorrelation between REE abundances and pyroxene mode may be understood as due to dilution by addition of silica to the chondrule melt, as in the gas‐melt interaction scenario of Libourel et al. (2006). The rapid cooling rate (of the order of 1000 K h^?1) which seems recorded by low‐Ca pyroxene, contrasted with the more diverse record of olivine, may point to a nonlinear cooling history or suggest that formation of pyroxene‐rich chondrule margins was an event distinct from the crystallization of the interior.  相似文献   

Lithium isotopes as indicators of meteorite parent body alteration     

Mark A. Sephton  Rachael H. James  Manuela A. Fehr  Philip A. Bland  Matthieu Gounelle 《Meteoritics & planetary science》2013,48(5):872-878

Hydrothermal processing on planetesimals in the early solar system produced new mineral phases, including those generated by the transformation of anhydrous silicates into their hydrated counterparts. Carbonaceous chondrites represent tangible remnants of such alteration products. Lithium isotopes are known to be responsive to aqueous alteration, yet previously recognized variability within whole rock samples from the same meteorite appears to complicate the use of these isotopes as indicators of processing by water. We demonstrate a new way to use lithium isotopes that reflects aqueous alteration in carbonaceous chondrites. Temperature appears to exert a control on the production of acetic acid‐soluble phases, such as carbonates and poorly crystalline Fe‐oxyhydroxides. Temperature and degree of water‐rock interaction determines the amount of lithium isotope fractionation expressed as the difference between whole rock and acetic acid‐leachable fractions. Using these features, the type 1 chondrite Orgueil (δ⁷Li_{(whole rock)} = 4.3‰; Δ⁷Li_{(acetic‐whole)} = 1.2‰) can be distinguished from the type 2 chondrites Murchison (δ⁷Li_{(whole rock)} = 3.8; Δ⁷Li_{(acetic‐whole)} = 8.8‰) and carbonate‐poor Tagish Lake (δ⁷Li_{(whole rock)} = 4.3; Δ⁷Li_{(acetic‐whole)} = 9.4‰). This initial study suggests that lithium isotopes have the potential to reveal the role of liquid water in the early solar system.  相似文献   

Reconstructing mid-to-recent Holocene paleoenvironments in the vicinity of ancient Amarynthos (Euboea,Greece)     

Matthieu Ghilardi  Sylvian Fachard  Kosmas Pavlopoulos  David Psomiadis  Christopher Collana  Andrew Bicket 《Geodinamica Acta》2013,26(1-2):38-51

This article examines the shoreline evolution and human occupation in the vicinity of the important archeological site of Amarynthos (Euboea Island, Greece) over the last six millennia. Archeological evidence indicates a continuous occupation of the site from the Bronze Age to the Roman period and the site is well-known, thanks to the existence of a sanctuary dedicated to the goddess Artemis. Based on the study of four boreholes, a paleogeographic reconstruction of the coastal landscape is proposed. Facies were determined based on mollusc identification, and sedimentology based on grain-size measurements (hand sieving for the fraction above 2?mm and LASER technique for particles below 2?mm) and loss-on-ignition. In addition, a series of 12 AMS radiocarbon dates define a reliable chronostratigraphy. Results suggest the presence of a fully marine environment from the early Holocene to ca. 2600–2400?cal. BC, which developed into a brackish environment from ca. 2600–2400?cal. BC to ca. 750?cal. BC due to the deltaic progradation of the nearby stream (Sarandapotamos River). From ca. 750?cal. BC onward, coastal swamps prevailed in the study area. Human-environmental interaction is discussed and particular attention is paid to the paleolandscape configuration of Amarynthos.  相似文献