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41.
The development of clusters of local growth is supported by different processes. Endogenous economic development produced by small and medium-sized enterprises (SMEs) is based on family firms in which local market characteristics influence the sectorial diversification that emerges within certain regions. In the Berguedà region (Catalonia, Spain), the formation of a successful network of SMEs in three main sectors (food, textile and machinery) in the 1990s demonstrated the importance of grass-roots prerequisites, including industrial tradition, social networks and a sense of spatial loyalty, one of the main concepts studied in this paper. The aim of this paper is to study how institutions, local economic networks and collective social agents generate a propitious economic space that constitutes favourable embedding in Berguedà. However, the key element in this industrial system is the loyalty that entrepreneurs and workers feel towards their industrial region. These two processes, territorial embeddedness and spatial loyalty, appear to be two of the major forces behind the economic dynamism of the region and have led to the formation of a new cluster of firms. 相似文献
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Biotic structures and processes of the comparatively large and deep Lake Constance are dominated by pelagic water bodies. Therefore, much more attention has thus far been paid to the carbon cycle of pelagic habitats as compared to littoral areas. Nevertheless, there is also an ongoing debate on the importance of littoral areas for the carbon cycle in this lake. Although actually existing data are certainly insufficient for a realistic carbon budget, investigations made during the past decade provide at least a rough basis for a first evaluation. Accordingly, littoral areas appear to contribute overproportionally (related to surface) both to production as well as to degradation of organic carbon in the lake. However, the relative effect seems to be more pronounced for heterotrophic activities, mostly due to intense degradation processes in littoral sediments. Related to volume, littoral water bodies exhibited similar or slightly higher microbial activities as compared to epilimnetic pelagic water bodies, while microbial abundances and activities observed for littoral sediments exceeded the corresponding overlying water layers by one to three orders of magnitude. As was confirmed by in situ measurements microbial oxygen consumption frequently exceeded photosynthetic oxygen production in the investigated littoral sites. Moreover, significant qualitative differences between water and sediment were found for the degradation potentials of xenobiotics as was exemplified for phenol and nitrilo-triacetic acid (NTA). Overall, a buffer function at the landwater interface may be ascribed to littoral areas due to which the large pelagic water bodies of the lake may become additionally protected against loads of undesired organic substances due to high littoral degradation capacities. 相似文献
43.
Voltammetric Determination of High Field‐Strength Elements (Ti,Zr, Hf,Nb, Ta) in Geological Matrices 
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下载免费PDF全文 A voltammetric method for the determination of the high field‐strength elements Ti, Zr, Hf, Nb and Ta by adsorptive stripping of their tartrate complexes is presented. The applicability of the method to geological and metallurgical samples is illustrated by the analysis of certified reference materials (USGS BCR‐2 basalt, BCS‐CRM 388 zircon and Euronorm CRM 579‐1 ferroniobium). Suitable sample preparation techniques, involving fusion with LiBO2 and acidic and basic fluxes, followed by preliminary separation by anion chromatography are described. The method is rapid, affordable and environmentally friendly as it does not require problematic compounds such as hydrofluoric acid or toxic solvents and represents an alternative to more commonly used methods (AAS, ICP‐OES, ICP‐MS). 相似文献
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Leonardo Casini Matteo Maino Antonio Langone Giacomo Oggiano Stefania Corvò Joan Reche Estrada Montserrat Liesa 《Journal of Metamorphic Geology》2023,41(1):25-57
The Variscan high-grade metamorphic basement of northern Sardinia and southern Corsica record lower Carboniferous anatexis related to post-collisional decompression of the orogen. Migmatites exposed in the Punta Bianca locality (Italy) consist of quartz + biotite + plagioclase + K-feldspar orthogneisses, garnet and cordierite-bearing diatexite and metatexites, derived from metasediments. Field evidence, petrographic observations, ELA-ICP-MS zircon and monazite dating and pseudosection modelling suggest that anatexis was apparently episodic involving two main stages of partial melting. Using pseudosection modelling, we infer that the first stage of partial melting is in the upper amphibolite facies (~0.45 GPa at ~740°C). Cordierite overgrowths replacing sillimanite, combined with the composition of plagioclase and K-feldspar, suggest decompression followed cooling below the solidus at low pressures of ~0.3 GPa. The age of the first anatectic event is not precisely constrained because of extensive resetting of the isotopic systems during the second melting stage, yet few zircons preserve a lower Carboniferous age which is consistent with the regional dataset. This lower Carboniferous migmatitic fabric is offset by a network of pseudotachylyte-bearing faults suggestive of cooling to greenschist facies conditions. Garnet/cordierite-bearing diatexites incorporate fragments of pseudotachylite-bearing orthogneiss and metatexites. Pseudosection modelling indicates nearly isobaric re-heating up to ~750°C, followed by further cooling below the solidus. The inferred P–T path is consistent with decompression and cooling of the Variscan crust through post-collisional extension and collapse of the thickened orogenic crust, followed by nearly isobaric re-heating at low pressures (~0.3 GPa) yielding to a second melting stage under LP-HT conditions. U/Th-Pb monazite ages for diatexite migmatites indicate an upper bound of 310–316 Ma for the second melting stage, suggesting that the second melting stage is coincident with the regional phase of crustal shearing. The cause of the high geothermal gradient required for re-heating during the second melting stage is unknown but likely requires some heat source that was probably related to dissipation of mechanical work within crustal-scale shear zones. According to this interpretation, some upper Carboniferous peraluminous granite precursors of the Corsica–Sardinia Batholith could be the outcome rather than the cause of the late-Variscan high-T metamorphism. 相似文献
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David Insausti Maite Carrasson Francesc Maynou Joan E. Cartes Montserrat Sol 《Marine pollution bulletin》2009,58(11):1635-1642
The fixed wavelength fluoresce (FF) method was used to estimate the levels of fluorescent aromatic compounds (FACs) in the bile of fourteen fish species of commercial and/or ecological interest. Sampling was carried out in the NW Mediterranean at depths ranging from 50 to 1000 m during four seasonal cruises. During the summer sampling period, some species were also collected from another site (Vilanova fishing grounds) for comparison. Baseline levels of the polycyclic aromatic hydrocarbons (PAHs) naphthalene, phenanthrene, pyrene and benzo[a]pyrene were measured. Some seasonality was observed, with reduced FF levels in summer and no differences among sites, consistent with sediment PAH levels. We discuss our results in relation to fish phylogeny, season, depth, diet, trophic level and swimming capacity. Overall FF levels indicated differences among species; the suprabenthic feeders from shallow and deep communities, and Mullus barbatus in particular, displayed elevated FF values and are potential candidates for additional monitoring studies. 相似文献
46.
Particle size distributions and the mineralogy of inorganic colloids in waters draining the adit of an abandoned mine (Goesdorf, Luxembourg) were quantified by single particle counting based on light scattering (100 nm–2 μm) combined with transmission electronic microscopy coupled with energy dispersive spectroscopy and selected area electron diffraction. This water system was chosen as a surrogate for groundwaters. The dependence of the colloid number concentration on colloid diameters can be described by a power-law distribution in all cases. Power-law slopes ranged from −3.30 to −4.44, depending on water ionic strength and flow conditions. The same main mineral types were found in the different samples: 2:1 phyllosilicates (illite and mica), chlorite, feldspars (albite and orthoclase), calcite and quartz; with a variable number of Fe oxide particles. The colloid mineralogical composition closely resembles the composition of the parent rock. Spatial variations in the structure and composition of the rock in contact with the waters, i.e. fissured rock versus shear joints, are reflected in the colloid composition. The properties of the study colloids, as well as the processes influencing them, can be considered as representative of the colloids present in groundwaters. 相似文献
47.
F. Montserrat W. Suykerbuyk R. Al-Busaidi T.J. Bouma D. van der Wal P.M.J. Herman 《Journal of Sea Research》2011,65(1):170-181
Benthic ecosystem engineering organisms attenuate hydrodynamic or biogeochemical stress to ameliorate living conditions. Bioturbating infauna, like the lugworm Arenicola marina, determine intertidal process dynamics by maintaining the sediment oxygenated and sandy. Maintaining the permeability of the surrounding sediment enables them to pump water through the interstitial spaces, greatly increasing the oxygen availability. In a field experiment, both lugworm presence and siltation regime were manipulated to investigate to what extent lugworms are able to cope with sedimentation of increasing mud percentage and how this would affect its ecosystem engineering. Fluorescent tracers were added to experimentally deposited mud to visualise bioturbation effects on fine sediment fractions. Lugworm densities were not affected by an increasing mud percentage in experimentally deposited sediment. Negative effects are expected to occur under deposition with significantly higher mud percentages. Surface chlorophyll a content was a function of experimental mud percentage, with no effect of lugworm bioturbation. Surface roughness and sediment permeability clearly increased by lugworm presence, whereas sediment erosion threshold was not significantly affected by lugworms. The general idea that A. marina removes fine sediment fractions from the bed could not be confirmed. Rather, the main ecosystem engineering effect of A. marina is hydraulic destabilisation of the sediment matrix. 相似文献
48.
AbstractThe Roc de Frausa Massif, located at the Eastern Pyrenees, is formed by a stratoid Pre-Hercynian deformed granite (orthogneiss) interbedded with metasedimentary series. Hercynian granitoids (St. Llorenç — La Jonquera pluton) surround the southern and eastern part of the massif and Hercynian basic igneous rocks (Ceret stock) occupy the central part of it. The Pre-Hercynian granite and the sedimentary series were involved, during the Hercynian orogeny, in complex polyphasic tectonics and metamorphism. As a result, an ubiquitous penetrative foliation was developed during the earlier stages. This foliation was subsequently folded into a complex antiformal structural formed by a double dome : Roc de Frausa dome and Mas Blanc dome. Main lithological boundaries (gneiss — metasediments and metasediments — granitoids) are broadly parallel to the regional foliation, and they all display the dome geometry. Interference fold pattern between two late phases, an ealier one with NE-SW trending folds and a younger one with NW-SE trending folds is responsible for the dome geometry. Mylonitic deformation, with W-E to NW-SE orientations has been attributed to the last folding phase. Regional metamorphic climax and contact metamorphism, the last one resulting from Hercynian granitoid emplacement, preceeded the above mentioned late folding event, which developed under retrograde metamorphic conditions. Regional peak metamorphism is recognized by the static crystallization of cordierite + potassium feldspar. This paragenesis indicates pressure — temperature conditions of about 3.1 Kbar and 660 °C maximum. Contact metamorphism overprints the earlier regional metamorphism. Parageneses and thermal gradient of contact metamorphism around La Jonquera pluton are very similar to those related to regional metamorphism, whereas parageneses produced around Ceret stock present garnet + potassium feldspar. Geothermometry indicates metamorphic conditions locally higher for this paragenesis (around 700 °C). 相似文献
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ABSTRACTThis paper explores dynamics of conflict over forests in Vietnam, as the country lays the groundwork for Reducing Emissions from Deforestation and Forest Degradation (REDD+). Drawing on a case study in Lam Dong province and applying an environmental justice lens, we examine how various social actors assert claims over forests and how these claims invoke different notions of justice, authority and identity. Our analysis highlights that the development and implementation of the project has generated renewed competing claims and conflicts over forests among social actors. Underlying these conflicts there are incompatible notions of justice and associated rights, which lead different actors to accord legitimacy variously to the global norms brought about by REDD+, the customary resource practices of indigenous people, or to the state’s laws. We show that the negotiations over forests in REDD+ reflect the influence of the specific historical and political-economic settings in which REDD+ activities take place, including pre-existing conflicts over forests and power relations underpinning forest management. From a policy perspective, our research suggests that any attempts to introduce simplified and uniform regulations for forest governance in REDD+ should be avoided, since local institutions and conceptions of justice will significantly influence what is regarded as legitimate policy and can thus be endorsed as inspiration for sustainable forest governance.Key policy insights
REDD+ in Vietnam has spurred contestations over who is legitimately entitled to govern and manage forests.
Claims and conflicts over forests can be explained by incompatible and distinct notions of justice, authority and identity.
Contestations over justice pose radical challenges to any global and national efforts that attempt to implement simplified rules and ideas for forest based-climate change mitigation.
Attention to justice, especially to compatibility and differences in ideas about justice, is crucial for sustainable forest governance.