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101.
Monika?HuraiováEmail author Jean?Dubessy Patrik?Kone?ny Klaus?Simon Ján?Král’ Grzegorz?Zielinski Jozef?Lipka Vratislav?Hurai 《Contributions to Mineralogy and Petrology》2005,148(5):615-633
Glassy orthopyroxene granodiorite-tonalite (named pincinite after type locality) was described from basaltic lapilli tuffs of the Pliocene maar near Pinciná village in the Slovakian part of the Pannonian Basin. Two pincinite types exhibit a qualitatively similar mineral composition (quartz, An20–55 plagioclase, intergranular silicic glass with orthopyroxene and ilmenite, ±K-feldspar), but strongly different redox potential and formation PT conditions. Peraluminous pincinite is reduced (6–7% of total iron as Fe3+ in corundum-normative intergranular dacitic glass) and contains ilmenite with 8–10 mol% Fe2O3 and orthopyroxene dominated by ferrosilite. High-density (up to 0.85 g/cm3) primary CO2 inclusions with minor H2, CH4, H2S, CO and N2 (<2 mol% total) are present in Qtz and Plg. Equilibrium PT conditions inferred from the intergranular Opx–Ilm–Glass assemblage and fluid density correspond to 1,170±50°C, 5.6±0.4 kbar, respectively. Metaluminous pincinite is more oxidised (25–27% of total iron as Fe3+ in diopside-normative intergranular glass of rhyolite–trachyte–dacite composition) and contains Fe2O3-rich ilmenite (17–29 mol%) associated with enstatite. Fluid inclusions are composed of CO2–H2O mixtures with up to 38 mol% H2O. Raman spectroscopy revealed H2S along with dominant CO2 in the carbonic phase. Equilibrium PT parameters for the intergranular Opx–Ilm–Glass assemblage correspond to 740±15°C, 2.8±0.1 kbar, respectively. Reducing gas species (<2 mol% total) in the CO2-inclusions of the peraluminous pincinite resulted from hydrogen diffusion due to fH2 gradient imposed during decrease of redox potential from the log fO2 values near QFM during Qtz + Plg growth, to QFM-2 incidental to the superimposed Opx + Ilm assemblage in the intergranular melt. The decrease in oxygen fugacity was recorded also in the metaluminous pincinite, where log fO2 values changed from ~QFM + 2.6 to QFM + 0.4, but hydrogen diffusion did not occur. Absence of OH-bearing minerals, major and trace element abundances (e.g. REE 300–320, Nb 55–57, Th 4–31, Zr 240–300 ppm, FeOtot/MgO up to 11), and Sr–O isotope ratios in the pincinites are diagnostic of high-temperature anorogenic magmas originated by dehydration melting of biotite in quartz-feldspathoid crust (87Sr/86Sr>0.705–0.706, 18O>9 V-SMOW) around alkali basalt reservoir in depths between 17 and 20 km, and around late stage derivatives of the basalt fractionation, intruding the crust up to depths of 10–11 km. Low water activity in the pincinite parental melt was caused by CO2-flux from the Tertiary basaltic reservoirs and intrusions. The anatexis leads to generation of a melt-depleted granulitic crust beneath the Pannonian Basin, and the pincinites are interpreted as equivalents of igneous charnockites and enderbites quenched at temperatures above solidus and unaffected by sub-solidus re-equilibration and metamorphic overprint. 相似文献
102.
Geochemical discriminations of sandstones from the Mohe Foreland basin,northeastern China: Tectonic setting and provenance 总被引:5,自引:0,他引:5
Andrey A. Sorokin 《中国科学D辑(英文版)》2005,48(5):613-621
The Mohe region near the border area of China with Russia is in Heilongjiang Province. Topographically the area consists of lower mountains or hills situated at the northern end of the Da Hinggan Mountains. Struc-turally the Mohe basin rests on the north margin of the Ergun Block, and the Mongol-Okhotsk Orogen is lo-cated to the north of the basin. Due to poor access conditions and good vegetation coverage, previous researches on the basin are much weak with few spe-cial geological inves… 相似文献
103.
David G. Barber Matthew G. Asplin Tim N. Papakyriakou Lisa Miller Brent G. T. Else John Iacozza C. J. Mundy M. Gosslin Natalie C. Asselin Steve Ferguson Jennifer V. Lukovich Gary A. Stern Ashley Gaden Monika Pu?ko N.-X. Geilfus Fei Wang 《Climatic change》2012,115(1):135-159
Change and variability in the timing and magnitude of sea ice geophysical and thermodynamic state have consequences on many aspects of the arctic marine system. The changes in both the geophysical and thermodynamic state, and in particular the timing of the development of these states, have consequences throughout the marine system. In this paper we review the ??consequences?? of change in sea ice state on primary productivity, marine mammal habitats, and sea ice as a medium for storage and transport of contaminants and carbon exchange across the ocean-sea-ice-atmosphere interface based upon results from the International Polar Year. Pertinent results include: 1) conditions along ice edges can bring deep nutrient-rich ??pacific?? waters into nutrient-poor surface waters along the arctic coast, affecting local food webs; 2) both sea ice thermodynamic and dynamic processes ultimately affect ringed seal/polar bear habitats by controlling the timing, location and amount of surface deformation required for ringed seal and polar bear preferred habitat 3) the ice edges bordering open waters of flaw leads are areas of high biological production and are observed to be important beluga habitat. 4) exchange of climate-active gases, including CO2, is extremely active in sea ice environments, and the overall question of whether the Arctic Ocean is (or will be) a source or sink for CO2 will be dependent on the balance of competing climate-change feedbacks. 相似文献
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普通黑光灯对稻纵卷叶螟和稻飞虱的诱虫量与气象因子的相关分析 总被引:2,自引:0,他引:2
以1991年至2008年广东省恩平市的观测数据,分析了普通黑光灯对稻纵卷叶螟和稻飞虱诱虫量与气象条件的相关性.结果表明:稻纵卷叶螟蛾年总诱量与年总降雨量呈正相关,稻飞虱成虫年诱量与年降雨量呈负相关,稻纵卷叶螟蛾与主要为害的5、6、8月降雨均呈正相关,与7月降雨则呈负相关;稻飞虱与5、7、8月降雨均为负相关,与6月降雨为正相关.此外,热带气旋个数与稻飞虱年诱虫量呈负相关;与稻纵卷叶螟蛾年诱虫量呈正相关.综合分析表明,稻纵卷叶螟蛾与稻飞虱与气象因子比较有较大的差别,对普通黑光灯诱虫量有极大的影响,可间接预测预报两迁飞性害虫的发生量,为准确预测预报两迁害虫为害提供参考. 相似文献
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110.
Sylvia-Monique?ThomasEmail author Monika?Koch-Müller Patrick?Reichart Dieter?Rhede Rainer?Thomas Richard?Wirth Stanislav?Matsyuk 《Physics and Chemistry of Minerals》2009,36(9):489-509
Mineral-specific IR absorption coefficients were calculated for natural and synthetic olivine, SiO2 polymorphs, and GeO2 with specific isolated OH point defects using quantitative data from independent techniques such as proton–proton scattering,
confocal Raman spectroscopy, and secondary ion mass spectrometry. Moreover, we present a routine to detect OH traces in anisotropic
minerals using Raman spectroscopy combined with the “Comparator Technique”. In case of olivine and the SiO2 system, it turns out that the magnitude of ε for one structure is independent of the type of OH point defect and therewith
the peak position (quartz ε = 89,000 ± 15,000
\textl \textmol\textH2\textO-1 \textcm-2\text{l}\,\text{mol}_{{\text{H}_2}\text{O}}^{-1}\,\text{cm}^{-2}), but it varies as a function of structure (coesite ε = 214,000 ± 14,000
\textl \textmol\textH2\textO-1 \textcm-2\text{l}\,\text{mol}_{{\text{H}_2}\text{O}}^{-1}\,\text{cm}^{-2}; stishovite ε = 485,000 ± 109,000
\textl \textmol\textH2\textO-1 \textcm-2\text{l}\,\text{mol}_{{\text{H}_2}\text{O}}^{-1}\,\text{cm}^{-2}). Evaluation of data from this study confirms that not using mineral-specific IR calibrations for the OH quantification in
nominally anhydrous minerals leads to inaccurate estimations of OH concentrations, which constitute the basis for modeling
the Earth’s deep water cycle. 相似文献