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91.
Mafic gneisses and associated paragneisses from the Cabo Frio Tectonic Domain in the southeastern part of the Ribeira Belt, along the coast of Rio de Janeiro State in southeast Brazil, were subjected to a geochemical and Sm–Nd isotope study. Four lithotypes are distinguished: aluminous paragneisses (mainly sillimanite–kyanite–garnet–biotite gneiss), calcsilicate lenses, quartzo–feldspathic metasedimentary gneisses and mafic–ultramafic lenses. The whole-rock major and trace, including rare earth element distributions in the mafic–ultramafic intercalations indicate that derivation from subalkaline basalt/gabbro of tholeiitic affinity with E-MORB signature from a non-subduction environment. These mafic rocks have positive εNd(t) and TDM of 1.1 Ga. The metasedimentary rocks have negative εNd(t) and TDM of 1.7 Ga. A Sm–Nd whole rock isochron of mafic rocks yielded an age of 604 ± 38 Ma for the crystallization. This matches with the age of some detrital zircon grains from the paragneisses. The depositional basin, named Buzios–Palmital, was active at least until 620 Ma (age of the youngest detrital zircon) and was subsequently deformed and metamorphosed at ca. 525 Ma (age of metamorphic zircons) during the Buzios Orogeny. It is interpreted as a back arc basin with relation to the 630 Ma magmatic arc of the Oriental Terrane in the Ribeira Belt to the NW. However, after 600 Ma, the Buzios–Palmital basin changed to an active margin setting because the arc collided with the continental margin and the subduction shifted to the back arc environment. By 610 Ma, most of the Brasiliano belts registered collisional events related to multiple convergent blocks. The stress fields and paleocontinent shapes would have allowed the occurrence of extensional areas with not only sedimentary deposition but also ocean floor spreading. Its remnants are preserved in this Brazilian coastal region as an ancient suture, reworked intensively during the Mesozoic rifting events. The reconnaissance of Late Neoproterozoic basins in the Brasiliano–Pan-African belts is of major importance to partially unravel the final amalgamation events of SW Gondwana. Considering that the Buzios–Palmital basin rock units are mostly covered by the marginal Atlantic basins, it is possible that other evidence could be preserved in the coastal regions of SW-Africa and SE-South America.  相似文献   
92.
Querying geographical information systems has been recognized as a difficult task for non‐expert users. Furthermore, user queries are often characterized by semantic aspects not directly managed by traditional spatial databases or GIS. Examples of such semantic geospatial queries are the use of implicit spatial relations between objects, or the reference of domain concepts not explicitly represented in data. To handle such queries, we envisage a system that translates natural language queries into spatial SQL statements on a database, thus improving standard GIS with new semantic capabilities. Within this general objective, the contribution of this article is to introduce a methodology to handle semantic geospatial queries issued over a spatial database. This approach captures semantics from an ontology built upon the spatial database and enriched by domain concepts and properties specifically defined to represent the localization of objects. Some examples of the use of the methodology in the urban domain are presented.  相似文献   
93.
The Middle Pleistocene palaeoclimate and palaeoenvironment evolution of the Las Tablas de Daimiel wetlands is described using a combination of sedimentology, pollen and δ13C and δ18O isotopic records of Unit B of core LT‐199906. This unit mostly contains fluvial and palustrine sediments. U/Th and amino acid racemization (AAR) dating and a comparison of the δ18O curve of Unit B with oceanic records suggests that Unit B spans the period from the end of Marine Isotope Stage (MIS) 10 (340 ka) to the first stages of MIS 7 (ca. 210 ka). MIS 9 was characterised by a regional vegetation dominated by Cupressaceae, with Pinus as a tree element. The water level was high and temperatures were very probably higher than during the Holocene. MIS 8 and the first substages of MIS 7 (7e, 7d and 7c) were dominated by xerophilous steppe vegetation in lowlands (elevations around 610 m above sea level) near to the wetland. At higher altitudes, far away from the wetland, there were fewer Pinus than in MIS 9, and a greater presence of warm, temperate and cool climate tree elements. The aquatic system in MIS 9 became shallower, with eutrophication and the accumulation of organic matter occurring; temperatures were similar to or lower than those of the Holocene. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
94.
Deriving vulnerability curves using Italian earthquake damage data   总被引:3,自引:1,他引:2  
The concerted effort to collect earthquake damage data in Italy over the past 30 years has led to the development of an extensive database from which vulnerability predictions for the Italian building stock can be derived. A methodology to derive empirical vulnerability curves with the aforementioned data is presented herein and the resulting curves have been directly compared with mechanics-based vulnerability curves. However, it has been found that a valid comparison between the empirical and analytical vulnerability curves is not possible mainly due to a number of shortcomings in the database of surveyed buildings. A detailed discussion of the difficulties in deriving vulnerability curves from the current observed damage database is thus also presented.  相似文献   
95.
The Lower Ugab and Goantagab structural domains are located at the junction between the N–S trending Kaoko and the E–W trending Damara belts (NW Namibia), where Neoproterozoic metavolcano-sedimentary sequences were intruded by several syenitic/granitic plutons. We present here new U–Pb ages on zircon grains from the Voetspoor and Doros plutons. Together with petrological, geochemical and structural data we evaluate the timing of the deformation and relation to the geodynamics during the final stage of Gondwana amalgamation.The plutons are composed of three main rock types: hornblende quartz-syenite, syenodiorite and biotite granite. The two former are predominant and show genetic correlation such as magma mingling structures and similar geochemical signatures. The biotite granite occurs in the SW parts of the intrusions and clearly cuts the syenitic rocks. Although the plutons are mainly isotropic, the structures around them demonstrate that their intrusion occurred during a second deformation phase (D2) with a component of sinistral solid state rotation with respect to the wall rocks in response to D2 transpression. Four samples were dated using U–Pb SHRIMP methodology in single zircon grains. A hornblende monzodiorite from the Voetspoor pluton yielded an age of 534 ± 4.5 Ma. A hornblende monzonite from the Doros pluton produced an age of 528 ± 5 Ma. The biotite granite facies was sampled in the Doros intrusion and yielded an age of 530 ± 4.5 Ma. In addition, a granitic vein folded by D2 close to the northeastern contact of the Doros pluton with the encasing phyllites (Amis River Formation) was also dated, yielding an age of 533 ± 6 Ma. The data show that all granite–syenite from Doros and Voetspoor intrusions are contemporaneous and crystallized in the period between 539 and 522 Ma within the errors. D1–D2 deformational phases took place under greenschist facies (biotite zone) conditions and during D3 the metamorphic grade was slightly lower. We interpret that the plutons are coeval to peak metamorphism of the region (530–520 Ma) and that D2 and D3 sinistral transpressional phases are due to collision in the Damara Belt. The E–W compressional event and second metamorphic episode in the Kaoko Belt occurred between 580 and 560 Ma and are apparently unrelated to the thermo-tectonic evolution described here, although D1 might be partially related to this event. The sinistral transpressional D2 phase resulted probably from the position of the area considered at the junction between the belts, and not in the frontal Damara collision further to the east. This new interpretation is consistent with the Ar–Ar ages for the region (about 500 Ma), interpreted to reflect cooling of the orogen. The enrichment in LREE, K, Rb, Ba and Sr, and depletion in Nb of these basic to intermediate alkalic rocks could indicate that they partially derived from melting of a subcontinental lithospheric mantle that was affected by subduction and the granitic rock types represent lower crust contamination. We interpret that they could be related to heating in the mantle caused by asthenosphere influx in a zone of slab-breakoff during collision between Kalahari and Congo cratons.  相似文献   
96.
The Local Group galaxies enable us to study the impact of metallicity on the structure and evolution of massive stars through spectroscopic analyses. However, color-based target selection for spectroscopy (in absence of known spectral types), though relatively successful, usually produces lists dominated by B-type modest-mass stars. We have developed a friends of friends code to find OB associations in Local Group galaxies (Garcia et al. in Astron. Astrophys. 502:1015, 2009; Bull. Soc. R. Sci. Liege 80:381, 2011a). The interpretation of the association’s color-magnitude diagrams (CMDs) and the automatic determination of evolutionary masses for the members, allow a more insightful choice of candidates for spectroscopy and to spot out potential advanced evolutionary stages (Garcia et al. in Astron. Astrophys. 523:A23, 2010). We show our results on the dwarf irregular IC 1613 as illustration of the potential of the method.  相似文献   
97.
Re-equilibration processes of natural H2O–CO2–NaCl-rich fluid inclusions quartz are experimentally studied by exposing the samples to a pure H2O external fluid at 600 °C. Experimental conditions are selected at nearly constant pressure conditions (309 MPa) between fluid inclusions and pore fluid, with only fugacity gradients in H2O and CO2, and at differential pressure conditions (394–398 MPa, corresponding to an internal under-pressure) in addition to similar CO2 fugacity gradients and larger H2O fugacity gradients. Modifications of fluid inclusion composition and density are monitored with changes in ice dissolution temperature, clathrate dissolution temperature and volume fraction of the vapour phase at room temperature. Specific modification of these parameters can be assigned to specific processes, such as preferential loss/gain of H2O and CO2, or changes in total volume. A combination of these parameters can clearly distinguish between modifications according to bulk diffusion or deformation processes. Bulk diffusion of CO2 according to fugacity gradients is demonstrated at constant pressure conditions. The estimated preferential loss of H2O is not in accordance with those gradients in both constant pressure and differential pressure experiments. The development of deformation halos in quartz around fluid inclusions that are either under-pressurized or over-pressurized promotes absorption of H2O from the inclusions and inhibits bulk diffusion according to the applied fugacity gradients.  相似文献   
98.
Aircraft measurements are presented of the Lagrangian evolution of a marine boundary layer over a 30‐h period during the ACE‐2 field campaign. At the start of the observational period, a 500‐m deep polluted marine internal boundary layer (MIBL) was overlain by the remnants of a polluted continental boundary layer extending to around 2 km below a clean, dry free troposphere. The MIBL grew rapidly to a thickness of 900–1000 m in response to increasing sea surface temperatures. No significant aerosol spectral evolution was observed in the boundary layer. Low concentrations of SO2 were observed in the MIBL suggesting that the air mass contained relatively aged aerosol. Aerosol spectra show a broad mode with a modal diameter of around 0.1μm. The polluted layer between the MIBL and the unpolluted free troposphere was only weakly and intermittently turbulent which prevented significant entrainment of clean air into the polluted layer from aloft. The polluted layer depth was thus controlled mainly by subsidence which as a result becomes shallower, decreasing from over 2000 m to around 1200 m during the observational period. The aerosol characteristics of the polluted layer were similar to those in the MIBL and so although the MIBL entrained considerable amounts of air from above the MIBL the aerosol characteristics underwent no significant change. This has important implications for the rate at which a polluted continental air mass is converted to a clean marine one. The dataset should prove useful in the validation of the modelling of continental pollution outbreaks.  相似文献   
99.
We present three new benthic foraminiferal δ13C, δ18O, and total organic carbon time series from the eastern Atlantic sector of the Southern Ocean between 41°S and 47°S. The measured glacial δ13C values belong to the lowest hitherto reported. We demonstrate a coincidence between depleted late Holocene (LH) δ13C values and positions of sites relative to ocean surface productivity. A correction of +0.3 to +0.4 [‰ VPDB] for a productivity-induced depletion of Last Glacial Maximum (LGM) benthic δ13C values of these cores is suggested. The new data are compiled with published data from 13 sediment cores from the eastern Atlantic Ocean between 19°S and 47°S, and the regional deep and bottom water circulation is reconstructed for LH (4–0 ka) and LGM (22–16 ka) times. This extends earlier eastern Atlantic-wide synoptic reconstructions which suffered from the lack of data south of 20°S. A conceptual model of LGM deep-water circulation is discussed that, after correction of southernmost cores below the Antarctic Circumpolar Current (ACC) for a productivity-induced artifact, suggests a reduced formation of both North Atlantic Deep Water in the northern Atlantic and bottom water in the southwestern Weddell Sea. This reduction was compensated for by the formation of deep water in the zone of extended winter sea-ice coverage at the northern rim of the Weddell Sea, where air–sea gas exchange was reduced. This shift from LGM deep-water formation in the region south of the ACC to Holocene bottom water formation in the southwestern Weddell Sea, can explain lower preformed δ13CDIC values of glacial circumantarctic deep water of approximately 0.3‰ to 0.4‰. Our reconstruction brings Atlantic and Southern Ocean δ13C and Cd/Ca data into better agreement, but is in conflict, however, with a scenario of an essentially unchanged thermohaline deep circulation on a global scale. Benthic δ18O-derived LGM bottom water temperatures, by 1.9°C and 0.3°C lower than during the LH at deepest southern and shallowest northern sites, respectively, agree with the here proposed reconstruction of deep-water circulation in the eastern South Atlantic Ocean.  相似文献   
100.
We have developed antibodies and a multi-array competitive immunoassay (MACIA) for the detection of a wide range of molecular size compounds, from single aromatic ring derivatives or polycyclic aromatic hydrocarbons (PAHs), through small peptides, proteins or whole cells (spores). Multiple microarrays containing target molecules are used simultaneously to run several competitive immunoassays. The sensitivity of the MACIA for small organic compounds like naphthalene, 4-phenilphenol or 4-tertbutilphenol is in the range of 100–500 ppb (ng ml−1), for others like the insecticide terbutryn it is at the ppt (ng l−1) level, while for small peptides, as well as for more complex molecules like the protein thioredoxin, the sensitivity is approximately 1–2 ppb, or 104–105 spores of Bacillus subtilis per milliliter. For organic compounds, a water–methanol solution was used in order to achieve a better dissolution of the organics without compromising the antibody–antigen interaction. The above-mentioned compounds were detected by MACIA in water–(10%) methanol extracts from spiked pyrite and hematite-containing rock powder samples, as well as from a spiked-sand sample subjected to organic extraction with dichloromethane–methanol (1/1).  相似文献   
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